Search NASA⌕ Search

SEARCH · Search NASA

Results for “Air Liquide”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Cryogenic hydrogen-induced air-liquefaction technologies for combined-cycle propulsion applications

Given here is a technical assessment of the realization of cryogenic hydrogen induced air liquefaction technologies in a prospective onboard aerospace vehicle process setting. The technical findings related to the status of air liquefaction technologies are reviewed. Compact lightweight cryogenic heat exchangers, heat exchanger atmospheric constituent fouling alleviation measures, para/ortho-hydrogen shift-conversion catalysts, cryogenic air compressors and liquid air pumps, hydrogen recycling using slush hydrogen as a heat sink, liquid hydrogen/liquid air rocket-type combustion devices, and technically related engine concepts are discussed. Much of the LACE work is related to aerospaceplane propulsion concepts that were developed in the 1960's. Emphasis is placed on the Liquid Air Cycle Engine (LACE).

Escher, William J. D.↗
DOE OSTI2022

Wickability-optimized textured liquid-desiccant air dehumidifiers for independent moisture management in energy-efficient buildings

Liquid-desiccant-based air conditioning systems are envisioned to enable independent humidity management, thereby improving the energy efficiency of future buildings. Existing liquid-desiccant-based air conditioning concepts, however, suffer from a poor liquid flow distribution deteriorating moisture removal rate. They are consequently flooded with the liquid-desiccant solution, which significantly degrades the energy efficiency of the dehumidification process. Here, in this work, the capillary forces and wickability effect of textured air dehumidifier surfaces are altered to minimize the liquid-desiccant flow rate of the fully wetted state, thereby transforming the physics of interfacial desiccant flow distribution. Consequently, the wickability-optimized air dehumidifier surface maximizes both moisture removal rate and dehumidification energy efficiency. It was interestingly found that the length scale of a textured air dehumidifier surface concept is optimized at an intermediate pattern density. Dry solid-air menisci appear at length scales exceeding the optimum pattern distance while the effective liquid–air interfacial area is reduced at smaller length scales, both of which degrade the moisture removal rate. At the optimum pattern density, the effective liquid–air interfacial area increases with the solution flow rate, thereby increasing the dehumidification rate. At a water vapor pressure potential of 3 kPa and a solution flow rate of 2.8 g/s, experimental results indicated a moisture removal rate of 0.16 g/m2-s for a textured surface concept with a capillary length scale of 3 mm, a 28% improvement compared with that of smooth-plate dehumidifier surfaces. A high moisture removal rate of the textured surface at a low desiccant flow rate led to a high thermal efficiency of 0.75 at a water vapor pressure potential of 5.6 kPa and a LiBr flow rate of 2.8 g/s. The insights gained from the present study accelerate the development of advanced textured surface concepts for next-generation liquid-desiccant-based air dehumidification systems offering independent humidity management for future energy-efficient buildings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2021

Benchmark Comparison of HyRAM and ALDEA Software for Hydrogen Release Behavior

There are several different calculation approaches and tools that can be used to evaluate the risk of hydrogen energy applications. A comparative study of Air Liquide’s ALDEA (Air Liquide Dispersion and Explosion Assessment) tools suite and Sandia’s HyRAM (Hydrogen Risk Assessment Models) toolkit has been conducted. The purpose of this study was to understand and evaluate the differences between the two calculation approaches, and identify areas for model improvements. There were several scenarios examined in this effort regarding hydrogen release dynamics. These scenarios include free jet release cases at varying pressures, vessel blowdown, and hydrogen build-up scenarios with and without ventilation. For each scenario, the input and output of the HyRAM calculations are documented, along with a comparison to the ALDEA results. Generally, the results from the two different tools were reasonably aligned. However, there were fundamental differences in evaluation methodology and functional limitations in HyRAM that caused discrepancies in some calculations.

08 HYDROGEN↗
DOE OSTI2025

Material properties of aqueous potassium acetate solutions for use in liquid desiccant air conditioning

We present thermophysical properties of aqueous potassium acetate solutions relevant to their application as a liquid desiccant in air-conditioning systems. Liquid desiccant air conditioners could provide up to 80% energy savings compared to high-efficiency vapor compression air conditioners. However, the commonly used liquid desiccants, particularly chloride salt solutions, are highly corrosive. This precludes the use of metallic components, necessitating specialized plastics and thereby driving up cost, weight, and limiting operational temperature and pressure ranges. Potassium acetate has been identified as a less corrosive alternative, potentially enabling broader material compatibility in LDAC components. In this study we systematically measured and modelled key thermophysical properties of KAc solutions density, vapor pressure, viscosity, specific heat capacity, phase behavior, and diffusion coefficient across a range of concentrations (10 - 70wt%) and temperatures. For instance, KAc exhibits a vapor pressure of 3.1 kPa at 50wt% and 40degrees C, demonstrating dehumidification capability comparable to chloride salts. By providing an extended dataset and associated models, this work advances the understanding needed to design energy-efficient, corrosion mitigating LDAC system.

