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At least 55 records · Page 3

NASA Tech Briefs, October 2012

Topics discussed include: Detection of Chemical Precursors of Explosives; Detecting Methane From Leaking Pipelines and as Greenhouse Gas in the Atmosphere; Onboard Sensor Data Qualification in Human-Rated Launch Vehicles; Rugged, Portable, Real-Time Optical Gaseous Analyzer for Hydrogen Fluoride; A Probabilistic Mass Estimation Algorithm for a Novel 7-Channel Capacitive Sample Verification Sensor; Low-Power Architecture for an Optical Life Gas Analyzer; Online Cable Tester and Rerouter; A Three-Frequency Feed for Millimeter-Wave Radiometry; Capacitance Probe Resonator for Multichannel Electrometer; Inverted Three-Junction Tandem Thermophotovoltaic Modules; Fabrication of Single Crystal MgO Capsules; Inflatable Hangar for Assembly of Large Structures in Space; Mars Aqueous Processing System; Hybrid Filter Membrane; Design for the Structure and the Mechanics of Moballs; Pressure Dome for High-Pressure Electrolyzer; Cascading Tesla Oscillating Flow Diode for Stirling Engine Gas Bearings; Compact, Low-Force, Low-Noise Linear Actuator; Ultra-Compact Motor Controller; Extreme Ionizing-Radiation-Resistant Bacterium; Wideband Single-Crystal Transducer for Bone Characterization; Fluorescence-Activated Cell Sorting of Live Versus Dead Bacterial Cells and Spores; Nonhazardous Urine Pretreatment Method; Laser-Ranging Transponders for Science Investigations of the Moon and Mars; Ka-Band Waveguide Three-Way Serial Combiner for MMIC Amplifiers; Structural Health Monitoring with Fiber Bragg Grating and Piezo Arrays; Low-Gain Circularly Polarized Antenna with Torus-Shaped Pattern; Stereo and IMU- Assisted Visual Odometry for Small Robots; Global Swath and Gridded Data Tiling; GOES-R: Satellite Insight; Aquarius iPhone Application; Monitoring of International Space Station Telemetry Using Shewhart Control Charts; Theory of a Traveling Wave Feed for a Planar Slot Array Antenna; Time Manager Software for a Flight Processor; Simulation of Oxygen Disintegration and Mixing With Hydrogen or Helium at Supercritical Pressure; A Superfluid Pulse Tube Refrigerator Without Moving Parts for Sub-Kelvin Cooling; Sapphire Viewports for a Venus Probe; The Mobile Chamber; Electric Propulsion Induced Secondary Mass Spectroscopy; and Radiation-Tolerant DC-DC Converters.

Source record↗

Supernova explosions.

The recent history of theoretical investigations of the supernova mechanism is considered, giving attention also to a number of nuclear physical problems which have yet to be solved in connection with the thermonuclear detonation. A variety of different processes of nucleo-synthesis are expected to occur in association with the supernova explosions. Aspects of the chemical evolution of the galaxy are discussed including the cosmic ray production of lithium, beryllium, and boron in the interstellar medium. Various hypotheses to account for the very large amount of light that comes from a supernova explosion are also examined.

Cameron, A. G. W.↗

The chemical abundances of the Cassiopeia A fast-moving knots - Explosive nucleosynthesis on a minicomputer

A simplified nuclear reaction network for explosive nucleosynthesis calculations is described in which only the most abundant nuclear species and the most important reactions linking these species are considered. This scheme permits the exploration of many cases without excessive computational effort. Good agreement with previous calculations employing more complex reaction networks is obtained. This scheme is applied to the observed chemical abundances of the fast-moving knots in the supernova remnant Cassiopeia A and it is found that a wide range of initial conditions could yield the observed abundances. The abundances of four of the knots with significant and different amounts of elements heavier than oxygen are consistent with an origin in material of the same initial composition but processed at different peak temperatures and densities. Despite the observed high oxygen abundances and low abundances of light elements in the knots, they did not necessarily undergo incomplete oxygen burning; in fact, it is not even necessary that oxygen have been present in the initial composition. The agreement between the calculated and observed chemical abundances in Cas A and similar supernova remnants depends primarily upon the relevant nuclear physics and does not provide strong evidence in favor of any particular model of the supernova event.

