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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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JANNAF 28th Propellant Development and Characterization Subcommittee and 17th Safety and Environmental Protection Subcommittee Joint Meeting

This volume contains 37 unclassified/unlimited-distribution technical papers that were presented at the JANNAF 28th Propellant Development & Characterization Subcommittee (PDCS) and 17th Safety & Environmental Protection Subcommittee (S&EPS) Joint Meeting, held 26-30 April 1999 at the Town & Country Hotel and the Naval Submarine Base, San Diego, California. Volume II contains 29 unclassified/limited-distribution papers that were presented at the 28th PDCS and 17th S&EPS Joint Meeting. Volume III contains a classified paper that was presented at the 28th PDCS Meeting on 27 April 1999. Topics covered in PDCS sessions include: solid propellant rheology; solid propellant surveillance and aging; propellant process engineering; new solid propellant ingredients and formulation development; reduced toxicity liquid propellants; characterization of hypergolic propellants; and solid propellant chemical analysis methods. Topics covered in S&EPS sessions include: space launch range safety; liquid propellant hazards; vapor detection methods for toxic propellant vapors and other hazardous gases; toxicity of propellants, ingredients, and propellant combustion products; personal protective equipment for toxic liquid propellants; and demilitarization/treatment of energetic material wastes.

Cocchiaro, James E.↗

High performance N2O4/amine elements blowapart

An experimental and analytical program was conducted to develop an understanding of the mechanisms controlling hypergolic propellant reactive stream separation (RSS). RSS is a combustion induced phenomenon that results in striation of hypergolic propellant oxidizer and fuel sprays fans. This reduced intraelement mixing can influence thrust chamber performance, heat transfer, and stability. The program and product were the development of design criteria for coping with RSS to allow the design of high performance, stable injectors.

Lawver, B. R.↗

Stress Corrosion Cracking of Metals in Propellants

Stress corrosion cracking (SCC) of a fracture critical metallic material can cause a premature failure if the material is susceptible in the unique service environment. Material fluid compatibility is an area of interest for the current NASA programs leading the human exploration path to Mars. White Sands Test Facility, the agency's lead on hypergolic propellant testing, identifies a lack in stress corrosion cracking susceptibility data for metallic materials in hypergolic propellants. The development of a stress corrosion cracking screening method is necessary to bridge the knowledge gap and enable the community to more confidently select materials for the use in systems containing corrosive fluids.

Alcantara, Ilse↗

Ultimate disposal of scrubber wastes

Part of the initial concern with using the wet scrubbers on the hypergolic propellants was the subsequential disposal of the liquid wastes. To do this, consideration was given to all possible methods to reduce the volume of the wastes and stay within the guidelines established by the state and federal environmental protection agencies. One method that was proposed was the use of water hyacinths in disposal ponds to reduce the waste concentration in the effluent to less than EPA tolerable levels. This method was under consideration and even in use by private industry, municipal governments, and NASA for upgrading existing wastewater treatment facilities to a tertiary system. The use of water hyacinths in disposal ponds appears to be a very cost-effective method for reduction and disposal of hypergolic propellants.

Cohenour, B. C.↗

Assessment of MON-25/MMH Propellant System for Deep-Space Engines

Hypergolic propellant system of oxidizer MON-25 and fuel MMH has been considered in propulsion trade studies for NASA science mission concepts. A propulsion system using this bi-propellant combination will be capable of operating at a lower temperature as compared to traditional MON-3/MMH for heater power reduction. Operation robustness can also be realized since such a propellant system is utilized under a wide range of temperatures. Propulsion system designs and engine test programs for MON-25/MMH have been carried out since 2008. Several engine development programs have been conducted. The thrust classes of 22-Newton [5-lb(sub f)] and 445-Newton [100-lb(sub f)] were tested with the capability of a pulse mode operation for a wide range of duty cycles. Additional engine development tests are followed. Outcomes of the development efforts suggest that there is a balance of mission benefits and potential engine design and operation challenges, although the propellants can handle a low temperature. This paper will report an assessment of using the MON-25/MMH system for deep- space application.

