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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Elastomeric Nanocomposite with Solvent‐Free, One Step, In Situ Shear Exfoliation of Graphite to Graphene

A graphene nanoflake (GNF)‐enhanced elastomeric nanocomposite (G‐EMC) is fabricated following an innovative, cost‐effective, single‐step, in situ shear exfoliation (ISE) method from low‐cost bulk material, graphite, where uniform mixing happens simultaneously within the elastomer matrix. Electron microscopy, atomic force microscopy, and photo‐induced force microscopy results show good dispersion of GNFs with exfoliation to a few layers and uniform distribution in the elastomer matrix. X‐ray photoelectron spectroscopy analysis shows less than 1% oxygen‐containing functional groups/impurity, enhanced bonding through the formation of edge sites as fracture occurs across the GNF basal plane, and pi‐pi interactions with newly exfoliated planar basal plane surfaces of the GNFs. Raman spectroscopy results confirm the formation of GNFs with only a few layers of graphene formed by the ISE process. Fabricated 10 wt.% G‐EMC nanocomposites show a 400%–500% increase in strength and fracture toughness. And 35 wt.% G‐EMCs provide an electrical conductivity of 25.64 S m −1 and a sensor gauge factor of 45. The resulting intrinsic piezo resistivity of the fabricated nanocomposite has been exploited to fabricate a multi‐functional wired and wireless sensor for detecting different body movements, speech, human vital functions, solvents, and biomolecules.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Event generator for jet tomography in electron-ion collisions

We develop the first event generator, the electron-heavy-ion-jet-interaction-generator (eHIJING), for the jet tomography study of electron-ion collisions. In this generator, energetic jet partons produced from the initial hard scattering undergo multiple collisions with the nuclear target. The collision rate is proportional to the transverse-momentum-dependent (TMD) gluon density in the nucleus, which is given by a simple model inspired by the physics of gluon saturation. Medium-modified QCD splitting functions within the higher-twist (HT) and generalized higher-twist (GHT) frameworks are utilized to simulate parton showering in the nuclear medium that takes into account the non-Abelian Landau-Pomeranchuck-Midgal interference effect. Employing eHIJING, we revisit hadron production in semi-inclusive deep inelastic scattering (SIDIS) as measured by EMC, HERMES, and recent CLAS experiments. eHIJING with both GT and GHT frameworks gives reasonably good descriptions of these experimental data. Predictions for experiments at the future electron-ion colliders are also provided. It is demonstrated that future measurements of the transverse momentum broadening of single hadron spectra can be used to map out the two-dimensional kinematic (Q 2 , x B ) dependence of the jet transport coefficient $\hat{q}$ in cold nuclear matter.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Visual Impact Assessment of the Energetic Materials Complex Construction Project on Manhattan Project–Era Historic Properties, the TA-06-0037 Concrete Bowl, and the TA-22-0001 Quonset Hut

Concern for potential visual effects to historic Manhattan Project–era properties emerged early in the planning and consultation phase for the upcoming Energetic Materials Complex (EMC) construction project. In initial discussions with project managers and design team members, resource managers became aware of the need to consider potential impacts to the viewsheds of two nearby properties that are eligible for inclusion in the Manhattan Project National Historical Park (MAPR). Resource managers recognized that viewshed characteristics important to the integrity of the Concrete Bowl (Technical Area [TA-]06-0037) and the Quonset Hut (TA-22-0001) conceivably faced the prospect of lasting and irreversible visual impacts. A strategy to gather necessary data soon emerged. The approach presented to the New Mexico State Historic Preservation Officer (SHPO) on April 7, 2021, combined gathering baseline information from field visits with a geographic information system (GIS)-supported viewshed analysis. Accordingly, results from the viewshed analysis would help resource managers determine if a more comprehensive visual impact assessment (VIA) would be needed. If necessitated by the outcome of the GIS viewshed analysis, initial consultation with the SHPO specified the production of a VIA that would explore any potential visual adverse impacts to the Concrete Bowl and the Quonset Hut. Cultural resources and GIS specialists with the Laboratory performed a viewshed analysis shortly after consultation with the SHPO. The analysis indicated a high likelihood that at least one of the two Manhattan Project–era properties would experience at least a minimal level of visual impact and that a VIA would be needed. The resulting analysis provides a description of the undertaking, an account of the properties affected along with an evaluation of historical significance, an examination of potential visual impacts, and a determination of effect to the identified historic properties.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Simultaneous Extraction of Unpolarized PDFs and Nuclear Effects

