Results for “Battery packaging” — Page 3

NASA NTRS2007

Advanced Systems for Monitoring Underwater Sounds

The term "Passive Acoustic Monitoring System" (PAMS) describes a developmental sensing-and-data-acquisition system for recording underwater sounds. The sounds (more precisely, digitized and preprocessed versions from acoustic transducers) are subsequently analyzed by a combination of data processing and interpretation to identify and/or, in some cases, to locate the sources of those sounds. PAMS was originally designed to locate the sources such as fish of species that one knows or seeks to identify. The PAMS unit could also be used to locate other sources, for example, marine life, human divers, and/or vessels. The underlying principles of passive acoustic sensing and analyzing acoustic-signal data in conjunction with temperature and salinity data are not new and not unique to PAMS. Part of the uniqueness of the PAMS design is that it is the first deep-sea instrumentation design to provide a capability for studying soniferous marine animals (especially fish) over the wide depth range described below. The uniqueness of PAMS also lies partly in a synergistic combination of advanced sensing, packaging, and data-processing design features with features adapted from proven marine instrumentation systems. This combination affords a versatility that enables adaptation to a variety of undersea missions using a variety of sensors. The interpretation of acoustic data can include visual inspection of power-spectrum plots for identification of spectral signatures of known biological species or artificial sources. Alternatively or in addition, data analysis could include determination of relative times of arrival of signals at different acoustic sensors arrayed at known locations. From these times of arrival, locations of acoustic sources (and errors in those locations) can be estimated. Estimates of relative locations of sources and sensors can be refined through analysis of the attenuation of sound in the intervening water in combination with water-temperature and salinity data acquired by instrumentation systems other than PAMS. A PAMS is packaged as a battery-powered unit, mated with external sensors, that can operate in the ocean at any depth from 2 m to 1 km. A PAMS includes a pressure housing, a deep-sea battery, a hydrophone (which is one of the mating external sensors), and an external monitor and keyboard box. In addition to acoustic transducers, external sensors can include temperature probes and, potentially, underwater cameras. The pressure housing contains a computer that includes a hard drive, DC-to- DC power converters, a post-amplifier board, a sound card, and a universal serial bus (USB) 4-port hub.

Lane, Michael↗

NASA NTRS2005

Tumbleweed Rovers

Tumbleweed rovers, now undergoing development, are lightweight, inflatable, approximately spherical exploratory robotic vehicles designed to roll across terrain, using only wind for propulsion. Tumbleweed rovers share many features with beach-ball rovers, which were discussed in several prior NASA Tech Briefs articles. Conceived for use in exploring remote planets, tumbleweed rovers could also be used for exploring relatively inaccessible terrain on Earth. A fully developed tumbleweed rover would consist of an instrumentation package suspended in an inflated twolayer (nylon/polypropylene) ball. The total mass of the rover would be of the order of 10 kg, the diameter of the ball when inflated would be 2 meters, and the minimum wind speed needed for propulsion would be about 5 m/s. The instrumentation package would contain a battery power supply, sensors, a Global Positioning System (GPS) receiver, and a radio transmitter that would send the sensor readings and the GPS position and time readings to a monitoring station via a satellite communication system. Depending on the specific exploratory mission, the sensors could include a thermometer, a barometer, a magnetometer (for studying the terrestrial magnetic field and/or detecting buried meteorites), a subsurface radar system (for measuring ice thickness and/or detecting buried meteorites), and/or one or two diametrally opposed cameras that would take the part of sending two side-looking images out. In the planned Antarctic field test, a prototype tumbleweed rover was released at a location near the South Pole. Using the global Iridium satellite network to send information about its position, the rover transmitted temperature, pressure, humidity, and light intensity data to NASA s Jet Propulsion Laboratory. The rover reached speeds of 30 km per hour over the Antarctic ice cap, and traveled at an average speed of about 6 km per hour. The test was designed to confirm the rover s long-term durability in an extremely cold environment, with the goal being eventual use of the device to explore the Martian polar caps and other planets in the solar system. On future Antarctic exploratory missions, tumbleweed rovers might be used to acquire sensor data for studies of global warming, ozone depletion, and impacts of meteorites.

