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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

The breakdown of both strange metal and superconducting states at a pressure-induced quantum critical point in iron-pnictide superconductors

Here we report the first observation of the concurrent breakdown of the strange metal (SM) normal state and superconductivity at a pressure-induced quantum critical point in Ca 10 (Pt 4 As 8 )((Fe 0.97 Pt 0.03 ) 2 As 2 ) 5 superconductor. We find that, upon suppressing the superconducting state, the power exponent (α) changes from 1 to 2, and the slope of the temperature-linear resistivity per FeAs layer (A $\Box$ ) gradually diminishes. At a critical pressure, A $\Box$ and superconducting transition temperature (T c ) go to zero concurrently, where a quantum phase transition from a superconducting state with a SM normal state to a non-superconducting Fermi liquid state occurs. Scaling analysis reveals that the change of A $\Box$ with T c obeys the relation of T c ~ (A $\Box$ ) 0.5 , similar to what is seen in other chemically doped unconventional superconductors. These results suggest that there is a simple but powerful organizational principle of connecting the SM normal state with the high-T c superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Pressure dependence of antiferromagnetic and superconducting phases in U 2 Rh 1–x Pt x C 2

In this work, we report temperature (T)- and pressure (P)-dependent resistivity measurements on the isostructural compounds U 2 Rh 1–x Pt x C 2 (x = 0, 0.5, and 0.9) from which we construct a T–P–x phase diagram. Compounds with x = 0 and x = 0.5 are antiferromagnets below 22.1 and 9.4 K, respectively, and their Néel temperature (T N ) decreases under applied pressure. For x = 0, the critical pressure P c required to suppress T N to zero temperature is projected to be about 8.8 GPa, but P c for x = 0.5 is between 1.6 and 2.1 GPa. At atmospheric pressure, increasing Pt concentration in U 2 Rh (1–x) Pt x C 2 tunes magnetic transition temperatures to zero at a critical value of x c ≈ 0.7, and, consequently, we surmise the existence of a quantum-phase boundary in the P–x plane at T = 0 K that extends from (P = 0, x = xc) to (P c ≈ 8.8 GPa, x = 0). For x = 0.9, superconductivity appears at T c = 1.09 K , which decreases at a rate of ≈ –1 K/GPa that is nearly twice that found for U 2 PtC 2 whose T c is 1.47 K. Together, these results indicate that domes of magnetism and superconductivity formed with T–P–x variations are detached and that the two broken symmetries are independent of each other. Fluctuations in average composition produce rare regions that play an important role in determining physical properties of materials with noninteger x.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2013

Estimating the Collapse Pressure of an Inflatable Aerodynamic Decelerator

The collapse pressure of an inflatable membrane is the minimum differential pressure which will sustain a specific desired shape under an applied load. In this paper, we present a method for estimating the collapse pressure of a tension-cone inflatable aerodynamic decelerator (IAD) that is subject to a static aerodynamic load. The IAD surface is modeled as an elastic membrane. For a given aerodynamic load and sufficiently high torus differential pressure, the IAD assumes a stable axisymmetric equilibrium shape. When the torus pressure is reduced sufficiently, the symmetric equilibrium state becomes unstable and we define this instance to be the critical pressure Pcr. In this paper, we will compare our predicted critical torus pressure with the corresponding observed torus collapse pressure (OTCP) for fifteen tests that were conducted by the third author and his collaborators at the NASA Glenn Research Center 10x10 Supersonic Wind Tunnel in April 2008. One of the difficulties with these types of comparisons is establishing the instance of torus collapse and determining the OTCP from quantities measured during the experiment. In many cases, torus collapse is gradual and the OTCP is not well-defined. However, in eight of the fifteen wind tunnel tests where the OTCP is well-defined, we find that the average of the relative differences (Pcr - OTCP/Pcr) was 8.9%. For completeness, we will also discuss the seven tests where the observed torus collapse pressure is not well-defined.

