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Spacecraft Cabin Atmospheric Major Constituent Monitoring Using Off-the-Shelf Techniques

Since the beginning of the crewed space exploration program, the National Aeronautics and Space Administration (NASA) recognized the need to monitor the composition of a spacecraft cabin atmosphere. Typically, major constituent monitoring has been limited to nitrogen, oxygen, carbon dioxide, and water vapor. For the International Space Station, mass spectroscopy was selected as the baseline technology for this task. Recently, new techniques for monitoring major atmospheric constituents have matured commercially making them viable for crewed spacecraft applications. These techniques have advantages over the mass spectroscopy and electrochemically-based instruments used on board the /SS and Shuttle. Fast laser diode oxygen analysis, solid-state infrared carbon dioxide detection, and thin-film capacitive humidity detection are among the emerging techniques. Representative instruments employing these techniques have been selected and tested to demonstrate their potential for crewed spacecraft applications. A summary of testing results is provided.

Perry, Jay L.

Performance Testing of a Photocatalytic Oxidation Module for Spacecraft Cabin Atmosphere Revitalization

Photocatalytic oxidation (PCO) is a candidate process technology for use in high volumetric flow rate trace contaminant control applications in sealed environments. The targeted application for PCO as applied to crewed spacecraft life support system architectures is summarized. Technical challenges characteristic of PCO are considered. Performance testing of a breadboard PCO reactor design for mineralizing polar organic compounds in a spacecraft cabin atmosphere is described. Test results are analyzed and compared to results reported in the literature for comparable PCO reactor designs.

Perry, Jay L.

Gas chromatography: Possible application of advanced instrumentation developed for solar system exploration to space station cabin atmospheres

Gas chromatography (GC) technology was developed for flight experiments in solar system exploration. The GC is a powerful analytical technique with simple devices separating individual components from complex mixtures to make very sensitive quantitative and qualitative measurements. It monitors samples containing mixtures of fixed gases and volatile organic molecules. The GC was used on the Viking mission in support of life detection experiments and on the Pioneer Venus Large Probe to determine the composition of the venusian atmosphere. A flight GC is under development to study the progress and extent of STS astronaut denitrogenation prior to extravehicular activity. Advanced flight GC concepts and systems for future solar system exploration are also studied. Studies include miniature ionization detectors and associated control systems capable of detecting from ppb up to 100% concentration levels. Further miniaturization is investigated using photolithography and controlled chemical etching in silicon wafers. Novel concepts such as ion mobility drift spectroscopy and multiplex gas chromatography are also developed for future flight experiments. These powerful analytical concepts and associated hardware are ideal for the monitoring of cabin atmospheres containing potentially dangerous volatile compounds.

Carle, G. C.

Investigation of the Ignition and Burning of Materials in Space Cabin Atmospheres. Part 1: Ignition and Burning of Material

An analytical study of the theory of ignition and burning of a plastic material immersed in an atmosphere of a space cabin which may be subjected to gravity force changes is considered. The hazardous condition in a space cabin environment where the changes of gravity may effect the combustion process is evaluated. The model considered the analysis of the coupled gas and solid phases and is based on the premise that material heating leads to the formation of pyrolysis gases from the decomposed solid which then react with the ambient oxidizer to further the combustion process. Moreover, free convection plays a dominant role in transporting these hot gases to the virgin material. A time-dependent study of the coupled gas-solid model as required for ignition processes with emphasis on the surface energy interchange of the gas and solid phases has been made. Detailed distribution of species composition and temperature patterns provide a spatial and time map of the evolving gases from the material combustion.

Lew, H. G.

Performance of Off-the-Shelf Technologies for Spacecraft Cabin Atmospheric Major Constituent Monitoring

Monitoring the atmospheric composition of a crewed spacecraft cabin is central to successfully expanding the breadth and depth of first-hand human knowledge and understanding of space. Highly reliable technologies must be identified and developed to monitor atmospheric composition. This will enable crewed space missions that last weeks, months, and eventually years. Atmospheric composition monitoring is a primary component of any environmental control and life support system. Instrumentation employed to monitor atmospheric composition must be inexpensive, simple, and lightweight and provide robust performance. Such a system will ensure an environment that promotes human safety and health, and that the environment can be maintained with a high degree of confidence. Key to this confidence is the capability for any technology to operate autonomously, with little intervention from the crew or mission control personnel. A study has been conducted using technologies that, with further development, may reach these goals.

Tatara, J. D.

