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At least 55 records · Page 3

Metal plasticity and ductile fracture modeling for cast aluminum alloy parts

Here in this study, plasticity and ductile fracture properties were characterized by performing various tension, shear, and compression tests. A series of 10 experiments were performed using notched round bars, flat-grooved plates, in-plane shear plates, and cylindrical bars. Two cast aluminum alloys used in automotive suspension systems were selected. Plasticity modelling was performed and the results were compared with experimental and corresponding simulation results; further, the relationships among the stress triaxiality, Lode angle parameter, and equivalent plastic strain at the onset of failure were determined to calibrate a ductile fracture model. Finally, the proposed ductile fracture model shows good agreement with experimental results.

36 MATERIALS SCIENCE↗

ON THE MISALIGNMENT BETWEEN CHROMOSPHERIC FEATURES AND THE MAGNETIC FIELD ON THE SUN

Observations of the upper chromosphere show an enormous amount of intricate fine structure. Much of this comes in the form of linear features, which are most often assumed to be well aligned with the direction of the magnetic field in the low plasma β regime that is thought to dominate the upper chromosphere. We use advanced radiative magnetohydrodynamic simulations, including the effects of ion-neutral interactions (using the generalized Ohm’s law) in the partially ionized chromosphere, to show that the magnetic field is often not well aligned with chromospheric features. This occurs where the ambipolar diffusion is large, i.e., ions and neutral populations decouple as the ion-neutral collision frequency drops, allowing the field to slip through the neutral population; where currents perpendicular to the field are strong; and where thermodynamic timescales are longer than or similar to those of ambipolar diffusion. We find this often happens in dynamic spicule or fibril-like features at the top of the chromosphere. This has important consequences for field extrapolation methods, which increasingly use such upper chromospheric features to help constrain the chromospheric magnetic field: our results invalidate the underlying assumption that these features are aligned with the field. In addition, our results cast doubt on results from 1D hydrodynamic models, which assume that plasma remains on the same field lines. Finally, our simulations show that ambipolar diffusion significantly alters the amount of free energy available in the coronal part of our simulated volume, which is likely to have consequences for studies of flare initiation.

79 ASTRONOMY AND ASTROPHYSICS↗

Numerical Simulation of the Effects of Horizontal and Vertical EMBr on Jet Flow and Mold Level Fluctuation in Continuous Casting

In this article, a new type of electromagnetic braking (EMBr), named vertical EMBr (V-EMBr) was introduced in the continuous casting process. In order to investigate its capability and applicability, the impacts of horizontal and vertical EMBrs on the flow pattern in a continuous casting mold were simulated by means of an implemented Reynolds-averaged Navier–Stokes (RANS) SST k–ω turbulence model. The characteristics of electromagnetic field and flow field inside a 1450 mm × 230 mm mold with Ruler-EMBr and V-EMBr have been compared. The numerical simulation results indicate that the static magnetic field generated by Ruler-EMBr can cover the main part of the discharging jet flow, which has a better control of the flow pattern in lower part of the mold. The static magnetic field generated by V-EMBr can cover both the vicinity of the mold narrow faces and the impingement region of the jet flow, which can effectively control the liquid steel flow in the upper recirculation zone. The parametric study also shows that the large vortices beneath the jet flow can be almost completely eliminated at an optimized magnetic flux density with Ruler-EMBr. In addition, the surface velocity and steel/slag interface fluctuation can be suppressed with the application of V-EMBr to acceptable values even with a wide variation of SEN port angles. It is estimated that to reach the same level of braking effect on the upper recirculation flow, a magnetic flux density of 0.1 T is sufficient for V-EMBr, while 0.2 T is needed for Ruler-EMBr. Based on the results, a second-generation V-EMBr has been developed, which combines both of the merits of Ruler-EMBr and V-EMBr.

