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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
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NASA NTRS1984

The ionization structure of planetary nebulae. IV - NGC 6853

Upgraded UV and IR data were taken of the planetary nebula NGC 6853 in the same region as previous optical data to improve the data base on various ionized species in the nebula. The spectral range 1400-9600 A was scanned, and good agreement was obtained between UV and optical ionization abundance data, although the 4267 A C II line yielded a C(2+) abundance larger than indicated by the UV data. The discrepancy concentrated around the central star. Ionization abundances were determined for He, O, N, NC, C, Ar, and S relative to H, and the causes of discrepancies in the abundances compared to those of previous investigators are discussed. It is noted that, as in the planetary nebula NGC 6720, lighter element abundances are higher than solar values, which suggests mixing of processed materials in the envelope of the two nebulae.

Barker, T.↗
NASA NTRS1985

Origin of the difference of the coverage-dependent vibrational shift for S on Ni(100) and O on Ni(100)

The p(2 x 2) and c(2 x 2) coverages of S on Ni(100) are studied with a cluster model. Consistent with a recent lattice-dynamics study, the chemical contribution (rigid Ni lattice) to the coverage-dependent shift of the S vibrational energy is of opposite sign to that for O. Analysis of the cluster wave functions suggests that S becomes less negatively charged with coverage, while O becomes more ionic; however, this effect is small.

Bauschlicher, C. W., Jr.↗
NASA NTRS1985

The ionization structure of planetary nebulae. V - NGC 3242

Spectrophotometric observations of emission line intensities over the spectral range 1400 A to 9600 A were made in five positions in the planetary nebula NGC 3242. In two of the positions, both the weakness of the 1548 A, 1550 A C IV resonance lines and the steepness of the Balmer decrement suggest the possibility of internal dust in the nebula. The measured electron temperature varies little from the average value of 11,100 K, which is in reasonably good agreement with the less accurate value of 12,900 K measured from the Balmer continuum. The 4267 A C II line implies a C(2+) abundance that is much higher than that determined from the 1906 A, 1908 A C III lines. This discrepancy decreases with increasing distance from the central star. Equations used to correct for the existence of elements in other than the optically-observable ionization stages give results that are consistent and in agreement with abundances calculated using ultraviolet lines. This discrepancy decreases with increasing distance from the central star. Equations used to correct for the existence of elements in other than the optically-observable ionization stages give results that are consistent and in agreement with abundances calculated using ultraviolet lines. The logarithmic abundances are He = 10.96, O = 8.64, N = 7.96, Ne = 8.04, C = 8.41, Ar = 6.15, and S = 6.51.

Barker, T.↗
NASA NTRS1985

Advanced Containerless Processing Technology

Breadboards for high temperature containerless processing systems are to be developed, the principles of operation are to be studied, the performance is to be characterized, the limitations identified, and the influence of the acoustic field on the samples established. The subjects to be addressed are experimental and theoretical studies of: (1) acoustic positioning and manipulation capabilities in a high temperature gradient environment (from 26 C to 990 C); (2) acoustic waveforms, harmonic contents, power transfer, sample transport and stability associated with high temperature gradient system; (3) high temperature ground based levitation systems which will allow melting, processing, and solidifying samples without crucibles in the laboratory, (4) KC-135 and laboratory tests of various acoustic geometries which may have spherical applications in the Materials Processing in Space Program; and (5) provide technical information to Acoustics Containerless Experimental System (ACES) engineering team and establish the operation conditions for ACES.

Wang, T. G.↗
NASA NTRS1986

Coverage dependent effects on metal surfaces - O, S, F, and Cl on Ni

The c(2 x 2) and p(2 x 2) vibrational frequencies for a rigid Ni lattice are computed for O, S, F, and Cl on Ni(100). It is found that only O/Ni(100) shows a large difference in rigid lattice vibrational frequency. A large shift in rigid lattice vibrational frequency is also found for O/Ni(111) between 0.25 and 0.5 monolayer coverages. Also associated with the change in coverage, is a change in the height above the surface R(perpendicular). This varies from a 0.11 A reduction for O/Ni(100), to an expansion of 0.06 A for F/Ni(100).