We present a new global QCD analysis of unpolarized parton distribution functions (PDFs) and nuclear effects including for the first time data from the SeaQuest and Marathon experiments in addition to high-energy weak-boson-production data from the Tevatron and Large Hadron Collider. Simultaneously extracting the PDFs and nuclear effects, we examine the impact of the SeaQuest and Marathon data on the light-quark sea asymmetry and the EMC ratios of deuterium, helium, and tritium.

Cocuzza, Christopher↗
DOE OSTI2023

Solvation Effects on the Dielectric Constant of 1 M LiPF6 in Ethylene Carbonate: Ethyl Methyl Carbonate 3:7

We report the dielectric constant of 1 M LiPF 6 in EC:EMC 3:7 w/w (ethylene carbonate/ethyl methyl carbonate) in addition to neat EC:EMC 3:7 w/w. Using three Debye relaxations, the static permittivity value, or dielectric constant, is extrapolated to 18.5, which is compared to 18.7 for the neat solvent mixture. The EC solvent is found to strongly coordinate with the Li + cations of the salt, which results in a loss of dielectric contribution to the electrolyte. However, the small amplitude and large uncertainty in relaxation frequency for EMC cloud definitive identification of the Li + solvation shell. Importantly, the loss of the free EC permittivity contribution due to Li + solvation is almost completely balanced by the positive contribution of the associated LiPF 6 salt, demonstrating that a significant quantity of dipolar ion pairs exists in 1 M LiPF 6 in EC:EMC 3:7.

25 ENERGY STORAGE↗
DOE OSTI2020

Electroweak interactions in Nucleons and Nuclei

The neutrino oscillation experiments are being performed using detectors having moderate to heavy nuclear targets like $^{12}{C}$, $^{16}{O}$, $^{40}{Ar}$, $^{56}{Fe}$, $^{208}{Pb}$, etc. to get a reasonably good number of events. Many present-day neutrino experiments are taking data in the few GeV (1 $\leq$ E$_{\nu}$ $\leq$ 10 GeV) energy region of neutrinos and antineutrinos to which some of the neutrino oscillation parameters are sensitive and required to understand CP violation in the lepton sector. This is the energy region which is most intriguing as it receives the contribution from the Quasielastic Scattering~(QE), Inelastic Scattering(IE), Shallow Inelastic Scattering (SIS) and the Deep Inelastic Scattering~(DIS) processes. This thesis details three different studies: \begin{itemize} \item First, a DIS study was performed with the MINERvA experiment at the Fermilab. MINERvA is a dedicated neutrino and antineutrino cross-section measurement experiment and uses (anti)neutrino beams in the two energy runs {\it viz.} the low energy run~(the peak of which lies $\sim$ 3 GeV) and the medium energy run(the peak lies at $\sim$ 6 GeV). The MINERvA experiment is using several nuclear targets like $^{4}$He, $^{12}$C, $^{16}$O, $^{56}$Fe and $^{208}$Pb and the aim is to perform EMC~(European Muon Collaboration experiment using charged lepton beam on several nuclear targets) kind of measurements to understand the nuclear medium effects in both the neutrino and antineutrino modes in the wide region of Bjorken scaling variable $x$, and the four-momentum transfer squared $Q^2$, covering the quasielastic, inelastic, and the deep inelastic scattering regions. In the medium energy region, it is expected that more than 30\% of the events would arise due to DIS processes. \item Second part of the thesis includes the analysis of the proposed India-based Neutrino Observatory(INO) atmospheric neutrino experiment. This work is dedicated to studying atmospheric neutrino and ant ineutrino oscillation parameters in the INO experiment. We present the ICAL sensitivity to confirm a non-zero value of the difference in atmospheric mass squared of neutrinos and anti-neutrinos i.e. ($|\Delta m^{2}_{32}|$-$|\Delta\overline{m^{2}}_{32}|$). \item Third, the theoretical work that was performed at the Aligarh Muslim University. This work has been performed keeping in mind the theoretical development of a model that will describe the associated particle production induced by photons, electrons, neutrinos, and antineutrinos. We have studied the associated particle production induced by photons which receive the contributions from the non-resonant terms and from the nucleon, hyperon, and kaon resonances. \end{itemize}