36 MATERIALS SCIENCE↗

Impact of carbonation on leaching of constituents from a cementitious waste form for treatment of low activity waste at the DOE Hanford site

Carbonation can be a major aging process during disposal of alkaline cementitious waste forms and can impact constituent leaching by changes in material alkalinity, pore structure, and controlling mineral phases. The effect of carbonation on the leaching of major and trace constituents from Cast Stone, a cementitious waste form developed to treat high salt content low activity waste, was studied through a combination of leaching experiments and reactive transport simulations. Diffusive transport of constituents in the waste form was evaluated using reactive transport modeling of diffusion-controlled leaching test results and a geochemical speciation model derived from pH-dependent leaching. Comparisons between Cast Stone materials aged under nitrogen, air, and 2% carbon dioxide in nitrogen showed that carbonation impacts solubility, physical retention and observed diffusivity of major and trace constituents. Carbonation under 2% CO 2 decreased the diffusion-controlled leaching of chromium by two orders of magnitude. Finally, modeling results suggest that carbonation may also decrease solubility of technetium while changes to microstructure by carbonation increases effective diffusivity of constituents in Cast Stone.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterisation and modelling of defect formation in direct-chill cast AZ80 alloy

Wrought magnesium alloys for demanding structural applications require high quality defect free cast feedstock. The aim of this study was to first identify and characterise typical defects in direct chill cast magnesium–aluminium–zinc (AZ) alloy billet and then use modelling to understand the origins of these defects so they can be prevented. Defects were first located using ultrasonic inspection and were then characterised using X-ray computed tomography (XCT) and serial sectioning, establishing the presence of oxide films and intermetallic particles Al{sub 8}Mn{sub 5} in all defects. A model was developed to predict the flow patterns and growth kinetics of the intermetallic phases during casting, which influence the formation of defects. Simulation of the growth of the intermetallic particles demonstrated that precipitation from the liquid occurs in the mould. The combination of the entrained oxide films and intermetallic particles recirculates in the liquid metal and continues to grow, until large enough to settle, which is predicted to occur at the centre of the mould where the flow is the slowest. Based on these predictions, strategies to reduce the susceptibility to defect formation are suggested. - Highlights: • Casting defects in magnesium direct chill casting have been imaged and characterised in 3-dimensions. • The occurrences of co-located clusters of particles and oxide films have been characterised and explained. • A coupled model has been developed to help interpret the observed trend for defects located towards the centre of billets.

36 MATERIALS SCIENCE↗

Direct numerical simulation of mechanical response in synthetic additively manufactured microstructures

Additive manufacturing (AM) processes for metals can yield as-built microstructures that vary significantly from their cast or wrought counterparts. These microstructural variations can in turn, have profound effects on the properties of a component. Here, a modeling methodology is presented to investigate microstructurally-influenced mechanical response in additively manufactured structures via direct numeral simulation. Three-dimensional, synthetic voxelized microstructures are generated by kinetic Monte Carlo (kMC) additive manufacturing process simulations performed at four scan speeds to create a thin-wall cylindrical geometry notionally constructed using a concentric-pathed directed energy deposition AM process. The kMC simulations utilize a steady-state molten pool geometry that is held constant throughout the study. Resultant microstructures are mapped onto a highly-refined conformal finite-element mesh of a part geometry. A grain-scale anisotropic crystal elasticity model is then used to represent the constitutive response of each grain. Here, the response of the structure subjected to relatively simple load conditions is studied in order to provide understanding of both the influence of AM processing on microstructure as well as the microstructure's influence on the macroscale mechanical response.

42 ENGINEERING↗

Similarity Criteria for the Study of Removal of Spherical Non-metallic Inclusions in Physical Models of Continuous Casting Tundishes: A More Fundamental Approach

Physical modeling is widely used for studying steelmaking processes. The accuracy of this technique depends on the use of appropriate similarity criteria during experimental design. The present work deduced rigorously the similarity criteria for the study of spherical non-metallic inclusions in isothermal physical models of tundishes. Initially, macroscopic quantities were used to simplify the multiphase problem. Then, the similarity criteria were obtained from the dimensionless form of the exact equation of motion for an inclusion in Stokes regime. The validity range of these criteria was discussed and they were compared with common literature practice. Some practical considerations were also presented. This work clarifies various implicit assumptions usually adopted in literature. Additionally, a restrictive criterion to choose the density of the inclusion simulating particles was obtained, which can be satisfied, for example, by hollow glass particles in water models. This criterion is necessary to adequately describe the inclusion motion in regions where fluid elements suffer strong acceleration (e.g., inside nozzles, near flow controllers or in the entering fluid jet). Moreover, it was established an upper limit for the concentration of particles injected in the inlet nozzle of physical models, which do not simulate the phenomenon of inclusion aggregation.

