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Broadband Performance of TPF's High-contrast Imaging Testbed: Modeling and Simulations

The broadband performance of the high-contrast imaging testbed (HCIT) at JPL is investigated through optical modeling and simulations. The analytical tool is an optical simulation algorithm developed by combining the HCIT's optical model with a speckle-nulling algorithm that operates directly on coronagraphic images, an algorithm identical to the one currently being used on the HCIT to actively suppress scattered light via a deformable mirror. It is capable of performing full three-dimensional end-to-end near-field diffraction analysis on the HCIT's optical system. By conducting speckle-nulling optimization, we clarify the HCIT's capability and limitations in terms of its broadband contrast performance under various realistic conditions. Considered cases include non-ideal occulting masks, such as a mask with optical density and wavelength dependent parasitic phase-delay errors (i.e., a not band-limited occulting mask) and the one with an optical-density profile corresponding to a measured, non-standard profile, as well as the independently measured phase errors of all optics. Most of the information gathered on the HCIT's optical components through measurement and characterization over the last several years at JPL has been used in this analysis to make the predictions as accurate as possible. The best contrast values predicted so far by our simulations obtainable on the HCIT illuminated with a broadband light having a bandwidth of 80nm and centered at 800nm wavelength are Cm=1.1x10-8 (mean) and C4=4.9x10-8 (at 4(lamda)/D), respectively. In this paper we report our preliminary findings about the broadband light performance of the HCIT.

integrated modeling↗

Broadband Fan Noise Prediction System for Turbofan Engines: Setup_BFaNS User's Manual and Developer's Guide - Volume 1

Pratt & Whitney has developed a Broadband Fan Noise Prediction System (BFaNS) for turbofan engines. This system computes the noise generated by turbulence impinging on the leading edges of the fan and fan exit guide vane, and noise generated by boundary-layer turbulence passing over the fan trailing edge. BFaNS has been validated on three fan rigs that were tested during the NASA Advanced Subsonic Technology Program (AST). The predicted noise spectra agreed well with measured data. The predicted effects of fan speed, vane count, and vane sweep also agreed well with measurements. The noise prediction system consists of two computer programs: Setup_BFaNS and BFaNS. Setup_BFaNS converts user-specified geometry and flow-field information into a BFaNS input file. From this input file, BFaNS computes the inlet and aft broadband sound power spectra generated by the fan and FEGV. The output file from BFaNS contains the inlet, aft and total sound power spectra from each noise source. This report is the first volume of a three-volume set documenting the Broadband Fan Noise Prediction System: Volume 1: Setup_BFaNS User s Manual and Developer s Guide; Volume 2: BFaNS User's Manual and Developer s Guide; and Volume 3: Validation and Test Cases. The present volume begins with an overview of the Broadband Fan Noise Prediction System, followed by step-by-step instructions for installing and running Setup_BFaNS. It concludes with technical documentation of the Setup_BFaNS computer program.

Morin, Bruce L.↗

Broadband Fan Noise Prediction System for Turbofan Engines: BFaNS User's Manual and Developer's Guide - Volume 2

Pratt & Whitney has developed a Broadband Fan Noise Prediction System (BFaNS) for turbofan engines. This system computes the noise generated by turbulence impinging on the leading edges of the fan and fan exit guide vane, and noise generated by boundary-layer turbulence passing over the fan trailing edge. BFaNS has been validated on three fan rigs that were tested during the NASA Advanced Subsonic Technology Program (AST). The predicted noise spectra agreed well with measured data. The predicted effects of fan speed, vane count, and vane sweep also agreed well with measurements. The noise prediction system consists of two computer programs: Setup_BFaNS and BFaNS. Setup_BFaNS converts user-specified geometry and flow-field information into a BFaNS input file. From this input file, BFaNS computes the inlet and aft broadband sound power spectra generated by the fan and FEGV. The output file from BFaNS contains the inlet, aft and total sound power spectra from each noise source. This report is the second volume of a three-volume set documenting the Broadband Fan Noise Prediction System: Volume 1: Setup_BFaNS User s Manual and Developer s Guide; Volume 2: BFaNS User s Manual and Developer s Guide; and Volume 3: Validation and Test Cases. The present volume begins with an overview of the Broadband Fan Noise Prediction System, followed by step-by-step instructions for installing and running BFaNS. It concludes with technical documentation of the BFaNS computer program.

