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NASA NTRS1972

Polarized absorption spectra of single crystals of lunar pyroxenes and olivines.

Measurements have been made of the polarized absorption spectra (360-2200 nm) of compositionally zoned pyroxene minerals in rocks 10045, 10047 and 10058 and olivines in rocks 10020 and 10022. The Apollo 11 pyroxenes with relatively high Ti/Fe ratios were chosen initially to investigate the presence of crystal field spectra of Fe(2+) and Ti(3+) ions in the minerals. Broad intense bands at about 1000 and 2100 nm arise from spin-allowed, polarization-dependent transitions in Fe(2+) ions in pyroxenes. Several weak sharp peaks occur in the visible region. Peaks at 402, 425, 505, 550, and 585 nm represent spin-forbidden transitions in Fe(2+) ions, while broader bands at 460-470 nm and 650-660 nm are attributed to Ti(3+) ions. Charge transfer bands, which in terrestrial pyroxenes often extend into the visible region, are displaced to shorter wavelengths in lunar pyroxenes. This feature correlates with the absence of Ti(3+) ions in these minerals.

Burns, R. G.↗

NASA NTRS1996

O2 A Band Studies for Cloud Detection and Algorithm Improvement

Detection of cloud parameters from space-based spectrometers can employ the vibrational bands of O2 in the (sup b1)Sigma(sub +)(sub g) yields X(sub 3) Sigma(sup -)(sub g) spin-forbidden electronic transition manifold, particularly the Delta nu = 0 A band. The GOME instrument uses the A band in the Initial Cloud Fitting Algorithm (ICFA). The work reported here consists of making substantial improvements in the line-by-line spectral database for the A band, testing whether an additional correction to the line shape function is necessary in order to correctly model the atmospheric transmission in this band, and calculating prototype cloud and ground template spectra for comparison with satellite measurements.

Chance, K. V.↗

NASA NTRS1990

Field-Induced-Gap Infrared Detectors

Semimetals become semiconductors under applied magnetic fields. New detectors require less cooling equipment because they operate at temperatures higher than liquid-helium temperatures required by extrinsic-semiconductor detectors. Magnetic fields for detectors provided by electromagnets based on recently-discovered high-transition-temperature superconducting materials. Detector material has to be semiconductor, in which photon absorbed by exciting electron/hole pair across gap Eg of forbidden energies between valence and conduction energy bands. Magnetic- and compositional-tuning effects combined to obtain two-absorber detector having narrow passband. By variation of applied magnetic field, passband swept through spectrum of interest.

Elliott, C. Thomas↗

NASA NTRS1993

An atlas of supernova remnant candidates in Messier 31

Narrow-band CCD imagery in H-alpha and forbidden SII of a large fraction of the spiral arms in the Northeast half of Messier 31 has been used to isolate a sample of 52 'forbidden-line' SNR candidates for which the integrated ratio forbidden SII:H-alpha is greater than 0.5. An atlas of images in these emission lines, red optical continuum, and 1465 MHz radio continuum is presented, together with the tabulated integral properties of these sources. Assessing the completeness of the sample yields a crude estimate of the massive supernova rate (due to stars more massive than 7 solar masses) of 1 in 80 yr. The range of measured luminosities in both H-alpha and radio continuum is fully consistent with those found for 'forbidden-line' SNR in Messier 33, the LMC, and the Galaxy. With the inclusion of our candidates the number of extragalactic SNRs (with well-known distances) now exceeds the number of known galactic SNRs.

