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Results for “Dynamical evolution and stability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Unveiling the Mechanism of Mn Dissolution Through a Dynamic Cathode‐Electrolyte Interphase on LiMn2O4

Abstract Understanding the formation and evolution of the cathode‐electrolyte interphase (CEI), which forms at the interface between the cathode and electrolyte, is crucial for revealing degradation mechanisms in cathode materials, especially for developing strategies to stabilize the interphase in the strongly oxidizing conditions that evolve at high operating voltages in next‐generation Li‐ion batteries. However, The present understanding of the CEI is challenged by its complex and dynamic nature. In this work, near‐edge X‐ray absorption fine structure spectroscopy, electrochemical characterization, and reactive molecular dynamics simulations are combined to reveal a mechanism for CEI formation and evolution above model LiMn 2 O 4 (LMO) thin‐film electrodes in contact with conventional carbonate‐based electrolytes. It is found that Mn dissolution from LMO can be understood in terms of repetitive Mn 3 O 4 formation and dissolution behavior during cycling, which is closely connected to electrolyte decomposition and a key aspect of the CEI formation and growth. The behavior of the CEI in this model system offers detailed insight into the dynamic chemistry of the interphase, underscoring the important role of electrolyte composition and cathode surface structure in interphase degradation.

Ou, Wenhan↗
NASA NTRS1984

Reversibility and stability of information processing systems

Classical and quantum models of dynamically reversible computers are considered. Instabilities in the evolution of the classical 'billiard ball computer' are analyzed and shown to result in a one-bit increase of entropy per step of computation. 'Quantum spin computers', on the other hand, are not only microscopically, but also operationally reversible. Readoff of the output of quantum computation is shown not to interfere with this reversibility. Dissipation, while avoidable in principle, can be used in practice along with redundancy to prevent errors.

Zurek, W. H.↗
NASA NTRS2011

Links Between Acceleration, Melting, and Supraglacial Lake Drainage of the Western Greenland Ice Sheet

The impact of increasing summer melt on the dynamics and stability of the Greenland Ice Sheet is not fully understood. Mounting evidence suggests seasonal evolution of subglacial drainage mitigates or counteracts the ability of surface runoff to increase basal sliding. Here, we compare subdaily ice velocity and uplift derived from nine Global Positioning System stations in the upper ablation zone in west Greenland to surface melt and supraglacial lake drainage during summer 2007. Starting around day 173, we observe speedups of 6-41% above spring velocity lasting 40 days accompanied by sustained surface uplift at most stations, followed by a late summer slowdown. After initial speedup, we see a spatially uniform velocity response across the ablation zone and strong diurnal velocity variations during periods of melting. Most lake drainages were undetectable in the velocity record, and those that were detected only perturbed velocities for approx 1 day, suggesting preexisting drainage systems could efficiently drain large volumes of water. The dynamic response to melt forcing appears to (1) be driven by changes in subglacial storage of water that is delivered in diurnal and episodic pulses, and (2) decrease over the course of the summer, presumably as the subglacial drainage system evolves to greater efficiency. The relationship between hydrology and ice dynamics observed is similar to that observed on mountain glaciers, suggesting that seasonally large water pressures under the ice sheet largely compensate for the greater ice thickness considered here. Thus, increases in summer melting may not guarantee faster seasonal ice flow.

Hoffman, M. J.↗
NASA NTRS2012

Links Between Acceleration, Melting, and Supraglacial Lake Drainage of the Western Greenland Ice Sheet

The impact of increasing summer melt on the dynamics and stability of the Greenland Ice Sheet is not fully understood. Mounting evidence suggests seasonal evolution of subglacial drainage mitigates or counteracts the ability of surface runoff to increase basal sliding. Here, we compare subdaily ice velocity and uplift derived from nine Global Positioning System stations in the upper ablation zone in west Greenland to surface melt and supraglacial lake drainage during summer 2007. Starting around day 173, we observe speedups of 6-41% above spring velocity lasting approximately 40 days accompanied by sustained surface uplift at most stations, followed by a late summer slowdown. After initial speedup, we see a spatially uniform velocity response across the ablation zone and strong diurnal velocity variations during periods of melting. Most lake drainages were undetectable in the velocity record, and those that were detected only perturbed velocities for approximately 1 day, suggesting preexisting drainage systems could efficiently drain large volumes of water. The dynamic response to melt forcing appears to 1) be driven by changes in subglacial storage of water that is delivered in diurnal and episodic pulses, and 2) decrease over the course of the summer, presumably as the subglacial drainage system evolves to greater efficiency. The relationship between hydrology and ice dynamics observed is similar to that observed on mountain glaciers, suggesting that seasonally large water pressures under the ice sheet largely compensate for the greater ice thickness considered here. Thus, increases in summer melting may not guarantee faster seasonal ice flow.