Johnston, M. D.↗

Composite overwrapped metallic tanks

Work is reported for fabricating and testing the fiberglass overwrapped titanium pressure vessel for cryogenic service. Difficulties encountered in the tank liner fabrication phase involved explosive forming, vacuum annealing, chemical milling and electron beam welding. While each of these processes and the nondestructive test methods employed are normally considered to be individually reliable, the combination of poor material together with fabrication and development reversals prevented the full achievement of the desired end results. Eight tanks plus a prototype and tool proofing article were produced. Six of the vessels failed during the hydrostatic sizing operation. One of the remaining tanks was hydrostatically pressurized to burst and the other was pressurized repeatedly at 75 F from 100 psi to the operating pressure until failure occurred. As a result, it is not possible to draw firm conclusions as to the true value of the design concept due to the problems encountered in the program.

Caudill, C. L.↗

Ejecta from large craters on the moon - Comments on the geometric model of McGetchin et al

Amendments to a quantitative scheme developed by T. R. McGetchin et al. (1973) for predicting the distribution of ejecta from lunar basins yield substantially thicker estimates of ejecta, deposited at the basin rim-crest and at varying ranges beyond, than does the original model. Estimates of the total volume of material ejected from a basin, illustrated by Imbrium, also are much greater. Because many uncertainties affect any geometric model developed primarily from terrestrial analogs of lunar craters, predictions of ejecta thickness and volume on the moon may range within at least an order of magnitude. These problems are exemplified by the variability of T, thickness of ejecta at the rim-crest of terrestrial experimental craters. The proportion of T to crater rim-height depends critically upon scaled depth-of-burst and whether the explosive is nuclear or chemical.

Pike, R. J.↗

Chemical and Thermal Analysis

Thermal decomposition activation energies have been determined using two methods of Thermogravimetric Analysis (TGA), with good correlation being obtained between the two techniques. Initial heating curves indicated a two-component system for Coflon (i.e. polymer plus placticizer) but a single component system for Tefzel. Two widely differing activation energies were for Coflon supported this view, 15 kcl/mol being associated with plasticizer, and 40 kcal/mol with polymer degradation. With Tefzel, values were 40-45 kcal/mol, the former perhaps being associated with a low molecular weight fraction. Appropriate acceleration factors have been determined. Thermomechanical Analysis (TMA) has shown considerable dimensional change during temperature cycles. For unaged pipe sections heating to 100 C and then holding the temperature resulted in a stable thickness increase of 2%, whereas the Coflon thickness decreased continuously, reaching -4% in 2.7 weeks. Previously strained tensile bars of Tefzel expanded on cooling during TMA. SEM performed on H2S-aged Coflon samples showed significant changes in both physical and chemical nature. The first may have resulted from explosive decompression after part of the aging process. Chemically extensive dehydrofluorination was indicated, and sulfur was present as a result of the aging. These observations indicate that chemical attack of PVDF can occur in some circumstances.

Bulluck, J. W.↗

Hydrodynamic study of Supernova 1987A: The phase of a wave of cooling and recombination

The dependence of the bolometric light curve and of the effective temperature on the density distribution in a progenitor, its chemical composition, mass, radius, and explosion energy is studied. It is shown that, just before the supernova 1987 A outburst, the outside layers of the blue supergiant Sk-69.202 deg had a density distribution similar to that of the polytropic model with an index of n equals 3, a chemical composition with a mass fraction of hydrogen of the order of 0.1, and a relative helium abundance of about 0.9.

Utrobin, V. P.↗

New Mission Concept: Investigation of the Galactic Center with the Galactic Center Explorer (GalCenEx)

The European Space Observatory INTEGRAL has been providing excellent results on X-ray and γ–ray astronomy since its launch in 2002. Among the most important results are the spectroscopy and imaging measurements of celestial γ-ray sources, including mapping the 511 keV radiation from the Galactic plane. However, the nature of the 511 keV positron annihilation line around the Galactic Center region is still a mystery. Similarly, the structure and nature of the Galactic Center supermassive black hole and its surroundings, as well as the structure of heavily populated sky regions such as Cygnus and Carina in γ-rays, remain unclear. We present a concept of a potential next-generation γ-ray telescope with the major science objectives: a) solve the mystery of the Galactic Center region 511 keV positron annihilation line by mapping the Galactic Center region with high energy (<1% FWHM) and angular (< 10 arcmin) resolution and with line sensitivity <10-5 ph cm-2 s-1; b) understand the nature of the Galactic Center supermassive black hole environment by creating a high-resolution spectral and intensity map of the surrounding region in 0.1 – 20 MeV γ rays; and c) explore Galactic chemical evolution and sites of explosive element synthesis by conducting high-sensitivity measurements of nuclear lines from Type 1a supernovae and other objects. The instrument is based on a novel high energy and position resolution CdZnTe Imager, coded aperture mask, and heavy-scintillator shield, and can be considered for a NASA Explorer mission.

