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NASA NTRS2003

Survival of Amino Acids in Micrometeorites During Atmospheric Entry

The delivery of amino acids by micrometeorites to the early Earth during the period of heavy bombardment could have been a significant source of the Earth's prebiotic amino acid inventory provided that these organic compounds survived atmospheric entry heating. To investigate the sublimation of amino acids from a micrometeorite analog at elevated temperature, grains from the CM-type carbonaceous chondrite Murchison were heated to 550 C inside a glass sublimation apparatus (SA) under reduced pressure. The sublimed residue that had collected on the cold finger of the SA after heating was analyzed for amino acids by HPLC. We found that when the temperature of the meteorite reached approx. 150 C, a large fraction of the amino acid glycine had vaporized from the meteorite, recondensed onto the end of the SA cold finger, and survived as the rest of the grains heated to 550 C. alpha-Aminoisobutryic acid and isovaline, which are two of the most abundant non-protein amino acids in Murchison, did not sublime from the meteorite and were completely destroyed during the heating experiment. Our experimental results suggest that sublimation of glycine present in micrometeorite grains may provide a way for this amino acid to survive atmospheric entry heating at temperatures less than 550 C; all other amino acids apparently are destroyed. Key Words: Amino acids-Exogenous delivery-Micrometeorites-Sublimation.

Glavin, Daniel P.↗

NASA NTRS2000

Innovative Balloon Buoyancy Techniques for Atmospheric Exploration

Until quite recently, the only practical means to control balloon buoyancy, and thus altitude, required consuming large amounts of fuel or the limited venting of helium balloons and/or dropping of ballast. With recent discoveries at JPL, novel long-life, balloon buoyancy techniques have been discovered that for the first time allow balloons to float in the primarily hydrogen atmospheres of Jupiter, Saturn, Uranus, and Neptune (using ambient fill-gas), and by using renewable energy sources, allow multiple controlled landings on Venus (using atmospheric temperature differences), Mars (solar heat), Titan (RTG heat), and Earth (planet radiant heat).

Balloon Planetary Aerobot Buoyancy Mars Titan Venu↗

NASA NTRS2008

A Closer Look at the Congo and the Lightning Maximum on Earth

The global maps of maximum mean annual flash density derived from a decade of observations from the Lightning Imaging Sensor on the NASA Tropical Rainfall Measuring Mission (TRMM) satellite show that a 0.5 degree x 0.5 degree pixel west of Bukavu, Democratic Republic of Congo (latitude 2S, longitude 28E) has the most frequent lightning activity anywhere on earth with an average value in excess of 157 fl/sq km/yr. This pixel has a flash density that is much greater than even its surrounding neighbors. By contrast the maximum mean annual flash rate for North America located in central Florida is only 33 fl/sq km/yr. Previous studies have shown that monthly-seasonal-annual lightning maxima on earth occur in regions dominated by coastal (land-sea breeze interactions) or topographic influences (elevated heat sources, enhanced convergence). Using TRMM, Landsat Enhanced Thematic Mapper, and Shuttle Imaging Radar imagery we further examine the unique features of this region situated in the deep tropics and dominated by a complex topography having numerous mountain ridges and valleys to better understand why this pixel, unlike any other, has the most active lightning on the planet.

