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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Expanding the Sample of Radio Minihalos in Galaxy Clusters

Radio minihalos are diffuse synchrotron sources of unknown origin found in the cool cores of some galaxy clusters. We use GMRT and VLA data to expand the sample of minihalos by reporting three new minihalo detections (A2667, A907, and PSZ1 G139.61+24.20) and confirming minihalos in five clusters (MACS J0159.8–0849, MACS J0329.6–0211, RXC J2129.6+0005, AS 780, and A3444). With these new detections and confirmations, the sample now stands at 23, the largest sample to date. For consistency, we also reanalyze archival VLA 1.4 GHz observations of seven known minihalos. We revisit possible correlations between the nonthermal emission and the thermal properties of their cluster hosts. Consistent with our earlier findings from a smaller sample, we find no strong relation between the minihalo radio luminosity and the total cluster mass. Instead, we find a strong positive correlation between the minihalo radio power and X-ray bolometric luminosity of the cool core (r < 70 kpc). This supplements our earlier result that most, if not all, cool cores in massive clusters contain a minihalo. Comparison of radio and Chandra X-ray images indicates that the minihalo emission is typically confined by concentric sloshing cold fronts in the cores of most of our clusters, supporting the hypothesis that minihalos arise from electron reacceleration by turbulence caused by core gas sloshing. Taken together, our findings suggest that the origin of minihalos should be closely related to the properties of thermal plasma in cluster cool cores.

Galaxies radio continuum↗
DOE OSTI2025

A Transferable Force Field for Predicting Adsorption and Diffusion of Water in Cationic Zeolites with Coupled Cluster Accuracy

We present a transferable force field for water in proton-exchanged, alkali (Li, Na, K, Rb, and Cs) metal-exchanged, and alkaline-earth (Mg, Ca, Sr, and Ba) metal-exchanged zeolites. The fitting methodology is based on adsorbate–adsorbent interaction energies obtained from periodic density functional theory calculations and corrected using the coupled-cluster method applied to small model clusters. To ensure an accurate prediction of both adsorption and diffusion properties of water, sets of configurations that sample both adsorption sites and intracrystalline hopping transition states were used in the fitting. The quality of the force field is assessed for a wide range of zeolites with different topologies and chemical compositions, demonstrating good agreement between theoretical predictions and experimental measurements of water adsorption and diffusion.

Adsorption↗
NASA NTRS1979

Diffuse X-ray emission from Abell clusters

Abell clusters of galaxies, specifically Abell 401 and Abell 399 regions, are discussed. Two sets of satellite observations were made. One was a lunar occultation pointed observation where there were two orbits in which to look at the regions while the moon scanned over it. The other was a scanning observation through the area. Two diffuse models of the X-ray emission were developed. Also, during the investigation three binary cluster systems were found where at least one member was an X-ray source. They were Abell 508, 509, 2177, 2178, 2204, and 2210.

Ulmer, M.↗
NASA NTRS1985

Rotation and flattening of globular clusters

Methods for measuring globular cluster ellipticities and the results of such measurements are reviewed, and the processes that determine the shapes of globular clusters and the ways in which they change with time are discussed. The use of the virial tensor theorem to study the connection between the global rotation, velocity anisotropy, and the shape of a self-gravitating system is addressed, and the employment of N-body models to simulate the evolution of globular clusters with initially anisotropic velocity distributions is examined. The application of a simple evaporation model and Fokker-Planck integrations to study the two-body diffusion in globular clusters is reviewed.

Fall, S. M.↗
NASA NTRS1991

A model of the evaporation of binary-fuel clusters of drops

A formulation has been developed to describe the evaporation of dense or dilute clusters of binary-fuel drops. The binary fuel is assumed to be made of a solute and a solvent whose volatility is much lower than that of the solute. Convective flow effects, inducing a circulatory motion inside the drops, are taken into account, as well as turbulence external to the cluster volume. Results obtained with this model show that, similar to the conclusions for single isolated drops, the evaporation of the volatile is controlled by liquid mass diffusion when the cluster is dilute. In contrast, when the cluster is dense, the evaporation of the volatile is controlled by surface layer stripping, that is, by the regression rate of the drop, which is in fact controlled by the evaporation rate of the solvent. These conclusions are in agreement with existing experimental observations. Parametric studies show that these conclusions remain valid with changes in ambient temperature, initial slip velocity between drops and gas, initial drop size, initial cluster size, initial liquid mass fraction of the solute, and various combinations of solvent and solute. The implications of these results for computationally intensive combustor calculations are discussed.