Hoffman, M. J.↗
DOE OSTI2024

Revealing Structural Evolution of Nickel Phosphide-Iron Oxide Core–Shell Nanocatalysts in Alkaline Medium for the Oxygen Evolution Reaction

Metal phosphide-containing materials have emerged as a potential candidate of non-precious metal-based catalysts for alkaline oxygen evolution reaction (OER). While it is known that metal phosphide undergoes structural evolution, considerable debate persists regarding the effects of dynamics on the surface activation and morphological stability of the catalysts. In this study, we synthesize NiP x -FeO x core-shell nanocatalysts with an amorphous NiP x core designed for enhanced OER activity. Using ex-situ X-ray absorption spectroscopy, we elucidate the local structural changes as a function of cyclic voltammetry cycles. Our studies suggest that the presence of corner-sharing octahedra in the FeO x shell improves structural rigidity through interlayer cross-linking, thereby inhibiting the diffusion of OH - /H 2 O. Thus, the FeO x shell preserves the amorphous NiP x core from rapid oxidation to Ni 3 (PO 4 ) 2 and Ni(OH) 2 . On the other hand, the incorporation of Ni from the core into the FeO x shell facilitates absorption of hydroxide ions for OER. As a result, the Ni/Fe(OH) x at the surface oxidizes to the active γ-(oxy)hydroxide phase under the applied potentials, promoting OER. This intriguing synergistic behavior holds significance as such synthetic route involving the FeO x shell can be extended to other systems, enabling manipulation of surface adsorption and diffusion of hydroxide ions. These findings also demonstrate that nanomaterials with core-shell morphology can be tuned to leverage the strength of each metallic component for improved electrochemical activities.

25 ENERGY STORAGE↗
NASA NTRS2017

Hinode: A Decade of Success in Capturing Solar Activity

As the present solar cycle passes into its minimum phase, the Hinode mission marks its tenth year of investigating solar activity. Hinode's decade of successful observations have provided us with immeasurable insight into the solar processes that invoke space weather and thereby affect the interplanetary environment in which we reside. The mission's complementary suite of instruments allows us to probe transient, high energy events alongside long-term, cycle-dependent phenomena from magnetic fields at the Sun's surface out to highly thermalized coronal plasma enveloping active regions (ARs). These rich data sets have already changed the face of solar physics and will continue to provoke exciting research as new observational paradigms are pursued. Hinode was launched as part of the Science Mission Directorate's (SMD) Solar Terrestrial Probes Program in 2006. It is a sophisticated spacecraft equipped with a Solar Optical Telescope (SOT), an Extreme-ultraviolet Imaging Spectrometer (EIS), and an X-Ray Telescope (XRT) (see x 4). With high resolution and sensitivity, Hinode serves as a microscope for the Sun, providing us with unique capabilities for observing magnetic fields near the smallest scales achievable, while also rendering full-Sun coronal context in the highest thermal regimes. The 2014 NASA SMD strategic goals objective to "Understand the Sun and its interactions with the Earth and the solar system, including space weather" forms the basis of three underlying Heliophysics Science Goals. While Hinode relates to all three, the observatory primarily addresses: Explore the physical processes in the space environment from the Sun to the Earth and through the solar system. Within the NASA National Research Council (NRC) Decadal Survey Priorities, Hinode targets: (a) Determine the origins of the Sun's activity and predict the variations of the space environment and (d) Discover and characterize fundamental processes that occur both within the heliosphere and throughout the universe. In response to the 2012 NRC Decadal Survey Science Challenges and 2014 Heliophysics Roadmap Research Focus Areas, the Hinode mission has set forth four Prioritized Science Goals (PSGs): (a) Study the sources and evolution of highly energetic dynamic events; (b) Characterize cross-scale magnetic field topology and stability; (c) Trace mass and energy flow from the photosphere to the corona; and (d) Continue long term synoptic support to quantify cycle variability.