Blakeslee, R. J.↗

NASA NTRSDate not supplied

Multi-Anvil Experimentation Applied to Planetary Differentiation

Planets undergo differentiation that includes segregation of metal from silicate at high temperatures and pressures ranging from deep planetary core pressures (>300 GPa for Earth)to very shallow conditions of asteroids (<100 MPa).The multi-anvil solid media apparatus accesses the middle part of this range from 3 to 30 GPa –pressure relevant to the interior of Mercury, Venus, Earth, Earth’s Moon, and Mars. Early planets are thought to have experienced high temperatures from a combination of heat sources including radioactive decay, gravitational and accretional heating, and impact processes. These heating events led to melting of mantles and cores, thus requiring an understanding of solid-liquid equilibria in metal-silicate systems. In 2006 we established a multi-anvil facility at NASA-JSC combining an 880 ton press and a Kawai/Walker type module from Rockland Research. Our high PT work has been greatly facilitated by use of the COMPRES multi-anvil assemblies (1). Our recent work has included studies of element partitioning between liquid metal and liquid silicate(e.g., 2), as well as between minerals and melts(e.g., 3), both of which have led to better constraints on the timing and conditions of planetary differentiation(e.g. 4). Several examples involving sustained efforts will be summarized below and for the presentation. The distribution of siderophile (iron-loving) elements between core and mantle is controlled by metal-silicate equilibrium across a wide range of pressures. Therefore, experimentation across this pressure range helps to calibrate elemental partitioning models that can be applied to planets, and used to predict mantle chemistry and composition during planetary differentiation. Our studies have focused on a wide range of siderophile elements (refractory Ni, Co, W, Mo; volatile P, Ga, Cu, Sn, Sb; highly siderophile Au, Pd) that have constrained partitioning, valence, and isotopic fractionation, and applied to Earth, Moon, and Mars. When molten mantles (magma oceans) cool enough to initiate crystallization, the solids precipitate at depth and in large planets this involves high pressure phases like garnet, majorite, akimotoite, and ringwoodite. As these solids precipitate they can segregate from liquid by density contrasts, thus causing elemental fractionation which can be used to decipher timing of differentiation. Mineral/melt and metal/silicate equilibria in our lab have helped to better understand high pressure fractionation of isotopic parent/daughter pairs Hf/W, Mn/Cr, Pd/Ag, Pt/Os, Re/Os, and U/Pb, and their application to Earth, Moon and Mars. There remains great potential for multi-anvil experimentation to shed light on many pressure–dependent aspects of planetary evolution such as core formation, high pressure phase equilibria, redox equilibria, and volatile evolution and storage. References1. Leinenweber, K., et al.(2012) American Mineralogist,97, 353–368. 2.Righter, K., et al.(2020) Geochem. Persp. Lett.15, 1-6.3. Righter, K., et al.(2020) Met. Planet. Sci 55, 2741-2757.4. Righter, K., et al.(2020)Earth and Planetary Science Letters,552, 116590.

pressure↗

NASA NTRS1974

Steady-state solution to the conduction problem of a spherical balloon radiometer, phases 1 and 2

A satellite system proposed for observing the earth's radiation balance employing spherical balloon radiometers is investigated. In the steady-state condition of radiative equilibrium, the magnitudes of absorbed external irradiances are sensed by internal radiometers mounted on the skin of each balloon. The temperatures of the radiometers are monitored as a measure of the balloons' internal irradiances (equal to absorbed external irradiances) and telemetered to earth. The effect of the magnitude of irradiant sources, balloon thickness, and thermal conductivity on the conduction of heat is assessed mathematically in order to determine its impact on measurement accuracy. Results indicate that observations are acceptable during daytime and nighttime modes of operation.

House, F. B.↗

NASA NTRS2013

Improved Data Reduction Algorithm for the Needle Probe Method Applied to In-Situ Thermal Conductivity Measurements of Lunar and Planetary Regoliths

