Research and development study related to the synthesis of formaldehyde from CO2 and H2 Quarterly progress report, May - Jul. 1967
Synthesis of formaldehyde by oxidation of methane
Budininkas, P.↗
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Research and Development Study Related to the Synthesis of Formaldehyde from CO2 and H2 Quarterly Progress Report, Feb. - Apr. 1967
Oxidation of methane to formaldehyde in reactors coated with potassium tetraborate
Budininkas, P.↗
The NASA high-power carbon dioxide laser - A versatile tool for laser applications
The NASA Lewis Research Center has designed and fabricated a closed-cycle, continuous wave (CW), carbon dioxide (CO2) high-power laser to support research for the identification and evaluation of possible high-power laser applications. The device is designed to generate up to 70 kW of laser power in annular-shape beams from 1 to 9 cm in diameter. Electric discharge, either self-sustained or electron-beam-sustained, is used for excitation. This laser facility can be used in two ways. First, it provides a versatile tool on which research can be performed to advance the state-of-the-art technology of high-power CO2 lasers in such areas as electric excitation, laser chemistry, and quality of output beams, all of which are important whether the laser application is government or industry oriented. Second, the facility provides a well-defined, continuous wave beam for various application experiments, such as propulsion, power conversion, and materials processing.
Lancashire, R. B.↗
Ames Air Revitalization
This is an informal presentation presented to the University of Colorado, Boulder Bioastronautics group seminar. It highlights the key focal areas of the Air Revitalization Group research over the past year, including progress on the CO2 Removal and Compression System, testing of CDRA drying bed configurations, and adsorption research.
Silica Gel↗
Design of Control Software for a High-Speed Coherent Doppler Lidar System for CO2 Measurement
The design of the software for a 2-micron coherent high-speed Doppler lidar system for CO2 measurement at NASA Langley Research Center is discussed in this paper. The specific strategy and design topology to meet the requirements of the system are reviewed. In order to attain the high-speed digitization of the different types of signals to be sampled on multiple channels, a carefully planned design of the control software is imperative. Samples of digitized data from each channel and their roles in data analysis post processing are also presented. Several challenges of extremely-fast, high volume data acquisition are discussed. The software must check the validity of each lidar return as well as other monitoring channel data in real-time. For such high-speed data acquisition systems, the software is a key component that enables the entire scope of CO2 measurement studies using commercially available system components.
Vanvalkenburg, Randal L.↗
LaRC-developed catalysts for CO2 lasers
Pulsed CO2 lasers have many remote sensing applications from space, airborne, and ground platforms. The NASA Laser Atmospheric Wind Sounder (LAWS) system will be designed to measure wind velocities from polar earth orbit for a period of up to three years. Accordingly, this and other applications require a closed-cycle pulsed CO2 laser which necessitates the use of an efficient CO-O2 recombination catalyst for these dissociation products which otherwise would degrade the laser operation. The required catalyst must not only operate at low temperatures but also must operate efficiently for long time periods. The research effort at NASA LaRC has centered around development and testing of CO oxidation catalysts for closed-cycle, pulsed, common and rare-isotope CO2 lasers. Researchers examined available commercial catalysts both in a laser and under simulated closed-cycle laser conditions with efforts aimed toward a thorough understanding of the fundamental catalytic reaction. These data were used to design and synthesize new catalyst compositions to better meet the catalyst requirements for closed-cycle pulsed CO2 lasers. Syntheses and test results for catalysts developed at Langley Research Center which have significantly better long-term decay characteristics than previously available catalysts and at the same time operate quite well under lower temperature conditions are discussed.