Space-Cabin Atmospheres: Part II - Fire and Blast Hazards. A Literature Review

The rapid evolution of aircraft and, lately, space vehicles has brought with it the ever-increasing difficulty of designing for prevention of fires and explosions. The present-day sealed cabin with its limited work space, unusual atmospheric constituents, and lack of flexibility in emergency situations has brought new and ill-defined hazards into the picture. In the past, numerous data have been compiled on the fire and explosion characteristics of all things combustible. Unfortunately, much of the material is not pertinent to the actual operational problems in space. The confusion and controversy arising from attempts to evaluate the space-cabin fire problem appear to stem from past failure to compile the scattered data and to expose it to critical review and selection. In the compilation that follows, an attempt has been made to review the best available data that was deemed actually pertinent to the present problem. The effects of unusual atmospheres have been emphasized, but, as will soon be evident, other physical parameters also play a major role in determining the nature of the problem. Chapter 1 contains a discussion of pertinent definitions and theory. This is detailed only to the point of anticipating some of the problems of interpretation that may arise in other chapters of the report. Included in this chapter is speculation on the impact of unusual environmental conditions such as aerodynamic heating, reduced gravitational acceleration, and low ambient pressures. Chapter 2 covers flammable fabrics and carbonaceous solids; Chapter 3, specific fire hazards involving flammable liquids, vapors, and gases; and Chapter 4, electrical fires. Chapter 5 covers the fire, blast, and flash hazards from meteoroid penetration; and Chapter 6, the problems of fire prevention and extinguishment in space cabins. Chapter 7 reviews the factors of fire and blast hazards in selection of a space-cabin atmosphere.

Roth, Emanuel M.

Pulse-modulated dual-gas control subsystem for space cabin atmosphere

An atmosphere control subsystem (ACS) was developed for use in a closed manned cabin, such as the Space Shuttle Orbiter. This subsystem uses the Perkin Elmer mass spectrometer for continuous measurement of major atmospheric constituents (H2, H2O, N2, O2, and CO2). The O2 and N2 analog signals are used as inputs to the controller, which produces a pulse-frequency-modulated output to operate the N2 gas admission solenoid valve and an on-off signal to operate the O2 valve. The proportional controller characteristic results in improved control accuracy as compared with previously used on-off controllers having significant dead-band. A 60-day evaluation test was performed on the ACS during which operation was measured at various values of control setpoint and simulated cabin leakage.

Jackson, J. K.

The shuttle orbiter cabin atmospheric revitalization systems

The Orbiter Atmospheric Revitalization Subsystem (ARS) and Pressure Control Subsystem (ARPCS) are designed to provide the flight crew and passengers with a pressurized environment that is both life-supporting and within crew comfort limitations. The ARPCS is a two-gas (oxygen-nitrogen) system that obtains oxygen from the Power Reactant Supply and Distribution (PRSD) subsystem and nitrogen from the nitrogen storage tanks. The ARS includes the water coolant loop; cabin CO2, odor, humidity and temperature control; and avionics cooling. Baseline ARPCS and ARS changes since 1973 include removal of the sublimator from the water coolant loop, an increase in flowrates to accommodate increased loads, elimination of the avionics bay isolation from the cabin, a decision to have an inert vehicle during ferry flight, elimination of coldwall tubing around windows and hatches, and deletion of the cabin heater.

Ward, C. F.

Investigation of the Ignition and Burning of Materials in Space Cabin Atmospheres. Part 2: Ignition of a Combustible Mixture by a Hot Body with the Effects of Gravity

The ignition of a combustible gas mixture by a hot cylinder under the effect of a gravity field for steady state conditions is examined. For this purpose a horizontal cylinder is considered with gravity as a parameter together with a finite chemical reacting flow generated by free convection with the additional effect of diffusion. Both mass transfer and zero mass transfer cases are considered. By defining an ignition criterion the surface temperature and species are obtained from the analysis as a function of the gravity field. It is supposed that at the point of ignition the heat evolved in the gas is sufficiently high to attain a sustained combustion without any energy from the hot cylinder.

Lew, H. G.

Application of cabin atmosphere monitors to rapid screening of breath samples for the early detection of disease states

Analysis of human breath is a nonintrusive method to monitor both endogenous and exogenous chemicals found in the body. Several technologies were investigated and developed which are applicable to monitoring some organic molecules important in both physiological and pathological states. Two methods were developed for enriching the organic molecules exhaled in the breath of humans. One device is based on a respiratory face mask fitted with a polyethylene foam wafer; while the other device is a cryogenic trap utilizing an organic solvent. Using laboratory workers as controls, two organic molecules which occurred in the enriched breath of all subjects were tentatively identified as lactic acid and contisol. Both of these substances occurred in breath in sufficient amounts that the conventional method of gas-liquid chromatography was adequate for detection and quantification. To detect and quantitate trace amounts of chemicals in breath, another type of technology was developed in which analysis was conducted using high pressure liquid chromatography and mass spectrometry.

Valentine, J. L.