Trinh, Huu P.↗

Generic propellant transfer unit: A project update

Currently, most satellite programs use dedicated hypergolic propellant ground servicing equipment. These 'carts' are typically program specific (non-interchangeable), costly, and non-Department of Transportation (DOT) compliant. They require safety waivers when used on government property and must be emptied before off-site transport. The emptying process usually generates large amounts of Hazardous Wastes. Fuel carts are usually loaded from multiple 208-liter (55 gallon) drums and oxidizer carts from 909-kg (2000 lb) cylinders. This further increases operating costs due to additional container samples and cart-filling transfers. NASA, Kennedy Space Center has developed reusable, generic, DOT compliant propellant delivery containers as possible replacements for the propellant-tank portion of servicing carts. Our ultimate goal is to reduce operating expenses by minimizing propellant transfers, samples, and waste generation through use of bulk propellant operations, minimizing drum or cylinder operations. This has the added benefit of increasing operating safety by decreasing overall propellant operations.

Davis, C. L.↗

Cis-Lunar Reusable In-Space Transportation Architecture for the Evolvable Mars Campaign

Human exploration missions to Mars or other destinations in the solar system require large quantities of propellant to enable the transportation of required elements from Earth's sphere of influence to Mars. Current and proposed launch vehicles are incapable of launching all of the requisite mass on a single vehicle; hence, multiple launches and in-space aggregation are required to perform a Mars mission. This study examines the potential of reusable chemical propulsion stages based in cis-lunar space to meet the transportation objectives of the Evolvable Mars Campaign and identifies cis-lunar propellant supply requirements. These stages could be supplied with fuel and oxidizer delivered to cis-lunar space, either launched from Earth or other inner solar system sources such as the Moon or near Earth asteroids. The effects of uncertainty in the model parameters are evaluated through sensitivity analysis of key parameters including the liquid propellant combination, inert mass fraction of the vehicle, change in velocity margin, and change in payload masses. The outcomes of this research include a description of the transportation elements, the architecture that they enable, and an option for a campaign that meets the objectives of the Evolvable Mars Campaign. This provides a more complete understanding of the propellant requirements, as a function of time, that must be delivered to cis-lunar space. Over the selected sensitivity ranges for the current payload and schedule requirements of the 2016 point of departure of the Evolvable Mars Campaign destination systems, the resulting propellant delivery quantities are between 34 and 61 tonnes per year of hydrogen and oxygen propellant, or between 53 and 76 tonnes per year of methane and oxygen propellant, or between 74 and 92 tonnes per year of hypergolic propellant. These estimates can guide future propellant manufacture and/or delivery architectural analysis.

McVay, Eric S.↗

A Hybrid Mars Ascent Vehicle Design and FY 2016 Technology Development

Hybrid propulsion is currently favored for a Mars Ascent Vehicle (MAV) concept from a thermal performance and Gross Lift Off Mass standpoint. However, it is at a relatively low level of maturity compared to conventional propulsion options. Technology development efforts are currently underway to bring hybrid propulsion to a technology readiness level that would enable its infusion into potential Mars Sample Return. A new propellant combination is being considered for this design that has excellent low temperature behavior. Preliminary results of two ground test campaigns are currently underway to characterize this propellant combination. Hotfire testing is being carried out in parallel at Parabilis Space Technologies and Space Propulsion Group. In addition to the new propellant combination, several other technologies are being pursued for a potential hybrid MAV: hypergolic ignition and Liquid Injection Thrust Vector Control. Both of these technologies have been applied in other rocket applications, e.g. liquid propulsion commonly uses hypergolic propellants and missiles, such as the Minuteman II, have used LITVC in the past. Hypergolic ignition, when oxidizer and fuel combust upon contact, is highly desirable for multiple starts required by the MAV concept. Therefore, testing at Penn State and Purdue is being completed in this area. An updated hybrid propulsion system design for a Mars Ascent Vehicle concept based on JPL’s current understanding of potential Mars Sample Return requirements will be presented, leveraging the advances in technology development as well as updated understanding of how requirements may evolve.