36 MATERIALS SCIENCE↗
NASA NTRS2001

Development of an advanced rocket propellant handler's suit

Most launch vehicles and satellites in the US inventory rely upon the use of hypergolic rocket propellants, many of which are toxic to humans. These fuels and oxidizers, such as hydrazine and nitrogen tetroxide have threshold limit values as low as 0.01 PPM. It is essential to provide space workers handling these agents whole body protection as they are universally hazardous not only to the respiratory system, but the skin as well. This paper describes a new method for powering a whole body protective garment to assure the safety of ground servicing crews. A new technology has been developed through the small business innovative research program at the Kennedy Space Center. Currently, liquid air is used in the environmental control unit (ECU) that powers the propellant handlers suit (PHE). However, liquid air exhibits problems with attitude dependence, oxygen enrichment, and difficulty with reliable quantity measurement. The new technology employs the storage of the supply air as a supercritical gas. This method of air storage overcomes all of three problems above while maintaining high density storage at relatively low vessel pressures (<7000 kPa or approximately 1000 psi). A one hour prototype ECU was developed and tested to prove the feasibility of this concept. This was upgraded by the design of a larger supercritical dewar capable of holding 7 Kg of air, a supply which provides a 2 hour duration to the PHE. A third version is being developed to test the feasibility of replacing existing air cooling methodology with a liquid cooled garment for relief of heat stress in this warm Florida environment. Testing of the first one hour prototype yielded data comparable to the liquid air powered predecessor, but enjoyed advantages of attitude independence and oxygen level stability. Thermal data revealed heat stress relief at least as good as liquid air supplied units. The application of supercritical air technology to this whole body protective ensemble marked an advancement in the state-of-the-art in personal protective equipment. Not only was long duration environmental control provided, but it was done without a high pressure vessel. The unit met human performance needs for attitude independence, oxygen stability and relief of heat stress. This supercritical air (and oxygen) technology is suggested for microgravity applications in life support such as the Extravehicular Mobility Unit. c 2001. Elsevier Science Ltd. All rights reserved.

Hazardous Substances↗
NASA NTRS1982

Droplets Generated from a new OGEE shaped, liquid, air-shear, electrostatic nozzle

A series of experimental tests was carried out on an 'OGEE' shaped planform, liquid air-shear electrostatic nozzle. Liquid was ejected from the upper surface of the nozzle and was then dispersed and atomized efficiently by a high speed air flow passing over the nozzle and by the effect of two very strong coherent air vortices generated by the 'OGEE' shaped nozzle surface. Initial test results which are presented show the nozzle to perform far superior to a similar delta wing shaped design which is used extensively in various industries applications.

Inculet, I. I.↗
DOE OSTI2021

Protective effects of non–catalytic proteins on endoglucanase activity at air and lignin interfaces

The manner in which added non-catalytic proteins during enzymatic hydrolysis of lignocellulosic substrates enhances hydrolysis mechanisms is not completely understood. Prior research has indicated that a reduction in the non-specific adsorption of enzymes on lignin, and deactivation of enzymes exposed to air–liquid interface provide rationale. This work investigated root causes including effects of the air–liquid interface on non-catalytic proteins, and effects of lignin on endoglucanase. Three different experimental designs and three variables (air–liquid interfacial area, the types of lignin (acid or enzymatic lignin), and the presence of non-enzymatic protein (bovine serum albumin [BSA] or soy proteins ) were used. The results showed that acid isolated lignin adsorbed almost all endoglucanase activity initially present in supernatant, independent of air interface conditions (25 or 250 ml flasks) with the presence of BSA preventing this effect. Endoglucanase lost 30%–50% of its activity due to an air–liquid interface in the presence of lignin while addition of non-enzymatic protein helped to preserve this enzyme's activity. Langmuir and Freundlich models applied to experimental data indicated that the adsorption increases with increasing temperature for both endoglucanase and BSA. Adsorption of the enzyme and protein were endothermic with an increase in entropy. Finally, these results, combined, show that hydrophobicity plays a strong role in the adsorption of both endoglucanase and BSA on lignin.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Fractal Model for Drag Reduction on Multiscale Nonwetting Rough Surfaces