36 MATERIALS SCIENCE↗

Study of Non-Newtonian Behavior of CaO-SiO{sub 2}-Based Mold Slag and Its Effect on Lubrication in Continuous Casting of Steel

To understand the effect of the non-Newtonian behavior of mold slag on lubrication during continuous casting of steel, the current study investigated the rheology of CaO-SiO{sub 2}-based mold slag using a rotational viscometer with variable rotating speed. The constitutive equations at different temperatures were determined. Subsequently, the obtained viscosity as a function of temperature and shear rate was incorporated into a validated mathematical model. The main results demonstrated that slag viscosity decreased dramatically with increased shear rate as the experimental temperature approached the break temperature of mold slag, meaning that the mold slag had a property of shear thinning. The predicted evolution of slag viscosity during mold oscillation was consistent with the shear thinning as the shear rate exerted on the slag channel varied. The calculated slag consumption was higher than that for slag treated as a Newtonian fluid, which agreed well with measurements using a miniature continuous caster. This study finds that the consideration of the non-Newtonian behavior of mold slag is significant to understand the lubrication mechanism and optimize related parameters via simulation.

36 MATERIALS SCIENCE↗

Engineering Nucleation Kinetics of Graphite Nodules in Inoculated Cast Iron for Reducing Porosity

Inoculation of cast iron with spherical graphite (SGI) controls nucleation kinetics of graphite nodules and is used for improving casting performance and eliminating solidification micro-porosity. In this study, thermodynamic simulations were used to design inoculants. Thermal and chemical stability of different potential heterogeneous nuclei formed in the melt above the liquidus temperature and in the mushy zone during solidification was predicted. Several inoculation treatments of SGI were performed in laboratory heats. An automated SEM/EDX analysis was applied to examine the graphite nodule size distribution and the family of the non-metallic inclusions in the experimental castings. The data were used to reconstruct a relative graphite nodule nucleation rate in the castings. It was shown that the graphite nodule nucleation kinetics in the castings were significantly different from those predicted by classical nucleation models. In inoculated SGI, the observed bi-modal distribution of graphite nodules was related to a continuous nucleation that occurred towards the end of solidification. The origin of the continuous nucleation and the possibility of engineering graphite nodules nucleation kinetics to control SGI casting soundness by inoculation are discussed.

36 MATERIALS SCIENCE↗

Cusps in the center of galaxies: a real conflict with observations or a numerical artefact of cosmological simulations?

Galaxy observations and N-body cosmological simulations produce conflicting dark matter halo density profiles for galaxy central regions. While simulations suggest a cuspy and universal density profile (UDP) of this region, the majority of observations favor variable profiles with a core in the center. In this paper, we investigate the convergency of standard N-body simulations, especially in the cusp region, following the approach proposed by [1]. We simulate the well known Hernquist model using the SPH code Gadget-3 and consider the full array of dynamical parameters of the particles. We find that, although the cuspy profile is stable, all integrals of motion characterizing individual particles suffer strong unphysical variations along the whole halo, revealing an effective interaction between the test bodies. This result casts doubts on the reliability of the velocity distribution function obtained in the simulations. Moreover, we find unphysical Fokker-Planck streams of particles in the cusp region. The same streams should appear in cosmological N-body simulations, being strong enough to change the shape of the cusp or even to create it. Our analysis, based on the Hernquist model and the standard SPH code, strongly suggests that the UDPs generally found by the cosmological N-body simulations may be a consequence of numerical effects. A much better understanding of the N-body simulation convergency is necessary before a 'core-cusp problem' can properly be used to question the validity of the CDM model.

