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At least 55 records · Page 3

DEVAP-EDDR-TES (Simulation framework for a desiccant assisted air conditioning system with heat pump regeneration and energy storage) [SWR-24-66]

This software is a simulation framework that models a load flexible air conditioner system. The system consists of an evaporatively cooled liquid desiccant air conditioner (eLD-AC) subsystem, an electrically driven desiccant regenerator (EDDR) subsystem, and a stratified liquid desiccant storage (SLDS) subsystem. The software can be used to 1) predict the steady-state performance of the system given user-specified convergence criteria; 2) predict the dynamic performance of the entire system over a typical drive cycle operation subjected to user-specified building thermal loads and desired electrical load profile; 3) evaluate the synergy of all three subsystems operating altogether and improve the energy storage control strategy.

Huang, Ransisi↗

Soil Desiccation Treatability Testing at BC Waste Disposal Cribs

During Hanford’s production period, low-level waste products generated from chemical processing of uranium fuel rods were discharged directly to the ground through a system of cribs and trenches located in the 200-BC-1 Operable Unit (OU). The site consists of 6 cribs and 20 trenches that received more than 117,000 m3 of radioactive liquid waste discharged to the soil. These unlined infiltration galleries held volumes of liquid waste while it seeped into the ground, with the understanding that the 100 m (330 ft) thick vadose zone in the area would effectively capture the effluent and prevent groundwater impacts. A conceptual model showing the operation of cribs and trenches is shown in Figure 1. Data show effluent from the 26 cribs and trenches containing about 410 curies of Technetium-99 (Tc-99) is primarily located between 30 m and 70 m (98 ft and 230 ft) depth (Corbin et al., 2005; Ward et al., 2004). Despite no evidence indicating that the contamination has reached the groundwater at BC cribs and trenches, the mobility of Tc-99 had been demonstrated in laboratory tests and was recognized as a threat to groundwater at the site. Using data from numerical models, laboratory analyses, field investigations, and information on historical discharges, the EPA and Ecology identified Tc-99 and U contamination of the vadose zone as a remediation priority. The U.S. DOE was notified by EPA and Ecology regarding risks associated with Tc-99 contamination in a letter requesting development of a strategy for improved methods to understand the nature and extent of vadose zone contamination, specifically Tc-99, and to develop remedial options for addressing such contamination. To develop the appropriate technology for characterizing, remediating, and monitoring the deep vadose zone Tc-99 contamination, the U.S. DOE worked with the EPA and Ecology to create a Treatability Test Plan under a Remedial Investigation/Feasibility Study (RI/FS) for the Hanford 200 Areas. Under this RI/FS, it was determined that a treatability test for soil desiccation should be carried out as it was identified as a promising in-situ treatment technology for mitigating risks posed by Tc-99 contamination to the groundwater table. The BC Cribs and Trenches site was identified as a representative site for Tc-99 and U contamination and selected for the soil desiccation treatability test. In this chapter, we summarize the overlying regulatory framework of RI/FS and treatability tests and illustrate how development and experimentation supported the evaluation of selected remedies. We briefly discuss the RI/FS for the 200 Areas of the Hanford Site and focus on the soil desiccation treatability testing performed at the BC cribs and trenches site under the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau (DVZ-TT). The DVZ-TT is one component of the remedial investigation/feasibility study for the Hanford 200 Areas and represents the underlying regulatory framework that drives site operations towards records of decision and site closure.

Mangel, Adam R.↗

Membrane-Based Air Dehumidification Using Organic Ionic Liquid Desiccant

Membrane Ionic Liquid Desiccant Air Dehumidification (MILDAD) is a promising alternative to conventional dehumidification systems that employ mechanical compressors and refrigerant-based cooling with evaporator and condensing coils. However, its application has been limited due to high manufacturing and installation cost, durability issues, concerns with corrosion due to leakage and salt carry over into the downstream air and onto surfaces. This paper reviews substantial progress made with new systems based on combining advanced ionic membranes that are pressure resistant, thin walled with high water permeability, and non-porous with synthetic organic, non-crystalline ionic liquid desiccants. Alternative design configurations are discussed comparing cross flow shell-and-tube membrane contactors employing ionic membrane tubes through which ionic liquid desiccant air flows. Performance data for MILDAD prototypes is provided. Dehumidification of the incoming supply airstream and regeneration into exhausted building air is demonstrated. The latent effectiveness of the MILDAD system will be discussed along with some future steps to improve performance of the system.

