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At least 55 records · Page 3

High-precision monitoring of outgassing species in model extreme ultraviolet photoresists with a cavity ring-down spectrometer

Background Extreme ultraviolet (EUV) photoresists play a pivotal role in advancing nanopatterning technologies by balancing image quality and sensitivity. The outgassing behavior of photoresist thin films under EUV and deep ultraviolet (DUV) exposure reveals chemical details relevant to their performance. Aim Here, we focus on utilizing an analytical technique not previously used in photolithography, the tabletop cavity ring-down spectrometer, to investigate outgassing dynamics in EUV photoresists, enabling precise chemical identification and deeper insights into resist processing. Approach The spectrometer’s enhanced laser path length (∼ 20 km) and broadband absorption capabilities in the C–H overtone region allow for sensitive and temporally resolved detection of mixtures of outgassed species. Using a model resist comprising a polymer matrix with a photoacid generator and quencher, we analyzed the influence of time delays between exposure and post-exposure bake (PEB) as well as storage under varying environmental conditions. Results Suppression of isobutylene outgassing and thickness loss was observed with extended delays between exposure and PEB, potentially linked to water absorption and acid deactivation. The technique proved highly effective in distinguishing subtle chemical differences between processing stages. Conclusions Delay times and their environmental conditions, particularly humidity, reduce outgassing and thickness loss of photoresists during PEB, suggesting decreased acid-driven deprotection. This can potentially impact sensitivity, defectivity, and roughness of resist patterns, necessitating precise monitoring and control.

Extreme ultraviolet photoresists

Comparison of Test and Finite Element Analysis for Two Full-Scale Helicopter Crash Tests

Finite element analyses have been performed for two full-scale crash tests of an MD-500 helicopter. The first crash test was conducted to evaluate the performance of a composite deployable energy absorber under combined flight loads. In the second crash test, the energy absorber was removed to establish the baseline loads. The use of an energy absorbing device reduced the impact acceleration levels by a factor of three. Accelerations and kinematic data collected from the crash tests were compared to analytical results. Details of the full-scale crash tests and development of the system-integrated finite element model are briefly described along with direct comparisons of acceleration magnitudes and durations for the first full-scale crash test. Because load levels were significantly different between tests, models developed for the purposes of predicting the overall system response with external energy absorbers were not adequate under more severe conditions seen in the second crash test. Relative error comparisons were inadequate to guide model calibration. A newly developed model calibration approach that includes uncertainty estimation, parameter sensitivity, impact shape orthogonality, and numerical optimization was used for the second full-scale crash test. The calibrated parameter set reduced 2-norm prediction error by 51% but did not improve impact shape orthogonality.

Annett, Martin S.

HNS/Teflon, a new heat resistant explosive

HNS/Teflon (90/10) is a new pressed explosive developed for use in the Apollo program. The major advantages of HNS/Teflon are (1) excellent thermal stability at elevated temperatures, (2) superior resistance to sublimation at high temperatures and low pressures and (3) ease of molding powder preparation, pressing and machining. The impact sensitivity of HNS/Teflon is between that of Comp B and Comp A-3 while its explosive performance is about the same as TNT. Under the severe environmental conditions of the moon's surface, this explosive successfully performed its intended function of generating seismic waves in the Apollo ALSEP and LSPE experiments. (Modified author abstract)

Heller, H.

High-Pressure Oxygen Test Evaluations

The relevance of impact sensitivity testing to the development of the space shuttle main engine is discussed in the light of the special requirements for the engine. The background and history of the evolution of liquid and gaseous oxygen testing techniques and philosophy is discussed also. The parameters critical to reliable testing are treated in considerable detail, and test apparatus and procedures are described and discussed. Materials threshold sensitivity determination procedures are considered and a decision logic diagram for sensitivity threshold determination was plotted. Finally, high-pressure materials sensitivity test data are given for selected metallic and nonmetallic materials.

Schwinghamer, R. J.