79 ASTRONOMY AND ASTROPHYSICS↗

Experimental Investigations on Solidification of 500-kg Steel Ingots with Laboratory Trials

The present work focuses on the solidification process of large steel ingots. Several complex solidification phenomena in large ingots were investigated by means of experimental hot modeling and cold modeling. In hot modeling, a 500 kg ingot solidified slowly in a specially insulated mold and this slow solidification process simulates the solidification of industrial scale ingots with a weight between 3 and 6 t. Temperature was measured by thermocouples during solidification and curves were plotted, and as-cast structure and macrosegregation of alloying elements were quantified. The A segregates were produced in the laboratory hot trials and quantitatively investigated. Meanwhile, water modeling (cold modeling) using NH{sub 4}Cl solution was conducted with different cooling/heating conditions. Macroscopic crystal growth phenomena, such as dendritic growth, sedimentation of crystals, and convective fluid flow, were directly observed and analyzed, and flow channels were also observed and compared with A segregates in the hot modeling.

36 MATERIALS SCIENCE↗

Study of the Mechanism of Liquid Slag Infiltration for Lubrication in Slab Continuous Casting

Consistent and uniform lubrication of the solidifying shell, especially in the meniscus, is crucial for the smooth continuous casting operation and production of strands free of surface defects. Thus, the current study established a coupled model to study the inflow behavior of liquid slag to the mold-strand channel, taking the solidification of steel and slag and the periodic oscillation of mold into account. The difficulties and solutions for the simulation were described in detail. The predicted profiles of the slag rim and initial shell were in good agreement with the reports. The main results indicated that liquid slag could be squeezed out and back into the slag pool in a negative strip period while a large amount of liquid slag could infiltrate into the mold-strand channel. Thus, the amount of slag consumed in the negative strip period was relatively small compared with that in the positive strip period. The predicted variation of slag consumption during mold oscillation was periodic, and the average value was 0.274 kg/m{sup 2}, which agreed well with the slag consumption in industrial practice. The current model can predict and optimize the oscillation parameters aiming at stable lubrication conditions.

36 MATERIALS SCIENCE↗

Materials for Advanced Ultrasupercritical Steam Turbines Task 4: Cast Superalloy Development