Bahar, Bamdad↗

Numerical and experimental analysis of precooled desiccant system

This paper presents a numerical and experimental study of four novel, desiccant air-conditioning systems based on pre-cooling of the ambient air. The purpose of the study is to: 1) establish which configuration is most profitable for the future studies through numerical and experimental methods; 2) verify the concept of precooled system and confirm that it is working in experimental conditions (for this purpose two prototypes of evaporative cooling units were developed and compared for different operation arrangements with desiccant wheel); 3) Analyze practical aspects of the systems, which includes water consumption analysis, economic analysis and establishing operational modes during a cooling season in temperate climate conditions (the proposed solution has a significant advantage during operation in a temperate climate, since it can utilize its first evaporative cooler the only source of cooling energy when the humidity of outdoor air allows to to meet the latent cooling load). Four arrangements of the system with different dew point evaporative air cooler prototypes were selected and developed for comparative analysis. The system was simulated as a whole, also, each component was individually tested on measurement station. develop the optimal arrangement of the system through numerical and experimental analysis. Four different performance indicators were considered: thermal COP (Coefficient Of Performance), the ERR (Energy Efficiency Ratio), coefficient a describing the potential in compensating indoor cooling loads, water consumption ratio. Also costs of the systems were compared through economic analysis. It was established that arrangement which is characterized by best-averaged performance in terms of all considered factors is a unit combined with two different types of evaporative coolers (marked as System B)- this is caused by the favorable arrangement of two units, where one is better suited to the pre-cooler role, while the other is better suited as the post-cooler.

42 ENGINEERING↗

The physics of desiccation cracks 2: Modeling and prediction of the crack patterns

Here, this paper extends the experimental results of our companion paper by modeling and predicting the onset and pattern formation of desiccation cracks in geomaterials (Ruoyu et al., 2023). Thin-layer silt samples in controlled atmospheric conditions were tested to obtain the surface strain maps with the digital image correlation (DIC) method during dehydration. Support experiments, including consolidation and displacement-controlled triaxial tests, were conducted for the properties of geomaterials. These experimental results were used to validate a viscoplastic theoretical model by comparing cracks and singularities locations that distribute following the Cnoidal wave pattern. A critical value exists in the viscoplastic model that determines the number of singularities, which accurately predicts the number of cracks in the experiment. The critical values contain two crucial parameters: rate sensitivity and λ. Rate sensitivity describes the rate-dependent stress–strain relation, while λ shows the ability of pore pressure redistribution under the external mechanical loading rate. These results provide a new view to analyze the desiccation cracks considering the rate-dependent viscoplasticity.

42 ENGINEERING↗

Anatomical and hydraulic responses to desiccation in emergent conifer seedlings

Premise The young seedling life stage is critical for reforestation after disturbance and for species migration under climate change, yet little is known regarding their basic hydraulic function or vulnerability to drought. Here, we sought to characterize responses to desiccation including hydraulic vulnerability, xylem anatomical traits, and impacts on other stem tissues that contribute to hydraulic functioning. Methods Larix occidentalis , Pseudotsuga menziesii , and Pinus ponderosa (all ≤6 weeks old) were imaged using x‐ray computed microtomography during desiccation to assess seedling biomechanical responses with concurrently measured hydraulic conductivity ( k s ) and water potential ( Ψ ) to assess vulnerability to xylem embolism formation and other tissue damage. Results In non‐stressed samples for all species, pith and cortical cells appeared circular and well hydrated, but they started to empty and deform with decreasing Ψ which resulted in cell tearing and eventual collapse. Despite the severity of this structural damage, the vascular cambium remained well hydrated even under the most severe drought. There were significant differences among species in vulnerability to xylem embolism formation, with 78% xylem embolism in L. occidentalis by Ψ of −2.1 MPa, but only 47.7% and 62.1% in P. ponderosa and P. menziesii at −4.27 and −6.73 MPa, respectively. Conclusions Larix occidentalis seedlings appeared to be more susceptible to secondary xylem embolism compared to the other two species, but all three maintained hydration of the vascular cambium under severe stress, which could facilitate hydraulic recovery by regrowth of xylem when stress is relieved.