Karp, Ashley C.↗

Low Leakage Valves for Long Duration Missions

I.Nomenclaturemtypical_mission=internal mass of propellant lost over the course of a mission with Qtypicalmmission_goal=mass of propellant loss over the course of a mission with Qgoaltmission=theoretical mission durationQtypical=internal leakage rate found in commercially available valvesQgoal=internal leakage rate design goalρH2_STP=density of hydrogen at standard temperature and pressure.1NASA AST, Liquid Propulsion Valve Engineer.Valves, Actuators, and Ducts Design and Development Branch (ER14)2NASA AST, Liquid Propulsion Valve Engineer.Valves, Actuators, and Ducts Design and Development Branch (ER14)3NASA AST, Liquid Propulsion Valve Engineer (Retired).Valves, Actuators, and Ducts Design and Development Branch (ER14)4JSEG ESSCA, Engineering Specialist.Valves Actuators and Ducts Design and Development Branch (ER14)5NASA AST, Liquid Propulsion Valve Engineer.Valves, Actuators, and Ducts Design and Development Branch (ER14)6JSEG ESSCA, Valve Design and Development Engineer.Valves Actuators and Ducts Design and Development Branch (ER14) II.IntroductionCurrent aerospace cryogenic valves present challenges to potential long duration missions that utilize cryogenic propellants. Small interplanetary and long-life communication satellites typically utilize hypergolic propellants that operate at higher temperatures, making it easier to achieve very low internal leakage rates. Larger vehicles for long duration missions will likely need to utilize cryogenic-based chemical and nuclear systems to achieve mission requirements. Some early propulsion concepts are projected to require valves with a nominal size ranging from 3” to 10”.Currently available cryogenic aerospace valves typically have internal leakage rates which can range from 100 to 300 SCIM for 3” valves, or upwards of 2,000 SCIM for 10” valves. With just a few of these valves in a system, internal leakage could account for multiple tons of propellant loss over the course of a potential Mars mission, as shown in Figure 1.Figure 1 - Potential Propellant Loss Over the Course of a Long Duration MissionMost internal leakage rates can be attributed to inherent imperfections and misalignments, which result in imperfect contact between sealing surfaces, as shown in Figure 2.Figure 2 - Imperfections and Misalignments Between Sealing Surfaces The ER14 Branch at Marshall Space Flight Center (MSFC) has created a self-aligning seat and poppet design (shown in Figure 3) that allows a valve to be more tolerant of imperfect contacts. This design utilizes a metallic poppet head with five degrees of freedom that allows the poppet toself-align with the seat, reducing the need for tight tolerances.Figure 3 - Self-Aligning Seat and Poppet DesignIII.Test Valve DescriptionA series of development tasks have been conducted to study potential improvements to internal leakage rates. These tasks include 3 test valves (shown in Figure 4) to demonstrate the potential application to various configurations and sizes:A 3” isolation valve for liquid flows (similar to a fill and drain valve)A 3” relief valve for low temperature gas flows.An 8” pre-valve (similar to the engine isolation valve needed on a Nuclear Thermal Propulsion (NTP) engine).Figure 4 - Low Leakage Development Test ValvesThese valves have been developed and are currently being tested at liquid nitrogen (LN2) temperatures, and are anticipated to undergo testing at liquid hydrogen (LH2) temperatures in late 2022