The Steam Turbine critical stationary structural components are high integrity Large Shell and Valve Casing heavy section Castings, containing high temperature steam under high pressures. Hence to support the development of advanced materials technology for use in an AUSC steam turbine capable of operating with steam conditions of 760°C (1400°F) and 35 Mpa (5000 psia), Casting alloy selection and evaluation of mechanical, metallurgical properties and castability with robust manufacturing methods are mandated. Alloy down select from Phase 1 based on producability criteria and creep rupture properties tested by NETL-Albany and ORNL directed the consortium to investigate cast properties of Haynes 282 and Haynes 263. The goals of Task 4 in Phase 2 are to understand a broader range of mechanical properties, the impact of manufacturing variables on those properties. Scale up the size of heats to production levels to facilitate the understanding of the impact of heat and component weight, on metallurgical and mechanical behavior. GE Power & Water Materials and Processes Engineering for the Phase 2, Task 4.0 Castings work, systematically designed and executed casting material property evaluation, multiple test programs. Starting from 15 lbs. cylinder castings to world’s first 17,000 lbs. poured weight, heavy section large steam turbine partial valve Haynes 282 super alloy casting. This has demonstrated scalability of the material for steam Turbine applications. Activities under Task 4.0, Investigated and characterized various mechanical properties of Cast Haynes 282 and Cast Nimonic 263. The development stages involved were: 1) Small Cast Evaluation: 4 inch diam. Haynes 282 and Nimonic 263 Cylinders. This provided effects of liquidus super heat range and first baseline mechanical data on cast versions of conventional vacuum re-melted and forged Ni based super alloys. 2) Step block castings of 300 lbs. and 600 lbs. Haynes 282 from 2 foundry heats were evaluated which demonstrated the importance of proper heat treat cycles for Homogenization, and Solutionizing parameters selection and implementation. 3) Step blocks casting of Nimonic 263: Carried out casting solidification simulation analysis, NDT inspection methods evaluation, detailed test matrix for Chemical, Tensile, LCF, stress rupture, CVN impact, hardness and J1C Fracture toughness section sensitivity data and were reported. 4) Centrifugal Casting of Haynes 282, weighing 1400 lbs. with hybrid mold (half Graphite and half Chromite sand) mold assembly was cast using compressor casing production tooling. This test provided Mold cooling rates influence on centrifugally cast microstructure and mechanical properties. Graphite mold section out performs sand mold across all temperatures for 0.2% YS; %Elongation, %RA, UTS at 1400°F. Both Stress-LMP and conditional Fracture toughness plots data were in the scatter band of the wrought alloy. 5) Fundamental Studies on Cooling rates and SDAS test program. Evaluated the influence of 6 mold materials Silica, Chromite, Alumina, Silica with Indirect Chills, Zircon and Graphite on casting solidification cooling rates. Actual Casting cooling rates through Liquidus to Solidus phase transition were measured with 3 different locations based thermocouples placed in each mold. Compared with solidification simulation cooling rates and measurement of SDAS, microstructure features were reported. The test results provided engineered casting potential methods, applicable for heavy section Haynes 282 castings for optimal properties, with foundry process methods and tools. 6) Large casting of Haynes 282 Drawings and Engineering FEM models and supplemental requirements with applicable specifications were provided to suppliers for the steam turbine proto type feature valve casing casting. Molding, melting and casting pouring completed per approved Manufacturing Process Plan during 2014 Q4. The partial valve casing was successfully cast after casting methods were validated with solidification simulation analysis and the casting met NDT inspection and acceptance criteria. Heat treated and sectioned to extract trepan samples at different locations comparing with cast on coupons test data. Material properties requisite for design, such as tensile, creep/rupture, LCF, Fracture Toughness, Charpy V-notch chemical analysis testing were carried out. The test results will be presented in the final report. The typical Haynes 282 large size Steam Turbine production casting from Order to Delivery foundry schedule with the activity break up is shown in Figures 107 and 108. • From Purchase Order placement to Casting pouring ~ 26 weeks. 1. Sales and commercial review 3 2. Engineering Drawings/models review 4 3. Pattern and core box manufacturing 6 4. Casting process engineering review 4 5. FEM and solidification simulation analysis 4 6. Gating & Feeder Attachments, Ceramic tiling 2 7. Molding and coremaking production scheduling 6 8. Melting planning and schedule 3 9. Pouring, cooling and shake out 2 • From Pouring to casting Delivery ~ 29 weeks 10. Shot blast and riser cutting, gates removal 3 11. Homogenizing , solutionizing HT furnace prep 4 12. Grinding, Fettling 2 13. Aging HT Cycle, cooling 2 14. VT and LPT NDT inspections 2 15. Radiographic inspection 4 16. Mechanical testing, Chemical analysis test certs 4 17. Casting weld repair upgrades and Aging PWHT 4 18. NDT after weld repairs and casting upgrades 3 19. Casting Final Inspection and test certifications 3 20. Package and delivery 2 Hence the Total Lead time from P.O to Casting delivery is approximately 55 weeks. The Task 4.2 and Task 4.3 activities and reporting completed.

Thangirala, Mani↗

Computational studies of impurity migration during induction stirring of molten uranium

Understanding and controlling impurity behavior in actinide metal casting processes are foundational for efficient part production yet remain major challenges for researchers and industry. To help provide insight regarding impurity distribution during actinide metal casting, we have developed computational fluid dynamics (CFD) models for a laboratory-scale system using commercial and open-source code. Multiple simulation frameworks allow for improved confidence in the resulting outputs, while taking advantage of the maturity and convenience offered by commercial platforms and simultaneously maintaining the transparency and flexibility often provided by open-source software. Here, we describe multiple experiment-informed models designed to simulate a specific laboratory system in which uranium melt, containing a known starting concentration of carbon impurity, is electromagnetically stirred in an induction furnace. Here, the goal of the simulations is to predict the motion of uranium carbide microparticles in the velocity field of the melt. Prior to simulating the uranium-carbon system, numerical models were validated using a previously published nonradioactive experimental system. Effects of the size and shape of impurity particles in the models were investigated and agree with experimental findings. Simulation of smaller particles (< 50 µm) shows more homogenous distribution throughout the stirred melt. With increased particle size (100 µm), the body forces, which include the buoyancy force, dominate over the drag force, causing larger particles to move toward the crucible walls and upward in the system.