Morin, Bruce L.↗

Broadband Fan Noise Prediction System for Turbofan Engines: Validation and Test Cases - Volume 3

Pratt & Whitney has developed a Broadband Fan Noise Prediction System (BFaNS) for turbofan engines. This system computes the noise generated by turbulence impinging on the leading edges of the fan and fan exit guide vane, and noise generated by boundary-layer turbulence passing over the fan trailing edge. BFaNS has been validated on three fan rigs that were tested during the NASA Advanced Subsonic Technology Program (AST). The predicted noise spectra agreed well with measured data. The predicted effects of fan speed, vane count, and vane sweep also agreed well with measurements. The noise prediction system consists of two computer programs: Setup_BFaNS and BFaNS. Setup_BFaNS converts user-specified geometry and flow-field information into a BFaNS input file. From this input file, BFaNS computes the inlet and aft broadband sound power spectra generated by the fan and FEGV. The output file from BFaNS contains the inlet, aft and total sound power spectra from each noise source. This report is the third volume of a three-volume set documenting the Broadband Fan Noise Prediction System: Volume 1: Setup_BFaNS User s Manual and Developer s Guide; Volume 2: BFaNS User s Manual and Developer s Guide; and Volume 3: Validation and Test Cases. The present volume begins with an overview of the Broadband Fan Noise Prediction System, followed by validation studies that were done on three fan rigs. It concludes with recommended improvements and additional studies for BFaNS.

Morin, Bruce L.↗

Characteristics of a Broadband Dye Laser Using Pyrromethene and Rhodamine Dyes

A broadband dye laser pumped by a frequency-doubled Nd:YAG laser with a full-width half-maximum (FWHM) from 592 to 610 nm was created for the use in a dual-pump broadband CARS system called WIDECARS. The desired broadband dye laser was generated with a mixture of Pyrromethene dyes as an oscillator gain medium and a spectral selective optic in the oscillator cavity. A mixture of Rhodamine dyes were used in the amplifier dye cell. To create this laser a study was performed to characterize the spectral behavior of broadband dye lasers created with Rhodamine dyes 590, 610, and 640, Pyrromethene dyes 597 and 650 as well as mixture of these dyes.

Tedder, Sarah A.↗

Improved Broadband Liner Optimization Applied to the Advanced Noise Control Fan

The broadband component of fan noise has grown in relevance with the utilization of increased bypass ratio and advanced fan designs. Thus, while the attenuation of fan tones remains paramount, the ability to simultaneously reduce broadband fan noise levels has become more desirable. This paper describes improvements to a previously established broadband acoustic liner optimization process using the Advanced Noise Control Fan rig as a demonstrator. Specifically, in-duct attenuation predictions with a statistical source model are used to obtain optimum impedance spectra over the conditions of interest. The predicted optimum impedance information is then used with acoustic liner modeling tools to design liners aimed at producing impedance spectra that most closely match the predicted optimum values. Design selection is based on an acceptance criterion that provides the ability to apply increased weighting to specific frequencies and/or operating conditions. Constant-depth, double-degree of freedom and variable-depth, multi-degree of freedom designs are carried through design, fabrication, and testing to validate the efficacy of the design process. Results illustrate the value of the design process in concurrently evaluating the relative costs/benefits of these liner designs. This study also provides an application for demonstrating the integrated use of duct acoustic propagation/radiation and liner modeling tools in the design and evaluation of novel broadband liner concepts for complex engine configurations.

Nark, Douglas M.↗

Modeling of Broadband Liners Applied to the Advanced Noise Control Fan

The broadband component of fan noise has grown in relevance with an increase in bypass ratio and incorporation of advanced fan designs. Therefore, while the attenuation of fan tones remains a major factor in engine nacelle acoustic liner design, the simultaneous reduction of broadband fan noise levels has received increased interest. As such, a previous investigation focused on improvements to an established broadband acoustic liner optimization process using the Advanced Noise Control Fan (ANCF) rig as a demonstrator. Constant-depth, double-degree of freedom and variable-depth, multi-degree of freedom liner designs were carried through design, fabrication, and testing. This paper addresses a number of areas for further research identified in the initial assessment of the ANCF study. Specifically, incident source specification and uncertainty in some aspects of the predicted liner impedances are addressed. This information is incorporated in updated predictions of the liner performance and comparisons with measurement are greatly improved. Results illustrate the value of the design process in concurrently evaluating the relative costs/benefits of various liner designs. This study also provides further confidence in the integrated use of duct acoustic propagation/radiation and liner modeling tools in the design and evaluation of novel broadband liner concepts for complex engine configurations.