Rough surfaces in contact with a flow of fluid exhibit alternating no-slip and free shear boundary conditions at the solid–liquid and air–liquid interfaces, respectively, thereby potentially offering drag reduction benefits. The balance between the dynamic pressure in the flow and the restoring capillary pressure in the interasperity spaces determines the stability of the Cassie state of wettability and is a function of the relative extent of no-slip and free shear regions per unit surface area. In the present study, using a fractal representation of rough surface topography, an analytical model is developed to quantify the stability of the Cassie state of wettability as well as drag reduction and the friction factor for laminar flow in a rectangular channel between nonwetting multiscale rough surfaces. A systematic study is conducted to quantify the effects of fractal parameters of the surfaces and the flow Reynolds number on drag reduction and the friction factor. The studies are used to develop friction factor curves extending the classical Moody diagram to hydrophobic and superhydrophobic surfaces. On the basis of the studies, regime maps are derived for estimating the extent of drag reduction offered by hydrophobic and superhydrophobic surfaces, revealing that superhydrophobic surfaces do not always offer the best drag reduction performance. The application of the fractal model to practical topographies of nonwetting surfaces of copper, aluminum, and zinc oxide fabricated via electrodeposition and etching is also discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

In Situ Monitoring the Nucleation and Growth of Nanoscale CaCO 3 at the Oil–Water Interface

Interfaces can actively control the nucleation kinetics, orientations, and polymorphs of calcium carbonate (CaCO 3 ). Prior studies have revealed that CaCO 3 formation can be affected by the interplay between chemical functional moieties on solid–liquid or air–liquid interfaces as well as CaCO 3 ’s precursors and facets. Yet little is known about the roles of a liquid–liquid interface, specifically an oil–liquid interface, in directing CaCO 3 mineralization which are common in natural and engineered systems. Here, in this study, by using in situ X-ray scattering techniques to locate a meniscus formed between water and a representative oil, isooctane, we successfully monitored CaCO 3 formation at the pliable isooctane–water interface and systematically investigated the pivotal roles of the interface in the formation of CaCO 3 (i.e., particle size, its spatial distribution with respect to the interface, and its mineral phase). Different from bulk solution, ∼5 nm CaCO 3 nanoparticles form at the isooctane–water interface. They stably exist for a long time (36 h), which can result from interface-stabilized dehydrated prenucleation clusters of CaCO 3 . There is a clear tendency for enhanced amounts and faster crystallization of CaCO 3 at locations closer to isooctane, which is attributed to a higher pH and an easier dehydration environment created by the interface and oil. Our study provides insights into CaCO 3 nucleation at an oil–water interface, which can deepen our understanding of pliable interfaces interacting with CaCO 3 and benefit mineral scaling control during energy-related subsurface operation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2014

Development of an Autonomous, Dual Chamber Bioreactor for the Growth of 3-Dimensional Epithelial-Stromal Tissues in Microgravity

We are developing a novel, autonomous bioreactor that can provide for the growth and maintenance in microgravity of 3‐D organotypic epithelial‐stromal cultures that require an air‐liquid interface. These complex 3‐D tissue models accurately represent the morphological features, differentiation markers, and growth characteristics observed in normal human epithelial tissues, including the skin, esophagus, lung, breast, pancreas, and colon. However, because of their precise and complex culture requirements, including that of an air‐liquid interface, these 3‐D models have yet to be utilized for life sciences research aboard the International Space Station. The development of a bioreactor for these cultures will provide the capability to perform biological research on the ISS using these realistic, tissue‐like human epithelial‐stromal cell models and will contribute significantly to advances in fundamental space biology research on questions regarding microgravity effects on normal tissue development, aging, cancer, and other disease processes. It will also allow for the study of how combined stressors, such as microgravity with radiation and nutritional deficiencies, affect multiple biological processes and will provide a platform for conducting countermeasure investigations on the ISS without the use of animal models. The technology will be autonomous and consist of a cell culture chamber that provides for air‐liquid, liquid‐liquid, and liquid‐air exchanges within the chambers while maintaining the growth and development of the biological samples. The bioreactor will support multiple tissue types and its modular design will provide for incorporation of add‐on capabilities such as microfluidics drug delivery, media sampling, and in situ biomarker analysis. Preliminary flight testing of the hardware will be conducted on a parabolic platform through NASA's Flight Opportunities Program.

Patel, Zarana S.↗
NASA NTRS1990

Cryogenic hydrogen-induced air-liquefaction technologies

Extensive use of a special advanced airbreathing propulsion archives data base, as well as direct contacts with individuals who were active in the field in previous years, a technical assessment of cryogenic hydrogen induced air liquefaction, as a prospective onboard aerospace vehicle process, was performed and documented in 1986. The resulting assessment report is summarized. Technical findings relating the status of air liquefaction technology are presented both as a singular technical area, and also as that of a cluster of collateral technical areas including: Compact lightweight cryogenic heat exchangers; Heat exchanger atmospheric constituents fouling alleviation; Para/ortho hydrogen shift conversion catalysts; Hydrogen turbine expanders, cryogenic air compressors and liquid air pumps; Hydrogen recycling using slush hydrogen as heat sinks; Liquid hydrogen/liquid air rocket type combustion devices; Air Collection and Enrichment System (ACES); and Technically related engine concepts.