Behar, Alberto↗

NASA NTRSDate not supplied

Performance of a Regenerative Fuel Cell System for the Lunar Surface

Regenerative fuel cells (RFCs) are an attractive energy storage solution for lunar missions as a technology capable of providing a higher specific energy (i.e., W∙h/kg) than state-of-the-art packaged Li-ion battery systems. An RFC consists of the (1 & 2) electrochemical stacks (chemical to electrical energy conversion to supply electricity to an external load, i.e. the fuel cell reaction, and electrical to chemical energy conversion of supplied electrical power to dissociate water into hydrogen and oxygen gases, i.e. water electrolysis), (3) fluidic conditioning, (4) reactant storage, (5) avionics, (6) power management and distribution (PMAD), and (7) thermal management. NASA’s Glenn Research Center has designed, assembled, and tested a breadboard RFC sys-tem capable of operating autonomously for multiple simulated lunar day/night cycles in a laboratory environment. The system is comprised of a non-flow through proton exchange membrane (PEM) fuel cell stack and a liquid-anode feed PEM electrolyzer (EZ) stack designed to electrochemically compress the reactants at balanced pressures up to 12.4 MPa (1800 psia). The fluidic conditioning, avionics, PMAD, and thermal management sub-systems are largely comprised of commercial-off-the-shelf components for this system-level development effort. The hardware is controlled by a CubeSat space processor running an operational program based on core flight architecture that can control the RFC hardware autonomously through a state machine with fault monitoring. The testing results highlighted here were completed with the system in an open-loop configuration such that reactants generated through water electrolysis were vented while gas cylinders supplied fuel cell operation. The breadboard operated autonomously, but there were five unplanned transitions to a safe state that required a manual restart after reviewing the data, determining a root cause, and implementing a solution. Four of the transitions were caused by the thermal management subsystem and the fifth was caused by a water management control issue in the EZ sub-system. The RFC system operated for over 550 hours with the final cycle being slightly abbreviated due to reasons unrelated to system performance.

Kerrigan Cain↗

NASA NTRSDate not supplied

Performance of a Regenerative Fuel Cell System for the Lunar Surface

Regenerative fuel cells (RFCs) are an attractive energy storage solution for lunar missions as a technology capable of providing a higher specific energy (i.e., W∙h/kg) than state-of-the-art packaged Li-ion battery systems. An RFC consists of the (1 & 2) electrochemical stacks (chemical to electrical energy conversion to supply electricity to an external load, i.e. the fuel cell reaction, and electrical to chemical energy conversion of supplied electrical power to dissociate water into hydrogen and oxygen gases, i.e. water electrolysis), (3) fluidic conditioning, (4) reactant storage, (5) avionics, (6) power management and distribution (PMAD), and (7) thermal management. NASA’s Glenn Research Center has designed, assembled, and tested a breadboard RFC sys-tem capable of operating autonomously for multiple simulated lunar day/night cycles in a laboratory environment. The system is comprised of a non-flow through proton exchange membrane (PEM) fuel cell stack and a liquid-anode feed PEM electrolyzer (EZ) stack designed to electrochemically compress the reactants at balanced pressures up to 12.4 MPa (1800 psia). The fluidic conditioning, avionics, PMAD, and thermal management sub-systems are largely comprised of commercial-off-the-shelf components for this system-level development effort. The hardware is controlled by a CubeSat space processor running an operational program based on core flight architecture that can control the RFC hardware autonomously through a state machine with fault monitoring. The testing results highlighted here were completed with the system in an open-loop configuration such that reactants generated through water electrolysis were vented while gas cylinders supplied fuel cell operation. The breadboard operated autonomously, but there were five unplanned transitions to a safe state that required a manual restart after reviewing the data, determining a root cause, and implementing a solution. Four of the transitions were caused by the thermal management subsystem and the fifth was caused by a water management control issue in the EZ sub-system. The RFC system operated for over 550 hours with the final cycle being slightly abbreviated due to reasons unrelated to system performance.