Nark, Douglas M.↗

Anomalous Temporal Behaviour of Broadband Ly Alpha Observations During Solar Flares from SDO/EVE

Although it is the most prominent emission line in the solar spectrum, there has been a notable lack of studies devoted to variations in Lyman-alpha (Ly-alpha) emission during solar flares in recent years. However, the few examples that do exist have shown Ly-alpha emission to be a substantial radiator of the total energy budget of solar flares (of the order of 10 percent). It is also a known driver of fluctuations in the Earth's ionosphere. The EUV (Extreme Ultra-Violet) Variability Experiment (EVE) on board the Solar Dynamics Observatory (SDO) now provides broadband, photometric Ly-alpha data at 10-second cadence with its Multiple EUV Grating Spectrograph-Photometer (MEGS-P) component, and has observed scores of solar flares in the 5 years since it was launched. However, the MEGS-P time profiles appear to display a rise time of tens of minutes around the time of the flare onset. This is in stark contrast to the rapid, impulsive increase observed in other intrinsically chromospheric features (H-alpha, Ly-beta, LyC, C III, etc.). Furthermore, the emission detected by MEGS-P peaks around the time of the peak of thermal soft X-ray emission and not during the impulsive phase when energy deposition in the chromosphere (often assumed to be in the form of non-thermal electrons) is greatest. The time derivative of Ly-alpha lightcurves also appears to resemble that of the time derivative of soft X-rays, reminiscent of the Neupert effect. Given that spectrally-resolved Ly-alpha observations during flares from SORCE / SOLSTICE (Solar Radiation and Climate Experiment / Solar Stellar Irradiance Comparison Experiment) peak during the impulsive phase as expected, this suggests that the atypical behaviour of MEGS-P data is a manifestation of the broadband nature of the observations. This could imply that other lines andor continuum emission that becomes enhanced during flares could be contributing to the passband. Users are hereby urged to exercise caution when interpreting broadband Ly-alpha observations of solar flares. Comparisons have also been made with other broadband Ly-alpha photometers such as PROBA2 (Project for On-Board Autonomy-2) / LYRA (Lyman Alpha Radiometer) and GOES (Geostationary Operational Environmental Satellite) / EUVE (Extreme Ultraviolet Explorer).

Milligan, Ryan O.↗

An Accurate Method for Correcting Spectral Convolution Errors in Intercalibration of Broadband and Hyperspectral Sensors

The intercalibration between a broadband and a hyperspectral satellite Earth observation system requires the convolution of the hyperspectral data with the spectral response functions (SRFs) of the corresponding broadband channels. There are two potential issues associated with the convolution procedure. First, the finite resolution of a hyperspectral spectrum, that is, the deviation from the highly accurate line-by-line monochromatic radiances, will contribute to convolution errors. The magnitude of the errors depends on the spectral resolution and the SRF shape of the hyperspectral instrument. This type of the convolution error has not been well recognized, and there is a lack of corresponding discussion in most published papers. Although it is small as compared with the instrument accuracy of existing hyperspectral sounders, the error is deemed to be signicant when it is compared with the stringent calibration requirement imposed by future climate missions like the Climate Absolute Radiance and Refractivity Observatory (CLARREO). Second, some broadband channels are insufficiently covered by the hyperspectral data, causing spectral gaps that lead to convolution errors. Although several methods have been developed to fill the spectral gaps and hence compensate for the second type of convolution error, the correction accuracy may still need improvement especially when a large spectral gap needs to be lled. This paper presents a methodology to accurately quantify and compensate for both types of convolution errors. This methodology utilizes the available hyperspectral information to correct the scene-dependent convolution errors due to either the limited spectral resolution or spectral gaps. We use simulations to characterize the intercalibration errors between the Moderate resolution Imaging Spectroradiometer (MODIS) and current operational infrared sounders. We demonstrate that convolution errors can be effectively removed to meet the highly accurate intersatellite calibration requirement proposed by the Climate Absolute Radiance and Refractivity Observatory. Our methodology is also validated using real satellite data for the intercalibration between Aqua MODIS and Aqua Atmospheric Infrared Sounders (AIRS). Our study demonstrates that the accurate characterization and correction for the convolution errors greatly reduces the scene-dependent and spectrally dependent errors, being critical to the consistency check between Infrared Atmospheric Sounding Interferometer (IASI) and AIRS using the double-difference method. The convolution correction also facilitates the evaluation for other intercalibration errors (e.g., the drift of MODIS SRFs). Our derived SRF shift values from MODIS-AIRS (after convolution error corrections) and from MODIS-IASI intercalibration are consistent with each other. We further extend the methodology to study the calibration of a broadband channel which is either completely or largely uncovered bya hyperspectral measurement.The large spectral gap-filling methodology is validated by demonstrating the accurate prediction of the MODIS radiance of band 29 using the Cross-track Infrared Sounder spectra, with the real IASI spectral data being used as the reference.