Escher, William J. D.↗
NASA NTRS1990

Cryogenic hydrogen-induced air liquefaction technologies

Extensively utilizing a special advanced airbreathing propulsion archives database, as well as direct contacts with individuals who were active in the field in previous years, a technical assessment of cryogenic hydrogen-induced air liquefaction, as a prospective onboard aerospace vehicle process, was performed and documented. The resulting assessment report is summarized. Technical findings are presented relating the status of air liquefaction technology, both as a singular technical area, and also that of a cluster of collateral technical areas including: compact lightweight cryogenic heat exchangers; heat exchanger atmospheric constituents fouling alleviation; para/ortho hydrogen shift conversion catalysts; hydrogen turbine expanders, cryogenic air compressors and liquid air pumps; hydrogen recycling using slush hydrogen as heat sink; liquid hydrogen/liquid air rocket-type combustion devices; air collection and enrichment systems (ACES); and technically related engine concepts.

Escher, William J. D.↗
DOE OSTI2020

Modeling Water Vapor Transport at Liquid/Membrane Interfaces for Applications in Liquid Desiccant Air Conditioners (CRADA CRD-17-679 Final Report)

Conventional compressor-based cooling has undergone incremental changes over the past 100 years. Further improvements in efficiency require evermore complex systems, especially under humid conditions. Meso-porous membranes offer unique opportunities for efficient humidity control in buildings using an absorbent desiccant solution, but membranes are not designed or optimized for this purpose. This project will use molecular dynamic simulations to determine optimal membrane properties for these air conditioning applications, focusing on the membrane properties at the membrane/liquid/air interface. Optimal membrane designs will enable smaller, more durable, and less expensive designs of these membrane air conditioning systems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Performance and Characterization of Membrane Liquid Desiccant Air Conditioning Systems

This document is intended to describe the work objectives and tasks for several projects between the National Renewable Energy Laboratory (NREL) and 7AC Technologies, with indirect support from 3M. The projects all revolve around the performance and characterization of membrane liquid desiccant air conditioning systems. Projects are listed in order of preference to 7AC's technical and business goals.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1976

Some early perspectives on ground requirements of liquid hydrogen air transports

The paper examines the problem of liquid-hydrogen (LH2) subsonic long-range air transport from the perspectives of airplane manufacturers, the airline operator, the air terminal authority and the LH2 supplier. Emphasis is placed on identifying common problems and interfaces that are likely to occur in preparing for commercial airline operations of LH2 subsonic air transport in the 1990-1995 period. General considerations are discussed relative to sources and cost of gaseous hydrogen, hydrogen liquefaction, and LH2 availability. The fact that hydrogen sustains combustion at altitudes substantially higher than hydrocarbon fuels suggests that air transport can be designed to operate at higher enroute air traffic flight levels. This can be an advantage if only to relieve traffic congestion on heavily traveled routes. Pertinent interfaces in planning for the use of LH2 in air transportation are identified, including productivity and profitability, passenger-fuel compatibility, and lightning and electrical discharges.

Korycinski, P. F.↗
DOE OSTI2021

Performance Analysis and Limiting Parameters of Cross-flow Membrane-based Liquid-desiccant Air Dehumidifiers

We report that to dehumidify a humid air stream, existing air conditioning (AC) systems substantially overcool the outdoor humid air below its dew point, thereby significantly reducing energy efficiency. Directly capturing humidity, membrane-based liquid-desiccant dehumidification systems separate sensible and latent cooling (SSLC) loads and thus offer a promising pathway for a high-performance AC solution. Design of an energy-efficient SSLC-AC system, however, rests largely on detailed understating of the dehumidification process. While some studies have identified the dehumidification process mainly depends on membrane characteristics, other studies have argued that the process is limited by desiccant liquid or alternatively air thermo-hydraulic physics for typical humid climate conditions. The present study examines performance and physics of the membrane-based liquid-desiccant dehumidification process over a wide range of climate conditions through a novel 3D, two-phase, multi-species CFD model. Decoupling the thermodynamic and hydraulic effects, the study reveals that the dehumidification rate is a linear function of the water vapor pressure potential ($J=α ΔP$) summarizing the system's thermodynamic state. The slope of the curve (i.e., α) depends on hydraulic transport characteristics of the membrane pores, air stream, and desiccant solution. More importantly, it was found that the air dehumidification process is mainly limited by the air-side transport physics for thin liquid-desiccant films and commonly used porous superhydrophobic membranes. Additionally, results show that, depending on ambient/desiccant conditions and physical dehumidifier characteristics, energy effectiveness and dehumidification rate vary from 13 to 34% and from 0.13 to 1.4 g m -2 s -1 , respectively. Therefore, the present study allows to efficiently design future SSLC-based AC systems exhibiting high performance energy metrics.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