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2026

Synergistic cellulase–xylanase formulations for enhanced dewatering and fiber bonding toward energy-efficient and sustainable paper and packaging production

A mechanistic understanding of the synergistic effects of enzymes on cellulosic fibers dewatering and fiber bonding is essential for advancing energy-efficiency and lightweight production of paper and packaging materials. This study investigates the impact of varying cellulase and xylanase formulations on equilibrium moisture content (EMC) after pressing and tensile strength of cellulosic fiber webs using a factorial experimental design. Nine custom enzyme formulations were evaluated at controlled dosages ranging from ∼20 to 76 FPU/mL cellulase and ∼500–1130 IU/mL xylanase. Response surface modeling revealed a significant synergy, particularly at 20–40 FPU/mL cellulase combined with ≥ 1000 IU/mL xylanase. Under these conditions, EMC decreased by up to 3.6% compared with the untreated refined control, while tensile index gains of up to 16% were statistically significant for optimized blends (p < 0.05). The interaction between cellulase and xylanase was also significant for the tensile response (p = 0.010). Protein efficiency analysis showed that optimized formulations containing 30–40% less protein outperformed the commercial benchmark. The nonlinear synergy between cellulase and xylanase is attributed to their complementary substrate specificities. Endoglucanase- and β‑glucosidase‑rich cellulases hydrolyze internal β‑1,4‑glycosidic bonds in amorphous cellulose, loosening fiber walls and increasing flexibility, while xylanases target hemicellulose, primarily xylan-rich domains, enhancing porosity and improve cellulase accessibility. Tailoring enzyme formulations at low loadings overcomes traditional trade-offs between strength and dewatering, enabling cost-effective, energy-efficient, low-carbon solutions for sustainable packaging and hygiene products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Ethylene Carbonate–Free Electrolytes for Stable, Safer High–Nickel Lithium–Ion Batteries

Ethylene carbonate (EC) is an important component in state-of-the-art electrolytes for lithium-ion batteries (LIBs). However, EC is highly susceptible to oxidation on the surface of high-nickel layered oxide cathodes, making it undesirable for next-generation high-energy-density LIBs. In this study, a simple, yet effective, EC-free electrolyte (20F1.5M-1TDI) is presented by adding 20 wt% fluoroethylene carbonate (FEC) and 1 wt% lithium 4,5-dicyano-2-(trifluoromethyl)imidazole (LiTDI) into 1.5 M LiPF 6 in an ethyl methyl carbonate (EMC) electrolyte. The 20F1.5M-1TDI electrolyte is found to efficiently passivate the graphite anode and stabilize high-nickel cathodes by a synergistic decomposition of FEC and LiTDI. The LiNi 0.9 Mn 0.05 Al 0.05 O 2 (NMA90)/graphite full cell with the 20F1.5M-1TDI electrolyte, therefore, exhibits an enhanced cycling stability and a suppressed voltage hysteresis growth compared to that with an EC-containing baseline electrolyte (1 M LiPF 6 in EC:EMC, 3:7 in weight, with 2 wt% vinyl carbonate). Advanced analytical tools, such as time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy, are employed to understand the underlying working mechanism of the EC-free electrolyte. Furthermore, the present study clearly showcases the great potential of EC-free electrolytes as a straightforward, practical approach for LIBs with high-nickel cathodes.

