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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Universal amplitude ratios and the interfacial tension near consolute points of binary liquid mixtures

The interfacial tension of the binary liquid mixtures triethylamine/heavy water, triethylamine/water, and cyclohexane/methanol near their consolute temperatures is determined experimentally by measuring the densities of the phases and the capillary lengths. The results are presented in tables and graphs and compared with published data obtained by other methods and with theoretical predictions. The findings are shown to be in good agreement with previous experiments, confirming the discrepancy between temperature-independent universal amplitude ratios calculated from such data and those predicted by renormalization-group calculations or Monte Carlo simulations of Ising models.

Moldover, M. R.↗
NASA NTRS1983

A semiempirical method for analysis of the reflectance spectra of binary mineral mixtures

A simple semiempirical method is presented for determination of the spectral reflectance of a powdered binary mineral mixture. This technique uses a two-stream radiative transfer model (a modified Kubelka-Munk model) on a particulate medium of isotroic scatterers The particles are assumed to be much larger than the wavelength of light under consideration. This same method can be used to determine the relative proportion of components in a mixture for which the spectral reflectance is known. Binary mixtures of olivine, two pyroxenes, and magnetite are used to test this model. The theoretical and empirical results agree approximately within experimental errors.

Johnson, P. E.↗
NASA NTRS1982

Solidification phenomena of binary organic mixtures

The coalescence rates and motion of liquid bubbles in binary organic mixtures were studied. Several factors such as temperature gradient, composition gradient, interfacial tension, and densities of the two phases play important roles in separation of phases of immiscible liquids. An attempt was made to study the effect of initial compositions on separation rates of well-dispersed organic mixtures at different temperatures and, ultimately, on the homogeneity of solidification of the immiscible binary organic liquids. These organic mixtures serve as models for metallic pseudo binary systems under study. Two specific systems were investigated: ethyl salicylate - diethyl glycol and succinonitrile - water.

Chang, K.↗
NASA NTRS1973

A fluidic device for measuring constituent masses of a flowing binary gas mixture

A continuous reading mass flow device was developed to measure the component flow of a binary gas mixture. The basic components of the device are a fluidic humidity sensor and a specially designed flow calorimeter. These components provide readings of gas mixture ratio, mixture heat capacity, heat dissipated by the calorimeter and the gas temperature rise across the calorimeter. These parameter values, applied in the general definitions of specific heat capacity and the heat capacity of a gas mixture, produce calculated component flow rates of the mixture being metered. A test program was conducted to evaluate both the steady state and dynamic performance of the device.

Prokopius, P. R.↗
NASA NTRS1992

Pycnonuclear reaction rates for binary ionic mixtures

Through a combination of compositional scaling arguments and examinations of Monte Carlo simulation results for the interparticle separations in binary-ionic mixture (BIM) solids, we have derived parameterized expressions for the BIM pycnonuclear rates as generalizations of those in one-component solids obtained previously by Salpeter and Van Horn and by Ogata et al. We have thereby discovered a catalyzing effect of the heavier elements, which enhances the rates of reactions among the lighter elements when the charge ratio exceeds a critical value of approximately 2.3.

Ichimaru, S.↗
NASA NTRS1994

Turbidity of a binary fluid mixture: Determining eta

A ground based (1-g) experiment is in progress that will measure the turbidity of a density-matched, binary fluid mixture extremely close to the critical point. By covering the range of reduced temperatures t is equivalent to (T-T(sub c))/T(sub c) from 10(exp -8) to 10(exp -2), the turbidity measurements will allow the critical exponent eta to be determined. No experiment has determined a value of the critical exponent eta, yet its value is significant to theorists in critical phenomena. Interpreting the turbidity correctly is important if future NASA flight experiments use turbidity as an indirect measurement of relative temperature in shuttle experiments on critical phenomena in fluids.