Upchurch, Billy T.↗
2-Micron Laser Transmitter for Coherent CO2 DIAL Measurement
Carbon dioxide (CO2) has been recognized as one of the most important greenhouse gases. It is essential for the study of global warming to accurately measure the CO2 concentration in the atmosphere and continuously record its variation. A high repetition rate, highly efficient, Q-switched 2-micron laser system as the transmitter of a coherent differential absorption lidar for CO2 measurement has been developed in NASA Langley Research Center. This laser system is capable of making a vertical profiling of CO2 from ground and column measurement of CO2 from air and space-borne platform. The transmitter is a master-slave laser system. The master laser operates in a single frequency, either on-line or off-line of a selected CO2 absorption line. The slave laser is a Q-switched ring-cavity Ho:YLF laser which is pumped by a Tm:fiber laser. The repetition rate can be adjusted from a few hundred Hz to 10 kHz. The injection seeding success rate is from 99.4% to 99.95%. For 1 kHz operation, the output pulse energy is 5.5mJ with the pulse length of ~50 ns. The optical-to-optical efficiency is 39% when the pump power is 14.5W. A Ho:YLF laser operating in the range of 2.05 micrometers can be tuned over several characteristic lines of CO2 absorption. Experimentally, a diode pumped Ho:Tm:YLF laser has been successfully used as the transmitter of coherent differential absorption lidar for the measurement of CO2 with a repetition rate of 5 Hz and pulse energy of 75 mJ. For coherent detection, high repetition rate is required for speckle averaging to obtain highly precise measurements. However, a diode pumped Ho:Tm:YLF laser can not operate in high repetition rate due to the large heat loading and up-conversion. A Tm:fiber laser pumped Ho:YLF laser with low heat loading can operate in high repetition rate. A theoretical model has been established to simulate the performance of Tm:fiber laser pumped Ho:YLF lasers. For continuous wave (CW) operation, high pump intensity with small beam size is suitable for high efficiency. For Q-switched operation, the optimal energy extraction relies on the pump intensity, pump volume, and pump duration which is inversely proportion to the repetition rate. CW and Q-switched Ho:YLF lasers with different linear cavity configurations have been designed and demonstrated for a 30 W Tm:fiber pump laser. The CW Ho laser slope efficiency and optical-to-optical efficiencies reach 65% and 55%, respectively. The pulsed laser efficiency depends on the repetition rate. For 1 kHz operation, the optical-to-optical efficiency is 39% when the pump power is 14.5W. Currently, the injection seeding success rate is between 99.4% and 99.95%. After a ten thousand pulses, the standard deviation of the laser frequency jitter is about 3 MHz. It meets the requirements of highly precise CO2 concentration measurement. In conclusion, an injection seeded, high repetition rate, Q-switched Ho:YLF laser has been developed for a coherent CO2 differential absorption lidar. This master-slave laser system has high optical-to-optical efficiency and seeding success rate. It can potentially meet the requirements of the coherent detection of CO2 concentration by a differential absorption lidar technique.
Singh, Upendra N.↗
Ice-cloud depolarization of backscatter for CO2 and other infrared lidars
The depolarization of backscatter from ice particles at the CO2 lidar wavelength of 10.59 microns was investigated through field measurements, with simultanous depolarization measurements taken at 0.6943 micron for comparison. The depolarization ratio at the infrared wavelength was usually at or below the lidar's sensitivity limit of 0.01, which is dramatically smaller than the typical 0.5 linear depolarization ratio for short-wave lidars. This behavior is explained by the strong absorption of ice at the infrared wavelength. Depolarization measurements at a 10.59-micron wavelength cannot discriminate between ice and water clouds in the manner of short-wave lidars. A possibility exists for more prominent depolarization at shorter CO2 lidar wavelengths, but additional research is required. Depolarization at the 2.09-micron wavelength is predicted to be substantial and useful for hydrometeor observations.
Eberhard, Wynn L.↗
Satellite Contributions to Global Change Studies
By providing a global view with a level playing field (no region missed because of unfavorable surface conditions or political boundaries), satellites have made major contributions to improved monitoring and understanding of our constantly changing planet. The global view has allowed surprising realizations like the relative sparsity of lightning strikes over oceans and the large-scale undulations on the massive Antarctic ice sheet. It has allowed the tracking of all sorts of phenomena, including aerosols, both natural and anthropogenic, as they move with the atmospheric circulation and impact weather and human health. But probably nothing that the global view allows is more important in the long term than its provision. of unbiased data sets to address the issue of global change, considered by many to be among the most important issues facing humankind today. With satellites we can monitor atmospheric temperatures at all latitudes and longitudes, and obtain a global average that lessens the likelihood of becoming endlessly mired in the confusions brought about by the certainty of regional differences. With satellites we can monitor greenhouse gases such as CO2 not just above individual research stations but around the globe. With satellites we can monitor the polar sea ice covers, as we have done since the late 1970s, determining and quantifying the significant reduction in Arctic sea ice and the slight growth in Antarctic sea ice over that period, With satellites we can map the full extent and changes in the Antarctic stratospheric ozone depletions that were first identified from using a single ground station; and through satellite data we have witnessed from afar land surface changes brought about by humans both intentionally, as with wide-scale deforestation, and unintentionally, as with the decay of the Aral Sea. The satellite data are far from sufficient for all that we need in order to understand the global system and forecast its changes, as we also need sophisticated climate models, in situ process studies, and data sets that extend back well before the introduction of satellite technology. Nonetheless, the repetitive, global view provided by satellites is contributing in a major way to our improved recognition of how the Earth im changing, a recognition that is none too soon in view of the magnitude of the impacts that humans can now have.