Bauschlicher, C. W., Jr.↗
NASA NTRS1986

The ionization structure of planetary nebulae. Part 7: New observations in the ring nebula

New optical spectrophotometric observations of emission-line intensities have been made in eight positions in the Ring Nebula corresponding to those observed previously with the Ultraviolet Explorer satellite; the total coverage is therefore 1400 to 7200 A. The intensities are in generally good agreement with those found previously in corresponding positions. The 0(++) and Balmer continuum electron temperatures agree well on the average and, like the N(+) electron temperatures, decrease with increasing distance from the central star. As found previously for the Ring Nebula and for other planetaries in this series, the lambda 4267 C 2 line intensity near the central star implies a C(++) abundance that is higher than that determined from the lambda 1906, 1909 C 3 lines. The discrepancy again decreases with increasing distance from the central star and vanishes from the outermost positions, again suggesting that the excitation mechanism from the lambda 4267 line is not understood. Standard equations used to correct for the existence of elements in other than the optically observable ionization stages give results that are consistent and in appropriate agreement with abundances calculated using UV lines. The rather high abundances of O, N, and C, and, to some extent N, indicate that some mixing of CNO processed material into the nebular shell may have occurred in the Ring Nebula.

Barker, Timothy↗
NASA NTRS1987

Ceramic honeycomb structures and the method thereof

The subject invention pertains to a method of producing an improved composite-composite honeycomb structure for aircraft or aerospace use. Specifically, the subject invention relates to a method for the production of a lightweight ceramic-ceramic composite honeycomb structure, which method comprises: (1) pyrolyzing a loosely woven fabric/binder having a honeycomb shape and having a high char yield and geometric integrity after pyrolysis at between about 700 and 1,100 C; (2) substantially evenly depositing at least one layer of ceramic material on the pyrolyzed fabric/binder of step (1); (3) recovering the coated ceramic honeycomb structure; (4) removing the pyrolyzed fabric/binder of the structure of step (3) by slow pyrolysis at between 700 and 1000 C in between about a 2 to 5% by volume oxygen atmosphere for between about 0.5 and 5 hr.; and (5) substantially evenly depositing on and within the rigid hollow honeycomb structure at least one additional layer of the same or a different ceramic material by chemical vapor deposition and chemical vapor infiltration. The honeycomb shaped ceramic articles have enhanced physical properties and are useful in aircraft and aerospace uses.

Riccitiello, Salvatore R.↗
NASA NTRS1987

The ionization structure of planetary nebulae. VII. New observations of the Ring Nebula

New optical spectrophotometric observations of emission-line intensities have been made in eight positions in the Ring Nebula corresponding to those observed previously with the Ultraviolet Explorer satellite; the total coverage is therefore 1400 to 7200 A. The intensities are in generally good agreement with those found previously in corresponding positions. The Oand Balmer continuum electron temperatures agree well on the average and, like the Nelectron temperatures, decrease with increasing distance from the central star. As found previously for the Ring Nebula and for other planetaries in this series, the lambda 4267 C 2 line intensity near the central star implies a Cabundance that is higher than that determined from the lambda 1906, 1909 C 3 lines. The discrepancy again decreases with increasing distance from the central star and vanishes from the outermost positions, again suggesting that the excitation mechanism from the lambda 4267 line is not understood. Standard equations used to correct for the existence of elements in other than the optically observable ionization stages give results that are consistent and in appropriate agreement with abundances calculated using UV lines. The rather high abundances of O, N, and C, and, to some extent N, indicate that some mixing of CNO processed material into the nebular shell may have occurred in the Ring Nebula.

Barker, Timothy↗
NASA NTRS1987

Planetary nebulae

The role of the IUE in the study of planetary nebulae (PN) is discussed as well as extinction, the central star and nebular spectra, plasma diagnostics, the chemical compositions of PN, and nebular models. Some information on the spatial distribution of C(2+) or C(3+) ions may be acquired for extended PN from IUE data, making it possible to probe ionization zones different from those observable in the visual region. For high resolution pertaining to filamentary structure and clumpiness, optical region images and data obtained with the Hubble Space Telescope are needed.