Correction Method↗

Physics Informed Broadband Noise Source Identification and Prediction of an Ideally Twisted Rotor

This work aims at a physics based approach for the prediction and isolation of broadband noise emanating from different regions of an ideally twisted rotor. A preliminary prediction was conducted using a lattice-Boltzmann method–very-large-eddy simulation (LBM-VLES) implemented within the software suite, PowerFLOW. Regions of particular interest to broadband noise were investigated by calculating one-third octave sound pressure levels of the unsteady pressure fluctuations acting on the rotor. These regions were then isolated and treated as individual Ffowcs Williams-Hawkings (FW-H) surfaces for three run conditions at a much finer spatial resolution to delineate the broadband noise from these separate regions from the total acoustic spectra. These predictions were then compared to experimentally acquired data as well as to semi-empirical prediction methods to highlight the acoustic contributions of various broadband noise generation mechanisms as well as to exemplify and explain shortcomings in the semi-empirical methodology.

Christopher S Thurman↗

Physics-Informed Broadband Noise Source Identification and Prediction of an Ideally Twisted Rotor

This work aims to provide a physics-based approach for the prediction and isolation of broadband noise emanating from different regions of an ideally twisted rotor. A preliminary prediction was conducted using a lattice-Boltzmann method–very-large-eddy simulation (LBM-VLES) implemented within the software suite, PowerFLOW. Regions of particular interest to broadband noise were investigated by calculating one-third octave sound pressure levels of the unsteady pressure fluctuations acting on the rotor. These regions were then treated as individual Ffowcs Williams and Hawkings (FW-H) surfaces and simulated for three run conditions at a finer spatial resolution to identify the broadband noise from these separate regions and isolate it from the total acoustic spectra. These predictions were then compared to experimentally acquired data and to semiempirical prediction methods to highlight the acoustic contributions of various broadband noise generation mechanisms as well as to exemplify and explain shortcomings in the semiempirical methodology.

Christopher S Thurman↗

Improved GEO Derived LW Broadband Fluxes for the Edition5 CERES SYN1Deg Data Product

The NASA Clouds and the Earth's Radiant Energy System (CERES) project provides over 24 years of accurately observed top-of-the-atmosphere (TOA) and surface flux data record for climate monitoring and diagnostic studies. The major level-3 data products include SSF1deg, SYN1deg, FluxByCldTyp, and EBAF data. The CERES SYN1deg product provides 1° gridded observed TOA fluxes and computed surface fluxes based on hourly GEO clouds and derived broadband TOA fluxes. The hourly GEO derived fluxes fill in the temporal gaps between the Terra and Aqua CERES observations. In order to maintain a climate quality dataset the GEO cloud and flux retrievals are consistent over the record. The CERES project is preparing for Edition 5 product providing an opportunity to improve the GEO flux retrieval algorithms. To achieve this, the GEO satellite channel radiances are calibrated against the Aqua-MODIS calibration reference. For SW the GEO channel radiances are then converted to broadband radiances using empirical and theoretical models. The SW broadband radiances are then converted to fluxes using the same CERES angular directional models. For LW the GEO channel radiances are directly converted to LW fluxes utilizing empirical models. The resulting GEO derived broadband fluxes are then normalized to the CERES fluxes regionally by regressing the instantaneous coincident flux pairs. The normalized GEO fluxes are then tied to the CERES instrument calibration, which is very stable over time. This study will attempt to improve the GEO derived LW fluxes based on machine learning technique for the future Edition5 SYN1deg data product.