The needle probe method (also known as the' hot wire' or 'line heat source' method) is widely used for in-situ thermal conductivity measurements on soils and marine sediments on the earth. Variants of this method have also been used (or planned) for measuring regolith on the surfaces of extra-terrestrial bodies (e.g., the Moon, Mars, and comets). In the near-vacuum condition on the lunar and planetary surfaces, the measurement method used on the earth cannot be simply duplicated, because thermal conductivity of the regolith can be approximately 2 orders of magnitude lower. In addition, the planetary probes have much greater diameters, due to engineering requirements associated with the robotic deployment on extra-terrestrial bodies. All of these factors contribute to the planetary probes requiring much longer time of measurement, several tens of (if not over a hundred) hours, while a conventional terrestrial needle probe needs only 1 to 2 minutes. The long measurement time complicates the surface operation logistics of the lander. It also negatively affects accuracy of the thermal conductivity measurement, because the cumulative heat loss along the probe is no longer negligible. The present study improves the data reduction algorithm of the needle probe method by shortening the measurement time on planetary surfaces by an order of magnitude. The main difference between the new scheme and the conventional one is that the former uses the exact mathematical solution to the thermal model on which the needle probe measurement theory is based, while the latter uses an approximate solution that is valid only for large times. The present study demonstrates the benefit of the new data reduction technique by applying it to data from a series of needle probe experiments carried out in a vacuum chamber on JSC-1A lunar regolith stimulant. The use of the exact solution has some disadvantage, however, in requiring three additional parameters, but two of them (the diameter and the volumetric heat capacity of the probe) can be measured and the other (the volumetric heat capacity of the regolith/stimulant) may be estimated from the surface geologic observation and temperature measurements. Therefore, overall, the new data reduction scheme would make in-situ thermal conductivity measurement more practical on planetary missions.

JSC-1A↗

NASA NTRS1993

Growth of new materials for solid state laser applications. The growth of ZnGeP2 by the vertical Bridgman method

This is the final technical report on the cooperative NASA program 'Growth of New Materials for Solid State Laser Applications,' covering the period from 9-1-86 through 3-31-91. The first two and one half years of the program, from 9-1-86 through 3-31-89, was devoted to the development of new eye-safe laser sources. Single crystal fibers of rare earth doped and co-doped YAG were grown by the laser-heated pedestal growth method, characterized for their structural properties and supplied to NASA/Langley for spectroscopic evaluation. From 4-1-89 though 3-31-91, research focused on the growth of zinc germanium phosphide for nonlinear optical applications in the IR. The vertical Bridgman growth process was evaluated as a means to achieve better control over the short wavelength optical absorption in this material that adversely affects 2 micron-pumped optical parametric oscillators.

Feigelson, R. S.↗

NASA NTRS2007

Effects of Free Molecular Heating on the Space Shuttle Active Thermal Control System

During Space Transportation System (STS) flight 121, higher than predicted radiator outlet temperatures were experienced from post insertion and up until nominal correction (NC) burn two. Effects from the higher than predicted heat loads on the radiator panels led to an additional 50 lbm of supply water consumed by the Flash Evaporator System (FES). Post-flight analysis and research revealed that the additional heat loads were due to Free Molecular Heating (FMH) on the radiator panels, which previously had not been considered as a significant environmental factor for the Space Shuttle radiators. The current Orbiter radiator heat flux models were adapted to incorporate the effects of FMH in addition to solar, earth infrared and albedo sources. Previous STS flights were also examined to find additional flight data on the FMH environment. Results of the model were compared to flight data and verified against results generated by the National Aeronautics and Space Administration (NASA), Johnson Space Center (JSC) Aero-sciences group to verify the accuracy of the model.