Moiseev, Alexander↗

New Mission Concept: Compton Telescope with Coded Aperture Mask (GECCO) for MeV Gamma-ray Astronomy

The Galactic Explorer with a Coded Aperture Mask Compton Telescope (GECCO) is a novel Explorer-class concept for a next-generation telescope covering the poorly explored hard X-ray and soft gamma-ray energy regimes. The instrument is based on a novel CdZnTe imaging calorimeter and a deployable coded aperture mask, which enable it to reach 1 arcmin angular resolution and 1% energy resolution. GECCO will connect the arcminute angular resolution observations from X-ray telescopes to high-energy images of the Galactic plane provided by Fermi-LAT, and will focus on the exploration of heavily populated sky regions such as the Galactic Center and the Carina and Cygnus regions to decipher the nature of their emission. These measurements will probe with unprecedented capabilities the possible origin of this emission as dark matter, new types of sources, or currently unresolved populations of point sources. Uncoded observations with GECCO’s Compton telescope will provide wide field-of-view sky monitoring for transient events, synergizing with gravitational wave and high-energy neutrino facilities. In addition, GECCO will conduct a high-sensitivity search for the positron sources in the Galactic Center responsible for the enigmatic 511 keV positron annihilation line excess, will search for as-yet untested candidates for dark matter, will detect and identify high-redshift blazars with excellent angular resolution, and will explore Galactic chemical evolution and sites of explosive element synthesis.

Alexander A Moiseev↗

Chemistry laboratory safety manual available

Chemistry laboratory safety manual outlines safe practices for handling hazardous chemicals and chemistry laboratory equipment. Included are discussions of chemical hazards relating to fire, health, explosion, safety equipment and procedures for certain laboratory techniques and manipulations involving glassware, vacuum equipment, acids, bases, and volatile solvents.

Elsbrock, R. G.↗

Jump phenomena

The paper considers jump phenomena composed of large amplitude responses of nonlinear systems caused by small amplitude disturbances. Physical problems where large jumps in the solution amplitude are important features of the response are described, including snap buckling of elastic shells, chemical reactions leading to combustion and explosion, and long-term climatic changes of the earth's atmosphere. A new method of rational functions was then developed which consists of representing the solutions of the jump problems as rational functions of the small disturbance parameter; this method can solve jump problems explicitly.

Reiss, E. L.↗

Higher-Sensitivity Ionization Trace-Species Detector

Electron source and electron optics of reversal electron-attachment detector modified to increase sensitivity. Original version described in "High-Sensitivity Ionization Trace-Species Detector" (NPO-17596). Used to detect molecules of particular chemical species of interest (e.g., narcotics, explosives, or organic wastes) present in air at low concentrations, and known to attach extremely low-energy electrons. Apparatus does this by ionizing molecules from sampled atmosphere, then detecting ions of species of interest. Detector features indirectly heated spherical cathode and redesigned electron optics, together, deliver more electrons at low kinetic energy to reversal plane, R. Greater electron current generates more ions for detection.

Boumsellek, Said↗

A Quantitative, Time-Dependent Model of Oxygen Isotopes in the Solar Nebula: Step one

The remarkable discovery that oxygen isotopes in primitive meteorites were fractionated along a line of slope I rather than along the typical slope 0,52 terrestrial fractionation line occurred almost 40 years ago, However, a satisfactory, quantitative explanation for this observation has yet to be found, though many different explanations have been proposed, The first of these explanations proposed that the observed line represented the final product produced by mixing molecular cloud dust with a nucleosynthetic component, rich in O-16, possibly resulting from a nearby supernova explosion, Donald Clayton suggested that Galactic Chemical Evolution would gradually change the oxygen isotopic composition of the interstellar grain population by steadily producing O-16 in supernovae, then producing the heavier isotopes as secondary products in lower mass stars, Thiemens and collaborators proposed a chemical mechanism that relied on the availability of additional active rotational and vibrational states in otherwise-symmetric molecules, such as CO2, O3 or SiO2, containing two different oxygen isotopes and a second, photochemical process that suggested that differential photochemical dissociation processes could fractionate oxygen , This second line of research has been pursued by several groups, though none of the current models is quantitative,