Cody L Gilliland↗

Control of Propellant Lead/Lag to the LAE in the AXAF Propulsion System

Control of the rate at which hypergolic propellants are supplied to a rocket engine prior to ignition is critically important. Potentially damaging explosions may result from excessive lead of either propellant into the combustion chamber. Because the injector fill process is governed by the engine as well as the propellant feed system design, proper management of this issue must take both into consideration. This was recognized early in the development of TRW's Advanced Columbium-Liquid Apogee Engine (LAE), which was flight-qualified in 1996 to maneuver the Advanced X-Ray Astrophysics Facility (AXAF) spacecraft into orbit. The LAE runs on hydrazine and nitrogen tetroxide (MON-3) at a nominal mixture ratio of 1.0. This paper describes the comprehensive test program conducted to ensure reliable startup operation of the LAE in the AYAF propulsion system. The most significant factors affecting chamber fuel lead were found to be: (1) engine location, (2) propellant saturation level, (3) amount of undissolved gas in the lines, and (4) off- nominal tank pressures. Hot-fire tests at a chamber fuel lead range over and above that expected for the LAEs in AXAF demonstrated extremely tolerant behavior of the engine. AY-AF is scheduled for launch on NASA's STS-93 in December 1998.

Casillas, A. R.↗

Oxygen/Alcohol Dual Thrust RCS Engines

A non-toxic dual thrust RCS engine offers significant operational, safety, and performance advantages to the space shuttle and the next generation RLVs. In this concept, a single engine produces two thrust levels of 25 and 870 lbf. The low thrust level is provided by the spark torch igniter, which, with the addition of 2 extra valves, can also be made to function as a vernier. A dual thrust RCS engine allows 38 verniers to be packaged more efficiently on a vehicle. These 38 vemiers improve translation and reduce cross coupling, thereby providing more pure roll, pitch, and yaw maneuvers of the vehicle. Compared to the 6 vemiers currently on the shuttle, the 38 dual thrust engines would be 25 to 40% more efficient for the same maneuvers and attitude control. The vernier thrust level also reduces plume impingement and contamination concerns. Redundancy is also improved, thereby improving mission success reliability. Oxygen and ethanol are benign propellants which do not create explosive reaction products or contamination, as compared to hypergolic propellants. These characteristics make dual-thrust engines simpler to implement on a non-toxic reaction control system. Tests at WSTF in August 1999 demonstrated a dual-thrust concept that is successful with oxygen and ethanol. Over a variety of inlet pressures and mixture ratios at 22:1 area ratio, the engine produced between 230 and 297 sec Isp, and thrust levels from 8 lbf. to 50 lbf. This paper describes the benefits of dual-thrust engines and the recent results from tests at WSTF.

Angstadt, Tara↗

Liquid Oxygen/Liquid Methane Test Summary of the RS-18 Lunar Ascent Engine at Simulated Altitude Conditions at NASA White Sands Test Facility

Tests were conducted with the RS18 rocket engine using liquid oxygen (LO2) and liquid methane (LCH4) propellants under simulated altitude conditions at NASA Johnson Space Center White Sands Test Facility (WSTF). This project is part of NASA s Propulsion and Cryogenics Advanced Development (PCAD) project. "Green" propellants, such as LO2/LCH4, offer savings in both performance and safety over equivalently sized hypergolic propellant systems in spacecraft applications such as ascent engines or service module engines. Altitude simulation was achieved using the WSTF Large Altitude Simulation System, which provided altitude conditions equivalent up to approx.120,000 ft (approx.37 km). For specific impulse calculations, engine thrust and propellant mass flow rates were measured. Propellant flow rate was measured using a coriolis-style mass-flow meter and compared with a serial turbine-style flow meter. Results showed a significant performance measurement difference during ignition startup. LO2 flow ranged from 5.9-9.5 lbm/sec (2.7-4.3 kg/sec), and LCH4 flow varied from 3.0-4.4 lbm/sec (1.4-2.0 kg/sec) during the RS-18 hot-fire test series. Thrust was measured using three load cells in parallel. Ignition was demonstrated using a gaseous oxygen/methane spark torch igniter. Data was obtained at multiple chamber pressures, and calculations were performed for specific impulse, C* combustion efficiency, and thrust vector alignment. Test objectives for the RS-18 project are 1) conduct a shakedown of the test stand for LO2/methane lunar ascent engines, 2) obtain vacuum ignition data for the torch and pyrotechnic igniters, and 3) obtain nozzle kinetics data to anchor two-dimensional kinetics codes.

Melcher, John C., IV↗