Moguo Sun↗

Broadband Noise Prediction of Two Small Hovering Rotors using FUN3D-ANOPP2

A computational study was performed on two small hovering rotors, the ideally twisted rotor and the optimum hovering 2-bladed rotor, using FUN3D-ANOPP2. The effects of different inviscid upwinding techniques and temporal resolutions on aerodynamic performance and acoustic prediction were compared against experimental data obtained in the Small Hover Anechoic Chamber facility at the NASA Langley Research Center. Decreasing the numerical dissipation with 𝜅 tuning or by using a higher-order inviscid flux reconstruction scheme was shown to improve aerodynamic performance predictions when compared to measured data for most cases. The effect of dissipation on the vorticity field was also seen to influence the amount of turbulence surrounding the vortex core of the first blade-vortex interaction (BVI), the coherence of the second and higher BVI vortex cores, and the downstream breakdown of the rotor wake for both rotor geometries. Tonal and broadband noise predictions from simulation cases with lower dissipation were seen to agree better with the experiment for the ideally twisted rotor, whereas temporal resolution differences had negligible impact on the broadband noise results. Similar fundamental BPF directivity patterns were obtained by all simulation cases for the optimum hovering 2-bladed rotor, while the most accurate 2*BPF directivity trend, compared to the experiment, was predicted by the lower-dissipation case at the coarse temporal resolution, albeit with an amplitude underprediction. Broadband noise spectral roll-off behavior was seen to occur at a higher frequency when using a finer temporal resolution for the optimum hovering 2-bladed rotor, unlike for the ideally twisted rotor geometry. The broadband noise prediction for the optimum hovering 2-bladed rotor from the higher-dissipation case at the coarse temporal resolution was also seen to predict a tone centered around approximately 8.5 kHz, which was similar in amplitude to the measured tone around 16.5 kHz.

Christopher S. Thurman↗

A Broadband X-Ray Imaging Spectroscopy with High-Angular Resolution: the FORCE Mission

We are proposing FORCE (Focusing On Relativistic universe and Cosmic Evolution) as a future Japan-lead X-ray observatory to be launched in the mid 2020s. Hitomi (ASTRO-H) possesses a suite of sensitive instruments enabling the highest energy-resolution spectroscopy in soft X-ray band, a broadband X-ray imaging spectroscopy in soft and hard X-ray bands, and further high energy coverage up to soft gamma-ray band. FORCE is the direct successor to the broadband X-ray imaging spectroscopy aspect of Hitomi (ASTRO-H) with significantly higher angular resolution. The current design of FORCE defines energy band pass of 1-80 keV with angular resolution of <15" in half-power diameter, achieving a 10 times higher sensitivity above 10 keV compared to any previous missions with simultaneous soft X-ray coverage. Our primary scientific objective is to trace the cosmic formation history by searching for "missing black holes" in various mass-scales: "buried supermassive black holes (SMBHs)" (> 10(exp 4) Stellar Mass) residing in the center of galaxies in a cosmological distance, "intermediate-mass black holes" (10(exp 2)-(10(exp 4) Stellar Mass) acting as the possible seeds from which SMBHs grow, and "orphan stellar-mass black holes" (< 10(exp 2) Stellar Mass) without companion in our Galaxy. In addition to these missing BHs, hunting for the nature of relativistic particles at various astrophysical shocks is also in our scope, utilizing the broadband X-ray coverage with high angular-resolution. FORCE are going to open a new era in these fields. The satellite is proposed to be launched with the Epsilon vehicle that is a Japanese current solid-fuel rocket. FORCE carries three identical pairs of Super-mirror and wide-band X-ray detector. The focal length is currently planned to be 10 m. The silicon mirror with multi-layer coating is our primary choice to achieve lightweight, good angular optics. The detector is a descendant of hard X-ray imager onboard Hitomi (ASTRO-H) replacing its silicon strip detector with SOI-CMOS silicon pixel detector, allowing an extension of the low energy threshold down to 1 keV or even less.

Hard X-ray↗

Radiative Transfer Models for Deriving Geostationary Broadband Shortwave Radiances Directly from Visible Channels for the Ceres SYN1DEG Product

The Clouds and the Earth's Radiant Energy System(CERES)project was designed to observe the Earth’s radiation budget at the 1° regional and global scale. The CERES instruments on the Terra (10:30 AM local equator crossing time) and Aqua (1:30 PM) satellite may not accurately capture the 24-hour mean flux over regions with systematic diurnal cycles. The Terra-only and Aqua-only derived regional monthly mean SW flux can differ by 25 Wm-2 over maritime stratus and land afternoon convective regions. The CERES project utilizes hourly Geostationary imager (GEO) derived broadband fluxes to more accurately estimate the regional diurnal flux in between CERES measurements. We propose an approach that converts the GEO visible radiance to broadband radiance using RTM radiances that are specific to the individual GEO visible channel spectral response functions. The RTM is first validated using the very spectrally narrow MODIS visible channel and CERES broadband radiances.