Baginski, Frank E.↗
DOE OSTI2025

Charge-density-wave quantum critical point under pressure in 2 H -TaSe 2

The presence of a quantum-critical point (QCP) at which a nearby ordered phase is suppressed to zero temperature is often invoked to explain emergent quantum phases, e.g. superconductivity. Yet, identifying a QCP and establishing its correlation with superconductivity remains challenging. Materials featuring charge-density-wave (CDW) order and superconductivity offer a clear scenario as both states can be associated with electron-phonon coupling. Here, we uncover a CDW-QCP and demonstrate its interrelation with superconductivity in the prototypical transition-metal dichalcogenide 2 H -TaSe 2 . We determine the evolution of the CDW state up to and beyond its suppression at the critical pressure p c = 19.9(1) GPa by means of X-ray diffraction and inelastic X-ray scattering measurements providing a full crystallographic refinement of the commensurate CDW superstructure. The pressure-induced CDW-QCP in close vicinity to the maximum superconducting transition temperature. Ab-initio lattice dynamical calculations corroborate that 2 H -TaSe 2 features order-parameter fluctuation enhanced superconductivity and can serve as a paradigm to investigate superconductivity near a CDW-QCP.

critical phenomena↗
NASA NTRS1992

What determines the volume of the oceans?

The volume of earth's oceans may be determined by a dynamic mechanism involving exchange of water between the crust and the mantle. Fast-spreading mid-ocean ridges are currently submerged to a depth at which the pressure is close to the critical pressure for seawater. This ensures optimal convective heat transport and, hence, maximal penetration of hydrothermal circulation along the ridge axes. The oceanic crust is hydrated to a depth of a kilometer or more and can therefore carry a substantial flux of water to the upper mantle when it is subducted. The current ingassing rate of water by this process is probably at least sufficient to balance the outgassing rate. If the oceans were shallower, as they may have been in the distant past, convective heat transport would be reduced and the depth of hydrothermal penetration and crustal hydration would decrease. Outgassing would exceed ingassing and ocean volume would increase. The system is self-stabilizing as long as the depth of the oceans does not exceed its present value. This mechanism could explain why continental freeboard has remained approximately constant since the Archean despite probable increases in continental area.

Kasting, James F.↗
NASA NTRS2020

High Pressure Transcritical Combustion (HPTC Combustion)

Combustion is the predominant source of the energy in the US and worldwide, and an overwhelming majority in the transportation sector, particularly liquid hydrocarbons (i.e., gasoline, diesel and jet fuel). Engine manufacturers move to higher operating pressures, above and beyond the critical pressures of the fuel, in order to optimize performance, maximize efficiency and reduce pollutant formation. The design of the next generation of engines, however, are limited by a lack of fundamental understanding of the thermo-physical properties, fluid behavior and chemical kinetics at these high pressures. Terrestrial laboratory studies are hampered by the ubiquitous buoyant flow that renders fundamental experiments difficult and/or impossible to interpret. Studying high pressure transcritical phenomena in microgravity allows researchers to investigate the fundamental aspects of phase change, chemical kinetics and property evaluation in a simplified geometry without the complicating influence of a buoyancy-induced flow.

Combustion↗
NASA NTRS1985

Nested subcritical flows within supercritical systems

In supercritical systems the design inlet and outlet pressures are maintained above the thermaodynamic critical pressure P sub C. Designers rely on this simple rule of thumb to circumvent problems associated with a subcritical pressure regime nested within the supercritical pressure system along with the uncertainties in heat transfer, fluid mechanics, and thermophysical property variations. The simple rule of thumb is adequate in many low-power designs but is inadequate for high-performance turbomachines and linear systems, where nested two-phase regions can exist. Examples for a free-jet expansion with backpressure greater than P sub C and a rotor (bearing) with ambient pressure greater than P sub C illustrate the existence of subcritical pressure regimes nested within supercritical systems.

Hendricks, R. C.↗
NASA NTRS1986

Thermofluid analysis of the SSME preburner using a gas-gas diffusion model for oxygen and hydrogen combustion at supercritical pressures

The paper discusses the thermofluid analysis of the Space Shuttle Main Engine (SSME) fuelside preburner. The governing equations have been solved numerically to predict flow, heat transfer, mixing, and combustion. A two-fluid approach is adopted in which oxygen is regarded as one fluid and hydrogen is regarded as the other fluid. The chemical kinetics is assumed to be very fast so that combustion is primarily controlled by the rate of mixing between oxygen and hydrogen. The preburner pressure is much greater than the critical pressures of oxygen and hydrogen; hence, a gas-gas diffusion model (rather than an evaporation model) has been developed to compute the rate of interphase mixing. Empirical correlations have been incorporated to account for the effect of slip on the interphase exchange. A sensitivity study has been performed with various model parameters. It is observed that the model can predict possibility of incomplete combustion and local regions of high temperatures under steady operating conditions. Some of these anomalies have been observed in actual tests, and the numerical model is useful for understanding possible causes and remedies. At least some measurements are needed for quantitative verification of the model.