Kerrigan Cain↗

NASA NTRSDate not supplied

Solid-state Architecture Batteries for Enhanced Rechargeability and Safety for Electric Aircraft

All electric vertical take-off and landing vehicles (eVTOL) for urban air mobility (UAM) concepts face numerous challenging technical barriers before their introduction into the consumer marketplace. The most challenging of these technical barriers to overcome is developing an energy storage system capable of meeting the rigorous aerospace safety and performance criteria. The performance metrics for eVTOL craft are at least 2 times greater than those of electric automobiles. Furthermore, safety is essential for operation of commercial electric aerovehicles. Preliminary systems level analysis has indicated that there are five key properties which must be optimized for successful implementation of battery systems. Those five key criteria are: safety, energy density, power, packaging design and scalability. Current state-of-the-art (SOA) lithium-ion batteries meet or exceed the requirements for electric aviation in the areas of power and scalability, yet are insufficient in the key performance criteria of energy, safety and packaging design. The SABERS concept proposes a battery that meets all five key performance criteria through development of a solid-state architecture battery utilizing high energy density and power density sulfur-selenium cathode with a lithium metal anode. The combination of sulfur and selenium offers a balanced energy-to-power density ratio, which can be tailored to the specific application by altering the stoichiometric ratios of sulfur to selenium. This cathode will be developed by implementing NASA patented holey graphene technology as a highly conductive, ultra-lightweight electrode scaffold. A solid-state electrolyte will be used as a safe, non-flammable replacement to the highly flammable liquid organic electrolytes currently used in SOA lithium-ion batteries. This solid-state lithium-sulfur-selenium cell will be designed into a serial stacking configuration to enable dense packaging of the battery cells. The serial stacking configuration is termed a bipolar stack, which has the advantages of reducing overall cell weight, reducing the amount of interfaced connections for the cell, and minimizing the cooling requirements for the cell. Lastly, optimization of battery components will occur through a robust and rigorous combination of various computational modeling techniques covering multiple length scales. The expected result will be a fully solid-state battery with operational temperatures from 0 °C to 150 °C which provides the required energy density, discharge rates, and inherent safety to meet the strict aerospace performance criteria. This presentation will show initial results that demonstrate the SABERS Team has developed a composite carbon-sulfur cathode which exceeds 1100 Wh/kg at a discharge rate of 0.4C, and 804 Wh/kg at a discharge rate of 1C. Additionally, this presentation will show the SABERS Team multiscale computational modeling approach and has produced a novel particle dynamics method called Solid Electrolyte Sphere Approximation Model (SESAM). SESAM is on the 1-10 µm scale and provides electromechanical and grain interactions for predictive design guidelines for the experimental team to follow.

Urban Air Mobility (UAM) Vehicles↗

NASA NTRSDate not supplied

Computational Modeling Development of Solid-state Architecture Batteries for Enhanced Rechargeability and Safety for Electric Aircraft

