Search NASA⌕ Search

SEARCH · Search NASA

Results for “CHEMILUMINESCENCE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Absolute rate constant for the O plus NO chemiluminescence in the near infrared

Infrared chemiluminescence from the process O + NO (+M) NO2 + hv (+M) has been studied between 1.3 and 4.1 micrometer. The wavelength dependence of the continuum between 1.3 and 3.3 micrometer is in fair agreement with previous studies and the measured radiative rate constant at 1.51 micrometer establishes the NO-O glow in this spectral range as a secondary emission standard. Comparison with previous studies of the visible region of the glow implies that the overall radiative rate constant lies in the range (9.4 to 11.2) x 10 to the minus 17 power cu cm sec/1. In the region 3.3 to 4.1 micrometer, the previously observed broad band, peaking at 3.7 micrometer, shows a complex kinetic dependence on O and M.

Golde, M. F.↗
NASA NTRS1973

Feasibility study for rocket ozone measurements in the 50 to 80 km region using a chemiluminescent technique

A study has been conducted to determine the feasibility of increasing sensitivity for ozone detection. The detection technique employed is the chemiluminescent reaction of ozone with a rhodamine-B impregnated disk. Previously achieved sensitivities are required to be increased by a factor of about 20 to permit measurements at altitudes of 80 km. Sensitivity was increased by using a more sensitive photomultiplier tube, by increasing the gas velocity past the disk, by different disk preparation techniques, and by using reflective coatings in the disk chamber and on the uncoated side of the glass disk. Reflective coatings provided the largest sensitivity increase. The sum of all these changes was a sensitivity increased by an estimated factor of 70, more than sufficient to permit measurement of ambient ozone concentrations at altitudes of 80 km.

Goodman, P.↗
NASA NTRS1975

Interference of oxygen, carbon dioxide, and water vapor on the analysis for oxides of nitrogen by chemiluminescence

The interference of small concentrations (less than 4 percent by volume) of oxygen, carbon dioxide, and water vapor on the analysis for oxides of nitrogen by chemiluminescence was measured. The sample gas consisted primarily of nitrogen, with less than 100 parts per million concentration of nitric oxide, and with small concentrations of oxygen, carbon dioxide, and water vapor added. Results obtained under these conditions indicate that although oxygen does not measurably affect the analysis for nitric oxide, the presence of carbon dioxide and water vapor causes the indicated nitric oxide concentration to be too low. An interference factor - defined as the percentage change in indicated nitric oxide concentration (relative to the true nitric oxide concentration) divided by the percent interfering gas present - was determined for carbon dioxide to be -0.60 + or - 0.04 and for water vapor to be -2.1 + or - 0.3.

Maahs, H. G.↗
NASA NTRS1976

Chemiluminescent prediction of service life

Technique can be used to predict polymer degradation under actual expected-use conditions, without imposing artificial conditions. Smooth or linear correlations are obtained between chemiluminescence and physical properties of purified polymer gums.

Hassell, J. A.↗
NASA NTRS1975

Analytical Applications of Bioluminescence and Chemiluminescence

Bioluminescence and chemiluminescence studies were used to measure the amount of adenosine triphosphate and therefore the amount of energy available. Firefly luciferase - luciferin enzyme system was emphasized. Photometer designs are also considered.

Chappelle, E. W.↗
NASA NTRS1976

NO sub X destruction by CO in NO sub X to NO converters of chemiluminescent NO analyzers

An instrument modification for chemiluminescent NO - NOx analyzers was developed which minimizes the NOx destruction in the NOx to NO converters of NO analyzers due to high concentrations of CO. This mechanism causes the NO analyzers to indicate incorrect NOx concentrations when the analyzers are operated in the NOx analysis mode. The modification is applicable to analyzers in which the detection chamber is evacuated.

Summers, R. L.↗
NASA NTRS1976

The direct measurement of nitric oxide concentration in the upper atmosphere by a rocket-borne chemiluminescent detector

The paper describes a rocket-borne chemiluminescent NO detector and gives some NO mixing ratios in the altitude range from 42 to 60 km calculated on the basis of data obtained from this instrument. The mixing ratios were calculated from the observed counting rates on the assumption of a standard atmospheric pressure profile and the known vehicle velocity profile. The NO mixing ratio decreased from 4.2 billionths at 42 km to 2.2 billionths at 50 km, and then increased to 5.2 billionths at 60 km. The results are deemed accurate to within 20% and may be viewed as upper bounds on nitric oxide concentration in the absence of any NO loss processes.

Mason, C. J.↗
NASA NTRS1977

Simplified ozone detection by chemiluminescence

Ozone is detected by film coated with solid, such as rubrene, that reacts with ozone to degree proportional to concentration in sample gas. Gas flow is stopped, and film is heated to produce light (chemiluminescence) in proportion to amount of reacted material on sensor.

Conway, E. J.↗
NASA NTRS1978

Chemiluminescence and bioluminescence microbe detection

Automated biosensors for online use with NASA Water Monitoring System employs bioluminescence and chemiluminescence techniques to rapidly measure microbe contamination of water samples. System eliminates standard laboratory procedures requiring time duration of 24 hours or longer.

Taylor, R. E.↗
NASA NTRS1979

NO2 measurement by chemiluminescence

Compact device monitors specific chemiluminescent reaction of heated solid material such as 3,5 diaminobezoic or polyvinyl alcohol after contact with gas sample to detect and quantify nitrogen dioxide concentration.

Conway, E. J.↗
NASA NTRS1978

Nitric oxide mixing ratios near the stratopause measured by a rocket-borne chemiluminescent detector

The nitric oxide mixing ratio between 43 km and 61 km was directly measured with a rocket-borne chemiluminescent detector. The ozone-generated background signal was monitored throughout the flight (in 1976) by periodically interrupting the atmospheric sample flow with a pure-N2 bias-supply gas. An error analysis of the 1976 results showed the need to correct results obtained from an earlier flight (in 1975). The corrected 1975 results are reported and compared with the 1976 results.

Horvath, J. J.↗
NASA NTRS1986

A preliminary study of ester oxidation on an aluminum surface using chemiluminescence

The oxidation characteristics of a pure ester (trimethyolpropane triheptanoate) were studied by using a chemiluminescence technique. Tests were run in a thin-film micro-oxidation apparatus with an aluminum alloy catalyst. Conditions included a pure oxygen atmosphere and a temperature range of 176 to 206 C. Results indicated that oxidation of the ester (containing 10 to the minus 3 power M diphenylanthracene as an intensifier) was accompanied by emission of light. The maximum intensity of light emission (I sub max) was a function of the amount of ester, the concentration of intensifier, and the test temperature. The induction period or the time to reach one-half of maximum intensity (t sub 1/2) was an inverse function of test temperature. Decreases in light emission at the later stages of a test were caused by depletion of the intensifier.

Jones, W. R., Jr.↗