Gas lubricant compositions Patent
High temperature gas lubricant consisting of two fluoro-bromo-methanes
Buckley, D. H.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Survival of endospores of Bacillus subtilis on spacecraft surfaces under simulated martian environments: implications for the forward contamination of Mars
Experiments were conducted in a Mars simulation chamber (MSC) to characterize the survival of endospores of Bacillus subtilis under high UV irradiation and simulated martian conditions. The MSC was used to create Mars surface environments in which pressure (8.5 mb), temperature (-80, -40, -10, or +23 degrees C), gas composition (Earth-normal N2/O2 mix, pure N2, pure CO2, or a Mars gas mix), and UV-VIS-NIR fluence rates (200-1200 nm) were maintained within tight limits. The Mars gas mix was composed of CO2 (95.3%), N2 (2.7%), Ar (1.7%), O2 (0.2%), and water vapor (0.03%). Experiments were conducted to measure the effects of pressure, gas composition, and temperature alone or in combination with Mars-normal UV-VIS-NIR light environments. Endospores of B. subtilis, were deposited on aluminum coupons as monolayers in which the average density applied to coupons was 2.47 x 10(6) bacteria per sample. Populations of B. subtilis placed on aluminum coupons and subjected to an Earth-normal temperature (23 degrees C), pressure (1013 mb), and gas mix (normal N2/O2 ratio) but illuminated with a Mars-normal UV-VIS-NIR spectrum were reduced by over 99.9% after 30 sec exposure to Mars-normal UV fluence rates. However, it required at least 15 min of Mars-normal UV exposure to reduce bacterial populations on aluminum coupons to non-recoverable levels. These results were duplicated when bacteria were exposed to Mars-normal environments of temperature (-10 degrees C), pressure (8.5 mb), gas composition (pure CO2), and UV fluence rates. In other experiments, results indicated that the gas composition of the atmosphere and the temperature of the bacterial monolayers at the time of Mars UV exposure had no effects on the survival of bacterial endospores. But Mars-normal pressures (8.5 mb) were found to reduce survival by approximately 20-35% compared to Earth-normal pressures (1013 mb). The primary implications of these results are (a) that greater than 99.9% of bacterial populations on sun-exposed surfaces of spacecraft are likely to be inactivated within a few tens of seconds to a few minutes on the surface of Mars, and (b) that within a single Mars day under clear-sky conditions bacterial populations on sun-exposed surfaces of spacecraft will be sterilized. Furthermore, these results suggest that the high UV fluence rates on the martian surface can be an important resource in minimizing the forward contamination of Mars. c2003 Elsevier Inc. All rights reserved.
Bacillus subtilis/growth & development/physiology/↗
Primordial retention of carbon by the terrestrial planets
The thermodynamics of graphite, carbide, and carbonate formation in the presence of a solar-composition gas is examined, including the feasibility of producing solid solutions of carbon and carbides in metallic iron-nickel alloy. Gas-phase composition and graphite activities for a very wide range of nebular pressures and temperatures are calculated by a computer program that considers several hundred compounds, particularly all the important gaseous species containing H, C, O, N, S, Cl, P, and F. The results obtained indicate that CH4 and CO would be the dominant carbon compounds under all likely circumstances of temperature and pressure in the solar nebula, that graphite may have been the most abundant carbon species in certain cases, and that direct precipitation of graphite, carbides, or carbonates would have been impossible in the solar nebula. Carbon retention by the terrestrial planets is also investigated.
Lewis, J. S.↗
Intelligent Control and Health Monitoring
Advanced model-based control architecture overcomes the limitations state-of-the-art engine control and provides the potential of virtual sensors, for example for thrust and stall margin. "Tracking filters" are used to adapt the control parameters to actual conditions and to individual engines. For health monitoring standalone monitoring units will be used for on-board analysis to determine the general engine health and detect and isolate sudden faults. Adaptive models open up the possibility of adapting the control logic to maintain desired performance in the presence of engine degradation or to accommodate any faults. Improved and new sensors are required to allow sensing at stations within the engine gas path that are currently not instrumented due in part to the harsh conditions including high operating temperatures and to allow additional monitoring of vibration, mass flows and energy properties, exhaust gas composition, and gas path debris. The environmental and performance requirements for these sensors are summarized.