Introduction to session on materials and structures

A review was given of the development of composites for aircraft. Supporting base technology and the Aircraft Energy Efficiency Composites Program are included. Specific topics discussed include: (1) environmental effects on materials; (2) material quality and chemical characterization; (3) design and analysis methods; (4) structural durability; (5) impact sensitivity; (6) carbon fiber electrical effects; and (7) composite components.

Vosteen, L. F.

NCAR Johns Hopkins/CDC Climate and Health Summer Institute

The interactions between climate and health are rife with complexity and present many conceptual and methodological challenges. Possible effects of climate change on health are considered some of the most sensitive impacts of climate change and are a high priority for policy-makers and the public. As a first step toward improving tlit: quality of research, we developed a Climate and Health Workshop (Institute), geared toward teaching students various aspects of how to conduct integrated climate and health research. At the workshop scientists presented selected case studies of climate and health (e.g., heat mortality, vector-borne diseases), thus demonstrating a subset of key analytical tools and databases most useful to researchers in this field. Key research gaps in this research area were discussed. In this six-day Institute (21-28 July 2004, Boulder, Colorado), health scientists and students benefited from lectures and hands-on tools taught by top NCAR scientists. The attendees learned about health databases and epidemiologic methods from leading health scientists from CDC, Johns Hopkins, and other institutions from around the globe.

Mearns, Linda O.

Toughened Thermal Blanket for MMOD Protection

Thermal blankets are used extensively on spacecraft to provide passive thermal control of spacecraft hardware from thermal extremes encountered in space. Toughened thermal blankets have been developed that greatly improve protection from hypervelocity micrometeoroid and orbital debris (MMOD) impacts. These blankets can be outfitted if so desired with a reliable means to determine the location, depth and extent of MMOD impact damage by incorporating an impact sensitive piezoelectric film. Improved MMOD protection of thermal blankets was obtained by adding selective materials at various locations within the thermal blanket. As given in Figure 1, three types of materials were added to the thermal blanket to enhance its MMOD performance: (1) disrupter layers, near the outside of the blanket to improve breakup of the projectile, (2) standoff layers, in the middle of the blanket to provide an area or gap that the broken-up projectile can expand, and (3) stopper layers, near the back of the blanket where the projectile debris is captured and stopped. The best suited materials for these different layers vary. Density and thickness is important for the disrupter layer (higher densities generally result in better projectile breakup), whereas a highstrength to weight ratio is useful for the stopper layer, to improve the slowing and capture of debris particles.

Christiansen, Eric L.

Trajectories leaving a sphere in the restricted 3-body problem

The set of trajectories leaving/impacting the surface of the Galilean satellites of Jupiter is analyzed from theoretical and computational veiwpoints in the ciruclular restricted three body problem in order to characterize the sensitive impact regions for spacecraft trajectory applications as well as the main dynmical structures influencing this set of trajecotries.

Lo, Martin

A Novel Additive Manufacturing Process Metric for Predicting Spatter-related Porosity in Laser Powder Bed Fusion

Components fabricated using the powder bed fusion laser beam metallic (PBF) additive manufacturing (AM) process comprise a multitude of sequential weld passes. Porosity defects resulting from weld pass inconsistencies are a concern for PBF materials and have a strong adverse effect on the mechanical properties. In an effort to understand and avoid spatter induced porosity, this work aims to provide a novel computational technique that can be used to quantify and predict the sequence-sensitive impact of spatter upon the PBF process stability and consequential porosity in as-printed material. A novel spatter impact AM model-based process metric (AM-PM) is introduced to model and quantify the impact that spatter has on the PBF process. The occurrence of spatter induced porosity is studied using thermal rise, lack of fusion, and spatter impact AM-PMs synchronized with porosity measured by high-resolution X-ray computed tomography. Six cylindrical specimens were designed to compare the AM-PM correlations with porosity across two different laser powers and three hatch scanning strategies. A point field based computational approach is shown to be effective for testing the influence of the different AM-PMs and interrogating the physical process conditions underlying the porosity formation. Further, characterization using optical metallography and scanning electron microscopy indicated that both keyhole and lack of fusion porosity correlated with the spatter impact AM-PM, which can be exploited to predict and control spatter related porosity by the hatch strategy. Efforts to predict porosity composition within PBF material should incorporate the PBF process disturbances that can result from spatter. The spatter impact AM-PM can be readily incorporated into the development of defect prediction models at the part scale.