Parkinson, Claire L.↗
Applied Meteorology Unit (AMU) Quarterly Report
By providing a global view with a level playing field (no region missed because of unfavorable surface conditions or political boundaries), satellites have made major contributions to improved monitoring and understanding of our constantly changing planet. The global view has allowed surprising realizations like the relative sparsity of lightning strikes over oceans and the large-scale undulations on the massive Antarctic ice sheet. It has allowed the tracking of all sorts of phenomena, including aerosols, both natural and anthropogenic,as they move with the atmospheric circulation and impact weather and human health. But probably nothing that the global view allows is more important in the long term than its provision of unbiased data sets to address the issue of global change, considered by many to be among the most important issues facing humankind today. With satellites we can monitor atmospheric temperatures at all latitudes and longitudes, and obtain a global average that lessens the likelihood of becoming endlessly mired in the confusions brought about by the certainty of regional differences. With satellites we can monitor greenhouse gases such as CO2 not just above individual research stations but around the globe. With satellites we can monitor the polar sea ice covers, as we have done since the late 1970s, determining and quantifying the significant reduction in Arctic sea ice and the slight growth in Antarctic sea ice over that period. With satellites we can map the full extent and changes in the Antarctic stratospheric ozone depletions that were first identified from a single ground station; and through satellite data we have witnessed from afar land surface changes brought about by humans both intentionally, as with wide-scale deforestation, and unintentionally, as with the decay of the Aral Sea. The satellite data are far from sufficient for all that we need in order to understand the global system and forecast its changes, as we also need sophisticated climate models, in situ process studies, and data sets that extend back well before the introduction of satellite technology. Nuomthc)cmm, the repetitive, global view provided by satellites is contributing in a major way to our improved recognition of how the Earth is changing, a recognition that is none too soon in view of the magnitude of the impacts that humans can now have.
Bauman, William↗
Visual Impairment and Intracranial Hypertension: An Emerging Spaceflight Risk
What is the risk? Given that astronauts exposed to microgravity experience a cephalad fluid shift, and that both symptomatic and asymptomatic astronauts have exhibited optic nerve sheath edema on MRI, there is a high probability that all astronauts have some degree of increased intracranial pressure (ICP; intracranial hypertension), and that those susceptible (via eye architecture, anatomy, narrow optic disc) have a high likelihood of developing papilledema (optic disc edema, globe flattening), choroidal folds, and/or hyperopic shifts and that the degree of edema may determine long-term or permanent vision impairment or loss. Back to back panels on this topic have been developed to address this emerging risk. The first panel will focus on the 6 clinical cases with emphasis on ophthalmic findings and imaging techniques used pre-, in-, and post-flight. The second panel will discuss the operational mitigation and medical requirements, the potential role of CO2 on ISS, and the research approach being developed. In total these back to back panels will explore what is known about this risk, what has been done immediately to address it, and how an integrated research model is being developed.