36 MATERIALS SCIENCE↗

Beyond packing of hard spheres: The effects of core softness, non-additivity, intermediate-range repulsion, and many-body interactions on the glass-forming ability of bulk metallic glasses

When a liquid is cooled well below its melting temperature at a rate that exceeds the critical cooling rate R{sub c}, the crystalline state is bypassed and a metastable, amorphous glassy state forms instead. R{sub c} (or the corresponding critical casting thickness d{sub c}) characterizes the glass-forming ability (GFA) of each material. While silica is an excellent glass-former with small R{sub c} < 10{sup −2} K/s, pure metals and most alloys are typically poor glass-formers with large R{sub c} > 10{sup 10} K/s. Only in the past thirty years have bulk metallic glasses (BMGs) been identified with R{sub c} approaching that for silica. Recent simulations have shown that simple, hard-sphere models are able to identify the atomic size ratio and number fraction regime where BMGs exist with critical cooling rates more than 13 orders of magnitude smaller than those for pure metals. However, there are a number of other features of interatomic potentials beyond hard-core interactions. How do these other features affect the glass-forming ability of BMGs? In this manuscript, we perform molecular dynamics simulations to determine how variations in the softness and non-additivity of the repulsive core and form of the interatomic pair potential at intermediate distances affect the GFA of binary alloys. These variations in the interatomic pair potential allow us to introduce geometric frustration and change the crystal phases that compete with glass formation. We also investigate the effect of tuning the strength of the many-body interactions from zero to the full embedded atom model on the GFA for pure metals. We then employ the full embedded atom model for binary BMGs and show that hard-core interactions play the dominant role in setting the GFA of alloys, while other features of the interatomic potential only change the GFA by one to two orders of magnitude. Despite their perturbative effect, understanding the detailed form of the intermetallic potential is important for designing BMGs with cm or greater casting thickness.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Model-Based Reconstruction for Collimated Beam Ultrasound Systems

Collimated beam ultrasound systems are a novel technology for imaging inside multi-layered structures such as geothermal wells. Such systems include a transmitter and multiple receivers to capture reflected signals. Common algorithms for ultrasound reconstruction use delay-and-sum (DAS) approaches; these have low computational complexity but produce inaccurate images in the presence of complex structures and specialized geometries such as collimated beams.In this paper, we propose a multi-layer, ultrasonic, model-based iterative reconstruction algorithm designed for collimated beam systems. We introduce a physics-based forward model to accurately ac-count for the propagation of a collimated ultrasonic beam in multi-layer media and describe an efficient implementation using binary search. We model direct arrival signals, detector noise, and a spatially varying image prior, then cast the reconstruction as a maximum a posteriori estimation problem. Using simulated and experimental data we obtain significantly fewer artifacts relative to DAS while running in near real time using commodity compute resources.

Alanazi, Abdulrahman M.↗

Secondary Waste Cementitious Waste Form Data Package for the Integrated Disposal Facility Performance Assessment

A review of the most up-to-date and relevant data currently available was conducted to develop a set of recommended values for use in the Integrated Disposal Facility (IDF) performance assessment (PA) to model contaminant release from a cementitious waste form for aqueous wastes treated at the Hanford Effluent Treatment Facility (ETF). This data package relies primarily upon recent data collected on Cast Stone formulations fabricated with simulants of low-activity waste (LAW) and liquid secondary wastes expected to be produced at Hanford. These data were supplemented, when necessary, with data developed for saltstone (a similar grout waste form used at the Savannah River Site). Work is currently underway to collect data on cementitious waste forms that are similar to Cast Stone and saltstone but are tailored to the characteristics of ETF-treated liquid secondary wastes. Recommended values for key parameters to conduct PA modeling of contaminant release from ETF-treated liquid waste are provided.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Towards string order melting of spin-1 particle chains in superconducting transmons using optimal control

Utilizing optimal control to simulate a model Hamiltonian is an emerging strategy that leverages the intrinsic physics of a device with digital quantum simulation methods. Here we evaluate optimal control for probing the nonequilibrium properties of symmetry-protected topological (SPT) states simulated with superconducting hardware. Assuming a tunable transmon architecture, we cast the evolution of these SPT states as a series of one- and two-site pulse optimization problems that are solved in the presence of leakage constraints. From the generated pulses, we classically simulate the time-dependent melting of the perturbed SPT string order across a six-site model with an average state infidelity of 10 -3 . The feasibility of these pulses as well as their efficient application indicate that high-fidelity simulations of string order melting are within reach of current quantum computing systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