Harstad, K.↗
NASA NTRS1977

Spatial distribution of Compton-produced X-ray flux from rich and regular clusters of galaxies

The spatial distribution of radio and X-ray fluxes from rich and regular clusters of galaxies is discussed. A diffusion model is investigated in which high-energy electrons are ejected from a point source at the center of the cluster. While diffusing out, the electrons lose energy by Compton scattering with the universal blackbody photons, thus producing the X-ray emission. Traversing intracluster magnetic fields, the electrons emit synchrotron radio emission. For the Coma cluster of galaxies good agreement is found between the observed and predicted X-ray counting-rate distribution for the Compton model. From the observed radio data a value of about 3 by 10 to the -8th power gauss is deduced for the average magnetic-field strength in the central region of Coma.

Rephaeli, Y.↗
NASA NTRS1960

Experimental Evaluation of Rocket Exhaust Diffusers for Altitude Simulation

An experimental investigation of exhaust diffusers has been conducted to evaluate various methods of minimizing the overall pressure ratio (from chamber to ambient pressure) required to establish and maintain full expansion of the nozzle flow (altitude simulation). Exhaust-diffuser configurations investigated were (1) cylindrical diffusers, (2) diffusers with contraction, and (3) diffusers including a right-angle turn. Cylindrical diffusers were evaluated with primary nozzles of various area ratios and types, as well as two clustered configurations; the other diffusers were evaluated with individual nozzles of constant area ratio and varied type. Air was the working fluid, except for two check points obtained with JP-4 fuel and liquid-oxygen rocket engines and cylindrical diffusers. The minimum length-diameter ratio of cylindrical diffusers was about 6 for minimum pressure-ratio requirements. With cylindrical diffusers of adequate length, the pressure-ratio requirements were primarily a function of the ratio of diffuser to nozzle-throat areas and were essentially independent of primary-nozzle type (including two clustered configurations) or area ratio. The two check points obtained with rocket engines indicated the pressure-ratio requirements at given ratios of diffuser to nozzle-throat areas were lowered, as compared with the requirements with air, as a result of the reduced ratio of specific heats. The minimum length-diameter ratio of the contraction throat of convergent-divergent diffusers was also about 6 for minimum pressure-ratio requirements. With adequate contraction-throat length, the pressure-ratio requirements of such diffusers were appreciably below those of comparable cylindrical diffusers when used with conical and cutoff-isentropic nozzles, but not when used with a bell nozzle. Minimum pressure-ratio requirements of a diffuser including a simple long-radius right-angle turn at maximum diffuser area, obtained with the center of radius of the turn a minimum of 2 diffuser diameters downstream of the nozzle exit, were not appreciably above those of a comparable optimum cylindrical diffuser. A diffuser including a long-radius right-angle turn at a contraction minimum area had somewhat lower pressure-ratio requirements than the aforementioned simple turn.

Sivo, Joseph N.↗
NASA NTRS1982

Surface diffusion activation energy determination using ion beam microtexturing

The activation energy for impurity atom (adatom) surface diffusion can be determined from the temperature dependence of the spacing of sputter cones. These cones are formed on the surface during sputtering while simultaneously adding impurities. The impurities form clusters by means of surface diffusion, and these clusters in turn initiate cone formation. Values are given for the surface diffusion activation energies for various materials on polycrystalline Cu, Al, Pb, Au, and Ni. The values for different impurity species on each of these substrates are approximately independent of impurity species within the experimental uncertainty, suggesting the absence of strong chemical bonding effects on the diffusion.

Rossnagel, S. M.↗
DOE OSTI2025

Coupled cluster and dislocation dynamics modeling of microstructure evolution in irradiated materials

We develop here a coupled cluster and dislocation dynamics framework to study the microstructure evolution of irradiated materials. The framework not only accounts for the three dimensional diffusion of radiation-generated clusters, but also their interaction with dislocation networks and the resultant climb motion of discrete dislocations within finite crystals. The framework is solved with a superposition solution scheme, and is applied to investigate the evolution of the irradiation-induced dislocation loops in zirconium (Zr), considering the effects of various bias factors including the diffusion anisotropy difference (DAD) of interstitials and interstitial clusters, the dislocation bias of defects to discrete dislocation segments, and the production bias of defects from the radiation cascade. We find that the DAD is the most critical factor influencing the kinetics of the loop evolution in Zr, while the recombination/interaction of mobile defects can induce a strong spatial dependence of the loop evolution together with the DAD. Here, the method is also adopted to study the evolution of interstitial $\langle$a$\rangle$ and vacancy $\langle$c$\rangle$ dislocation loop ensembles consistent with the microstructure observed during irradiation-induced growth of Zr. Our findings not only reveal the spatial dependence of the size and ellipticity of the dislocation loops, but also suggest a limit on the anisotropy factor of interstitials to reproduce the co-growth of $\langle$a$\rangle$ and $\langle$c$\rangle$ loops in zirconium, in good agreement with experimental observations and other simulation results.

