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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

An investigation of the optical constants and band gap of chromium disilicide

Optical properties of polycrystalline thin films of CrSi2 grown by the diffusion couple method on silicon substrates were investigated. An analysis of the energy dependence of the absorption coefficient indicates that the material is an indirect forbidden gap semiconductor with a band-gap value of slightly less than 0.35 eV. This result was confirmed by measurements of the temperature dependence of the intrinsic conductivity. The value of the bandgap corresponds well to an important window of transparency in the earth's atmosphere (3-5 microns), which makes the material of potential interest for IR detector applications.

Bost, M. C.↗
NASA NTRS1982

Reflectance spectroscopy of diogenite meteorite types from Antarctica and their relationship to asteroids

Measurements of the spectral reflectance (0.4-2.5 microns) of three diogenite meteorites found in Antarctica are examined. Comparisons are made with previous measurements of diogenites in order to correlate the mineralogy and petrography with the spectral characteristics that can also be measured on solar system objects of unknown composition. Even though the Antarctic diogenites have the same spectral characteristics as other diogenites, there are measurable differences between all diogenite spectra. Bands caused by spin-forbidden transitions of Fe(2+) ions in pyroxene, which are identified for the first time in reflectance spectra of powdered samples, are revealed in an analysis of the spectra into sums of Gaussian components. It is shown from these laboratory measurements that spectral reflectance measurements of asteroids and other solar system objects made with the visible CVF (circular variable filter) spectrometer used for laboratory measurements can provide useful information on their surface composition.

Mcfadden, L. A.↗
NASA NTRS1991

First results from the Faint Object Camera - SN 1987A

The first images of SN 1987A taken on day 1278 after outburst with the Faint Object Camera on board the Hubble Space Telescope are presented. The supernova is well detected and resolved spatially in three broadband ultraviolet exposures spanning the 1500-3800 A range and in a narrow-band image centered on the forbidden O III 5007 line. Simple uniform disk fits to the profiles of SN 1987A yield an average angular diameter of 170 + or - 30 mas, corresponding to an average expansion velocity of 6000 km/s. The derived broadband ultraviolet fluxes, when corrected for interstellar absorption, indicate a blue ultraviolet spectrum corresponding to a color temperature near 13,000 K.

Jakobsen, P.↗
NASA NTRS1993

CCD mosaic images of the supernova remnant 3C 400.2

We have constructed CCD mosaic images of the old Galactic supernova remnant 3C 400.2 in lines of H-alpha + forbidden N II, forbidden S II, and forbidden O III, plus a continuum band. These are the first CCD images covering the full extent of this remnant, and they reveal significantly more nebulosity than the deepest photographic plates. Comparison with radio and X-ray images indicates dramatically different morphology in the three regimes. The optical images both in H-alpha + forbidden N II and in forbidden S II show an almost complete, irregular shell of emission, with a diameter of about 16 arcmin, little over half that of the radio shell, while the X-ray structure is a centrally peaked ellipsoid. Approximate values for optical line fluxes are obtained; we estimate L(H-alpha) about 3 x 10 exp 35 ergs/s, roughly three times the X-ray luminosity. We also report a previously uncataloged planetary nebula southwest of 3C 400.2.

Winkler, P. F.↗
NASA NTRS1999

Measurement of Oxygen A Band Line Parameters by Using Modulation Spectroscopy with Higher Harmonic Detection

Wavelength modulation spectroscopy is used to demonstrate that extremely weak absorption lines can be measured even when these lines suffer from interference from the wings of adjacent stronger lines. It is shown that the use of detection at several harmonics allows such interference to be examined clearly and conveniently. The results of experimental measurements on a weak magnetic dipole driven, spin-forbidden line in the oxygen A band, which experiences interference from the wings of a pair of adjacent lines towards the blue and red regions of line center, are presented. A comparison of the experimental results to theory is given.

Dharamsi, Amin↗
NASA NTRS1972

Crystal field spectra of lunar pyroxenes.