review↗
DOE OSTI2023

Isotope physics of heat and particle transport with tritium in JET-ILW type-I ELMy H-mode plasmas

As part the DTE2 campaign in the JET tokamak, we conducted a parameter scan in T and D-T complementing existing pulses in H and D. For the different main ion masses, type-I ELMy H-modes at fixed plasma current and magnetic field can have the pedestal pressure varying by a factor of 4 and the total pressure changing from <?CDATA $\beta_{\mathrm{N}} = 1.0$?> β N = 1.0 to 3.0. We investigated the pedestal and core isotope mass dependencies using this extensive data set. The pedestal shows a strong mass dependence on the density, which influences the core due to the strong coupling between both plasma regions. To better understand the causes for the observed isotope mass dependence in the pedestal, we analysed the interplay between heat and particle transport and the edge localised mode (ELM) stability. For this purpose, we developed a dynamic ELM cycle model with basic transport assumptions and a realistic neutral penetration. The temporal evolution and resulting ELM frequency introduce an additional experimental constraint that conventional quasi-stationary transport analysis cannot provide. Our model shows that a mass dependence in the ELM stability or in the transport alone cannot explain the observations. One requires a mass dependence in the ELM stability as well as one in the particle sources. The core confinement time increases with pedestal pressure for all isotope masses due to profile stiffness and electromagnetic turbulence stabilisation. Interestingly, T and D-T plasmas show an improved core confinement time compared to H and D plasmas even for matched pedestal pressures. For T, this improvement is largely due to the unique pedestal composition of higher densities and lower temperatures than H and D. With a reduced gyroBohm factor at lower temperatures, more turbulent drive in the form of steeper gradients is required to transport the same amount of heat. This picture is supported by quasilinear flux-driven modelling using TGLF -SAT2 within Astra . With the experimental boundary condition TGLF -SAT2 predicts the core profiles well for gyroBohm heat fluxes <?CDATA ${\gt}15$?> > 15 , however, overestimates the heat and particle transport closer to the turbulent threshold.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

On Practical Aspects of Variational Consistency in Contact Dynamics

Usage of contact mechanics methodologies is a pervasive modeling requirement in dynamic simulations. While for some trivial problems, solutions taken from analytical geometry are available, use of a finite element framework is common to achieve formulation generality. This work explores two dynamic contact formulations: one based on the traditional node-to-segment (NTS) approach, and a variationally consistent segment-to-segment (STS) mortar formulation. The NTS formulation employed here enforces the constraints kinematically (i.e., the interpenetration is enforced to the solver tolerance), whereas the mortar approach uses Lagrange multipliers to enforce the contact constraints. Both approaches are implemented in the open-source finite element framework Multiphysics Object-Oriented Simulation Environment (MOOSE). The results highlight two relevant contact-interface-related dynamic phenomena in finite element simulations. First, stabilization of contact constraints is discussed, taking into account the evolution of the total energy in a benchmark problem. Second, the influence of finite element discretization on both of the aforementioned contact formulations is analyzed by exercising a large-deformation example with continuous relative sliding. Variationally consistent contact approaches such as the mortar formulation lead to improved energy preservation and avoid spurious excitation of the system's frequencies. This is especially relevant in settings where inertia and vibrations are of importance.

42 ENGINEERING↗
DOE OSTI2026

Pathways to High-Performance Salt Hydrate Thermochemical Energy Storage Materials and Systems

Thermochemical materials (TCMs) based on salt hydrates are promising for thermal energy storage as they combine high energy densities with low reaction temperatures. However, their adoption is hindered by poor structural integrity and degradation under hygrothermal cycling. Storage performance is governed not only by the chemical reaction, but also by the coupled thermo-chemo-mechanical behavior that evolves with cycling. Understanding and controlling this coupling across length scales (material-to-reactor) is necessary to improve TCM stability and lifetime. In this perspective, we discuss the shortcomings of current characterization approaches and emphasize the need for measuring transport properties and structural transformations using in situ techniques that capture the dynamic evolution of these materials. We also outline opportunities for multiscale modeling frameworks that link thermodynamics and mechanics, enabling predictive evaluation of composite architectures designed for cycling stability. We conclude by identifying research questions that must be addressed to transform TCMs into viable energy storage technologies.