Additive Manufacturing

Assessment of VIIRS on-orbit polarization sensitivity and its impact on CLARREO pathfinder inter-calibration

The primary objective of the CLARREO Pathfinder (CPF) mission is to demonstrate essential measurement technologies to enable highly accurate decadal change observations traceable on-orbit to SI standards. Another important objective of the CPF is to demonstrate inter-calibration with the VIIRS sensor and to show that such high-accuracy reference inter-calibration is achievable. To satisfy this requirement, it is important to understand and quantify uncertainties in VIIRS sensor measurements. Based on prelaunch test results, the reflective solar bands of both SNPP and NOAA-20 VIIRS have exhibited polarization sensitivities in the shortest wavelength bands, with an unexpectedly larger sensitivity observed for NOAA-20 VIIRS, particularly in bands M1 to M4. In this study, we use VIIRS Level-1B reflectance data collected over the Pseudo-Invariant Calibration Sites over North African desert region to examine the polarization associated uncertainty for these four bands. Impact due to BRDF on the reflectance data is considered by comparing baseline results obtained from the same viewing and solar zenith angles under relatively low polarization sensitivity. Impact due to detector relative difference in polarization sensitivity is examined by normalizing reflectances by the value of the middle detector. Results of this study provide useful information on VIIRS uncertainty contribution due to polarization when conducting CPF and VIIRS inter-calibration.

VIIRS

Airburst & Blast Damage Modeling Sensitivities for Asteroid Impact Risk Assessment

Blast overpressure from a high-energy airburst or surface impact is the primary source of damage from potentially hazardous asteroid strikes. There are many sources of uncertainty in evaluating these potential damage risks, both in the approaches used to model the entry, breakup, and airburst behaviors of diverse asteroid properties, and in the blast modeling approaches used to estimate the ground damage from these very large-scale, high-energy events. In this study, we use NASA’s Probabilistic Asteroid Impact Risk (PAIR) model to investigate trends and sensitivities in asteroid airburst altitudes and the resulting blast damage estimates across a range of asteroid sizes. In particular, we show how uncertainties in asteroid breakup behavior and effective airburst altitudes combine with height-of-burst (HOB) blast damage models to produce key sensitivities and trends in the amount of damage expected from different asteroid sizes and airburst altitudes. We show airburst altitude ranges and probabilities stemming from asteroid entry and breakup modeling uncertainties, compare differences between traditional nuclear-based HOB blast models and simulation-based HOB models for larger asteroid energies, and show how the resulting interplay between likely burst altitudes and optimal burst heights affects blast damage trends across different asteroid sizes. Finally, we combine the relative likelihoods of asteroid sizes, airburst altitudes, and resulting blast damage severity to evaluate what airburst regimes pose the highest overall level of risk (when considering both the relative likelihood and scale of potential damage) for a mid-sized asteroid threat scenario. Results show what asteroid size regimes are most sensitive to airburst and blast modeling uncertainties, provide insight into nonintuitive trends in the size and severity of blast damage expected from different airburst events, and highlight where additional blast modeling studies or refinements may help improve future impact risk estimates

ATAP

Sensitivities of particle impact noise detection

The results of a study on Particle Impact Noise Detection commonly referred to as PIND testing is described. Certain sensitivities of PIND testing as applicable to hybrid microcircuits were determined, and techniques for removing particles from sealed hybrid packages were evaluated. Methods for freeing particles which have become trapped or hung up inside the hybrid package and, therefore, give no PIND test response were examined.