Jacobs, Donald T.↗
NASA NTRS1996

Turbidity of a Binary Fluid Mixture: Determining Eta

A ground based (1-g) experiment is in progress that will measure the turbidity of a density-matched, binary fluid mixture extremely close to its liquid-liquid critical point. By covering the range of reduced temperatures t equivalent to (T-T(sub c)) / T(sub c) from 10(exp -8) to 10(exp -2), the turbidity measurements will allow the critical exponent eta to be determined. No experiment has precisely determined a value of the critical exponent eta, yet its value is significant to theorists in critical phenomena. Relatively simple critical phenomena, as in the liquid-liquid system studied here, serve as model systems for more complex systems near a critical point.

Jacobs, Donald T.↗
NASA NTRS1979

On matching the spectrum of Io - Variations in the photometric properties of sulfur-containing mixtures

The problem of comparing laboratory spectra of sulfur-containing binary mixtures with the spectrum of Io is discussed. For the satellite, the observable is the geometric albedo as a function of wavelength, whereas in the laboratory one often measures some other type of albedo. A previous paper demonstrated that for pure sulfur the multiplicative factor which converts the laboratory albedos to geometric albedos can be strongly wavelength dependent. The present paper demonstrates that this is also true for binary sulfur-containing mixtures. Furthermore, there is no universal conversion factor applicable to all binary mixtures, nor can the factor be interpolated for a particular mixture from the conversion factors of the two end members. The conversion factor is a function not only of the specific composition of a binary mixture but also of the relative particle size distributions of the two components, and must be measured specifically for each individual sample if a quantitative comparison between a laboratory sample and Io's surface is desired.

Veverka, J.↗
NASA NTRS1990

Shock waves in mixtures - A re-examination

The structure of normal shock waves in binary mixtures is analyzed, using Monte Carlo direct simulation, and compared with previous experimental data. Previous work by Erwin et al. used a collision method based directly on the intermolecular potential function; the present work extends this approach to binary mixtures, obtaining heteromolecular collision cross sections from the corresponding potentials. Results are presented for helium-argon mixtures, with conditions corresponding to the experiments of Harnett and Muntz (1972).

Erwin, Daniel A.↗
NASA NTRS1973

Characteristics of slush and boiling methane and methane mixtures

Review of investigation results on the characteristics of slush (i.e., mixtures of liquid and solid) and boiling methane, and of binary mixtures of methane and other natural gas constituents, intended for use as fuels for high performance aircraft, rocket engines, and motor vehicles. The investigation extends to the characterization of slush prepared from pure methane and binary mixtures of methane with nitrogen, ethane, and propane, and the boiling properties of these mixtures.

Sindt, C. F.↗
NASA NTRS1999

The Dissolution of an Interfween Miscible Liquids

The disappearance of the surface tension of the interface of a binary mixture, measured using the dynamic surface light scattering technique, is slower for a binary mixture of higher density contrast. A comparison with a naive diffusion model, expected to provide a lower limit for the speed of dissolution in the absence of gravity shows that the interfacial surface tension disappears much slower than even by diffusion with the effect becoming much more pronounced when density contrast between the liquid phases is increased. Thus, the factor most likely to be responsible for this anomalously slow dissolution is gravity. A mechanism could be based on the competition between diffusive relaxation and sedimentation at the dissolving interface.

Vlad, D.H.↗
NASA NTRS1972

Viscosity and thermal conductivity of moderately dense gas mixtures.

Derivation of a simple, semitheoretical expression for the initial density dependence of the viscosity and thermal conductivity of gaseous mixtures in terms of the appropriate properties of the pure components and of their interaction quantities. The derivation is based on Enskog's theory of dense gases and yields an equation in which the composition dependence of the linear factor in the density expansion is explicit. The interaction quantities are directly related to those of the mixture extrapolated to zero density and to a universal function valid for all gases. The reliability of the formulation is assessed with respect to the viscosity of several binary mixtures. It is found that the calculated viscosities of binary mixtures agree with the experimental data with a precision which is comparable to that of the most precise measurements.

Wakeham, W. A.↗