Bias factors↗
DOE OSTI2025

Comparing approaches for introducing polycyclic aromatic hydrocarbons to Ge(001) to seed graphene nanoribbon synthesis by CH 4 chemical vapor deposition

Here, we evaluate two approaches for introducing polycyclic aromatic hydrocarbons (PAHs) to a graphene catalyst substrate as part of a two-step chemical vapor deposition (CVD) process for growing graphene nanoribbons (GNRs). In this process, PAHs first form graphene-like seeds on Ge, and then GNRs are subsequently evolved from these PAH-derived seeds via substrate-mediated anisotropic growth kinetics during the CVD of CH4. The first seeding approach sublimes controlled doses of PAH thin films into the CVD chamber, while the second delivers PAHs directly from the vapor phase at set concentrations. Using these two approaches, we measure the dependence of GNR density on PAH dose and compare the experimental results with predictions from a rate model of PAH diffusion, desorption, and clustering. We find that PAHs that more strongly adsorb to the catalyst surface (generally larger PAHs) desirably remain more individualized prior to GNR evolution whereas smaller, more weakly bound PAHs aggregate into larger clusters with various sizes on Ge that are undesirable for synthesizing more monodisperse GNRs. As a result, this work is important because it offers a framework that enables the rational selection and design of seed molecules, advancing anisotropic GNR CVD synthesis.

CVD↗
DOE OSTI2025

A Comparison of Electronic Structure Methods for Predicting the Hydrogenation Energies of Candidate Molecules for Hydrogen Storage

The development of novel energy materials and fuels is required to expand current available energy sources. Aiming to reach this goal, there is growing interest in using molecular hydrogen as an energy carrier due to its abundance and high energy density. Liquid organic hydrogen carriers (LOHCs) are a promising route to the large-scale storage and transport of hydrogen for use in the energy economy. The search for thermodynamically viable LOHC molecules for real world use has led to a set of constraints on the dehydrogenation enthalpy and the minimum gravimetric hydrogen capacity. These constraints allow one to formulate the search for an ideal LOHC candidate molecule as an optimization problem well suited to the strengths of machine learning and artificial intelligence computational approaches. A critical barrier to a large-scale, high-throughput screening of LOHC candidate molecules is the lack of reliable training data. Computational electronic structure methods including density functional theory, coupled cluster approximations, and diffusion Monte Carlo can be used to provide training data where experimental data are either unreliable or do not exist. In this work, we use these methods to calculate the dehydrogenation energies and enthalpies of candidate LOHC molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1983

A survey by HEAO 1 of clusters of galaxies. III - The complete Abell catalog

A catalog of 128 X-ray emitting clusters, including the Virgo Cluster, is presented. Ninety-one of these are new identifications. The catalog was obtained by searching the HEAO 1 survey observations for coincidences of X-ray sources with Abell clusters. The distribution of these sources in the sky has been examined in search of associations with other Abell clusters, with a null result. The X-ray luminosity has been correlated with cluster richness, but no association with Bautz-Morgan class has been found. The cluster luminosity function has been evaluated, and using this function the contribution of clusters to the diffuse X-ray background radiation has been estimated. It amounts to less than 15% at 2 keV and 3% at 6 keV.

Johnson, M. W.↗
NASA NTRS1992

Fractal dimension of alumina aggregates grown in two dimensions

The concepts of fractal geometry are applied to the analysis of 0.4-micron alumina constrained to agglomerate in two dimensions. Particles were trapped at the bottom surface of a drop of a dilute suspension, and the agglomeration process was directly observed, using an inverted optical microscope. Photographs were digitized and analyzed, using three distinct approaches. The results indicate that the agglomerates are fractal, having a dimension of approximately 1.5, which agrees well with the predictions of the diffusion-limited cluster-cluster aggregation model.

Larosa, Judith L.↗
NASA NTRS2000

The Influence of Microgravity on Silica Sol-Gel Formation

We discuss space-flight experiments involving the growth of silica particles and gels. The effect of microgravity on the growth of silica particles via the sol-gel route is profound. In four different recipes spanning a large range of the parameter space that typically produces silica nanoparticles in unit-gravity, low-density gel structures were instead formed in microgravity. The particles that did form were generally smaller and more polydisperse than those grown on the ground. These observations suggest that microgravity reduces the particle growth rate, allowing unincorporated species to form aggregates and ultimately gel. Hence microgravity favors the formation of more rarefied structures, providing a bias towards diffusion-limited cluster-cluster aggregation. These results further suggest that in unit gravity, fluid flows and sedimentation can significantly perturb sol-gel substructures prior to gelation and these deleterious perturbations may be "frozen" into the resulting microstructure. Hence, sol-gel pores may be expected to be smaller, more uniform, and less rough when formed in microgravity.