McCloud, Peter L.↗

NASA NTRS1996

Hydrothermal systems on Mars: an assessment of present evidence

Hydrothermal processes have been suggested to explain a number of observations for Mars, including D/H ratios of water extracted from Martian meteorites, as a means for removing CO2 from the Martian atmosphere and sequestering it in the crust as carbonates, and as a possible origin for iron oxide-rich spectral units on the floors of some rifted basins (chasmata). There are numerous examples of Martian channels formed by discharges of subsurface water near potential magmatic heat sources, and hydrothermal processes have also been proposed as a mechanism for aquifer recharge needed to sustain long term erosion of sapping channels. The following geological settings have been identified as targets for ancient hydrothermal systems on Mars: channels located along the margins of impact crater melt sheets and on the slopes of ancient volcanoes; chaotic and fretted terranes where shallow subsurface heat sources are thought to have interacted with ground ice; and the floors of calderas and rifted basins (e.g. chasmata). On Earth, such geological environments are often a locus for hydrothermal mineralization. But we presently lack the mineralogical information needed for a definitive evaluation of hypotheses. A preferred tool for identifying minerals by remote sensing methods on Earth is high spatial resolution, hyperspectral, near-infrared spectroscopy, a technique that has been extensively developed by mineral explorationists. Future efforts to explore Mars for ancient hydrothermal systems would benefit from the application of methods developed by the mining industry to look for similar deposits on Earth. But Earth-based exploration models must be adapted to account for the large differences in the climatic and geological history of Mars. For example, it is likely that the early surface environment of Mars was cool, perhaps consistently below freezing, with the shallow portions of hydrothermal systems being dominated by magma-cryosphere interactions. Given the smaller gravitational field, declining atmospheric pressure, and widespread, permeable megaregolith on Mars, volatile outgassing and magmatic cooling would have been more effective than on Earth. Thus, hydrothermal systems are likely to have had much lower average surface temperatures than comparable geological settings on Earth. The likely predominance of basaltic crust on Mars suggests that hydrothermal fluids and associated deposits should be enriched in Fe, Mg, Si and Ca, with surficial deposits being dominated by lower temperature, mixed iron oxide and carbonate mineralogies.

Review↗

NASA NTRS1992

Atmospheric entry survival of large micrometeorites: Implications for their sources and for the cometary contribution to the zodiacal cloud

Atmospheric entry heating simulations indicate that a large fraction of the micrometeorites larger than 100 microns in diameter which survive atmospheric entry must have entered the Earth's atmosphere with velocities very near the Earth's escape velocity. Thus, these particles must have been captured by Earth from heliocentric orbits with small eccentricities and low inclinations, indicating a main-belt asteroidal source. Space exposure ages measured on these large micrometeorites are also consistent with a main-belt asteroidal source. However, dynamical calculations have previously indicated that particles larger than 100 microns in diameter were likely to be destroyed by catastrophic collisions in the time required for orbital evolution from the main-belt to Earth capture by Poynting-Robertson drag. The absence of a large amount of collisional debris in the less than 50 microns size range indicates these large micrometeorites are not the few, rare survivors of a mostly collisionally disrupted population. The measured space exposure ages, which are about an order of magnitude larger than their calculated catastrophic collision lifetimes, confirm the survival of these large micrometeorites for times much longer than the calculated catastrophic collision lifetimes. Since collisions with cometary dust less than 20 microns in size were expected to be the major contributor to the collisional destruction of these larger particles, the contribution of cometary material to the zodiacal cloud is likely to be much smaller than previously believed.

Flynn, George J.↗

NASA NTRS1977

Solubility of K in Fe-S liquid, silicate-K/Fe-S/liq equilibria, and their planetary implications

Potassium has been found to have extremely limited absolute solubility in Fe-S liquid in the pressure-temperature range of 18 to 40 kbars, 1050 to 1150 C, and fO2 within the field of metallic iron. It also partitioned into a certain silicate phase highly in preference to Fe-S liquid at 30 kbar and 1100 C. The dependence of the partitioning of K between solid silicate and Fe-S liquid on fO2 and compositions of mineral solid solutions have been analyzed. These experimental data, along with those of others, limit the amount of K that could fractionate in Fe-S liquid layers or a core in the early history of the moon and, thus, act as localized heat sources in its thermal history models; the data also seem to argue against a chondritic abundance of potassium for earth. The question of fractionation of enough K-40 in an Fe-S liquid outer core of earth to provide the necesary thermal energy for the geomagnetic dynamo remains unresolved.