Miller, Megan L.↗

Mass spectrometry and spectroscopic characterization of a tetrameric photosystem I supercomplex from Leptolyngbya ohadii , a desiccation-tolerant cyanobacterium

Cyanobacteria inhabiting desert biological soil crusts face the harsh conditions of the desert. They evolved a suite of strategies toward desiccation-hydration cycles mixed with high light irradiations, etc. In this study we purified and characterized the structure and function of Photosystem I (PSI) from Leptolyngbya ohadii, a desiccation-tolerant desert cyanobacterium. We discovered that PSI forms tetrameric (PSI-Tet) aggregate. We investigated it by using sucrose density gradient centrifugation, clear native PAGE, high performance liquid chromatography, mass spectrometry (MS), time-resolved fluorescence (TRF) and time-resolved transient absorption (TA) spectroscopy. MS analysis identified the presence of two PsaB and two PsaL proteins in PSI-Tet and uniquely revealed that PsaLs are N-terminally acetylated in contrast to non-modified PsaL in the trimeric PSI from Synechocystis sp. PCC 6803. Chlorophyll (Chl) a fluorescence decay profiles of the PSI-Tet performed at 77 K revealed two emission bands at ∼690 nm and 725 nm with the former appearing only at early delay time. The main fluorescence emission peak, associated with emission from the low energy Chls a, decays within a few nanoseconds. TA studies demonstrated that the 725 nm emission band is associated with low energy Chls a with absorption band clearly resolved at ∼710 nm at 77 K. As a result, our work suggests that the heterogenous composition of PsaBs and PsaL in PSI-Tet is related with the adaptation mechanisms needed to cope with stressful conditions under which this bacterium naturally grows.

59 BASIC BIOLOGICAL SCIENCES↗

Performance Analysis of a Membrane-based Ionic Liquid Desiccant (ILD) Dehumidifier

Air dehumidification through cooling is an energy-intensive process, which consumes about 20-40% of the overall energy for air-conditioning. Liquid desiccant dehumidification can separate dehumidification from space cooling and has potential to improve the cooling efficiency and reduce the overall energy consumption for air-conditioning. However, the drawbacks such as liquid carryover and corrosion, membrane contamination and blocking, limit its application. To eliminate these problems, a new dehumidifier using nonporous membrane and ionic liquid desiccant (ILD) was developed. The dehumidification performance of the new dehumidifier was characterized through a series of lab tests. Test results indicate that the new dehumidifier can achieve a moisture removal rate up to 180.3 g/h and a dehumidification effectiveness up to 12.7%. A parametric study found that the dehumidification performance is sensitive to the flowrates of the air and the ILD solution. A higher mass flow ratio between the ILD solution and the air could result in better dehumidification performance.

Wang, Lingshi↗

Dynamic Simulation Modeling and Control of a Desiccant Assisted Direct-expansion Air Handling Unit

Desirable built environments demand simultaneous regulation of thermal comfort and indoor air quality (IAQ) with energy-efficient operation of heating, ventilation and air conditioning (HV AC) systems, which involves controls of temperature, humidity and airborne contaminants simultaneously. This paper presents the efforts of dynamic modeling and initial development control strategy for a desiccant-assisted multi-functional air handling unit (AHU) coupled with a direct-expansion rooftop unit (RTU) system, which aims to achieve multiple functions for indoor environment conditioning with energy efficient control. The RTU-AHU system includes a desiccant wheel for dehumidification and a conceptual direct air capture (DAC) filtering device for CO2 regulation. A Modelica-based dynamic model is developed for this conceptual system, and a simple decentralized control strategy is designed, which combines a differential-enthalpy based AHU return-air ratio control, a demand-controlled ventilation, and supply-air temperature humidity control via the RTU and DW controls. The proposed control method is evaluated with the Modelica simulation model for a selected set of scenarios

Pan, Chao↗

Independent temperature and humidity control of a precooled desiccant air cooling system with proportional and fuzzy logic + proportional based controllers

Providing room comfort quickly by using less energy in cooling systems is important both in terms of efficiency and environment. In this study, independent temperature/humidity control strategies are designed for precooled desiccant based evaporative cooling system to provide room comfort quickly with less energy. Therefore, the speed controls of the system's actuators become important depending on the room, cooler and atmosphere conditions. The mathematical models are obtained to determine the relation between voltages of actuators and the variations in the room's temperature and humidity. After that, new control strategies are developed based on Proportional and Fuzzy+Proportional techniques and the control performance is increased by adding extra modes to the operation of the actuators. The effects of the control techniques on the cooling performance and energy consumption were investigated for different cases. It has been observed that the room temperature and relative humidity reach the set values in a short time for both techniques and are successfully kept at these values under the disturbances. By using Fuzzy+Proportional controller, the robustness of the cooler increases due to more precisely adjustment of controller's parameter depending the system conditions. Finally, both control strategies provide more than 20% energy savings compared to the traditional ON/OFF control.