Braun, R.↗

NASA NTRS1980

Spectrophotometry of Comet West

Postperihelion observations of Comet West (1975n = 1976 VI) have been made with a Fourier transform spectrometer at heliocentric distances from 0.57 to 1.68 AU. Measurements were made of the emission bands of C2, CN, C3, CH, and NH2, as well as the emission lines of Na D and forbidden (O I), and the flux in the continuum in nine different bandpasses. Several ratios of the band strengths of CN have been used to determine the two free parameters in the fluorescence equilibrium model of CN of Danks and Arpigny (1973). From the values of the parameters it is inferred that the vibrational transition probability for the ground electronic state is between 0.025 and 0.075 per sec and that the ratio of oscillator strengths between the (0-0) bands of the violet and red systems is between 25 and 30. When corrected for field-of-view effects, NH2 shows no systematic variation in abundance relative to C2 while CH shows a small increase. The cometary continuum is found to be slightly redder than the solar continuum, consistent with results for other bright, dusty comets. The equivalent width of the Delta u = 0 sequence of C2 shows a marked decrease at r(H) = 1.2 AU.

Ahearn, M. F.↗

NASA NTRS2005

Near Infrared Spectra of Mixtures Relevant to Icy Satellites

We will present near IR spectra of ice mixtures and review the differences between spectra of mixtures and those of pure solids: the creation of new features, weakening and shifting of bands, dependence on concentration, and changes with temperature. The forbidden CO2 (2nu3) overtone at 2.134 microns (4685/cm) is absent from the spectrum of pure CO2, but present in all of the following mixtures: H2O/CO2 = 5 and = 25, H2O:CH3OH:CO2 = 100:2.5:1, and CH3OH:CO2 = 5. Also, in mixtures of H2O and any other material, we see a feature at 1.89 microns (5290/cm) that is possibly related to the "dangling OH" feature at 2.73 microns (3360/cm). The features of a material in H2O are generally weaker and shifted to longer wavelength in comparison to the pure substance. For example, the largest near-IR absorption of pure solid CH4 is located at 2.324 microns (4303/cm) but is broader and at slightly longer wavelength in samples mixed with H2O. The degree of shifting and weakening depends on the ratio of the mixture. The mixture mentioned above was at a ratio of H2O/ CH4 = 3. When the ratio rises to H2O/ CH4 = 87, the CH4 feature at 2.324 microns is shifted to shorter wavelength and is much broader and weaker. In CH4/ H2O mixtures the peaks shift to higher frequency and become increasingly broad, but this trend is reversible on re-cooling, even though the phase transitions of H2O are irreversible. In short, mixtures created in the lab produce spectra that are very different from modeled combinations of end member species. Recent Cassini VIMS observations show the CO2 fundamental at 4.255 microns (2350/cm) on Iapetus [l] and at 4.26 microns (2347/cm) on Phoebe [2], while Galileo NIMS observed it at 4.25 microns (2353/cm) on Ganymede [3]. Since pure CO2 is located at 4.266 (2344/cm), the CO2 must be mixed with something else to produce the shift. A mixture of CH3OH:CO2 = 5 at 90 K shifts the fundamental to 4.262 microns (2346/cm). The shifts in the feature between satellites could indicate variations in concentration and temperature, or the introduction of a new compound, encouraging further lab investigation.

Mastrapa, Rachel M. E.↗

NASA NTRS1999

Variations in the strength of the infrared forbidden 2328.2 cm-1 fundamental of solid N2 in binary mixtures

We present the 2335-2325 cm-1 infrared spectra and band positions, profiles and strengths (A values) of solid nitrogen and binary mixtures of N2 with other molecules at 12 K. The data demonstrate that the strength of the infrared forbidden N2 fundamental near 2328 cm-1 is moderately enhanced in the presence of NH3, strongly enhanced in the presence of H2O and very strongly enhanced (by over a factor of 1000) in the presence of CO2, but is not significantly affected by CO, CH4, or O2. The mechanisms for the enhancements in N2-NH3 and N2-H2O mixtures are fundamentally different from those proposed for N2-CO2 mixtures. In the first case, interactions involving hydrogen-bonding are likely the cause. In the latter, a resonant exchange between the N2 stretching fundamental and the 18O = 12C asymmetric stretch of 18O12C16O is indicated. The implications of these results for several astrophysical issues are briefly discussed.

