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Oxidation and formation of deposit precursors in hydrocarbon fuels

The oxidation of two jet turbine fuels and some pure hydrocarbons was studied at 130 C with and without the presence of small amounts of N-methyl pyrrole (NMP) or indene. Tendency to form solid-deposit precursors was studied by measuring soluble gum formation as well as dimer and trimer formation using field ionization mass spectrometry. Pure n-dodecane oxidized fastest and gave the smallest amount of procursors. An unstable fuel oil oxidized much slower but formed large amounts of precursors. Stable Jet A fuel oxidized slowest and gave little precursors. Indene either retarded or accelerated the oxidation of n-dodecane, depending on its concentration, but always caused more gum formation. The NMP greatly retarded n-dodecane oxidation but accelerated Jet A oxidation and greatly increased the latter's gum formation. In general, the additive reacted faster and formed most of the gum. Results are interpreted in terms of classical cooxidation theory. The effect of oxygen pressure on gum formation is also reported.

Mayo, F. R.↗

A discussion of the ground-based radio observations

It is reasserted that the Gum nebula is not a single nebula but appears to be composed of several different entities. All the surveys of the southern sky in the continuum, recombination line, H I, and OH were considered. The large amount of high frequency radio emission from the small nebula is noted. The outer part of the Gum nebula has not been seen in any radio observations so far. Only the inner part has been observed to date. It is not justifiable to work out any parameters for the whole nebula by taking an average over the whole solid angle subtended by the big nebula. There appears to be a large difference in density between the small nebula and the big one.

Kerr, F. J.↗

X-Rays form the Vela-Puppis Complex

A review of X-ray observations in the vicinity of the Gum nebula is presented. There is little doubt that the filamentary nebula Stromlo 16, the radio source Vela X, and the extended X-ray object Vel XR-2 are indications of the same, relatively nearby, supernova remnant. X-ray absorption measurements are consistent with a distance of 500 + or - 100 pc. The observed X-ray spectra have not yet distinguished between thermal bremsstrahlung and synchrotron radiation as the source mechanism. A search for low energy X-ray emission lines, both within the 5 deg diameter remnant and in the larger Gum nebula, may provide an important test for models of supernova remnant evolution.

Bunner, A. N.↗

Large nebular complexes in the northern portion of the galaxy

Several northern complexes of ionized hydrogen, stars, and possibly nonthermal radio emission are known whose properties are similiar to those of the Gum nebula. Among the best known complexes are the Ori I and Ceph IV associations and IC 1795, IC 1805, and IC 1848. Each of these complexes contains an extended ring structure and requires more excitation than is available from the known early stars. The properties of these objects were examined and many of the properties of the Gum nebula are common to such galactic complexes.

Webster, W. J., Jr.↗

A description of the mechanical behavior of composite solid propellants based on molecular theory

Both the investigation and the representation of the stress-strain response (including rupture) of gum and filled elastomers can be based on a simple functional statement. Internally consistent experiments are used to sort out the effects of time, temperature, strain and crosslink density on gum rubbers. All effects are readily correlated and shown to be essentially independent of the elastomer when considered in terms of non-dimensionalized stress, strain and time. A semiquantitative molecular theory is developed to explain this result. The introduction of fillers modifies the response, but, guided by the framework thus provided, their effects can be readily accounted for.

Landel, R. F.↗

An experiment to detect gut monopoles

Recent advances in the development of Grand Unification Theories have led to several interesting predictions. One of these states that Grand Unification Monopoles (GUMs) exist as solutions in may nonabelian gauge theories. Another consequence of Unification is the possibility of baryon decay. The efficiency of the water tank detector in registering a Rubakov type decay will vary with both the interaction length and the GUM's velocity, expressed in terms of beta ( 0.01). The efficiency decreases at large values of because of the limited resolving time of the detector (approx. 50 ns). At lower values of Beta the time between interactions is such that the criterion of 4 events in 2 mu s can no longer be satisfied. The Rubakov experiment has now been in operation for almost 2 years with an estimated live time of 80%. During this time no candidate events have been observed leading to an estimated upper limit on the flux of 7.82 x 0.00001 m(-2) d(-1) Sr(-1). The ionization loss detection system has only recently come on line and as yet no results are available from this experiment.

