Search NASA⌕ Search

SEARCH · Search NASA

Results for “INFRARED SPECTRUM”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

The infrared spectrum and angular size of Eta Carinae.

The angular size of the infrared source associated with the peculiar optical object Eta Carinae was measured at wavelengths from 2.2 to 18 microns. The angular diameter, which is 2 arc sec at 2.2 microns, is found to increase with increasing wavelength to 6 arc sec at 10 to 18 microns. The solid materials responsible for the thermal radiation have a temperature of roughly 425 K in the inner shell, and 250 K in the outer region. The observed bolometric magnitude of -11.5 is mostly produced by the cool shell, which in turn must be powered by absorption of shortwave radiation emitted by a central object of corresponding bolometric magnitude.

Gehrz, R. D.↗
NASA NTRS2008

The Mid-infrared Spectrum of the Transiting Exoplanet HD 209458b

We report the spectroscopic detection of mid-infrared emission from the transiting exoplanet HD 209458b. Using archive data taken with the Spitzer IRS instrument, we have determined the spectrum of HD 209458b between 7.46 and 15.25 micrometers. We have used two independent methods to determine the planet spectrum, one differential in wavelength and one absolute, and find the results are in good agreement. Over much of this spectral range, the planet spectrum is consistent with featureless thermal emission. Between 7.5 and 8.5 m, we find evidence for an unidentified spectral feature. If this spectral modulation is due to absorption, it implies that the dayside vertical temperature profile of the planetary atmosphere is not entirely isothermal. Using the IRS data, we have determined the broadband eclipse depth to be 0:00315 +/- 0:000315, implying significant redistribution of heat from the dayside to the nightside. This work required the development of improved methods for Spitzer IRS data calibration that increase the achievable absolute calibration precision and dynamic range for observations of bright point sources.

data analysis↗
NASA NTRS1982

The far-infrared spectrum of the OH radical

It is thought likely that the study of spectral lines in the far-infrared might provide at least as much information about the physics and chemistry of the interstellar environment as radioastronomy. However, by comparison with the microwave region, the far-infrared is largely unexplored. There is a pressing need for good laboratory data to aid searches and assignments of spectra from the interstellar clouds and nebulae. Brown et al. (1981) have conducted a study of the laser magnetic resonance (LMR) spectrum of the OH radical in its ground state at far-infrared wavelengths. The present investigation is concerned with the computation of the frequencies of individual hyperfine transitions involving all rotational levels up to J = 4 1/2. The results of the calculation are presented in a table. The results are summarized in a diagram which shows the low-lying energy levels of OH. The frequencies of transitions between levels studied directly in the LMR spectrum are quite reliable.

Brown, J. M.↗
NASA NTRS2003

The Infrared Spectrum of Matrix Isolated Aminoacetonitrile: A Precursor to the Amino Acid Glycine

We present infrared (IR) spectral data from matrix isolation experiments and density functional theory calculations on the pre-biologically interesting molecule aminoacetonitrile, a precursor to glycine. We find that this nitrile has an unusually weak nitrile (C=N) stretch in the infrared, in contrast to expectations based on measurements and models of other nitriles under astrophysical conditions. The absence of an observable nitrile absorption feature in the infrared will make the IR search for this molecule considerably more difficult, and will raise estimates of upper limits on nitriles in interstellar and outer Solar System ices. This is also of relevance to assessing the formation routes of the amino acid glycine, since aminoacetonitrile is the putative precursor to glycine via the Strecker synthesis, the mechanism postulated to have produced the amino acids in meteorites.

Bernstein, Max P.↗
NASA NTRS1992

The synthetic infrared spectrum of Titan at high spectral resolution

A systematic study made of the observability of minor species in Titan's atmosphere is reported. This was done by modeling its thermal spectrum at 0.5/cm resolution under the conditions of the Infrared Space Observatory (ISO) and Composite Infrared Radiometer Spectrometer (CIRS), and by exploring the capabilities of the 0.03/cm resolution mode of ISO.

Coustenis, Athena↗
NASA NTRS1986

The infrared spectrum of M8 E - Evidence for circumstellar CO

High-resolution spectroscopic observations of the compact infrared source M8 E are reported in the region from 3 to 5 microns. Very prominent CO absorption lines are observed in the v = 1-0 band at 4.7 microns. The velocity width and rotational temperature suggest that this CO absorption occurs in a highly excited region. The high background continuum flux level and the prominent appearance of the CO features suggest that the CO line-forming region must be in front of the dust emission region. A blister model for M8 E, which places most of the dust continuum emission behind the source, satisfies this requirement. According to this picture, the observed circumstellar CO spectrum shows a high rotational temperature and a large velocity dispersion because of the combined effects of the strong stellar wind and possible shock heating near the dust zone as the wind encounters the ambient molecular cloud.

Larson, H. P.↗
NASA NTRS1991

The mid-infrared spectrum of the carbon star HD 38218 and its possible relation to polycyclic aromatic hydrocarbons

The mid-infrared spectra of carbon giant stars with hot companions are investigated in order to search for infrared emission bands from polycyclic aromatic hydrocarbons (PAH) in the envelopes of the C giants. A strong 8-micron emission band found in TU Tau = HD 38218 is attributed to the binary A star companion. It is argued that if the 8-micron feature in HD 38218 arises from PAHs, they seem to be important constituents of the C-giant shell, and they might be large compared with some interstellar PAHs. It is suggested that because no other IR spectra of C giants show clear PAH features, the greater flux of hard radiation in the binary HD 38218 seems likely to be responsible for the 8-micron feature and for its absence in many other C giants. Thus, PAHs could be present in the same amounts relative to SiC grains in the shells of similar single C giants, and the formation of carbonaceous grains could proceed through the formation of PAHs in C giant shells.