NASA Discipline Exobiology↗

NASA NTRS1993

Observations of (S III) emission from Galactic radio sources - The detection of distant planetary nebulae and a search for supernova remnant emission

Narrow-band near-infrared imaging observations at wavelengths corresponding to forbidden S III 9069,9532 A have been carried out at the MDM 1.3 m telescope for 23 radio sources near the Galactic plane in an attempt to detect emission associated with nebulae marking the endpoints of stellar evolution. While none of the known remnants or remnant candidates were detected, 10 of the 11 PN candidates from a new radio imaging survey of the Galactic plane were clearly seen in the forbidden S III 9532 A line. We present a calculation of the relative efficacy of searching for PNe in the forbidden O III and forbidden S III lines; for the majority of all PNe, the observed forbidden S III 9532 A line is predicted to be stronger than forbiden O III 5007 A whenever the visual extinction exceeds 3 magnitudes. This makes forbidden S III the superior tracer of PNe at distances exceeding a few kpc. We briefly comment on the significance of this approach to defining the spatial distribution of the PN population of the Galaxy.

Kistiakowsky, V.↗

NASA NTRS2002

Variations in the Strength of the Infrared Forbidden 2328.2 cm-1 Fundamental of Solid N2 in Binary Mixtures

We present the 2335-2325 cm(exp -1) infrared spectra and band positions, profiles, and strengths (A values) of solid nitrogen and binary mixtures of N2 with other molecules at 12 K. The data demonstrate that the strength of the infrared forbidden N2 fundamental near 2328 cm(exp -1) is moderately enhanced in the presence of NH3, strongly enhanced in the presence of H2O and very strongly enhanced in the presence of CO2, but is not significantly affected by CO, CH4, or O2. The mechanisms for the enhancements in N2-NH3 and N2-H2O mixtures are fundamentally different from those proposed for N2-CO2 mixtures. In the first case, interactions involving hydrogen-bonding are likely the cause. In the latter, a resonant exchange between the N2 stretching fundamental and the O-18=C-12 asymmetric stretch of O-18C-12O-16 is indicated. The implications of these results for several astrophysical issues are briefly discussed.

Bernstein, Max P.↗

NASA NTRS1990

Optical and infrared spectrophotometry of the symbiotic system V1016 Cygni

Spectrophotometry from 0.46 to 1.3 micron of the peculiar emission-line object V1016 Cyg is presented. The optical region displays a weak continuum underlying the rich emission-line spectrum detailed in past studies. The infrared spectrum consists of prominent emission lines of H I, He I, He II, forbidden Ni, O I, and forbidden S III overlying a strong stellar continuum. The latter displays bands at 0.94 micron and 1.13 micron characteristic of a late-type, oxygen-rich giant as well as an absorption at 1.05 micron which is due to VO. The presence of these molecular features indicates a spectral class of M6 or later for the cool secondary. The reddening of the secondary does not appear to be much different from that of the emission lines. Among the infrared emission features is the rarely seen permitted transition of neutral oxygen at 1.1287 micron. Its presence at a strength comparable to O I 8446 A, together with the absence of O I 13164 A, confirms the result of Strafella that the strong O I lines arise primarily from fluorescent excitation by Ly-beta.

Rudy, Richard J.↗

NASA NTRS1992

How old is the z = 3.4 radio galaxy B2 0902+34?

The redshift 3.395 radio galaxy B2 0902+34 has been observed at K and in a 0.09 micron wide 2.21 micron filter which includes the redshifted forbidden O III 4959 and 5007 A emission lines. A value of m(K) = 19.9 +/- 0.3 is found in a 4 arcsec aperture, a magnitude fainter than Lilly's (1988) value, while the narrow-band image reveals that most of this flux is actually due to line emission. After correcting for forbidden O III 4959 and 5007A, a color is found which is consistent with the flat F(v) spectrum considered characteristic of a protogalaxy. Ages for the galaxy derived from stellar population models based on the limit R - K less than 3.8 are much younger than those for the I - K = 4.5 value reported by Lilly.