Nuth, J. A.↗

Mechanism of ignition in shock wave interactions with reactive liquid droplets

A detailed qualitative analysis of the processes leading to the explosive ignition of a reactive liquid droplet that is suspended in a gas-phase oxidizer and subjected to the passage of a shock wave, is presented. The interval of time between shock wave passage and ignition is described by identifying a two-stage process which consists of a period of relative reactive dormancy that is followed by a chemical induction period leading to the thermal explosion of reactant that has been stripped from the liquid drop, vaporized, and mixed with the gas-phase oxidizer. The results of first-order calculations based on this model are presented and compared with experimental data for diethlcyclohexane drops in oxygen.

Pierce, T. H.↗

The hard start phenomena in hypergolic engines. Volume 3: Physical and combustion characteristics of engine residuals

An investigation was conducted to determine the cause of starting problems in the hypergolic rocket engines of the Apollo reaction control (RCS) engines. The scope of the investigation was as follows: (1) to establish that chemical reactions occurred during the preignition and post combustion periods, (2) to identify the chemical species of the products of preignition and post combustion reaction, and (3) to determine the explosive nature of the identified species. The methods used in identifying the chemical products are described species. The infrared spectra, X-ray spectra, and other signatures of the compounds are presented. The physical and explosion characteristics of various hypergolic agents are reported.

Miron, Y.↗

Evolution of a localized thermal explosion in a reactive gas

Experimental observations of ignition in premixed gaseous reactants indicate that perfectly homogeneous initiation is practically unrealizable. Instead, combustion first sets in, as a rule, at small, discrete sites where inherent inhomogeneities cause chemical activity to proceed preferentially and lead to localized explosions. Combustion waves propagating away from these hot spots or reaction centers eventually envelop the remaining bulk. This study examines the spatial structure and temporal evolution of a hot spot for a model involving Arrhenius kinetics. The hot spot, characterized by peaks in pressure and temperature with little diminution in local density, is shown to have one of two possible self-similar structures. The analysis employs a combination of asymptotics and numerics, and terminates when pressure and temperature in the explosion have peaked.

Jackson, T. L.↗

A Summary of NASA and USAF Hypergolic Propellant Related Spills and Fires

Several unintentional hypergolic fluid related spills, fires, and explosions from the Apollo Program, the Space Shuttle Program, the Titan Program, and a few others have occurred over the past several decades. Spill sites include the following government facilities: Kennedy Space Center (KSC), Johnson Space Center (JSC), White Sands Test Facility (WSTF), Vandenberg Air Force Base (VAFB), Cape Canaveral Air Force Station (CCAFS), Edwards Air Force Base (EAFB), Little Rock AFB, and McConnell AFB. Until now, the only method of capturing the lessons learned from these incidents has been "word of mouth" or by studying each individual incident report. The root causes and consequences of the incidents vary drastically; however, certain "themes" can be deduced and utilized for future hypergolic propellant handling. Some of those common "themes" are summarized below: (1) Improper configuration control and internal or external human performance shaping factors can lead to being falsely comfortable with a system (2) Communication breakdown can escalate an incident to a level where injuries occur and/or hardware is damaged (3) Improper propulsion system and ground support system designs can destine a system for failure (4) Improper training of technicians, engineers, and safety personnel can put lives in danger (5) Improper PPE, spill protection, and staging of fire extinguishing equipment can result in unnecessary injuries or hardware damage if an incident occurs (6) Improper procedural oversight, development, and adherence to the procedure can be detrimental and quickly lead to an undesirable incident (7) Improper materials cleanliness or compatibility and chemical reactivity can result in fires or explosions (8) Improper established "back-out" and/or emergency safing procedures can escalate an event The items listed above are only a short list of the issues that should be recognized prior to handling hypergolic fluids or processing vehicles containing hypergolic propellants. The summary of incidents in this report is intended to cover many more issues than those listed above.

Nufer, Brian M.↗