electrode/electrolyte interface↗
DOE OSTI2021

Probing the Reactivity of the Active Material of a Li-Ion Silicon Anode with Common Battery Solvents

Calculations and modeling have shown that replacing the traditional graphite anode with silicon can greatly improve the energy density of lithium-ion batteries. However, the large volume change of silicon particles and high reactivity of lithiated silicon when in contact with the electrolyte lead to rapid capacity fading during charging/discharging processes. In this report, we use specific lithium silicides (LS) as model compounds to systematically study the reaction between lithiated Si and different electrolyte solvents, which provides a powerful platform to deconvolute and evaluate the degradation of various organic solvents in contact with the active lithiated Si-electrode surface after lithiation. Nuclear Magnetic Resonance (NMR) characterization results show that a cyclic carbonate such as ethylene carbonate is chemically less stable than a linear carbonate such as ethylmethyl carbonate, fluoroethylene carbonate, and triglyme as they are found to be more stable when mixed with LS model compounds. Furthermore, guided by the experimental results, two ethylene carbonate (EC)-free electrolytes are studied, and the electrochemical results show improvements with graphite-free Si electrodes relative to the traditional ethylene-carbonate-based electrolytes. More importantly, the study contributes to our understanding of the significant fundamental chemical and electrochemical stability differences between silicon and traditional graphite lithium-ion battery (LIB) anodes and suggests a focused development of electrolytes with specific chemical stability vs lithiated silicon which can passivate the surface more effectively.

25 ENERGY STORAGE↗
DOE OSTI2024

A Compact, Single Stage, >1 kV Medium-Voltage Line Impedance Stabilization Network

This paper presents the design of a single-phase, single-stage line impedance stabilization network (LISN) for medium-voltage (MV) applications. More than 1 kV rated widebandgap (WBG) power semiconductor switches are increasingly utilized in new, emerging power electronics energy systems to improve power density and efficiency. However, due to inherently fast-switching speeds, WBG switch modules emit considerable electromagnetic interference (EMI) (e.g., common mode (CM) or differential mode (DM)). State-of-the-art offers standardized LISN solutions to validate and certify the new energy system for electromagnetic compatibility (EMC). However, most are for low voltage applications (i.e., < 1 kV). MV LISNs (i.e., > 1 kV) are rare until recently and literature does not provide sufficient guidelines for designing and characterizing such devices. It has been a critical challenge for many scientists and engineers to reliably certify the emerging MV energy systems (e.g., electric ships and aircraft). This paper addresses such a technology gap. Specifically, a CISPR 16-1-2 compliant 50Ω/50μH LISN with 1.5kV, 75A and 30MHz measurement capability has been proposed. Detailed performance study versus non-linear parasitic parameters variations in MV inductors and capacitors have been done. Based on new understandings, novel techniques to intuitively mitigate unwanted parasitic have been proposed to develop the proposed LISN successfully. Thorough characterization of important LISN parameters are presented and factors influencing them are analyzed. A rigorous analysis, experimental tests, and in-depth comparisons over state-of-the-art have been made to validate the effectiveness. This is done through the state-of-the-art 300kVA MV EMI testbed.

