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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Continuous Precipitation of Ceria Nanoparticles from a Continuous Flow Micromixer

Cerium oxide nanoparticles were continuously precipitated from a solution of cerium(III) nitrate and ammonium hydroxide using a micro-scale T-mixer. Findings show that the method of mixing is important in the ceria precipitation process. In batch mixing and deposition, disintegration and agglomeration dominates the deposited film. In T-mixing and deposition, more uniform nanorod particles are attainable. In addition, it was found that the micromixing approach reduced the exposure of the Ce(OH)3 precipates to oxygen, yielding hydroxide precipates in place of CeO2 precipitates. Advantages of the micro-scale T-mixing approach include shorter mixing times, better control of nanoparticle shape and less agglomeration.

Environmental Molecular Sciences Laboratory↗

Global methane emissions from coal mining to continue growing even with declining coal production

This paper presents projections of global methane emissions from coal mining under different coal extraction scenarios and with increasing mining depth through 2100. The paper proposes an updated methodology for calculating fugitive emissions from coal mining, which accounts for coal extraction method, coal rank, and mining depth and uses evidence-based emissions factors. A detailed assessment shows that coal mining-related methane emissions in 2010 were higher than previous studies show. This study also uses a novel methodology for calculating methane emissions from abandoned coal mines and represents the first estimate of future global methane emissions from those mines. The results show that emissions from abandoned mines increase faster than those from active ones. Using coal production data from six integrated assessment models, this study shows that by 2100 methane emissions from active underground mines increase by a factor of 4, while emissions from abandoned mines increase by a factor of 8. Abandoned mine methane emissions continue through the century even with aggressive mitigation actions.

coal mine methane, abandoned coal mine methane, em↗

Entangled Photon Correlations Allow a Continuous-Wave Laser Diode to Measure Single-Photon, Time-Resolved Fluorescence

Fluorescence lifetime experiments are a standard approach for measuring excited state dynamics and local environment effects. Here, we show that entangled photon pairs produced from a continuous-wave (CW) laser diode can replicate pulsed laser experiments without phase modulation. As a proof of principle, picosecond fluorescence lifetimes of indocyanine green are measured in multiple environments. Here, the use of entangled photons has three unique advantages. First, low power CW laser diodes and entangled photon source design lead to straightforward on-chip integration for a direct path to distributable fluorescence lifetime measurements. Second, the entangled pair wavelength is easily tuned by temperature or electric field, allowing a single source to cover octave bandwidths. Third, femtosecond temporal resolutions can be reached without requiring major advances in source technology or external phase modulation. Entangled photons could therefore provide increased accessibility to time-resolved fluorescence while also opening new scientific avenues in photosensitive and inherently quantum systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Self-organized micro-holes on titania based sol-gel films under continuous direct writing with a continuous wave ultraviolet laser

The microstructuring of titania based sol-gel films is investigated by direct writing with a continuous wave ultraviolet laser beam emitting at 244 nm. Depending on the exposure conditions, the films exhibit a volume expansion, a volume shrinkage, a self-shaped delamination, or are damaged. This paper is mainly focused on the regime where spontaneous local delamination occurs, which corresponds to a narrow range of laser irradiances and writing speeds. In this regime, self-organized round-shape micro-holes opened on the substrate are generated.

36 MATERIALS SCIENCE↗

Continuous control of spin polarization using a magnetic field

The giant magnetoresistance (GMR) of a point contact between a Co/Cu multilayer and a superconductor tip varies for different bias voltage. Direct measurement of spin polarization by Andreev reflection spectroscopy reveals that the GMR change is due to a change in spin polarization. This work demonstrates that the GMR structure can be utilized as a spin source and that the spin polarization can be continuously controlled by using an external magnetic field.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Continuous doping of a cuprate surface: Insights from in situ angle-resolved photoemission [Continuous doping of a cuprate surface: Insights from in situ ARPES]

Here, we report a technique of a continuously doped surface of Bi 2 Sr 2 CaCu 2 O 8+x through ozone/vacuum annealing and a systematic measurement over the nearly whole superconducting dome on the same sample surface by in situ angle-resolved photoemission spectroscopy. We find that the quasiparticle weight on the antinode is proportional to the doped carrier concentration x within the entire superconducting dome, while the nodal quasiparticle weight changes more mildly. More significantly, we discover that a d-wave pairing energy gap extracted from the nodal region scales well with the onset temperature of the Nernst signal. These findings suggest that the emergence of superconducting pairing is concomitant with the onset of free vortices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Flow Intermittency, Dispersion, and Correlated Continuous Time Random Walks in Porous Media

We study the intermittency of fluid velocities in porous media and its relation to anomalous dispersion. Lagrangian velocities measured at equidistant points along streamlines are shown to form a spatial Markov process. As a consequence of this remarkable property, the dispersion of fluid particles can be described by a continuous time random walk with correlated temporal increments. This new dynamical picture of intermittency provides a direct link between the microscale flow, its intermittent properties, and non-Fickian dispersion.

Environmental Molecular Sciences Laboratory↗

A Model for Approximately Stretched-Exponential Relaxation with Continuously Varying Stretching Exponents

Relaxation in glasses is typically approximated by a stretched-exponential form: \(f(t) = A \exp [-(t/\tau )^{\beta }]\) . Here, we show that the relaxation in a model of sheared non-Brownian suspensions developed by Corté et al. (Nat Phys 4:420–424, 2008 ) can be well approximated by a stretched exponential with an exponent \(\beta \) that depends on the strain amplitude: \(0.25< \beta < 1\) . In a one-dimensional version of the model, we show how the relaxation originates from density fluctuations in the initial particle configurations. Our analysis is in good agreement with numerical simulations and reveals a functional form for the relaxation that is distinct from, but well approximated by, a stretched-exponential function.

36 MATERIALS SCIENCE↗