Eisenhardt, Peter↗

NASA NTRS1994

High-resolution 6450-24500 A spectra of eta Carinae

We discuss high-resolution (Delta lambda/lambda approximately equals 3000-8600) spectra of the central knot or 'star' in eta Car between approximately 6450 and approximately 24,500 A, and of the Homunculus approximately 7 sec southeast of the knot between approximately 6450 and approximately 9250 A. A complete flux calibrated list of more than 170 emission lines is provided longward of approximately 8780 A, with additional measurements of the strongest forbidden lines and Fe II features down to approximately 6700 A. The continuum flux increased by a factor of approximately 1.6 to approximately 2.0 at 23,000 A compared to recent measurements, by remained the same at approximately 11,000 A. This brightening and reddening of the IR continuum was accompanied by stronger H I and He I lines, constant or slightly weaker Fe II and (Fe II) lines, and increased extinction to A(sub V) approximately 5 mag to 6 mag (from A(sub V) approximately less than 3.2 mag previously). The complex line profiles fall into two categories: (1) broad emission and sometimes blueshifted absorptions that form in a high-velocity wind reaching at least 700 km/s and (2) narrow emission cores that may be associated with a low-velocity (equatorial?) wind with speeds approximately less than 100 km/s. The broad lines in the Homunculus have profiles and equivalent widths similar to the broad components in the know, but they are redshifted by approximately greater than 250 km/s due to rapid expansion of the reflecting dust. The reflected light spectrum of the Homunculus offers a better 'view' of the high-velocity wind because it is free of the many strong narrow lines in the knot. The range of excitation in both the high- and low-velocity regions encompasses He I recombination and Fe II emission, but excludes the lower ionization required for Fe I, the CO band heads, and the infrared Ca II triplet, which are not detected. The narrow forbidden lines indicate densities in excess of the critical densities, ranging from approximately 10(exp 4) to nearly 10(exp 7)/cu cm. The narrow permitted lines are slightly broader than the forbidden lines and probably form in a denser region nearer the central star. All of the strongest Fe II lines at wavelengths approximately greater than 7000 A, in both the broad and narrow-line regions, can be attributed to cascades from excited states that are 'pumped' by resonant absorption of H I Lyman alpha.

Hamann, Fred↗

NASA NTRS1993

The asymmetric wind of R127

We present optical, linear polarimetry in broad-band UBVRI filters plus narrow-band filters centered on the emission lines of H-alpha and the red forbidden N II and spectropolarimetry in the wavelength range from 4120 A to 6770 A of the luminous blue variable R127 in the LMC. Both observations display a decrease of the percentage polarization across the H-alpha emission line with respect to the continuum. We assume that H-alpha is recombination-line dominated and thus intrinsically unpolarized, and we use the continuum subtracted line polarization to estimate the interstellar foreground polarization. The resulting amount of intrinsic continuum polarization of R127 is very large, of order 1-1.5 percent, implying both the presence of copious free electrons and a considerable asphericity in their distribution. The two data sets, taken two months apart, display significant variations in the continuum polarization, which confirms that the stellar-wind properties of R127 are time-dependent in the maximum state. We discuss several possible wind geometries and present arguments favoring a clumpy, axisymmetric outflow.

Schulte-Ladbeck, R. E.↗

NASA NTRS1976

Infrared emission from the atmosphere above 200 km

The infrared radiation over the range from 4 to 1000 microns from atoms and molecules in the earth's atmosphere, between 200 and 400 km, was calculated. Only zenith lines of sight were considered. The excitation of the atoms and molecules is due to collisions with other molecules and to absorption of radiation from the earth and sun. In some cases, the abundances of the molecules had to be estimated. The most important lines are the forbidden lines from atomic oxygen at 63.1 and 147 micron, and the vibration-rotation band of nitric oxide at 5.3 micron. These lines can have intensities as high as a few times 0.001 ergs/sq cm/sec/steradian at 200 km altitude. In addition, the vibration-rotation bands of NO(+) at 4.3 micron and CO at 4.7 micron and the pure rotation lines of NO and NO(+) could be detected by infrared telescopes in space.