All electric vertical take-off and landing vehicles (eVTOL) for urban air mobility (UAM) concepts face numerous challenging technical barriers before their introduction into the consumer marketplace. The most challenging of these technical barriers to overcome is developing an energy storage system capable of meeting the rigorous aerospace safety and performance criteria. The performance metrics for eVTOL craft are at least 2 times greater than those of electric automobiles. Furthermore, safety is essential for operation of commercial electric aerovehicles. Preliminary systems level analysis has indicated that there are five key properties which must be optimized for successful implementation of battery systems. Those five key criteria are: safety, energy density, power, packaging design and scalability. Current state-of-the-art (SOA) lithium-ion batteries meet or exceed the requirements for electric aviation in the areas of power and scalability, yet are insufficient in the key performance criteria of energy, safety and packaging design. The SABERS concept proposes a battery that meets all five key performance criteria through development of a solid-state architecture battery utilizing high energy density and power density sulfur-selenium cathode with a lithium metal anode. The combination of sulfur and selenium offers a balanced energy-to-power density ratio, which can be tailored to the specific application by altering the stoichiometric ratios of sulfur to selenium. This cathode will be developed by implementing NASA patented holey graphene technology as a highly conductive, ultra-lightweight electrode scaffold. A solid-state electrolyte will be used as a safe, non-flammable replacement to the highly flammable liquid organic electrolytes currently used in SOA lithium-ion batteries. This solid-state lithium-sulfur-selenium cell will be designed into a serial stacking configuration to enable dense packaging of the battery cells. The serial stacking configuration is termed a bipolar stack, which has the advantages of reducing overall cell weight, reducing the amount of interfaced connections for the cell, and minimizing the cooling requirements for the cell. Lastly, optimization of battery components will occur through a robust and rigorous combination of various computational modeling techniques covering multiple length scales. The expected result will be a fully solid-state battery with operational temperatures from 0 °C to 150 °C which provides the required energy density, discharge rates, and inherent safety to meet the strict aerospace performance criteria. This presentation will show initial results that demonstrate the SABERS Team has developed a composite carbon-sulfur cathode which exceeds 1100 Wh/kg at a discharge rate of 0.4C, and 804 Wh/kg at a discharge rate of 1C. Additionally, this presentation will show the SABERS Team multiscale computational modeling approach and has produced a novel particle dynamics method called Solid Electrolyte Sphere Approximation Model (SESAM). SESAM is on the 1-10 µm scale and provides electromechanical and grain interactions for predictive design guidelines for the experimental team to follow.

Urban Air Mobility (UAM) Vehicles↗

NASA NTRSDate not supplied

Solid-state Architecture Batteries for Enhanced Rechargeability and Safety (SABERS) for Extended Deep Space Applications

Extended duration deep space missions as well as permanent space habitats face numerous technical challenges, key among them is energy generation and energy storage. There are considerable monetary and technical barriers to the generation of power in space. Therefore, it is important to store and be able to access power in an efficient and safe manner over a large number of cycles. Energy storage and in particular, batteries, are vital to the operation of next-generation extraterrestrial shuttles, rovers, habitats and extravehicular activity (EVA) space suits. The performance metrics for extended duration space missions are at least 2 times greater than those set for terrestrial applications such as electric automobiles. Furthermore, safety is essential for operation of space missions particularly involving astronauts such as shuttles, habitats and EVA space suits. Preliminary systems level analysis has indicated that there are five key properties which must be optimized for successful implementation of battery systems. Those five key criteria are: safety, energy density, power, packaging design and scalability. Current state-of-the-art (SOA) lithium-ion batteries can meet or exceed the requirements for certain space applications in the areas of power and scalability, yet are insufficient in the key performance criteria of energy, safety and packaging design. The SABERS concept proposes a battery that meets all five key performance criteria through development of a solid-state architecture battery utilizing high capacity sulfur-selenium cathode and lithium metal anode. The combination of sulfur and selenium offers a balanced energy-to-power density ratio, which can be tailored to the specific application by altering the stoichiometric ratios of sulfur to selenium. This hybrid cathode will be developed by implementing NASA patented holey graphene technology as a highly conductive, ultra-lightweight electrode scaffold. A solid-state electrolyte will be used as a safe, non-flammable replacement to the highly flammable liquid organic electrolytes currently used in SOA lithium-ion batteries. This solid-state lithium-sulfur/selenium cell will be designed into a serial stacking configuration to enable dense packaging of the battery cells. The serial stacking configuration is termed a bipolar stack, which has the advantages of reducing overall cell weight, simplifying the interfaced connections for the cell, and minimizing the cooling requirements for the cell. Lastly, optimization of battery components will occur through a robust and rigorous combination of various computational modeling techniques covering multiple length scales. The expected result will be a fully solid-state battery with operational temperatures up to 150 °C which provides the required energy density, discharge rates, and inherent safety to meet the strict space mission performance criteria. In particular, the wide operational temperature window is required for the large temperature ranges which are experienced across a broad range of potential space missions. This presentation will show initial results that demonstrate the SABERS team has developed a composite carbon-sulfur cathode which exceeds 1100 Wh/kg at a discharge rate of 0.4C, and 804 Wh/kg at a discharge rate of 1C. Additionally, this presentation will show the SABERS team multiscale computational modeling approach and has produced a novel particle dynamics method called Solid Electrolyte Sphere Approximation Model (SESAM). SESAM is on the 1-10 µm scale and provides electromechanical and grain interactions for predictive design guidelines for the experimental team to follow.