Koeppen, J.↗
NASA NTRS1987

Dicarboxylic acids generated by thermal alteration of kerogen and humic acids

Significant amounts (up to 2 percent of organic geopolymers) of low-molecular-weight (LMW) dicarboxylic acids (C2-C10) have been detected during thermal alteration (270 C, 2 h) of kerogens and humic acids isolated from young or ancient lithified sediments. Their distribution is characterized by the predominance of oxalic acid followed by succinic, fumaric, and methylsuccinic acids. These acids are probably released by the breakdown of macromolecular structures, which have incorporated biogenic organic compounds, including diacids, during early digenesis in sediments. Because of their reactivity, LMW diacids may play geochemically important roles under natural conditions.

Kawamura, Kimitaka↗
NASA NTRS1989

Optimization of the lithium/thionyl chloride battery

A 1-D math model for the lithium/thionyl chloride primary cell is used in conjunction with a parameter estimation technique in order to estimate the electro-kinetic parameters of this electrochemical system. The electro-kinetic parameters include the anodic transfer coefficient and exchange current density of the lithium oxidation, alpha sub a,1 and i sub o,i,ref, the cathodic transfer coefficient and the effective exchange current density of the thionyl chloride reduction, alpha sub c,2 and a sup o i sub o,2,ref, and a morphology parameter, Xi. The parameter estimation is performed on simulated data first in order to gain confidence in the method. Data, reported in the literature, for a high rate discharge of an experimental lithium/thionyl chloride cell is used for an analysis.

White, Ralph E.↗
NASA NTRS1989

Analytic theory for the determination of velocity and stability of bubbles in a Hele-Shaw cell. Part 1: Velocity selection

An asymptotic theory is presented for the determination of velocity and linear stability of a steady symmetric bubble in a Hele-Shaw cell for small surface tension. In the first part, the bubble velocity U relative to the fluid velocity at infinity is determined for small surface tension T by determining transcendentally small correction to the asymptotic series solution. It is found that for any relative bubble velocity U in the interval (U(c),2), solutions exist at a countably infinite set of values of T (which has zero as its limit point) corresponding to the different branches of bubble solutions. U(c) decreases monotonically from 2 to 1 as the bubble area increases from 0 to infinity. However, for a bubble of arbitrarily given size, as T approaches 0, solution exists on any given branch with relative bubble velocity U satisfying the relation 2-U = cT to the 2/3 power, where c depends on the branch but is independent of the bubble area. The analytical evidence further suggests that there are no solutions for U greater than 2. These results are in agreement with earlier analytical results for a finger. In Part 2, an analytic theory is presented for the determination of the linear stability of the bubble in the limit of zero surface tension. Only the solution branch corresponding to the largest possible U for given surface tension is found to be stable, while all the others are unstable, in accordance with earlier numerical results.

Tanveer, Saleh↗
NASA NTRS1989

The effect of density variations on elemental abundance ratios in gaseous nebulae

Using numerical analysis it is demonstrated that when there are changes in gas density within a nebulae various empirical methods for determining the electron density can give different results. Eleven different species are considered which have line pair ratios that are well-known electron density (Ne) diagnostic tools. In the presence of varying density, there is a progression in inferred values of Ne from N+ (122/204 microns) at the lowest to C(2+) (1906/1909 A) at the highest. For many of the 11 species there is a fixed order in the inferred density, while for others the order can change somewhat for different mixes of densities. When there are nonconstant density conditions, it is shown that systematic biases may occur in the empirical determination of chemical abundance ratios. Tabular material is presented that delineates the maximum bias that can occur in the determination of a particular abundance ratio in a two-component model.

Rubin, R. H.↗
NASA NTRS1990

Flux creep in Bi2Sr2CaCu2O8(sub +x) single crystals

The results of a magnetic study on a Bi2Sr2CaCu2O(8+x) single crystal are reported. Low field susceptibility (dc and ac), magnetization cycles and time dependent measurements were performed. With increasing the temperature the irreversible regime of the magnetization cycles is rapidly restricted to low fields, showing that the critical current J(sub c) becomes strongly field dependent well below T(sub c). At 2.4 K the critical current in zero field, determined from the remanent magnetization by using the Bean formula for the critical state, is J(sub c) = 2 10(exp 5) A/sq cm. The temperature dependence of J(sub c) is satisfactorily described by the phenomenological law J(sub c) = J(sub c) (0) (1 - T/T(sub c) (sup n), with n = 8. The time decay of the zero field cooled magnetization and of the remanent magnetization was studied at different temperatures for different magnetic fields. The time decay was found to be logarithmic in both cases, at least at low temperatures. At T = 4.2 K for a field of 10 kOe applied parallel to the c axis, the average pinning energy, determined by using the flux creep model, is U(sub o) = 0.010 eV.