Absorption spectra in the visible and near infrared regions have been obtained for pyroxene single crystals in rocks from the Apollo 11, 12, 14, and 15 missions. The polarized spectra are compared with those obtained from terrestrial calcic clinopyroxenes, subcalcic augites, pigeonites, and orthopyroxenes. The lunar pyroxenes contain several broad, intense absorption bands in the near infrared, the positions of which are related to bulk composition, Fe(2+) site occupancy and structure type of the pyroxene. The visible spectra contain several sharp, weak peaks mainly due to spin-forbidden transitions in Fe(2+). Additional weak bands in this region in Apollo 11 pyroxenes are attributed to Ti(3+) ions. Spectral features from Fe(3+), Mn(2+), Cr(3+), and Cr(2+) were not observed.

Burns, R. G.↗
NASA NTRS1980

Two-dimensional photometry of planetary nebulae

Monochromatic images of three planetary nebulae, NGC 6720, NGC 7662 and NGC 2392, were taken using narrow band interference filters centered on the forbidden emission lines of Oxygen I, II, III, Nitrogen II, Sulfur II and the permitted emission lines of Hydrogen I, Helium I and Helium II. The data was taken with a silicon intensified vidicon using the Palomar 1.5 meter telescope and was recorded digitally to an encoding level of 12 bits. The data was processed at the Image Processing Laboratory of the Jet Propulsion Laboratory. The calibrated images were used to investigate the three dimensional structure of the nebulae and to generate two-dimensional electron and temperature maps.

Kupferman, P. N.↗
NASA NTRS1991

HH 5, HH 6, and their exciting stars

Long-slit optical spectroscopy, astrometry, and H-alpha forbidden S II and broad-band 2 micron images of HH 5 and of the HH 6 complex have been obtained. The excitations and radial velocities of the individual HH knots are described. The morphology of the optical and the 2 micron images (the latter dominated by H2 emission and/or the continuum of any embedded exciting stars) is compared; and the new astrometry is discussed. Finally, the likely sources of excitation of these HH nebulae are commented on.

Cohen, Martin↗
DOE OSTI2021

Design of High-Performance Lead-Free Quaternary Antiperovskites for Photovoltaics via Ion Type Inversion and Anion Ordering

The emergence of halide double perovskites significantly increases the compositional space for lead-free and air-stable photovoltaic absorbers compared to halide perovskites. Nevertheless, most halide double perovskites exhibit oversized band gaps (>1.9 eV) or dipole-forbidden optical transition, which are unfavorable for efficient single-junction solar cell applications. The current device performance of halide double perovskite is still inferior to that of lead-based halide perovskites, such as CH 3 NH 3 PbI 3 (MAPbI 3 ). Here, by ion type inversion and anion ordering on perovskite lattice sites, two new classes of pnictogen-based quaternary antiperovskites with the formula of X 6 B 2 AA' and X 6 BB'A 2 are designed. Phase stability and tunable band gaps in these quaternary antiperovskites are demonstrated based on first-principles calculations. Further photovoltaic-functionality-directed screening of these materials leads to the discovery of 5 stable compounds (Ca 6 N 2 AsSb, Ca 6 N 2 PSb, Sr 6 N 2 AsSb, Sr 6 N 2 PSb, and Ca 6 NPSb 2 ) with suitable direct band gaps, small carrier effective masses and low exciton binding energies, and dipole-allowed strong optical absorption, which are favorable properties for a photovoltaic absorber material. The calculated theoretical maximum solar cell efficiencies based on these five compounds are all larger than 29%, comparable to or even higher than that of the MAPbI 3 based solar cell. Finally, our work reveals the huge potential of quaternary antiperovskites in the optoelectronic field and provides a new strategy to design lead-free and air-stable perovskite-based photovoltaic absorber materials.

three-dimensional electronic transport↗
NASA NTRS1972

Polarized absorption spectra of single crystals of lunar pyroxenes and olivines.