Sanjay Garg↗
Mechanical Behavior of Notched SiC/SiC Composites
Gas turbine components such as combustor liners or turbine vanes are subject to regions of high stress-concentration, e.g., attachment to the frame or at cooling holes. Ceramic matrix composites (CMCs) are potential materials for high temperature applications in gas turbines. They offer some capability to relieve stress at regions of high stress-concentration via matrix damage accumulation. In this study notch sensitivity was examined for woven SiC fiber reinforced, melt-infiltrated SiC matrix composites with a BN interphase, utilizing either Hi-Nicalo(TM) fibers or the stiffer Sylramic fibers. The double-edge notched tensile test approach was used for a wide range of notch sizes and specimen widths. Both composite systems exhibited mild notch sensitivity similar to other CMC systems. Acoustic emission, detected during the tensile tests, indicated that matrix cracking occurred around notches at net-section stresses below the stress where matrix cracking first occurs in unnotched specimens. However, thermoelastic stress analysis did not show any measurable stress relief around notches after the specimens were preloaded.
Morscher, Gregory N.↗
Shock wave structure in an ideal dissociating gas
Composition changes within the shock layer due to chemical reactions are considered. The Lighthill ideal dissociating gas model was used in an effort to describe the oxygen type molecule. First, the two limiting cases, when the chemical reaction rates are very slow and very fast in comparison to local convective rates, are investigated. Then, the problem is solved for arbitrary chemical reaction rates.
Liu, K. H.↗
Advanced High Temperature Polymer Matrix Composites for Gas Turbine Engines Program Expansion
This document, submitted by AlliedSignal Engines (AE), a division of AlliedSignal Aerospace Company, presents the program final report for the Advanced High Temperature Polymer Matrix Composites for Gas Turbine Engines Program Expansion in compliance with data requirements in the statement of work, Contract No. NAS3-97003. This document includes: 1 -Technical Summary: a) Component Design, b) Manufacturing Process Selection, c) Vendor Selection, and d) Testing Validation: 2-Program Conclusion and Perspective. Also, see the Appendix at the back of this report. This report covers the program accomplishments from December 1, 1996, to August 24, 1998. The Advanced High Temperature PMC's for Gas Turbine Engines Program Expansion was a one year long, five task technical effort aimed at designing, fabricating and testing a turbine engine component using NASA's high temperature resin system AMB-21. The fiber material chosen was graphite T650-35, 3K, 8HS with UC-309 sizing. The first four tasks included component design and manufacturing, process selection, vendor selection, component fabrication and validation testing. The final task involved monthly financial and technical reports.
Hanley, David↗
Melt-infiltrated Sic Composites for Gas Turbine Engine Applications
SiC-SiC ceramic matrix composites (CMCs) manufactured by the slurry -cast melt-infiltration (MI) process are leading candidates for many hot-section turbine engine components. A collaborative program between Goodrich Corporation and NASA-Glenn Research Center is aimed at determining and optimizing woven SiC/SiC CMC performance and reliability. A variety of composites with different fiber types, interphases and matrix compositions have been fabricated and evaluated. Particular focus of this program is on the development of interphase systems that will result in improved intermediate temperature stressed-oxidation properties of this composite system. The effect of the different composite variations on composite properties is discussed and, where appropriate, comparisons made to properties that have been generated under NASA's Ultra Efficient Engine Technology (UEET) Program.
Morscher, Gregory N.↗
The origin of planetary atmospheres
Reasons for the difference in planetary atmospheres are reviewed. Atmospheric formation by outgassing from terrestrial planets is contrasted with the retention of the primary material by the outer planets. The differences in Venusian, earth, and Martian atmospheres are explained in terms of planet distance from the sun. Data on terrestrial planet pressures, temperatures, and gas compositions, as well as on rates and gas composition of outgassing material are presented. The significance of planet mass is considered.
Bauer, S. J.↗
A Model of Thermal Conductivity for Planetary Soils: 1. Theory for Unconsolidated Soils
We present a model of heat conduction for mono-sized spherical particulate media under stagnant gases based on the kinetic theory of gases, numerical modeling of Fourier s law of heat conduction, theoretical constraints on the gas thermal conductivity at various Knudsen regimes, and laboratory measurements. Incorporating the effect of the temperature allows for the derivation of the pore-filling gas conductivity and bulk thermal conductivity of samples using additional parameters (pressure, gas composition, grain size, and porosity). The radiative and solid-to-solid conductivities are also accounted for. Our thermal model reproduces the well-established bulk thermal conductivity dependency of a sample with the grain size and pressure and also confirms laboratory measurements finding that higher porosities generally lead to lower conductivities. It predicts the existence of the plateau conductivity at high pressure, where the bulk conductivity does not depend on the grain size. The good agreement between the model predictions and published laboratory measurements under a variety of pressures, temperatures, gas compositions, and grain sizes provides additional confidence in our results. On Venus, Earth, and Titan, the pressure and temperature combinations are too high to observe a soil thermal conductivity dependency on the grain size, but each planet has a unique thermal inertia due to their different surface temperatures. On Mars, the temperature and pressure combination is ideal to observe the soil thermal conductivity dependency on the average grain size. Thermal conductivity models that do not take the temperature and the pore-filling gas composition into account may yield significant errors.