Urban Air Mobility (UAM) Vehicles↗

DOE OSTI2025

BATMODS-lite [SWR-25-108]

Battery Analysis and Training Models for Optimization and Design Studies (BATMODS) is a Python package with an API for pre-built battery models. The original purpose of the package was to quickly generate synthetic data for machine learning models to train with. However, the models are generally useful for any battery simulations or analysis. BATMODS-lite includes the following: 1) A library and API for pre-built battery models 2) Kinetic/transport properties for common battery materials

Randall, Corey [National Laboratory of the Rockies↗

NASA NTRS2018

JSC 63322 Rev B: Packaging Requirements for Launch, On-Orbit Storage, and Disposal of Batteries

This presentation discusses the JSC 63322 changes and updates to accompanying OCAD.

Battery↗

NASA NTRS2020

Solid-state Architecture Batteries for Enhanced Rechargeability and Safety (SABERS)

All-electric vertical take-off and landing vehicles (eVTOL) for urban air mobility (UAM) concepts face numerous challenging technical barriers before their introduction into the consumer marketplace. The most challenging of these technical barriers to overcome is developing an energy storage system capable of meeting the rigorous aerospace safety and performance criteria. The performance metrics for eVTOL craft, such as specific energy and cycle life, are at least 2 times greater than those of electric automobiles. Furthermore, safety is essential for operation of commercial electric aerovehicles. Preliminary systems level analysis studies have indicated that there are five key properties which must be optimized for successful implementation of battery systems. Those five key criteria are safety, energy density, power, packaging design and scalability. Current state-of-the-art (SOA) lithium-ion batteries meet or exceed the requirements for electric aviation in the areas of power and scalability, yet are insufficient in the key performance criteria of energy, safety and packaging design. The SABERS concept proposes a battery that meets all five key performance criteria through the development of a solid-state architecture cell design utilizing high energy density and power density sulfur-selenium cathode with a lithium metal anode. Data will be presented demonstrating high performing sulfur - selenium cathode that offers a balanced energy to power density ratio, which can be tailored to the specific application by altering the stoichiometric ratios of sulfur to selenium. This cathode is being developed by implementing NASA patented holey graphene technology as a highly conductive, ultra-lightweight electrode scaffold. Novel processing methods allow developing solid-state electrolyte that is a safe, non-flammable replacement to the highly flammable liquid organic electrolytes currently used in SOA lithium-ion batteries. The all solid-state lithium-sulfur-selenium cell design enables the implementation of a bipolar stack configuration, which has the advantages of reducing overall cell weight, reducing the amount of interfaced connections for the cell, and minimizing cooling requirements for the battery. In particular, the solid-state design allows for a serial stacking configuration to enable dense packaging of the cells within the bipolar stack. Lastly, optimization of battery components occurs through a robust and rigorous combination of various computational modeling techniques covering multiple length scales. The expected result will be a solid-state battery with operational temperatures from 0 °C to 150 °C which provides the required energy density, discharge rate, and inherent safety to meet strict aerospace performance criteria.

solid state batteries↗

NASA NTRS2022

COMPASS Final Report: 2008 International Lunar Network (ILN)