42 ENGINEERING↗

Modeling Water Vapor Transport at Liquid/Membrane Interfaces for Applications in Liquid Desiccant Air Conditioners (CRADA CRD-17-679 Final Report)

Conventional compressor-based cooling has undergone incremental changes over the past 100 years. Further improvements in efficiency require evermore complex systems, especially under humid conditions. Meso-porous membranes offer unique opportunities for efficient humidity control in buildings using an absorbent desiccant solution, but membranes are not designed or optimized for this purpose. This project will use molecular dynamic simulations to determine optimal membrane properties for these air conditioning applications, focusing on the membrane properties at the membrane/liquid/air interface. Optimal membrane designs will enable smaller, more durable, and less expensive designs of these membrane air conditioning systems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance and Characterization of Membrane Liquid Desiccant Air Conditioning Systems

This document is intended to describe the work objectives and tasks for several projects between the National Renewable Energy Laboratory (NREL) and 7AC Technologies, with indirect support from 3M. The projects all revolve around the performance and characterization of membrane liquid desiccant air conditioning systems. Projects are listed in order of preference to 7AC's technical and business goals.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Moisture Absorbing and Water Self‐Releasing from Hybrid Hydrogel Desiccants

Abstract Atmospheric moisture is a valuable resource for fresh water and potentially sustainable energy. However, direct harvesting water from moisture (the vapor form) remains the most challenging. Hybrid desiccants made from hydrogels embedded with salt offer promise in absorbing moisture. However, the desorption process often requires additional energy to heat the samples. Here, poly(acrylic acid) (PAA) hydrogels embedded with lithium chloride are prepared, demonstratng simultaneous moisture absorption and self‐release of liquid water at room temperature with 50–90% relative humidity. The water self‐releasing process can be separated into two distinct stages: 1) surface release, where water droplets grow on the hydrogel surface due to differences in nucleation and diffusion rates, and 2) bulk release, triggered by the collapse of polymer chains, subsequently releasing water from the hydrogel network. Factors such as salt concentration, hydrogel crosslinking density, and film thickness are investigated to better understand the moisture absorption and water‐releasing processes. Moreover, hydrophobic domains are introduced onto the salt‐embedded PAA films, creating an edge effect that enhances the droplet growth rates. When the hydrophobic domains are patterned, the movement of released water can be guided, resulting in a threefold increase in water removal rate attributed to gravitational force.

Chemistry↗

Heat-pump driven desiccant regeneration

Disclosed herein are systems and processes to thermally regenerate and re-concentrate a liquid desiccant (absorbent) with an electrically driven heat pump. The regeneration and re-concentration may be performed in a cost and energy efficient manner.

Woods, Jason David↗

Liquid desiccant based dehumidification and cooling system

A liquid desiccant system including a high desorber, a low desorber, and an absorber that are in fluid communication with a working solution, where the high desorber provides rejected water vapor from the working fluid for condensation in a condenser of the low desorber that provides heat for rejection of additional water from the working solution in the low desorber effectively multiplying the heat provided for desorption. The low desorber provided the concentrated working solution to the absorber where water from ambient air is condensed into the concentrated working solution to provide a dilute working solution within a working solution conduit of the absorber that is thermally coupled to an internal cooler of the absorber. In some embodiments, the working solution can be an aqueous solution of at least one ionic liquid.

Moghaddam, Saeed↗

Liquid desiccant based dehumidification and cooling system

A liquid desiccant system including a high desorber, a low desorber, and an absorber that are in fluid communication with a working solution, where the high desorber provides rejected water vapor from the working fluid for condensation in a condenser of the low desorber that provides heat for rejection of additional water from the working solution in the low desorber effectively multiplying the heat provided for desorption. The low desorber provided the concentrated working solution to the absorber where water from ambient air is condensed into the concentrated working solution to provide a dilute working solution within a working solution conduit of the absorber that is thermally coupled to an internal cooler of the absorber. In some embodiments, the working solution can be an aqueous solution of at least one ionic liquid.

Moghaddam, Saeed↗