Prakash, C.↗
NASA NTRS1975

Liquid neon heat transfer as applied to a 30 tesla cryomagnet

A 30-tesla magnet design is studied which calls for forced convection liquid neon heat transfer in small coolant channels. The design also requires suppressing boiling by subjecting the fluid to high pressures through use of magnet coils enclosed in a pressure vessel which is maintained at the critical pressure of liquid neon. This high pressure reduces the possibility of the system flow instabilities which may occur at low pressures. The forced convection heat transfer data presented were obtained by using a blowdown technique to force the fluid to flow vertically through a resistance heated, instrumented tube.

Papell, S. S.↗
NASA NTRS1988

Studies on pressure response of gas bubbles contributions of condensed droplets in bubbles generated by a uniform nucleation

The response of a tiny gas bubble under reduced pressure is investigated in its relation to cavitation. Equations of motion are formulated for gas mixtures inside the bubble and numerical calculations performed for several examples. The conclusions are as follows: (1) at the onset of bubble growth, the gas mixture inside it adiabatically expands and the temperature decreases. Condensed droplets appear inside the gas mixture due to a uniform nucleation and the temperature recovers, thus the motion of the bubble is apparently isothermal; (2) the evaporation and condensation coefficient largely affects bubble motions (maximum radius, period and rate of attenuation of the bubble oscillation) including the uniform contraction; (3) the oscillation period of the bubble is longer as the equilibrium bubble radius is larger when the surrounding pressure decreases stepwise. In this circumstance the temperature inside the bubble is kept constant due to condensation evaporation phenomena and is nearly isothermal; and (4) when the surrounding pressure decreases in a stepwise fashion, the critical pressure bubble radius relation becomes closer to that for the isothermal process if the bubble radius is larger than 8 microns.

Matsumoto, Y.↗
NASA NTRS1956

Performance of variable two-dimensional inlet designed for engine-inlet matching I : performance at design Mach number of 3.07

The inlet was investigated with both a two-oblique-shock and an isentropic compression ramp. Provisions for a variety of bypass systems were incorporated and none decreased pressure recovery by more than about 1 percent. By utilizing throat boundary-layer control, critical pressure recoveries of 64 and 70 percent were obtained with the two-shock and isentropic ramps, respectively. Diffuser-exit air distortion was about 5 percent at critical operation Theoretical cowl pressure drag was equal to about 10 percent of the net thrust of an assumed engine.

Beheim, M A↗
NASA NTRS1975

Pressure distribution in a converging-diverging nozzle during two-phase choked flow of subcooled nitrogen

Choked flow rates and axial pressure distributions were measured for subcooled nitrogen in a converging-diverging nozzle with a constant area section in the throat region. Stagnation pressures ranged from slightly above saturation to twice the thermodynamic critical pressure. Stagnation temperatures ranged from 0.75 to 1.03 times the thermodynamic critical temperature. The choking plane is at the divergence end of the constant area throat section. At high stagnation pressures the fluid stays liquid well into the constant area throat region; at near saturation stagnation pressures it appears that vaporization occurs at or before the entrance to the constant area throat region. The throat-to-stagnation pressure ratio data exhibits an anomalous flat region, and this anomaly is related to the two-phase process. The fluid is metastably all liquid below the saturation pressure.

Simoneau, R. J.↗
NASA NTRS1972

High-pressure liquid-monopropellant strand combustion.

Examination of the influence of dissolved gases on the state of the liquid surface during high-pressure liquid-monopropellant combustion through the use of a strand burning experiment. Liquid surface temperatures were measured, using fine-wire thermocouples, during the strand combustion of ethyl nitrate, normal propyl nitrate, and propylene glycol dinitrate at pressures up to 81 atm. These measurements were compared with the predictions of a variable-property gas-phase analysis assuming an infinite activation energy for the decomposition reaction. The state of the liquid surface was estimated using a conventional low-pressure phase equilibrium model, as well as a high-pressure version that considered the presence of dissolved combustion-product gases in the liquid phase. The high-pressure model was found to give a superior prediction of measured liquid surface temperatures. Computed total pressures required for the surface to reach its critical mixing point during strand combustion were found to be in the range from 2.15 to 4.62 times the critical pressure of the pure propellant. Computed dissolved gas concentrations at the liquid surface were in the range from 35 to 50% near the critical combustion condition.