Piqueux, S.↗
Gain and power of CO2 gasdynamic lasers.
This paper presents experimental and theoretical studies of the small signal gain and the radiant power for one configuration of CO2 gasdynamic lasers to define the optimum-gas temperature, pressure and gas compositions for the gain and the laser power. The laser was operated with two gas mixtures (CO2-N2-He and CO2-N2-H2O) at temperatures of 800-2200 deg K, pressures of 2-16 atm, and a wide range of gas compositions. For this laser optimum gas temperatures were roughly 1500-1600 deg K for gain and more than 2200 deg K for power. It was found that the gasdynamic laser would not oscillate for He or H2O concentrations of less than 10% and 1%, respectively. The various kinetic processes for establishing gain and the various laser cavity parameters that determine laser power were examined. The theories were assessed for their ability to predict gain and power. In most cases, the gain theory gave excellent quantitative results whereas the power theory gave only qualitative results. Laser power of nearly 2 kw was obtained.
Lee, G.↗
Chemistry of primitive solar material
The paper reviews chemical processes that occurred in the cooler outer regions of the primitive solar nebula (PSN) at the time of intimate chemical contact between the preplanetary condensate and the nebular gas. The elemental composition of the PSN is discussed, the 15 most abundant elements in it are listed, and numerical models of it are examined. Various condensation models are described and tested against observed properties of the planets, their satellites, and the asteroids. The chemistry of abundant volatile elements in the PSN is investigated along with stability limits of graphite in a solar-composition gas, regions of dominance of the most abundant carbon-containing gas species in the same gas, and implications of the moon's composition for its origin. Some theories that have been proposed as alternatives to the condensation models are noted.
Barshay, S. S.↗
Prediction of Combustion Gas Deposit Compositions
Demonstrated procedure used to predict accurately chemical compositions of complicated deposit mixtures. NASA Lewis Research Center's Computer Program for Calculation of Complex Chemical Equilibrium Compositions (CEC) used in conjunction with Computer Program for Calculation of Ideal Gas Thermodynamic Data (PAC) and resulting Thermodynamic Data Base (THDATA) to predict deposit compositions from metal or mineral-seeded combustion processes.
Kohl, F. J.↗
Certain preliminary results of the development of a method for the quantitative determination of the composition of a gas mixture by an omegatron mass spectrometer
Quantitative analysis of gas mixture composition by omegatron mass spectrometer
MASS SPECTROMETER↗
Combustion gas properties. 2: Natural gas fuel and dry air
A series of computations has been made to produce the equilibrium temperature and gas composition for natural gas fuel and dry air. The computed tables and figures provide combustion gas property data for pressures from 0.5 to 50 atmospheres and equivalence ratios from 0 to 2.0. Only samples tables and figures are provided in this report. The complete set of tables and figures is provided on four microfiche films supplied with this report.
Wear, J. D.↗
Combustion gas properties. Part 3: Hydrogen gas fuel and dry air
A series of computations has been made to produce the equilibrium temperature and gas composition for hydrogen gas fuel and dry air. The computed tables and figures provide combustion gas property data for pressures from 0.5 to 50 atmospheres and equivalence ratios from 0 to 2.0. Only sample tables and figures are provided in this report.
Wear, J. D.↗
Constraining Oxygen and Sulfur Fugacity in Venus Weathering Experiments in the Glenn Extreme Environment Rig
Experimental efforts to understand chemical weathering of Venus surface rocks and minerals have been undertaken using a range of methods and conditions. A challenge with many of these experiments is measuring and maintaining the gas composition at the desired values because of the lack of instruments and sensors that can monitor gas compositions within vessels at Venus conditions. Thus, the oxygen fugacity, f O2 , and sulfur fugacity, f S2 , for Venus experiments are often not well known or constrained. Oxygen and sulfur fugacities dictate the stability of many minerals such as iron oxides and sulfides, and thus play a crucial role in weathering reactions.
A. R. Santos↗
An experimental investigation of base heating on typical Mars entry body shapes.
Hypersonic experiments on wire supported high angle blunt cones were conducted to determine the base heating characteristics. Heating distributions were obtained for several base configurations with variations in free stream Reynolds Number and gas composition. The dependence of the heating in the base region on angle of attack was also investigated. It was found that gas composition effects can be accounted for by comparison at equal Reynolds Number. Angle of attack effects can result in either increasing or decreasing base heating depending upon the location in the base region.
Zappa, O. L.↗