Composites↗
NASA NTRS1983

The diffusivity of hydrogen in Nb stabilized stainless steel

The evolution of hydrogen from 347 stainless steel has been studied by using a real time dynamic technique under ultrahigh vacuum conditions. Auger electron spectroscopy was used to determine the surface composition as a function of time and temperature. The surface film on the electropolished samples was found to be approximately 15 A thick and consisted of a carbon-oxygen complex and a metal oxide (FexOy). Upon heating to 400 C, the carbon-oxygen complex desorbed as CO and the remaining oxygen and carbon began to incorporate. Also at this temperature sulfur began to diffuse out of the bulk to the surface and at approximately 800 C formed a complete monolayer. At 900 C, carbon and oxygen virtually disappeared, leaving the monolayer of sulfur as the only surface contaminant. The hydrogen diffusivity was found to follow closely the equation D = 7.01 x 10 to the -7th exp(-48.0/RT) sq m per second over the entire temperature range studied, thus indicating that hydrogen evolution is not significantly affected by the changing surface composition. The somewhat higher value of the diffusivity obtained in this work compared to past measurements in austenitic stainless steels may indicate the importance of sample preprocessing and ultrahigh vacuum conditions in minimizing the effects of surface layers.

Outlaw, R. A.↗
DOE OSTI2021

Exomoons in Systems with a Strong Perturber: Applications to α Cen AB

The presence of a stellar companion can place constraints on occurrence and orbital evolution of satellites orbiting exoplanets, i.e., exomoons. In this work we revise earlier orbital stability limits for retrograde orbits in the case of a three-body system consisting of a star, planet, and satellite. The revised limit reads a{sub sat}{sup crit}≈0.668(1-1.236e{sub p}) for e {sub p} ≤ 0.8 in units of the Hill Radius and represents the lower critical orbit as a function of the planetary eccentricity e {sub p}. A similar formula is determined for exomoons hosted by planets in binary star systems, where e {sub p} is replaced with the components of free and forced eccentricity from secular orbit evolution theory. By exploring the dynamics of putative exomoons in α Centauri AB we find that the outer stability limit can be much less than half the Hill Radius due to oscillations in the planetary orbital eccentricity caused by the gravitational interaction with the binary star. We show, furthermore, how the resulting truncation of the outer stability limit can affect the outward tidal migration and potential observability of exomoons through transit-timing variations (TTVs). Typical TTV (rms) amplitudes induced by exomoons in binary systems are ≲10 minutes and appear more likely for planets orbiting the less massive stellar component.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2020

Dynamic Stability And Adaptive Control of Networked Evolving Formations with Weak Nonlinearities

The dynamic stability of formation geometry is vital to the design of large scale multiagent systems. In this paper, we probe into the structure of the formation system matrix using the Laplacian of a digraph to develop several fundamental theoretical results on the stability of formation geometry. Our key-results include the integration of the graph Laplacian into linear and weak-nonlinear relative dynamics, the development of several new coordinate transformations that expose the influence of the graph Laplacian matrix on the control laws of the agents, and the use of direct adaptive control as stability restoring devices. We also develop two fundamental results that provide upper bounds for stable formation evolution under nonlinear perturbations of agent dynamics. Finally, we use an illustrative example to demonstrate our theoretical findings.

Gehlot, Vinod P.↗
NASA NTRS2017

Effects of Variable Eccentricity on the Climate of an Earth-Like World

The Kepler era of exoplanetary discovery has presented the Astronomical community with a cornucopia of planetary systems very different from the one which we inhabit. It has long been known that Jupiter plays a major role in the orbital parameters of Mars and its climate, but there is also a long-standing belief that Jupiter would play a similar role for Earth if not for its large moon. Using a three dimensional general circulation model (3-D GCM) with a fully-coupled ocean we simulate what would happen to the climate of an Earth-like world if Mars did not exist, but a Jupiter-like planet was much closer to Earths orbit. We investigate two scenarios that involve evolution of the Earth-like planets orbital eccentricity from 0 to 0.066 on a time scale of 4500 years, and from 0 to 0.283 over 6500 years. We discover that during most of the 6500 year scenario the planet would experience a moist greenhouse effect when near periastron. This could have implications for the ability of such a world to retain an ocean on time scales of 109 years. More Earth-like planets in multi-planet systems will be discovered as we continue to survey the skies and the results herein show that the proximity of large gas giant planets may play an important role in the habitabilty of these worlds. These are the first such 3-D GCM simulations using a fully-coupled ocean with a planetary orbit that evolves over time due to the presence of a giant planet.