geostationary derived broadband radiances↗

Correlating Broadband Photoluminescence with Structural Dynamics in Layered Hybrid Halide Perovskites

The emission of white light from a single material is atypical and is of interest for solid-state lighting applications. Broadband light emission has been observed in some layered perovskite derivatives, A 2 PbBr 4 (A = R-NH 3 + ), and correlates with static structural distortions corresponding to out-of-plane tilting of the lead bromide octahedra. While materials with different organic cations can yield distinct out-of-plane tilts, the underlying origin of the octahedral tilting remains poorly understood. Using high energy resolution (e.g., quasi-elastic) neutron scattering, this contribution details the rotational dynamics of the organic cations in A 2 PbBr 4 materials where A = n-butylammonium (nBA), 1,8-diaminooctammonium (ODA), and 4-aminobutyric acid (GABA). The organic cation dynamics differentiate (nBA) 2 PbBr 4 from (ODA)PbBr 4 or (GABA) 2 PbBr 4 in that the larger spatial extent of dynamics of nBA yields a larger effective cation radius. The larger effective volume of the nBA cation in (nBA) 2 PbBr 4 yields a closer to ideal A-site geometry, preventing the out-of-plane tilt and broadband luminescence. In all three compounds, we observe hydrogen dynamics attributed to rotation of the ammonium headgroup and at a time scale faster than the white light photoluminescence studied by time-correlated single photon counting spectroscopy. This supports a previous assignment of the broadband emission as resulting from a single ensemble, such that the emissive excited state experiences many local structures faster than the emissive decay. Furthermore, the findings presented here highlight the role of the organic cation and its dynamics in hybrid organic–inorganic perovskites and white light emission.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Broadband unidirectional visible imaging using wafer-scale nano-fabrication of multi-layer diffractive optical processors

We present a broadband and polarization-insensitive unidirectional imager that operates at the visible part of the spectrum, where image formation occurs in one direction, while in the opposite direction, it is blocked. This approach is enabled by deep learning-driven diffractive optical design with wafer-scale nano-fabrication using high-purity fused silica to ensure optical transparency and thermal stability. Our design achieves unidirectional imaging across three visible wavelengths (covering red, green, and blue parts of the spectrum), and we experimentally validated this broadband unidirectional imager by creating high-fidelity images in the forward direction and generating weak, distorted output patterns in the backward direction, in alignment with our numerical simulations. This work demonstrates wafer-scale production of diffractive optical processors, featuring 16 levels of nanoscale phase features distributed across two axially aligned diffractive layers for visible unidirectional imaging. This approach facilitates mass-scale production of ~0.5 billion nanoscale phase features per wafer, supporting high-throughput manufacturing of hundreds to thousands of multi-layer diffractive processors suitable for large apertures and parallel processing of multiple tasks. Beyond broadband unidirectional imaging in the visible spectrum, this study establishes a pathway for artificial-intelligence-enabled diffractive optics with versatile applications, signaling a new era in optical device functionality with industrial-level, massively scalable fabrication.

36 MATERIALS SCIENCE↗

Ultra broadband yellow emitting lead-free metal halide perovskite like compounds with near-unity emission quantum yields

Metal halide perovskites (MHPs) are interesting semiconductor materials with potential for use in optoelectronic and photonic devices. Their practical applications are hindered due to the negative environmental effects of the lead ions (Pb 2+ ) used in these materials and stability issues. Exploring new environmentally friendly materials with lead-free metal halides and investigating the factors affecting their optical properties and stability are essential. The broadband emission and high (near-unity; ~100%) photoluminescence quantum yield (PLQY) of low-dimensional copper(I) halides make them great candidates for the next-generation luminescent materials for lighting applications. Here, a Cu(I) iodide based organic/inorganic hybrid halide (benzo-15-crown-5) 2 NaH 2 OCu 4 I 6 (BCNCI) with a zero-dimensional (0D) cluster was prepared. The BCNCI has a broadband yellow emission peaked at 548 nm with a near-unity PLQY (99.1%) upon excitation at 365 nm (ultraviolet). Upon excitation at 450 nm (blue), a high PLQY of 82% was also achieved. The luminescence mechanism was discussed in detail. Interestingly, BCNCI exhibits ultra-broad band excitation in the 300–500 nm range, which matches commercially available UV and blue-emitting chips. Compared to commercial YAG:Ce 3+ phosphors, the emission spectrum is sufficiently broad to cover the visible spectral region. This work illustrates a good example of developing an environmentally friendly white light source, using high-performance copper halides with adequate broadband excitation and emission.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