Measurements have been made of the polarized absorption spectra (360-2200 nm) of compositionally zoned pyroxene minerals in rocks 10045, 10047 and 10058 and olivines in rocks 10020 and 10022. The Apollo 11 pyroxenes with relatively high Ti/Fe ratios were chosen initially to investigate the presence of crystal field spectra of Fe(2+) and Ti(3+) ions in the minerals. Broad intense bands at about 1000 and 2100 nm arise from spin-allowed, polarization-dependent transitions in Fe(2+) ions in pyroxenes. Several weak sharp peaks occur in the visible region. Peaks at 402, 425, 505, 550, and 585 nm represent spin-forbidden transitions in Fe(2+) ions, while broader bands at 460-470 nm and 650-660 nm are attributed to Ti(3+) ions. Charge transfer bands, which in terrestrial pyroxenes often extend into the visible region, are displaced to shorter wavelengths in lunar pyroxenes. This feature correlates with the absence of Ti(3+) ions in these minerals.

Burns, R. G.↗
DOE OSTI2024

Fundamental optical transitions in hexagonal boron nitride epilayers

Fundamental optical transitions in hexagonal boron nitride (h-BN) epilayers grown on sapphire by metal–organic chemical vapor deposition (MOCVD) using triethylboron as the boron precursor have been probed by photoluminescence (PL) emission spectroscopy. The low temperature (10 K) PL spectrum exhibits two groups of emission lines. The first group includes the direct observation of the free exciton and impurity bound exciton (BX) transitions and phonon replicas of the BX transition, whereas the second group is attributed to the direct observation of the band-to-band transition and its associated phonon replicas. The observations of zero-phonon lines of the band-to-band and exciton transitions, which are supposedly forbidden or “dark” in perfect h-BN crystals, result from a relaxed requirement of momentum conservation due to symmetry-breaking in the presence of high concentrations of impurities/defects and strain, which in turn provided more deterministic values of the energy bandgap (E g ), exciton binding energy (E x ), and binding energy of impurity bound excitons (E BX ) in h-BN epilayers. Excitonic parameters of h-BN epilayers grown by MOCVD, carbon-free chemical vapor deposition, and high purity h-BN bulk materials are compared and discussed. The present results, together with available information in the literature, represent a significant improvement in the understanding of the fundamental optical properties and excitonic parameters of h-BN ultrawide bandgap semiconductors.

36 MATERIALS SCIENCE↗
NASA NTRS1996

O2 A Band Studies for Cloud Detection and Algorithm Improvement

Detection of cloud parameters from space-based spectrometers can employ the vibrational bands of O2 in the (sup b1)Sigma(sub +)(sub g) yields X(sub 3) Sigma(sup -)(sub g) spin-forbidden electronic transition manifold, particularly the Delta nu = 0 A band. The GOME instrument uses the A band in the Initial Cloud Fitting Algorithm (ICFA). The work reported here consists of making substantial improvements in the line-by-line spectral database for the A band, testing whether an additional correction to the line shape function is necessary in order to correctly model the atmospheric transmission in this band, and calculating prototype cloud and ground template spectra for comparison with satellite measurements.

Chance, K. V.↗
DOE OSTI2021

Coupling between Emissive Defects on Carbon Nanotubes: Modeling Insights

Covalent functionalization of single-walled carbon nanotubes (SWCNTs) with organic molecules results in red-shifted emissive states associated with sp 3 -defects in the tube lattice, which facilitate their improved optical functionality, including single-photon emission. The energy of the defect-based electronic excitations (excitons) depends on the molecular adducts, the configuration of the defect, and concentration of defects. In this work, we model the interactions between two sp 3 -defects placed at various distances in the (6,5) SWCNT using time-dependent density functional theory. Calculations reveal that these interactions conform to the effective model of J-aggregates for well-spaced defects (>2 nm), leading to a red-shifted and optically allowed (bright) lowest energy exciton. H-aggregate behavior is not observed for any defect orientations, which is beneficial for emission. The splitting between the lowest energy bright and optically forbidden (dark) excitons and the pristine excitonic band are controlled by the single-defect configurations and their axial separation. These findings enable a synthetic design strategy for SWCNTs with tunable near-infrared emission.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1990