The Compass team developed three designs for a soft lander for the International Lunar Network (ILN) using different power systems. These systems included solar arrays and batteries and two radioisotope power system (RPS) options scaled down from previous designs. These are a half Stirling radioisotope generator and a one-eighth Radioisotope Thermoelectric Generator (RTG). The COMPASS design consists of a soft-lander capable of network science (seismic, magnetospheric, laser reflector, and thermal transfer) that can land anywhere on the near side of the Moon and operate for at least six years. The baseline version, using only batteries and solar arrays, requires a very large battery (~80 kg) for the roughly 20 W night-time power requirements. The lander launch mass (with solid rocket breaking motor) is almost 900 kg. With such a large battery, the lander will require a launcher larger than the desired Minotaur V; a Taurus II (being developed for NASA Commercial Orbital Transportation Services (COTS)) or larger (Delta II or Atlas V) would be needed. The two RPS cases, half an Advanced Stirling Radioisotope Generators (ASRG) and one-eighth RTG have much smaller launch masses of 500 and 600 kg respectively. (The one-eighth RTG case lacks the power for the full science package, so a solar array battery is still needed.) Unfortunately, the Minotaur V’s launch capability is still not large enough (~430 kg to trans-lunar injection (TLI)) for the RPS systems. Consequently, a fourth case was developed to fly a limited science floor suite of instruments (seismometer only) which reduced the RPS Lander launch mass to fit on a Minotaur V.

Radioisotope Power Systems↗

NASA NTRS1979

Design tradeoff studies and sensitivity analysis, appendix B

Further work was performed on the Near Term Hybrid Passenger Vehicle Development Program. Fuel economy on the order of 2 to 3 times that of a conventional vehicle, with a comparable life cycle cost, is possible. The two most significant factors in keeping the life cycle cost down are the retail price increment and the ratio of battery replacement cost to battery life. Both factors can be reduced by reducing the power rating of the electric drive portion of the system relative to the system power requirements. The type of battery most suitable for the hybrid, from the point of view of minimizing life cycle cost, is nickel-iron. The hybrid is much less sensitive than a conventional vehicle is, in terms of the reduction in total fuel consumption and resultant decreases in operating expense, to reductions in vehicle weight, tire rolling resistance, etc., and to propulsion system and drivetrain improvements designed to improve the brake specific fuel consumption of the engine under low road load conditions. It is concluded that modifications to package the propulsion system and battery pack can be easily accommodated within the confines of a modified carryover body such as the Ford Ltd.

Source record↗

NASA NTRS1980

Vehicles testing of near-term batteries

Vehicles test results are reported for nickel-iron, nickel-zinc, and improved lead-acid batteries developed under the Near-Term Battery Program sponsored by the Department of Energy. The batteries have demonstrated a range improvement of up to 90% over current lead-acid batteries due to improved energy density and ampere-hour capacity, combined with relatively small weight and volume. However, the nickel-iron battery requires a substantial development effort in packaging the circulating electrolyte system and handling the generated hydrogen volume, while the nickel-zinc batteries tested suffer from short cycle life.

Conover, R. C.↗

NASA NTRS1973

The advanced OPLE for search and rescue

Recent technological advances have made it possible to develop an advanced OMEGA position location experiment for a global search and rescue application. This application generated some new problem areas such as the OMEGA lane ambiguity, random access, location accuracy, real time processing, and size and weight of the Search and Rescue Communication (SARCOM). This experiment will demonstrate the feasibility of instantaneous alarm and position location by using a relatively inexpensive, battery operated, three-pound package. This package can transmit the alarm and position through a synchronous satellite to a search and rescue station in less than three minutes.

Morakis, J. C.↗

NASA NTRS1972

The Global Rescue Alarm Net (GRAN) experiment

The OMEGA Position Location Experiment (OPLE) was performed in 1967 by the Goddard Space Flight Center in order to demonstrate a position location and data collection system. OMEGA navigation signals were received at a remote site and retransmitted via a synchronous satellite to a ground processing center where data collecting and position determination were performed. Recent technological advances have made it possible to develop an Advanced OPLE System towards a global search and rescue application. This application generated some new problem areas such as the OMEGA lane ambiguity, random access, location accuracy, real-time processing, and size and weight of the Search and Rescue Communications (SARCOM). This experiment demonstrates the feasibility of instantaneous alarm and position location by using a relatively inexpensive, battery operated, three-pound package.

Morakis, J. C.↗

NASA NTRS1977

Batteryless implanted echosonometer

Miniature ultrasonic echosonometer implanted within laboratory animals obtains energy from RF power oscillator that is electronically transduced via induction loop to power receiving loop located just under animal's skin. Method of powering device offers significant advantages over those in which battery is part of implanted package.