Fogarty, Jennifer A.↗
NASA Exploration Systems & Habitation (X-Hab)Academic Innovation Challenge 2020: Microgravity Gas/Liquid Separator for the CO2 Revitalization System Final Report
This report outlines the efforts of UNT X-Hab Team on a project titled, Microgravity Gas/Liquid Separator for the CO2 Revitalization System. The project is executed as a senior design project during academic year 2019-2020. The X-Hab 2020 Academic Innovation Challenge has selected eleven senior design teams from colleges across the US to demonstrate working prototypes for exploration systems and habitation. UNT has been tasked with the creation of a gas-liquid separator for an air revitalization system. Air revitalization technology has been used to support spaceflight by removing CO2 from enclosed systems in order to maintain breathable air. Solid sorbents such as zeolites or lithium hydroxide have been used in the past for these systems but are difficult to handle in microgravity environments and require a large amount of energy. This challenge aims to demonstrate vortex phase separator (VPS) technology for removing H2O from a CO2 stream. However, VPS technology also has the capability of using liquid sorbents for removing CO2 from an air stream. Further research could be done on liquid sorbents, such as liquid amine, in use with VPS systems. This would potentially be an alternative technology in replacing use of solid sorbents in CO2 removal systems. In 2019, NASA proposed a design that uses a gas/liquid contactor to allow for efficient contact between the two fluid phase. This was integrated into an overall CO2 removal system. The subsystems for gas-liquid separation and storage in NASA’s previous models for CO2 removal system could be replaced with a VPS. Innovative vortex separator technology is expected to allow for high throughput flow and highly efficient CO2 removal compared to other gas-liquid separation technologies. VPS relies on centripetal driven buoyancy forces to form a gas-liquid vortex within a fixed, right circular cylinder. The gas stream enters the separator through a tangential nozzle and breaks into very small bubbles (<<1 mm) resulting in a very large contact surface area for interaction with the liquid stream via energy and mass exchange. VPS technology can handle mismatches in inlet and outlet flow rates and system volume changes through the range of liquid thickness held in the separator (i.e., buffering and accumulating capability), and requires low pressure differences (<5-10 in H2O in most cases) for operation. The X-Hab 2020 team leverages these characteristics to investigate VPS technology as an alternative CO2 removal technology.
Alyssa Sarvadi↗
Enhanced Climatic Warming in the Tibetan Plateau Due to Double CO2: A Model Study
The NCAR (National Center for Atmospheric Research) regional climate model (RegCM2) with time-dependent lateral meteorological fields provided by a 130-year transient increasing CO2 simulation of the NCAR Climate System Model (CSM) has been used to investigate the mechanism of enhanced ground temperature warming over the TP (Tibetan Plateau). From our model results, a remarkable tendency of warming increasing with elevation is found for the winter season, and elevation dependency of warming is not clearly recognized in the summer season. This simulated feature of elevation dependency of ground temperature is consistent with observations. Based on an analysis of surface energy budget, the short wave solar radiation absorbed at the surface plus downward long wave flux reaching the surface shows a strong elevation dependency, and is mostly responsible for enhanced surface warming over the TP. At lower elevations, the precipitation forced by topography is enhanced due to an increase in water vapor supply resulted from a warming in the atmosphere induced by doubling CO2. This precipitation enhancement must be associated with an increase in clouds, which results in a decline in solar flux reaching surface. At higher elevations, large snow depletion is detected in the 2xCO2run. It leads to a decrease in albedo, therefore more solar flux is absorbed at the surface. On the other hand, much more uniform increase in downward long wave flux reaching the surface is found. The combination of these effects (i.e. decrease in solar flux at lower elevations, increase in solar flux at higher elevation and more uniform increase in downward long wave flux) results in elevation dependency of enhanced ground temperature warming over the TP.
Chen, Baode↗
Development of a Pulsed 2-Micron Integrated Path Differential Absorption Lidar for CO2 Measurement
Atmospheric carbon dioxide (CO2) is an important greenhouse gas that significantly contributes to the carbon cycle and global radiation budget on Earth. Active remote sensing of CO2 is important to address several limitations that contend with passive sensors. A 2-micron double-pulsed, Integrated Path Differential Absorption (IPDA) lidar instrument for ground and airborne atmospheric CO2 concentration measurements via direct detection method is being developed at NASA Langley Research Center. This active remote sensing instrument will provide an alternate approach of measuring atmospheric CO2 concentrations with significant advantages. A high energy pulsed approach provides high-precision measurement capability by having high signal-to-noise ratio level and unambiguously eliminates the contamination from aerosols and clouds that can bias the IPDA measurement. Commercial, on the shelf, components are implemented for the detection system. Instrument integration will be presented in this paper as well as a background for CO2 measurement at NASA Langley research Center
Singh, Upendra N.↗
Is CO2 ice permanent?