Gangully, J.↗

NASA NTRS1984

Long-wavelength Magnetic and Gravity Anomaly Correlations of Africa and Europe

Preliminary MAGSAT scalar magnetic anomaly data were compiled for comparison with long-wavelength-pass filtered free-air gravity anomalies and regional heat-flow and tectonic data. To facilitate the correlation analysis at satellite elevations over a spherical-Earth, equivalent point source inversion was used to differentially reduce the magnetic satellite anomalies to the radial pole at 350 km elevation, and to upward continue the first radial derivative of the free-air gravity anomalies. Correlation patterns between these regional geopotential anomaly fields are quantitatively established by moving window linear regression based on Poisson's theorem. Prominent correlations include direct correspondences for the Baltic Shield, where both anomalies are negative, and the central Mediterranean and Zaire Basin where both anomalies are positive. Inverse relationships are generally common over the Precambrian Shield in northwest Africa, the Basins and Shields in southern Africa, and the Alpine Orogenic Belt. Inverse correlations also presist over the North Sea Rifts, the Benue Rift, and more generally over the East African Rifts. The results of this quantitative correlation analysis support the general inverse relationships of gravity and magnetic anomalies observed for North American continental terrain which may be broadly related to magnetic crustal thickness variations.

Vonfrese, R. R. B.↗

NASA NTRS1985

Long-wavelength magnetic and gravity anomaly correlations on Africa and Europe

Preliminary MAGSAT scalar magnetic anomaly data were compiled for comparison with long-wavelength-pass filtered free-air gravity anomalies and regional heat-flow and tectonic data. To facilitate the correlation analysis at satellite elevations over a spherical-Earth, equivalent point source inversion was used to differentially reduce the magnetic satellite anomalies to the radial pole at 350 km elevation, and to upward continue the first radial derivative of the free-air gravity anomalies. Correlation patterns between these regional geopotential anomaly fields are quantitatively established by moving window linear regression based on Poisson's theorem. Prominent correlations include direct correspondences for the Baltic shield, where both anomalies are negative, and the central Mediterranean and Zaire Basin where both anomalies are positive. Inverse relationships are generally common over the Precambrian Shield in northwest Africa, the Basins and Shields in southern Africa, and the Alpine Orogenic Belt. Inverse correlations also presist over the North Sea Rifts, the Benue Rift, and more generally over the East African Rifts. The results of this quantitative correlation analysis support the general inverse relationships of gravity and magnetic anomalies observed for North American continental terrain which may be broadly related to magnetic crustal thickness variations.

Vonfrese, R. R. B.↗

NASA NTRS1998

Mars Atmospheric Dynamics

The Martian atmosphere is dynamically similar to the Earth's. Its spin-axis rotation rate is only minutes longer than Earth's so the Coriolois force is nearly identical to Earth's. The inclination of its spin axis is also similar to Earth's giving it similarity in seasonal change. And the Martian atmosphere is nearly transparent to solar radiation (except during dust periods) such that it is heated primarily by upwelling infrared radiation from the surface. These characteristics make Mars an ideal laboratory for studying the dynamics of rapidly rotating differentially heated atmospheres. This talk reviews what we have learned about Mars atmospheric dynamics and how if compares with Earth. The source of information to make such a comparison comes from observations and models. The former are sparse and that the latter have played a major role in shaping our thinking about the general circulation on Mars. However, the models need validation. Fortunately, the first two orbiters in NASA's Mars Surveyor Program have instrumentation to address many of the issues related to the general circulation and climate of Mars. The first, Mars Global Surveyor, is already at Mars gathering data. The second, the Mars 98 Orbiter to be launched later this year, carries a dedicated atmospheric sounder. Thus, much will be learned about Mars' atmosphere in the next few years.