Simpson, J. P.↗

NASA NTRS1990

The C2 Ballik-Ramsay transitions in carbon stars

The bands of C2 are an important source of opacity in the near-infrared spectral region of carbon stars. In the 2 micron spectral region, the Delta v = -1 and -2 transitions of the Ballik-Ramsay b 3Sigma(g)(-) - a 3Pi(u) system are especially important. A general method for calculating highly accurate transition parameters of the Ballik-Ramsay band is presented. This method allows the easy calculation of the satellite lines and the forbidden lines resulting from the perturbation of the upper b 3Sigma(g)(-) state by the X 1Sigma(0)(+) state. Included in the calculation is the effect of the isotopic molecules (C-12)2, (C-12)(C-13), and (C-13)2. Three consistency tests of the calculated strengths are presented. A comparison of synthetic spectra is made with an observed spectrum of WZ Cas in the 3940/cm spectral region.

Goorvitch, David↗

NASA NTRS1971

Coronal active regions and flare-associated events.

Comparison of models of coronal condensations derived from nonoptical and optical observations. Recent empirical models of coronal active regions, based on observations outside the optical wavelength band, are reviewed. Models derived from optical observations are then considered, with special emphasis on the optical forbidden line spectrum. The formation of sporadic condensations and loop prominences following a flare is discussed.

Zirker, J. B.↗

NASA NTRS1989

Optical imagery and spectrophotometry of CTB 80

Narrow-band imagery and spectrophotometry of the central region of CTB 80 are presented. The images show weak forbidden O III and ubiquitous filamentary forbidden S II and H-alpha emission from the extended radio lobes in which the core is embedded. The data indicate that the extended component is shock heated. Balmer line-dominated emission is observed around the perimeter of the core. Assuming that the volume of the radio shell is similar to the volume of the thermal shell, it is found that a magnetic field of about 600 microG and a cosmic-ray proton-to-electron ratio of about 200 are required to explain the pressure and synchrotron volume emissivity in the radio shell. It is suggested that the optical emission form the core of CTB 80 arises behind shocks which are being driven into a magnetized thermal plasma by the confined relativistic wind from PSR 1951+32.

Hester, J. Jeff↗

NASA NTRS2007

Extended-Range Ultrarefractive 1D Photonic Crystal Prisms

A proposal has been made to exploit the special wavelength-dispersive characteristics of devices of the type described in One-Dimensional Photonic Crystal Superprisms (NPO-30232) NASA Tech Briefs, Vol. 29, No. 4 (April 2005), page 10a. A photonic crystal is an optical component that has a periodic structure comprising two dielectric materials with high dielectric contrast (e.g., a semiconductor and air), with geometrical feature sizes comparable to or smaller than light wavelengths of interest. Experimental superprisms have been realized as photonic crystals having three-dimensional (3D) structures comprising regions of amorphous Si alternating with regions of SiO2, fabricated in a complex process that included sputtering. A photonic crystal of the type to be exploited according to the present proposal is said to be one-dimensional (1D) because its contrasting dielectric materials would be stacked in parallel planar layers; in other words, there would be spatial periodicity in one dimension only. The processes of designing and fabricating 1D photonic crystal superprisms would be simpler and, hence, would cost less than do those for 3D photonic crystal superprisms. As in 3D structures, 1D photonic crystals may be used in applications such as wavelength-division multiplexing. In the extended-range configuration, it is also suitable for spectrometry applications. As an engineered structure or artificially engineered material, a photonic crystal can exhibit optical properties not commonly found in natural substances. Prior research had revealed several classes of photonic crystal structures for which the propagation of electromagnetic radiation is forbidden in certain frequency ranges, denoted photonic bandgaps. It had also been found that in narrow frequency bands just outside the photonic bandgaps, the angular wavelength dispersion of electromagnetic waves propagating in photonic crystal superprisms is much stronger than is the angular wavelength dispersion obtained by use of conventional prisms and diffraction gratings and is highly nonlinear.

Ting, David Z.↗