Keister, F. Z.

Sensitivity Analysis of the Human Research Program’s Impact 1.0 Model

Sensitivity analysis estimates the relative contribution of the uncertainty in input values to the uncertainty of model outputs. Partial Rank Correlation Coefficient (PRCC) and Leave One Out (LOO) are methods of conducting sensitivity analysis on non-linear simulation models like the IMPACT Model. The PRCC method estimates the sensitivity using partial correlation of the ranks of the generated input values to each generated output value. The “partial” part is due to the adjustments made for the linear effects of all the other input values in the calculation of correlation between a particular input and each output. LOO removes a medical condition from test suite and calculates the change in the outcome. This is used to identify the influence of the condition input in the model The inputs to the sensitivity procedures include the number of occurrences of each of the one hundred plus IMPACT medical conditions generated over the simulations, and the IMPACT outputs from the MEDPRAT mathematical model. The outputs total task time lost (TTL), number of return to definitive care (RTDC), and number of loss of crew lives (LOCL). The IMPACT team will report the results of using PRCC and LOO on IMPACT 1.0. Tornado plots will assist in the visualization of the condition-related input sensitivities to each of the main outcomes. The outcomes of this sensitivity analysis will drive review focus by identifying conditions where changes in uncertainty, and input values could drive changes in overall model output uncertainty. These efforts are an integral part of the overall verification, validation, and credibility review of IMPACT 1.0.

Sensitivity Anaylsis

Impacts of an Early Morning Low Earth Orbit Observing Platform in A Future Global Observing Network Scenario

Significant changes to the global observing network are expected in the coming decades including the launch of a global ring of geostationary satellites and a reduction in the number of low earth orbit (LEO) platforms. It is anticipated that there may be a gap in the LEO coverage between the planned mid-morning and early afternoon orbits. Here, the utility of an early morning LEO orbit for numerical weather prediction is considered using an observing system simulation experiment (OSSE). A global observing network with two LEO platforms including microwave and hyperspectral infrared instruments and three geostationary hyperspectral infrared platforms is considered for a future baseline scenario. Two instruments, a microwave radiometer modeled on the Advanced Technology Microwave Sounder (ATMS) and a hyperspectral infrared radiometer modeled on the Cross-track Infrared Sounder (CrIS), are tested both individually and in conjunction on a new early morning orbit in addition to the future baseline scenario. The microwave instrument is found to have beneficial impacts for up to 4–7 days in the medium range forecast period with beneficial impacts for the infrared instrument for up to 3–5 days. Short-range forecast impacts estimated with Forecast Sensitivity Observation Impacts (FSOI) over the conterminous United States for the early morning orbit are somewhat weaker than for the same instruments in the early afternoon orbit due to the orbital passage being coincident with rawinsondes while the afternoon orbit is coincident with the minima of both rawinsondes and aircraft.

Nikki C Prive

Surveys for sensitivity to fibers and potential impacts from fiber induced failures

The surveys for sensitivities to fibers and potential impacts from fiber induced failures begins with a review of the survey work completed to date and then describes an impact study involving four industrial installations located in Virginia. The observations and results from both the surveys and the study provide guidelines for future efforts. The survey work was done with three broad objectives: (1) identify the pieces of potentially vulnerable equipment as candidates for test; (2) support the transfer function work by gaining an understanding of how fibers could get into a building; and (3) support the economic analysis by understanding what would happen if fibers precipitated a failure in an item of equipment.

Butterfield, A. J.

Characterization of NBCMA—A DAPO Precursor

As part of our investigation into the process optimization of 2,6-diaminopyrazine-1-oxide (DAPO), small-scale sensitivity testing (impact, friction, and ESD) was conducted on the precursor, N-nitroso-bis(cyanomethyl)amine (NBCMA). NBCMA exhibited moderate sensitivity to friction, whereas no sensitivity to impact or spark was observed.

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