Macneill, G.↗

Measurements of anisotropy in the cosmic microwave background radiation at 0.5 deg angular scales near the star gamma ursae minoris

We present results from a four-frequency observation of a 6 deg x 0.6 deg strip of the sky centered near the star Gamma Ursae Minoris (GUM) during the fourth flight of the Millimeter-wave Anistropy experiment(MAX). The observation was made with a 1.4 deg peak-to-peak sinusoidal chop in all bands. The FWHM beam sizes were 0.55 deg +/- 0.05 deg at 3.5 per cm and 0.75 deg +/- 0.05 deg at 6, 9, and 14 per cm. During this observation significant correlated structure was observed at 3.5, 6 and 9 per cm with amplitudes similar to those observed in the GUM region during the second and third fligts of MAX. The frequency spectrum is consistent with cosmic microwave background (CMB) and inconsistent with thermal emission from interstellar dust. The extrapolated amplitudes of synchrotron and free-free emission are too small to account for the amplitude of the observed structure, If all of the structure is attributed to CMB anisotropy with a Gaussian autocorrelation function and a coherence angle of 25 min, then the most probable values of delta T/T(sub CMB) in the 3.5, 6 and 9 per cm bads are (4.3 +2.7/-1.6) x 10(exp -5), 2.8 (+4.3/-1/1) x 10(exp -5), and 3.5 (+3.0/-1.6) x 10(exp -5) (95% confidence upper and lower limits), respectively.

Devlin, M. J.↗

Measurements of the millimeter-wave spectrum of interstellar dust emission

We report measurements of the differential brightness of interstellar dust emission near the Galactic plane and at high Galactic latitudes. The data were obtained as part of a program to measure anisotropy in the cosmic microwave background (CMB). The measurements were made with a 0.5 deg beam size and a 1.3 deg sinusoidal chop, in broad bands (Delta nu/nu approximately 0.3) centered near frequencies of 6, 9, and 12 cm(exp -1). A measurement made toward the Galactic plane, at longitude 1 = 23.7 deg, is compared with the contrast observed in the 100 micrometers IRAS data. Assuming the dust emission has a brightness I(sub nu) proportional to nu(sup n)B(sub nu)(T(sub d)), where B(sub nu) is the Planck function, a best fit yields n = 1.6 +/- 0.4, T(sub d) = 24 +/- 5 K. In a region near the star mu Pegasi (mu PEG l = 91 deg, b = -31 deg), the comparison of our data with the 100 micrometers IRAS data yields n = 1.4 +/- 0.4, and T(sub d) = 18 +/- 3 K. In a second region near the star gamma Ursa Minoris (GUM l = 108 deg, b = 41 deg), an upper limit is placed on contrast in dust emission. This upper limit is consistent with spectrum measured at mu PEG and the IRAS 100 micrometer emission contrast at GUM, which is approximately 8 times lower than mu PEG.

Fischer, M. L.↗

Rheologically interesting polysaccharides from yeasts

We have examined the relationships between primary, secondary, and tertiary structures of polysaccharides exhibiting the rheological property of friction (drag) reduction in turbulent flows. We found an example of an exopolysaccharide from the yeast Cryptococcus laurentii that possessed high molecular weight but exhibited lower than expected drag reducing activity. Earlier correlations by Hoyt showing that beta 1 --> 3, beta 2 --> 4, and alpha 1 --> 3 linkages in polysaccharides favored drag reduction were expanded to include correlations to secondary structure. The effect of sidechains in a series of gellan gums was shown to be related to sidechain length and position. Disruption of secondary structure in drag reducing polysaccharides reduced drag reducing activity for some but not all exopolysaccharides. The polymer from C. laurentii was shown to be more stable than xanthan gum and other exopolysaccharides under the most vigorous of denaturing conditions. We also showed a direct relationship between extensional viscosity measurements and the drag reducing coefficient for four exopolysaccharides.

Friction↗

Computer-implemented system and method for automated and highly accurate plaque analysis, reporting, and visualization

A computer-implemented system and method of intra-oral analysis for measuring plaque removal is disclosed. The system includes hardware for real-time image acquisition and software to store the acquired images on a patient-by-patient basis. The system implements algorithms to segment teeth of interest from surrounding gum, and uses a real-time image-based morphing procedure to automatically overlay a grid onto each segmented tooth. Pattern recognition methods are used to classify plaque from surrounding gum and enamel, while ignoring glare effects due to the reflection of camera light and ambient light from enamel regions. The system integrates these components into a single software suite with an easy-to-use graphical user interface (GUI) that allows users to do an end-to-end run of a patient record, including tooth segmentation of all teeth, grid morphing of each segmented tooth, and plaque classification of each tooth image.