42 ENGINEERING↗
DOE OSTI2024

Superfast quarks in deuterium

An extension to our previous study on nuclear parton distribution functions (nPDFs) [Kim and Miller, Phys. Rev. C 106, 055202 (2022)] using light-front holographic quantum chromodynamics (LFHQCD) [Brodsky, de Teramond, Dosch, and Erlich, Phys. Rep. 584, 1 (2015)] is presented. We apply the effects of nucleon motion inside the nucleus (Fermi motion/smearing) to deuterium, extending our deuterium nPDFs to the superfast , 𝑥 > 1, region [Frankfurt and Strikman, Phys. Rep. 160, 235 (1988)] where we estimate our results to be reasonable up to 𝑥 ≈ 1.7. We utilize four different deuteron wave functions (AV18, NijmI, NijmII, Nijm93). We find that our model, with no additional new parameters, shows very good agreement with deuterium EMC ratio data obtained from the BONuS experiment [Fenker et al., Nucl. Instrum. Methods Phys. Res. A 592, 273 (2008); Baillie et al. (CLAS Collaboration), Phys. Rev. Lett. 108, 142001 (2012); Phys. Rev. Lett. 108, 199902(E) (2012); Tkachenko et al. (CLAS Collaboration), Phys. Rev. C 89, 045206 (2014); Phys. Rev. C 90, 059901(E) (2014); Griffioen et al., Phys. Rev. C 92, 015211 (2015)]. Looking beyond conventional nuclear physics, and in anticipation of 12 GeV experiments at Jefferson Lab, we use a LFHQCD ansatz to predict the contributions of an exotic six-quark state to the deuteron 𝐹 2 structure function, 𝐹$^D_2$, in the superfast region. We find that the effects of using other potentials are about the same magnitude as six-quark effects—both have small effects in 𝑥 < 1, but have significant contributions at 𝑥 > 1.

Physics↗
DOE OSTI2021

Modeling and analyzing parasitic parameters in high frequency converters

This research focuses on electromagnetic interference (EMI) / electromagnetic compatibility (EMC) design and analysis in power electronics systems. To limit the EMI under the standards, different methods and strategies are investigated. Parasitic parameters of high frequency (HF) transformer are analyzed using a novel analytical method, finite element method (FEM), and experimental measurements for different structures and windings arrangements. Also, the magnetic field, electric field, electric displacement, and electric potential distribution are simulated and analyzed. Moreover, a high voltage system is considered and analyzed to improve the EMC. The EMI propagation paths are analyzed. The EMI noise level of the system is obtained and compared to the IEC61800-3 standard. To improve the EMC, the parasitic parameters of the transformer, as the main path of EMI circulation, are analyzed and optimized to block the propagation. Furthermore, the geometry structure of the HF transformer is optimized to lower the parasitics in the system. Three pareto-optimal techniques are investigated for the optimization. The models and results are verified by 3D-FEM and experimental results for several given scenarios. Furthermore, the EMC modeling and conducted EMI analysis are developed for a system including an AC-DC-DC power supply (rectifier and dual active bridge (DAB) converter). Moreover, the common mode (CM) EMI noise propagation through the system is discussed and the noise sources and effect of components on the noise are analyzed. Additionally, the CM impedance of different parts of the system and the noise levels are discussed. Finally, EMI attenuation techniques were applied to the system.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Effects of solvent formulations in electrolytes on fast charging of Li-ion cells

Improving the fast charging performance of lithium ion batteries (LIBs) has the promise to increase the widespread adoption of electric vehicles (EVs). Electrolyte development plays an important role in enabling fast charging. In this study, fast charging performance of LIBs is studied with different electrolytes of 1.2 M LiPF 6 in Ethylene Carbonate (EC)/Ethyl Methyl Carbonate (EMC)/co-solvents at 30/50/20 wt%. The co-solvents are methyl acetate (MA), ethyl acetate (EA), ethyl formate (EF), dimethyl carbonate (DMC) and EMC. Long term cycling performance under fast charging shows different capacity retention behaviors for different co-solvents. The structural changes in the electrode material are studied by X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD). The molarity changes in electrolyte is investigated by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The electrode/electrolyte interfaces before and after fast charging are analyzed by X-ray photoemission spectroscopy (XPS). The characterization results are in good agreement with the long-term cycling performance. DMC shows the highest fast-charging capability among the five studied co-solvents due to its increased conductivity, improved electrode/electrolyte interface and stable electrode structural integrity.