Field-Induced-Gap Infrared Detectors

Semimetals become semiconductors under applied magnetic fields. New detectors require less cooling equipment because they operate at temperatures higher than liquid-helium temperatures required by extrinsic-semiconductor detectors. Magnetic fields for detectors provided by electromagnets based on recently-discovered high-transition-temperature superconducting materials. Detector material has to be semiconductor, in which photon absorbed by exciting electron/hole pair across gap Eg of forbidden energies between valence and conduction energy bands. Magnetic- and compositional-tuning effects combined to obtain two-absorber detector having narrow passband. By variation of applied magnetic field, passband swept through spectrum of interest.

Elliott, C. Thomas↗
NASA NTRS1993

An atlas of supernova remnant candidates in Messier 31

Narrow-band CCD imagery in H-alpha and forbidden SII of a large fraction of the spiral arms in the Northeast half of Messier 31 has been used to isolate a sample of 52 'forbidden-line' SNR candidates for which the integrated ratio forbidden SII:H-alpha is greater than 0.5. An atlas of images in these emission lines, red optical continuum, and 1465 MHz radio continuum is presented, together with the tabulated integral properties of these sources. Assessing the completeness of the sample yields a crude estimate of the massive supernova rate (due to stars more massive than 7 solar masses) of 1 in 80 yr. The range of measured luminosities in both H-alpha and radio continuum is fully consistent with those found for 'forbidden-line' SNR in Messier 33, the LMC, and the Galaxy. With the inclusion of our candidates the number of extragalactic SNRs (with well-known distances) now exceeds the number of known galactic SNRs.

Braun, R.↗
DOE OSTI2026

Contrasting decays of 3-quasiparticle isomers in 173 W: A discerning test of 𝐾 conservation and 𝐾 mixing

Two isomers with K π = 19/2 + at 1876 keV with a half-life of 21(1) ns, and K π = 23/2− at 2159 keV with a half-life of 93(6) ns have been identified in 173 W, the lightest tungsten isotope to exhibit this phenomenon. An unusually high number of 13 branches have been established in the decay of the K π = 23/2 − isomer. This decay is associated with transitions involving significantly higher degrees of K forbiddenness and is in sharp contrast with the usual preferential deexcitation through branches, which are less forbidden, as is evident for the K π = 19/2 + state in 173 W. The inclusion of K-mixing effects, arising from band crossings in the sequences to which decays with larger degrees of K forbiddenness are observed, can qualitatively account for this contrasting behavior. These results provide a striking illustration of the competition between K conservation and K mixing in the decay of such isomers.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1980

Spectrophotometry of Comet West

Postperihelion observations of Comet West (1975n = 1976 VI) have been made with a Fourier transform spectrometer at heliocentric distances from 0.57 to 1.68 AU. Measurements were made of the emission bands of C2, CN, C3, CH, and NH2, as well as the emission lines of Na D and forbidden (O I), and the flux in the continuum in nine different bandpasses. Several ratios of the band strengths of CN have been used to determine the two free parameters in the fluorescence equilibrium model of CN of Danks and Arpigny (1973). From the values of the parameters it is inferred that the vibrational transition probability for the ground electronic state is between 0.025 and 0.075 per sec and that the ratio of oscillator strengths between the (0-0) bands of the violet and red systems is between 25 and 30. When corrected for field-of-view effects, NH2 shows no systematic variation in abundance relative to C2 while CH shows a small increase. The cometary continuum is found to be slightly redder than the solar continuum, consistent with results for other bright, dusty comets. The equivalent width of the Delta u = 0 sequence of C2 shows a marked decrease at r(H) = 1.2 AU.

Ahearn, M. F.↗