Carbon dioxide ice has been inferred to exist at the south pole in summertime, but Earth based measurements in 1969 of water vapor in the Martian atmosphere suggest that all CO2 ice sublined from the southern polar cap and exposed underlying water ice. This implies that the observed summertime CO2 ice is of recent origin. It appears possible to construct an energy balance model that maintains seasonal CO2 ice at the south pole year round and still reasonably simulates the polar cap regression and atmospheric pressure data. This implies that the CO2 ice observed in the summertime south polar cap could be seasonal in origin, and that minor changes in climate could cause CO2 ice to completely vanish, as would appear to have happened in 1969. However, further research remains before it is certain whether the CO2 ice observed in the summertime south polar cap is seasonal or is part of a permanent reservoir.
Lindner, Bernhard Lee↗
Development of Thermostable Carbonic Anhydrases Using Structure-Guided Recombination for Use in CO2 Removal Systems on Spacecraft
Carbon capture and storage has been a research area of great interest in recent years as a method for mitigation of CO2 emissions, due to the effects of climate change. The development of technologies for the efficient capture of CO2 are also of great interest for human spaceflight applications. One of the most promising technologies in this area is CO2 scrubbing using liquid amines, unfortunately, liquid amines with low heats of desorption tend to have slow CO2 binding kinetics. One potential solution to this problem is to use the enzyme carbonic anhydrase (CA) to enhance the kinetics of CO2 binding to liquid amines, allowing the overall process to be more energy efficient. Interest in using carbonic anhydrase as a biocatalyst has led to a number of efforts to improve the thermostability and solvent tolerance of several distinct carbonic anhydrase enzymes. In the work described here, we screened through a diverse set of natural carbonic anhydrases to identify candidates for protein engineering aimed at increased stability and activity in various liquid amines. We then used SCHEMA structure-guided recombination to develop a set of chimeric carbonic anhydrases with high thermostability and activity. These chimeras were used as the starting points for further protein engineering work targeting activity in liquid amine systems. Our ultimate goal is to test the engineered enzymes in a liquid amine system for cabin air revitalization on ISS or other spacecraft.
Life Support, Carbon dioxide, Carbonic anhydrase, ↗
Advanced CO2 Removal Technology Development
The Advanced CO2 Removal Technical Task Agreement covers three active areas of research and development. These include a study of the economic viability of a hybrid membrane/adsorption CO2 removal system, sorbent materials development, and construction of a database of adsorption properties of important fixed gases on several adsorbent material that may be used in CO2 removal systems. The membrane/adsorption CO2 removal system was proposed as a possible way to reduce the energy consumption of the four-bed molecular sieve system now in use. Much of the energy used by the 4BMS is used to desorb water removed in the device s desiccant beds. These beds might be replaced by a desiccating membrane that moves the water from [he incoming stream directly into the outlet stream. The approach may allow the CO2 removal beds to operate at a lower temperature. A comparison between models of the 4BMS and hybrid systems is underway at Vanderbilt University. NASA Ames Research Center has been investigating a Ag-exchanged zeolites as a possible improvement over currently used Ca and Na zeolites for CO2 removal. Silver ions will complex with n:-bonds in hydrocarbons such as ethylene, giving remarkably improved selectivity for adsorption of those materials. Bonds with n: character are also present in carbon oxides. NASA Ames is also continuing to build a database for adsorption isotherms of CO2, N2, O2, CH4, and Ar on a variety of sorbents. This information is useful for analysis of existing hardware and design of new processes.
Finn, John E.↗
Wheat response to CO2 enrichment: CO2 exchanges transpiration and mineral uptakes
When simulating canopies planted in varied densities, researchers were able to demonstrate that increase of dry matter production by enhancing CO2 quickly becomes independant of increase of leaf area, especially above leaf area index of 2; dry matter gain results mainly from photosynthesis stimulation per unit of surface (primary CO2 effect). When crop density is low (the plants remaining alone a longer time), the effects of increasing leaf surface (tillering, leaf elongation here, branching for other plants etc.) was noticeable and dry matter simulation factor reached 1.65. This area effect decreased when canopy was closed in, as the effect of different surfaces no longer worked. The stimulation of photosynthesis reached to the primary CO2 effect. The accumulation in dry matter which was fast during that phase made the original weight advantage more and more neglectible. Comparison with short term measurements showed that first order long term effect of CO2 in wheat is predictible with short term experiment, from the effect of CO2 on photosynthesis measured on reference sample.
Andre, M.↗