Faeth, G. M.↗
NASA NTRS1975

Maximum two-phase flow rates of subcooled nitrogen through a sharp-edged orifice

Data are presented of an experiment in which subcooled liquid nitrogen was discharged through a sharp-edged orifice at flow rates near the maximum. The data covered a range of inlet stagnation pressures from slightly above saturation to twice the thermodynamic critical pressure. The data were taken along five separate inlet stagnation isotherms ranging from 0.75 to 1.035 times the thermodynamic critical temperature. The results indicate that subcooled liquids do not choke or approach maximum flow in an asymptotic manner even though the back pressure is well below saturation; and orifice flow coefficients are not constant as is frequently assumed. A metastable jet appears to exist which breaks down if the difference between back pressure and saturation pressure is large enough.

Simoneau, R. J.↗
NASA NTRS1975

Maximum two-phase flow rates of subcooled nitrogen through a sharp-edged orifice

An experiment was conducted and data are presented in which subcooled liquid nitrogen was discharged through a sharp-edged orifice at flow rates near the maximum. The data covered a range of inlet stagnation pressure from slightly above saturation to twice the thermodynamic critical pressure. The data were taken along five separate inlet stagnation isotherms ranging from 0.75 to 1.035 times the thermodynamic critical temperature. The results indicate that: (1) subcooled liquids do not choke or approach maximum flow in an asymptotic manner even though the back pressure is well below saturation; (2) orifice flow coefficients are not constant as is frequently assumed. A metastable jet appears to exist which breaks down if the difference between back pressure and saturation pressure is large enough.

Simoneau, R. J.↗
NASA NTRS1975

Pressure distribution in a converging-diverging nozzle during two-phase choked flow of subcooled nitrogen

Choked flow rates and axial pressure distributions were measured for subcooled nitrogen in a converging-diverging nozzle with a constant area section in the throat region. Stagnation pressures ranged from slightly above saturation to twice the thermodynamic critical pressure. Stagnation temperatures ranged from 0.75 to 1.03 times the thermodynamic critical temperature. The choking plane appears to be at the divergence end of the constant area throat section. At high stagnation pressures the fluid appears to stay liquid well into the constant area throat region; however, at near saturation stagnation pressures it appears that vaporization occurs at or before the entrance to the constant area throat region. The throat-to-stagnation pressure ratio data exhibits an anomalous flat region. This anomaly appears to be fundamentally related to the two-phase process and not merely to the present specific nozzle geometry. The fluid appears to be metastably all liquid below the saturation pressure. The data are compared to various flow models. No model adequately describes the whole range of the experiment.

Simoneau, R. J.↗
NASA NTRS1993

High-pressure droplet combustion studies

This is a joint research program, pursued by investigators at the University of Tokyo, UCSD, and NASA Lewis Research Center. The focus is on high-pressure combustion of miscible binary fuel droplets. It involves construction of an experimental apparatus in Tokyo, mating of the apparatus to a NASA-Lewis 2.2-second drop-tower frame in San Diego, and performing experiments in the 2.2-second tower in Cleveland, with experimental results analyzed jointly by the Tokyo, UCSD, and NASA investigators. The project was initiated in December, 1990 and has now involved three periods of drop-tower testing by Mikami at Lewis. The research accomplished thus far concerns the combustion of individual fiber-supported droplets of mixtures of n-heptane and n-hexadecane, initially about 1 mm diameter, under free-fall microgravity conditions. Ambient pressures ranged up to 3.0 MPa, extending above the critical pressures of both pure fuels, in room-temperature nitrogen-oxygen atmospheres having oxygen mole fractions X of 0.12 and 0.13. The general objective is to study near-critical and super-critical combustion of these droplets and to see whether three-stage burning, observed at normal gravity, persists at high pressures in microgravity. Results of these investigations will be summarized here; a more complete account soon will be published.

Mikami, Masato↗
NASA NTRS1974

Two-phase choked flow of subcooled nitrogen through a slit

Two-phase choked flow rate and pressure distribution data are reported for subcooled nitrogen flowing through a slit. The slip was a narrow rectangular passage of equal length and width. The inlet stagnation pressure ranged from slightly above saturation to twice the thermodynamic critical pressure. Four stagnation isotherms were investigated covering a range which spanned the critical temperature. The results suggested a uniform two-phase flow pattern with vaporization occurring at or near the exit in most cases. The results compared favorably with the theory of Henry for nonequilibrium subcooled two-phase choked flow in long tubes.

Simoneau, R. J.↗