Kemp, James Herbert↗

Periodontal Probe Improves Exams, Alleviates Pain

Dentists, comedian Bill Cosby memorably mused, tell you not to pick your teeth with any sharp metal object. Then you sit in their chair, and the first thing they grab is an iron hook!" Conventional periodontal probing is indeed invasive, uncomfortable for the patient, and the results can vary greatly between dentists and even for repeated measurements by the same dentist. It is a necessary procedure, though, as periodontal disease is the most common dental disease, involving the loss of teeth by the gradual destruction of ligaments that hold teeth in their sockets in the jawbone. The disease usually results from an increased concentration of bacteria in the pocket, or sulcus, between the gums and teeth. These bacteria produce acids and other byproducts, which enlarge the sulcus by eroding the gums and the periodontal ligaments. The sulcus normally has a depth of 1 to 2 millimeters, but in patients with early stages of periodontal disease, it has a depth of 3 to 5 millimeters. By measuring the depth of the sulcus, periodontists can have a good assessment of the disease s progress. Presently, there are no reliable clinical indicators of periodontal disease activity, and the best available diagnostic aid, periodontal probing, can only measure what has already been lost. A method for detecting small increments of periodontal ligament breakdown would permit earlier diagnosis and intervention with less costly and time-consuming therapy, while overcoming the problems associated with conventional probing. The painful, conventional method for probing may be destined for the archives of dental history, thanks to the development of ultrasound probing technologies. The roots of ultrasound probes are in an ultrasound-based time-of-flight technique routinely used to measure material thickness and length in the Nondestructive Evaluation Sciences Laboratory at Langley Research Center. The primary applications of that technology have been for corrosion detection and bolt tension measurements (Spinoff 2005). This ultrasound measurement system was adapted to the Periodontal Structures Mapping System, invented at Langley by John A. Companion, under the supervision of Dr. Joseph S. Heyman. Support of the research and development that led to this invention was provided by NASA s Technology Applications Engineering Program and by the Naval Institute for Dental and Biomedical Research, in Great Lakes, Illinois.

Source record↗

Software and Algorithms for Biomedical Image Data Processing and Visualization

A new software equipped with novel image processing algorithms and graphical-user-interface (GUI) tools has been designed for automated analysis and processing of large amounts of biomedical image data. The software, called PlaqTrak, has been specifically used for analysis of plaque on teeth of patients. New algorithms have been developed and implemented to segment teeth of interest from surrounding gum, and a real-time image-based morphing procedure is used to automatically overlay a grid onto each segmented tooth. Pattern recognition methods are used to classify plaque from surrounding gum and enamel, while ignoring glare effects due to the reflection of camera light and ambient light from enamel regions. The PlaqTrak system integrates these components into a single software suite with an easy-to-use GUI (see Figure 1) that allows users to do an end-to-end run of a patient s record, including tooth segmentation of all teeth, grid morphing of each segmented tooth, and plaque classification of each tooth image. The automated and accurate processing of the captured images to segment each tooth [see Figure 2(a)] and then detect plaque on a tooth-by-tooth basis is a critical component of the PlaqTrak system to do clinical trials and analysis with minimal human intervention. These features offer distinct advantages over other competing systems that analyze groups of teeth or synthetic teeth. PlaqTrak divides each segmented tooth into eight regions using an advanced graphics morphing procedure [see results on a chipped tooth in Figure 2(b)], and a pattern recognition classifier is then used to locate plaque [red regions in Figure 2(d)] and enamel regions. The morphing allows analysis within regions of teeth, thereby facilitating detailed statistical analysis such as the amount of plaque present on the biting surfaces on teeth. This software system is applicable to a host of biomedical applications, such as cell analysis and life detection, or robotic applications, such as product inspection or assembly of parts in space and industry.