Agostinelli, E.↗
NASA NTRS1990

Superconductivity in 2-2-3 Y2Ba2Cu3O(sub 8+ delta)

Researchers synthesized a new high T(sub c) 2-2-3 superconductor (Y2Ba2Cu3O8+delta) by a special preparation technique and characterized it by ac-susceptibility measurements. Diamagnetism and Meissner effect sets in at low fields and superconducting transition onsets at 90 K. The systematic investigation of the real and imaginary components of ac-susceptibility as a function of temperature and applied ac magnetic field reveals that the magnetic behavior is that of a granular type superconductor.

Joshi, H. H.↗
NASA NTRS1990

A complex permittivity and permeability measurement system for elevated temperatures

The three goals of this research include: (1) to fully develop a method to measure the permittivity and permeability of special materials as a function of frequency in the range of 2.6 to 18 GHz, and of temperatures in the range of 25 to 1100 C; (2) to assist LeRC in setting up an in-house system for the measurement of high-temperature permittivity and permeability; and (3) to measure the complex permittivity and permeability of special materials as a function of frequency and temperature to demonstrate the capability of the method. The method chosen for characterizing the materials relies on perturbation of a resonant cavity with a small volume of sample material. Different field configurations in the cavity can be used to separate electric and magnetic effects. The cavity consists of a section of rectangular waveguide terminated at each end of a vertical slot iris. The center of one wall is a small hole through which the sample is introduced.

Friederich, Paul↗
NASA NTRS1986

Long-chain carboxylic acids in pyrolysates of Green River kerogen

Long-chain fatty acids (C10-C32), as well as C14-C21 isoprenoid acids (except for C18), have been identified in anhydrous and hydrous pyrolyses products of Green River kerogen (200-400 degrees C, 2-1000 hr). These kerogen-released fatty acids are characterized by a strong even/odd predominance (CPI: 4.8-10.2) with a maximum at C16 followed by lesser amounts of C18 and C22 acids. This distribution is different from that of unbound and bound geolipids extracted from Green River shale. The unbound fatty acids show a weak even/odd predominance (CPI: 1.64) with a maximum at C14, and bound fatty acids display an even/odd predominance (CPI: 2.8) with maxima at C18 and C30. These results suggest that fatty acids were incorporated into kerogen during sedimentation and early diagenesis and were protected from microbial and chemical changes over geological periods of time. Total quantities of fatty acids produced during heating of the kerogen ranged from 0.71 to 3.2 mg/g kerogen. Highest concentrations were obtained when kerogen was heated with water for 100 hr at 300 degrees C. Generally, their amounts did not decrease under hydrous conditions with increase in temperature or heating time, suggesting that significant decarboxylation did not occur under the pyrolysis conditions used, although hydrocarbons were extensively generated.

Non-NASA Center↗
NASA NTRS1960

Factors Affecting the Ductility and Strength of NaCl Single Crystals Tested in Flexure

An experimental investigation has revealed that the initial deformation of NaCl single crystals is anelastic rather than Hookean. This anelastic deformation is manifested by a low slope foot in the load‐deflection curve. The magnitude of the foot is dictated by the pretreatment given the specimen. Treatments which increase or decrease the fresh dislocation density respectively increase or decrease the length of the initial anelastic foot. The order of increasing ductility and strength with specimen pretreatment was found to be (1) heated at 135 C, (2) as cleaved, (3) coated with silver, (4) heated at 135 C and then water polished, (5) water polished and then coated with silver, (6) water polished, (7) water polished and then heated at 135 C, (8) annealed at 700 C, and (9) annealed at 700 C and then water polished. The experimental results have been discussed in terms of the role played in deformation and fracture by surface cracks, grown‐in dislocations, and fresh dislocations.

Stearns, C. A.↗