25 ENERGY STORAGE↗
DOE OSTI2023

The Impact of Fluoroethylene Carbonate Additive on Charged Sodium Ion Electrodes/Electrolyte Reactivity Studied Using Accelerating Rate Calorimetry

The effects of fluoroethylene carbonate (FEC) electrolyte additive on charged sodium ion electrode/electrolyte reactivity at elevated temperatures were investigated using accelerating rate calorimetry (ARC). The beneficial effect of FEC on cell lifetime was demonstrated using Na 0.97 Ca 0.03 [Mn 0.39 Fe 0.31 Ni 0.22 Zn 0.08 ]O 2 (NCMFNZO)/hard carbon (HC) pouch cells first prior to ARC measurements. Electrodes from these pouch cells were utilized as sample materials and 1.0 M NaPF 6 in propylene carbonate (PC):ethyl methyl carbonate (EMC) (1:1 by vol.) was chosen as control electrolyte. Adding 2 wt% and 5 wt% FEC to the electrolyte does not significantly affect the reactivity of de-sodiated NCMFNZO compared to the control electrolyte. However, the addition of FEC obviously changed the reactivity between sodiated HC and electrolytes, especially by showing a suppression on the exothermal behavior between 160 °C and 230 °C. These results give a head to head comparison of the reactivity of FEC additive containing electrolytes with charged sodium ion electrode materials at elevated temperatures and show that the use of FEC at additive levels should not compromise the cell safety when extending cell lifetime.

25 ENERGY STORAGE↗
DOE OSTI2023

Designing Li 4 Ti 5 O 12 /LiMn 2 O 4 Cells: Negative-to-Positive Ratio and Electrolyte

Li 4 Ti 5 O12/LiMn2O 4 (LTO/LMO) system is a promising candidate for behind-the-meter storage (BTMS) applications due to its critical-material-free chemistry exhibiting good safety and long lifetime. In this paper we design LTO/LMO cells to mitigate their major degradation mechanism, loss of Li inventory, and improve their long-term cyclability. First, LMO electrodes with different loadings (2.61, 3.29, and 4.26 mAh cm -2 ) are paired with an LTO electrode (3.35 mAh cm -2 ) to create varying negative-to-positive ratios (N/P>1, =1, and <1). Additionally, conventional ethylene carbonate (EC)/ethyl methyl carbonate (EMC) mixture electrolyte and safety enhanced EC-only electrolyte are examined. We show that storing additional Li inventory in the cathode (i.e., using a thicker electrode and having N/P<1) is a convenient method to enhance the capacity retention of LTO/LMO cells, but only if the electrode utilization is not limited by the Li + ion transport. For systems that suffer from limited transport properties, prelithiating the anode will be more effective since LTO (~165 mAh g -1 LTO ) can store the same amount of capacity using less material compared to LMO (~100 mAh g -1 LMO ). In this work, we demonstrate how the electrolyte properties and the electrode thickness of LTO/LMO cells can be designed to enhance their performance.

25 ENERGY STORAGE↗
DOE OSTI2021

Interfacial Effects on Transport Coefficient Measurements in Li-ion Battery Electrolytes