Sibille, L.↗
NASA NTRS2001

Porosity and Variations in Microgravity Aerogel Nano-Structures: New Laser Speckle Characterization Methods - 2

The transition from sol to gel is a process that is critical to the properties of engineered nanomaterials, but one with few available techniques for observing the dynamic processes occurring during the evolution of the gel network. Specifically, the observation of various cluster aggregation models, such as diffusion-limited and reaction-limited cluster growth can be quite difficult. This can be rather important as the actual aggregation model can dramatically influence the mechanical properties of gels, and is significantly affected by the presence of convective flows, or their absence in microgravity. We have developed two new non-intrusive optical methods for observing the aggregation processes within gels in real time. These make use of the dynamic behavior of laser speckle patterns produced when an intense laser source is passed through a gelling sol. The first method is a simplified time-correlation measurement, where the speckle pattern is observed using a CCD camera and information on the movement of the scattering objects is readily apparent. This approach is extremely sensitive to minute variations in the flow field as the observed speckle pattern is a diffraction-based image, and is therefore sensitive to motions within the sol on the order of the wavelength of the probing light. Additionally, this method has proven useful in determining a precise time for the gel-point, an event often difficult to measure. Monitoring the evolution of contrast within the speckle field is another method that has proven useful for studying aeration. In this case, speckle contrast is dependent upon the size (correlation length) and number of scattering centers, increasing with increasing size, and decreasing with increasing numbers. The dynamic behavior of cluster growth in gels causes both of these to change simultaneously with time, the exact rate of which is determined by the specific aggregation model involved. Actual growth processes can now be observed, and the effects of varying gravity fields on the growth processes qualitatively described. Results on preliminary ground-based measurements have been obtained.

Hunt, A. J.↗
NASA NTRSDate not supplied

STAR-X: Survey and Time-domain Astrophysical Research eXplorer

STAR-X is a MIDEX mission proposed to NASA in December 2021. Comprising an X-ray telescope (XRT) provided by GSFC and MIT, a UV telescope (UVT) provided by the University of Colorado, and a spacecraft (SC) provided by Ball Aerospace, STAR-X is designed to conduct time-domain survey and to respond rapidly to transient events discovered by other observatories such as LIGO, Rubin LSST, Roman WFIRST, and SKA. The key features of the XRT are its excellent PSF (2.5 arc-seconds half-power diameter), large effective area (1,800 cm2 at 1 keV), and large field of view (1 deg2), making it more than an order of magnitude more capable and more sensitive than Chandra and Swift/XRT to conduct survey and to find and study transient sources. The UVT has a 30-cm aperture with 5 filters covering the 160nm to 340nm band, providing simultaneous spectral coverage with the XRT and enabling reverberation mapping of accretion disk geometries around black holes. The SC is highly autonomous and is capable of fast slewing, enabling efficient raster scans and time-domain surveys. In particular, in combination with a state-of-the-art mission operations center at the University of Colorado, the SC can respond to targets of opportunity within 2 hours 90% of the time. With its nearly equatorial low-earth orbit, STAR-X’s telescopes will have low particle background, enabling them to have unprecedented sensitivity for measuring faint diffuse emissions from clusters of galaxies. STAR-X is a timely response to Astro2020’s recommendation for a space-based, sustaining time-domain and multi-messenger program.

William W. Zhang↗
NASA NTRS1984

Cluster of galaxies as a probe of the intergalactic medium

The use of galactic clusters as probes of the intercluster medium is discussed, and the effects of a postulated hot intercluster medium on the diffuse gas associated with clusters of galaxies is examined. It is shown that diffuse intracluster gas, which is observed at X-ray wavelengths, is a powerful probe of intergalactic space. The consequences of conduction are explored and the existence and properties of the intracluster gas are used to constrain the temperature and density of a uniform gas filling the universe. The effects of a nonuniform medium on the results are discussed and it is shown that for plausible scenarios the evaporative mass loss rates are insensitive to changes in the density and temperature of the intracluster medium in the vicinity of clusters. The parameters such a gas would have to have in order to explain the larger energy per unit mass found in the intracluster gas compared to that in galaxies are calculated.

Forman, W.↗