Kojima, G. K.↗

NASA NTRS1989

Summary of activities

Four space projects' activities are summarized. Design work on the Mars Penetrator Project, in cooperation with the NASA Ames Research Center, is being continued. Efforts are focused on the drilling mechanism which must penetrate the martian subsurface soil to collect and retrieve an uncontaminated sample. The new design consists of a rotary-percussive drill mechanism. This mechanism is optimum for dry drilling, necessary to avoid contamination of the soil sample, in many different soil types. The need for a small, relatively inexpensive device to study the chemical structure of this martian soil was also established. The egg design was chosen for its low cost compared to other systems and potential for a large number of eggs to be deployed on the martian surface. The design process included analysis of the dynamics of reentry, dissipation of heat during reentry, impact with the surface, access to undisturbed soil samples, and ability to gather samples from the soil at three depths. The egg consists of the reentry systems, soil probe lifting system, soil probe package, gas chromatograph, transmitter, and battery power supply. The egg must function only once, but is designed to withstand one martian year. The Mars Mole is designed as a rover-based device which penetrates the martian soil to a depth of up to 10 m, obtains a sample of soil, and returns it to the surface for analysis. The mole was designed to meet the following specifications: (1) weight less than 10 kg; (2) size less than 20 x 20 x 30 cm; (3) power less than 100 W; (4) ability to obtain a sample of at least 5 cc; (5) ability to penetrate fine, loose sand; and (6) need to obtain at least one sample. The space station umbilical connector project is a device which provides the translational motion of the connectors on the Space Station Freedom to allow engagement for power and data transfer. The design is capable of delivering a 20 lb force within the necessary tolerances and will operate reliably in the space environment.

Source record↗

NASA NTRS2004

Lithium Polymer Electrolytes and Solid State NMR

Research is being done at the Glenn Research Center (GRC) developing new kinds of batteries that do not depend on a solution. Currently, batteries use liquid electrolytes containing lithium. Problems with the liquid electrolyte are (1) solvents used can leak out of the battery, so larger, more restrictive, packages have to be made, inhibiting the diversity of application and decreasing the power density; (2) the liquid is incompatible with the lithium metal anode, so alternative, less efficient, anodes are required. The Materials Department at GRC has been working to synthesize polymer electrolytes that can replace the liquid electrolytes. The advantages are that polymer electrolytes do not have the potential to leak so they can be used for a variety of tasks, small or large, including in the space rover or in space suits. The polymers generated by Dr. Mary Ann Meador's group are in the form of rod -coil structures. The rod aspect gives the polymer structural integrity, while the coil makes it flexible. Lithium ions are used in these polymers because of their high mobility. The coils have repeating units of oxygen which stabilize the positive lithium by donating electron density. This aids in the movement of the lithium within the polymer, which contributes to higher conductivity. In addition to conductivity testing, these polymers are characterized using DSC, TGA, FTIR, and solid state NMR. Solid state NMR is used in classifying materials that are not soluble in solvents, such as polymers. The NMR spins the sample at a magic angle (54.7') allowing the significant peaks to emerge. Although solid state NMR is a helpful technique in determining bonding, the process of preparing the sample and tuning it properly are intricate jobs that require patience; especially since each run takes about six hours. The NMR allows for the advancement of polymer synthesis by showing if the expected results were achieved. Using the NMR, in addition to looking at polymers, allows for participation on a variety of other projects, including aero-gels and carbon graphite mat en als. The goals of the polymer electrolyte research are to improve the physical properties of the polymers. This includes improving conductivity, durability, and expanding the temperature range over which it is effective. Currently, good conductivity is only present at high temperatures. My goals are to experiment with different arrangements of rods and coils to achieve these desirable properties. Some of my experiments include changing the number of repeat units in the polymer, the size of the diamines, and the types of coil. Analysis of these new polymers indicates improvement in some properties, such as lower glass transition temperature; however, they are not as flexible as desired. With further research we hope to produce polymers that encompass all of these properties to a high degree.

Berkeley, Emily R.↗