Talukder, Ashit↗

Fourier transform-infrared spectroscopic methods for microbial ecology: analysis of bacteria, bacteria-polymer mixtures and biofilms

Fourier transform-infrared (FT-IR) spectroscopy has been used to rapidly and nondestructively analyze bacteria, bacteria-polymer mixtures, digester samples and microbial biofilms. Diffuse reflectance FT-IR (DRIFT) analysis of freeze-dried, powdered samples offered a means of obtaining structural information. The bacteria examined were divided into two groups. The first group was characterized by a dominant amide I band and the second group of organisms displayed an additional strong carbonyl stretch at approximately 1740 cm-1. The differences illustrated by the subtraction spectra obtained for microbes of the two groups suggest that FT-IR spectroscopy can be utilized to recognize differences in microbial community structure. Calculation of specific band ratios has enabled the composition of bacteria and extracellular or intracellular storage product polymer mixtures to be determined for bacteria-gum arabic (amide I/carbohydrate C-O approximately 1150 cm-1) and bacteria-poly-beta-hydroxybutyrate (amide I/carbonyl approximately 1740 cm-1). The key band ratios correlate with the compositions of the material and provide useful information for the application of FT-IR spectroscopy to environmental biofilm samples and for distinguishing bacteria grown under differing nutrient conditions. DRIFT spectra have been obtained for biofilms produced by Vibrio natriegens on stainless steel disks. Between 48 and 144 h, an increase in bands at approximately 1440 and 1090 cm-1 was seen in FT-IR spectra of the V. natriegens biofilm. DRIFT spectra of mixed culture effluents of anaerobic digesters show differences induced by shifts in input feedstocks. The use of flow-through attenuated total reflectance has permitted in situ real-time changes in biofilm formation to be monitored and provides a powerful tool for understanding the interactions within adherent microbial consortia.

NASA Discipline Number 61-10↗

Quick don-doff electrode pastes

Evaluation of electrode pastes for use in electrocardiographs and electroencephalographs found that the one having the desired don-doff properties had to be water soluble or a water dispersible base. Poly /methyl vinyl ether/maleic anhydride/ or starch gels of the gum drop variety are two such bases.

Mosier, B.↗

Formation of giant H II regions following supernova explosions

The principal optical properties of type I supernovae are summarized. These include the light curve and the spectrum. The spectra consist of broad bands with very little continuum. According to the theory presented, the observed light is principally fluorescence, excited in the medium surrounding the supernova by ultraviolet radiation originating from the explosion. It is proposed that the spectrum that impinges on the fluorescent medium while emission is taking place must fall abruptly across the Lyman edge of He II. Such a filtering action is plausibly provided by a much denser internal region, rich in helium, immediately surrounding the exploding object. This will form a Stromgren sphere during the time the intense UV pulse is passing through it. The dense region also slows down the photons below the edge by Thomson scattering, thereby spreading out the UV pulse in time. Various proposed mechanisms for the production of ionization in the Gum nebula are discussed.

Sartori, L.↗

The velocity and composition of supernova ejecta

In case of the Gum nebula, a pulsar - a presumed neutron star - is believed to be a relic of the supernova explosion. Regardless of the mechanism of the explosion, the velocity distribution and composition of the ejected matter will be roughly the same. The reimploding mass fraction is presumed to be neutron rich. The final composition is thought to be roughly 1/3 iron and 2/3 silicon, with many small fractions of elements from helium to iron. The termination of helium shell burning occurs because the shell is expanded and cooled by radiation stress. The mass fraction of the helium burning shell was calculated.

Colgate, S. A.↗

Three proposed B-associations in the vicinity of zeta puppis

There appear to be three loose B associations in the general vicinity of zeta Puppis, all at distances of approximately 300 to 400 parsecs from the sun. Their diameters, perpendicular to the line of sight, are 20 to 50 parsecs, and their separations are of similar size. All three are situated in bright areas of the Gum nebula. The proposed associations A and C lie in the two brightest parts of the nebula. The three associations are not all of the same age. Association C is about 50 million years old, whereas A and B are decidedly younger. The ages of A and B cannot be determined from the present data, as their color-magnitude diagrams show no clear turnoff from the main sequence. Association A may be young enough to qualify as the birthplace of zeta Puppis. There is no other identifiable association in which zeta Puppis can have originated, unless its age is substantially greater than the 3 million years assumed.

Upton, E. K. L.↗

A discussion of the H-alpha filamentary nebulae and galactic structure in the Cygnus region

From observation of the galactic structure in Cygnus, the system of filamentary nebulae was found to lie at a distance of roughly 1.5 kpc, in the same region as about half the thermal radio sources in Cygnus X, the supernova remnant near gamma Cygni, and the association Cygnus OB2, in the direction of which the X-ray source Cygnus XR-3 is observed. The source of excitation was probably the pulse of radiation from a supernova explosion, as proposed in the case of Gum nebula. However continuing excitation by early stars in the region of Cygnus X cannot be excluded.

Matthews, T. A.↗