Development of Li + -containing electrolytes with improved transport properties requires reliable, reproducible, and ideally low volume techniques to rigorously understand ion-transport with varying composition. Precisely measuring the complete set of transport coefficients in liquid electrolytes under battery-relevant operating conditions is difficult and the reliability of these methods are sparsely described in electrolyte transport literature. In this work, we apply a potentiostatic polarization-based transport characterization approach typically used for polymer electrolytes to liquid electrolyte systems in an attempt to fully measure all transport coefficients (conductivity, total salt diffusion coefficient, thermodynamic factor and transference number) for the model system of LiPF 6 in an ethylene carbonate—ethyl methyl carbonate (EC:EMC) mixture. Using systematic timescale and statistical analyses, we find that transport coefficients measured using potentiostatic polarization of Li-Li symmetric cells exhibit strong correlation to Li electrode interfacial resistance, indicating that such methods are probing both bulk and interfacial phenomena. This reveals a major roadblock in characterizing electrolyte systems where the interfacial resistance is significantly larger than ohmic electrolyte resistance. As a result, we find that methods that rely on potentiostatic Li metal stripping/plating do not readily result in reliable liquid electrolyte transport coefficients, unlike similar methods for solid polymer electrolytes, where interfacial resistances are typically smaller than electrolyte resistances at the elevated temperatures typically of interest for such electrolytes.

25 ENERGY STORAGE↗
DOE OSTI2025

Isolation and conversion of electrolyte components into a value-added product

The overall objective of this work was to develop a process for effectively (i) recycling the electrolyte components from the end-of-life batteries and reduce the environmental hazard, (ii) understand the fundamental differences between pristine and recycled electrolyte components, (iii) electrochemically and analytically evaluate the recycled electrolyte components and (iv) establish deviations from the pristine electrolyte, and effectively separation of value-added product. We focused on determining scaling up the electrolyte recovery process by distillation of end-of-life batteries to get yield enough to use it for electrolyte formulation of reuse in the battery cell. The used cells from the ORNL battery manufacture facility (BMF)as well as received from the industry partner, Austin Elements Inc., was scaled to 10 used multilayered pouch cells in each batch of distillation and systematically separated and identified the electrolyte components of the used cells with FTIR and NMR studies. We were able to recovery 10g of solvent mass from the used pouch cells. NMR spectroscopy showed that the solvent was pure EMC,DMC and the sample was used to make a new battery cell. The end-of-life battery, it was noted that some cells were visually drier than the other cells and were more advanced in aged. In that case, even though the same distillation conditions were utilized, no usable mass of electrolyte solvent was recovered. It is expected that most of the solvent was decomposed during the battery charge-discharge cycling. The solid salt residue was separated by chemical and water treatment processes. Components of resulting solid product was analyzed by XRD and XPS measurements. The solid products are very much related to the salts used in the electrolyte solution.

25 ENERGY STORAGE↗
DOE OSTI2025

Isolation and Conversion of Electrolyte Components into a Value-Added Product

The overall objective of this work was to develop a process for effectively (i) recycling the electrolyte components from the end-of-life batteries and reduce the environmental hazard, (ii) understand the fundamental differences between pristine and recycled electrolyte components, (iii) electrochemically and analytically evaluate the recycled electrolyte components and (iv) establish deviations from the pristine electrolyte, and effectively separation of value-added product. We focused on determining scaling up the electrolyte recovery process by distillation of end-of-life batteries to get yield enough to use it for electrolyte formulation of reuse in the battery cell. The used cells from the ORNL battery manufacture facility (BMF) as well as received from the industry partner, Austin Elements Inc., was scaled to 10 used multilayered pouch cells in each batch of distillation and systematically separated and identified the electrolyte components of the used cells with FTIR and NMR studies. We were able to recovery 10g of solvent mass from the used pouch cells. NMR spectroscopy showed that the solvent was pure EMC, DMC and the sample was used to make a new battery cell. The end-of-life battery, it was noted that some cells were visually drier than the other cells and were more advanced in aged. In that case, even though the same distillation conditions were utilized, no usable mass of electrolyte solvent was recovered. It is expected that most of the solvent was decomposed during the battery charge-discharge cycling. The solid salt residue was separated by chemical and water treatment processes. Components of resulting solid product was analyzed by XRD and XPS measurements. The solid products are very much related to the salts used in the electrolyte solution.

25 ENERGY STORAGE↗