Stability↗
NASA NTRS2019

A New Method to Retrieve the Diurnal Variability of Planetary Boundary Layer Height from Lidar Under Different Thermodynamic Stability Conditions

The planetary boundary layer height (PBLH) is an important parameter for understanding the accumulation of pollutants and the dynamics of the lower atmosphere. Lidar has been used for tracking the evolution of PBLH by using aerosol backscatter as a tracer, assuming aerosol is generally well-mixed in the PBL; however, the validity of this assumption actually varies with atmospheric stability. This is demonstrated here for stable boundary layers (SBL), neutral boundary layers (NBL), and convective boundary layers (CBL) using an 8-year dataset of micropulse lidar (MPL) and radiosonde (RS) measurements at the ARM Southern Great Plains, and MPL at the GSFC site. Due to weak thermal convection and complex aerosol stratification, traditional gradient and wavelet methods can have difficulty capturing the diurnal PBLH variations in the morning and forenoon, as well as under stable conditions generally. A new method is developed that combines lidar-measured aerosol backscatter with a stability dependent model of PBLH temporal variation (DTDS). The latter helps “recalibrate” the PBLH in the presence of a residual aerosol layer that does not change in harmony with PBL diurnal variation. The hybrid method offers significantly improved PBLH detection, with better correlation and smaller biases, under most thermodynamic conditions, especially for SBL and CBL. Relying on the physical process of PBL diurnal development, different schemes are developed for growing, maintenance, and decaying periods. Comprehensive evaluation of this new method shows much better tracking of diurnal PBLH variation and significantly smaller biases under various pollution levels.

Tianning Su↗
NASA NTRS1987

Computational vortex dynamics in two and three dimensions

A discussion of some solutions and outstanding problems of dissipationless and nearly dissipationless flows in two and three dimensions is presented. In particular, two-dimensional steady-state solutions, linear stability and nonlinear evolutions including axisymmetrization of isolated vortex regions and merger or condensation of like-signed vorticity regions, are reviewed. These results are obtained from pseudo-spectral codes, contour dynamical (CD) codes and a new Hamiltonian moment-model of the Euler equations

Melander, Mogens V.↗
DOE OSTI2023

Electrolyte Role in SEI Evolution at Si in the Pre-lithiation Stage vs the Post-lithiation Stage

The formation and evolution of the dynamic solid electrolyte interphase (SEI) at the Si anode/electrolyte interface are yet to be completely understood to solve irreversible capacity loss and increase battery cycle life. Herein, the evolution of SEI and its dynamic properties at the Si anode/electrolyte interface are investigated in two electrolyte systems, a 1.2 M LiPF6 in EC: EMC 3:7 (wt%) electrolyte (referred to as Gen2) and a 1.2 M LiTFSI in EC: EMC 3:7 (wt%) electrolyte (referred to as LiTFSI). Two lithiation stages are studied: the pre-lithiation (pre-Li) SEI stage and the post-lithiation (post-Li) stage. Findings reveal at the pre-Li, SEI formation starts at an early potential and contributes to the greater mass gain in the Si/Gen2, and it is dominated by the formation of a non-uniform F- and P-rich layer in Si/Gen2, in contrast to a homogeneous F- and C-containing layer at the Si/LiTFSI interphase. The initially formed SEI in LiTFSI further benefits the charge transfer kinetics. At the post-Li stage, a more substantial SEI evolution is observed at Si/LiTFSI. This paper offers a foundational understanding of the SEI dynamic evolution with electrolyte dependence. Findings from this report offer important insights into solving the complex SEI stability issues on Si.

25 ENERGY STORAGE↗
NASA NTRS2003

Report of the Stability and Dynamics Session

Important issues: Mass gauging; Stability dynamics of disconnected capillary surfaces; Slow capillary driven flow (i.e. wicking); Long-term material property evolution in micro-g; Dumping problem with freezing of dump lines.

Alexander, Iwan↗