Haberle, Robert↗

NASA NTRS1983

Magnetism and thermal evolution of the terrestrial planets

The absence in the cases of Venus and Mars of the substantial intrinsic magnetic fields of the earth and Mercury is considered, in light of thermal history calculations which suggest that, while the cores of Mercury and the earth are continuing to freeze, the cores of Venus and Mars may still be completely liquid. It is noted that completely fluid cores, lacking intrinsic heat sources, are not likely to sustain thermal convection for the age of the solar system, but cool to a subadiabatic, conductive state that cannot maintain a dynamo because of the gravitational energy release and the chemically driven convection that accompany inner core growth. The models presented include realistic pressure- and composition-dependent freezing curves for the core, and material parameters are chosen so that correct present-day values of heat outflow, upper mantle temperature and viscosity, and inner core radius, are obtained for the earth.

Stevenson, D. J.↗

NASA NTRS1992

Water and cheese from the lunar desert: Abundances and accessibility of H, C, and N on the Moon

The Moon has been underrated as a source of H, N, C, and other elements essential to support life and to provide fuel for rockets. There is enough of these elements in each cubic meter of typical lunar soil to provide a substantial lunch for two, if converted to edible forms. The average amount of C per square meter of the lunar surface to a depth of 2 m is some 35 percent of the average amount per square meter tied up in living organisms on Earth. The water equivalent of H in the upper 2 m of the regolith averages at least 1.3 million liters per square kilometer. Mining of H from a small fraction of the regolith would provide all the rocket fuel needed for thousands of years. These elements can be removed from the soil by heating it to high temperature. Some favor the unproven resources of Phobos, Deimos, or near-Earth asteroids instead of the Moon as a source of extraterrestrial material for use in space, or Mars over the Moon as a site for habitation, partly on the basis that the chemical elements needed for life support and propellant are readily abundant on those bodies, but not on the Moon. Well, the Moon is not as barren of H, C, and N as is commonly perceived. In fact, the elements needed for life support and for rocket fuel are plentiful there, although the ore grades are low. Furthermore, the proximity of the Moon and consequent lower cost of transportation and shorter trip and communication times favor that body as the logical site for early acquisition of resources and extraterrestrial living.

Haskin, L. A.↗

NASA NTRS2005

Latent Heating from TRMM Satellite Measurements

Rainfall production is a fundamental process within the Earth;s hydrological cycle because it represents both a principal forcing term in surface water budgets, and its energetics corollary, latent heating, is the principal source of atmospheric diabatic heating. Latent heat release itself is a consequence of phase changes between the vapor, liquid, and frozen states of water. The properties of the vertical distribution of latent heat release modulate large-scale meridional and zonal circulations with the Tropics - as well as modify the energetic efficiencies of mid-latitude weather systems. This paper highlights the retrieval of observatory, which was launched in November 1997 as a joint American-Japanese space endeavor. Since then, TRMM measurements have been providing an accurate four-dimensional amount of rainfall over the global Tropics and sub-tropics - information which can be used to estimate the spacetime structure of latent heating across the Earth's low latitudes. A set of algorithm methodologies has and continues to be developed to estimate latent heating based on rain rate profile retrievals obtained from TRMM measurements. These algorithms are briefly described followed by a discussion of the foremost latent heating products that can be generate from them. The investigation then provides an overview of how TRMM-derived latent heating information is currently being used in conjunction with global weather and climate models, concluding with remarks intended to stimulate further research on latent heating retrieval from satellites.

Tao, W.-K.↗

NASA NTRS1975

Application of a finite difference technique to thermal wave propagation

A finite difference formulation is presented for thermal wave propagation resulting from periodic heat sources. The numerical technique can handle complex problems that might result from variable thermal diffusivity, such as heat flow in the earth with ice and snow layers. In the numerical analysis, the continuous temperature field is represented by a series of grid points at which the temperature is separated into real and imaginary terms. Computer routines previously developed for acoustic wave propagation are utilized in the solution for the temperatures. The calculation procedure is illustrated for the case of thermal wave propagation in a uniform property semi-infinite medium.

Baumeister, K. J.↗