Buss, Richard H., Jr.↗
NASA NTRS1993

Modeling Titan's thermal infrared spectrum for high-resolution space observations

The observability of minor species in Titan's atmosphere in its infrared thermal range is systematically studied and modeled to generate synthetic spectra. The model results on methane, water vapor, benzene, allene, and other heavier trace molecules are used to illustrate the capabilities of instruments aboard the Infrared Space Observatory, in particular a high-resolution composite infrared spectrometer, to determine vertical distributions of the molecules in a few hours of integration time.

Coustenis, A.↗
DOE OSTI2020

The Near-infrared Spectrum of the Nuclear Star Cluster: Looking below the Tip of the Iceberg, and Comparisons with Extragalactic Nuclei

Long-slit near-infrared (NIR) spectra of the Galactic nuclear star cluster (NSC) are discussed. The spectra sample the major axis of the NSC out to its half-light radius. The absorption spectrum of the central regions of the NSC is averaged over angular scales of tens of arc seconds in order to sample globular cluster-like total luminosities, and the results are compared with model spectra. The equivalent widths of Na i2.21 μm and Ca 2.26 μm outside of the center of the NSC, where light from nuclear bulge stars contributes a large fraction to the total flux, are consistent with solar chemical mixtures. In contrast, the equivalent widths of Na i2.21 μm and Ca i2.26 μm near the center of the NSC are larger than expected from models with solar chemical mixtures, even after light from the brightest evolved stars is removed. The depths of spectroscopic features changing along the major axis of the NSC are consistent with imaging studies that have found evidence of population gradients in the NSC. That Na i2.21 μm and Ca i2.26 μm are deeper than predicted for solar chemical mixtures over a range of evolutionary states is consistent with previous studies that find that the majority of stars near the center of the NSC formed from material that had nonsolar chemical mixtures. The depths of the Na i2.21 μm and Ca i2.26 μm features in the central regions of the NSC are comparable to those in the nuclear spectrum of the early-type Virgo disk galaxy NGC 4491, and are deeper than in the central spectra of NGC 253 and 7793. A spectrum of nebular emission and the youngest stars near the galactic center is also extracted. The equivalent widths of emission features in the extracted NIR spectrum are similar to those in the nuclear spectrum of NGC 253, and it is argued that this agreement is best achieved if the current episode of star formation near the center of the NSC has been in progress for at least a few megayears.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1987

Experimental and theoretical investigation of the far-infrared spectrum of H2-He mixtures

New measurements of the rototranslational collision-induced absorption spectra in the far-infrared (FIR) frequency region of gaseous mixtures of hydrogen and helium are reported. The frequency range extends up to 1500/cm at the temperature of 195 K, and 1700/cm at 296 K. The uncertainties of the measurement are assessed. Comparison with previous measurements shows substantial agreement at frequencies where the measurements overlap. For comparison with the measurement, spectra are computed from the fundamental theory using a state of the art ab initio dipole function and an isotropic potential surface as input. The observed agreement suggests that, for important applications, such as the analysis of the FIR spectra of the outer planets, the spectra can be obtained reliably as a function of frequency and temperature from quantum calculations of the kind presented here.

Birnbaum, George↗
NASA NTRS1989

Infrared spectrum of the complex of formaldehyde with carbon dioxide in argon and nitrogen matrices

The complex of formaldehyde with carbon dioxide has been studied by infrared spectroscopy in argon and nitrogen matrices. The shifts relative to the free species show that the complex is weak and similar in argon and nitrogen. The results give evidence for T-shaped complexes, which are isolated in several configurations. Some evidence is also presented which indicates that, in addition to the two well-known sites in argon, carbon dioxide can be trapped in a third site.

Van Der Zwet, G. P.↗
NASA NTRS1975

Jupiter: Its infrared spectrum from 10 to 40 microns

Spectral measurements of the thermal radiation from Jupiter in the 16-40 micrometer band were analyzed under the assumption that pressure broadened H2 transitions are responsible for the bulk of the infrared opacity over most of this spectral interval. Both the vertical pressure-temperature profile and the hydrogen mixing ratio were determined. The derived value of the molecular hydrogen mixing ratio, 0.89 + or - 0.11, is consistent with the solar value, 0.86.

Houck, J. R.↗
NASA NTRS1975

Jupiter - Its infrared spectrum from 16 to 40 micrometers

Spectral measurements of the thermal radiation from Jupiter in the band from 16 to 40 micrometers are analyzed under the assumption that pressure-broadened molecular hydrogen transitions are responsible for the bulk of the infrared opacity over most of this spectral interval. Both the vertical pressure-temperature profile and the molecular hydrogen mixing ratio are determined. The derived value of the molecular hydrogen mixing ratio, 0.89 plus or minus 0.11, is consistent with the solar value of 0.86.

Houck, J. R.↗
DOE OSTI2021

Towards complete assignment of the infrared spectrum of the protonated water cluster H + (H 2 O) 21

The spectroscopic features of protonated water species in dilute acid solutions have been long sought after for understanding the microscopic behavior of the proton in water with gas-phase water clusters H + (H 2 O) n extensively studied as bottom-up model systems. We present a new protocol for the calculation of the infrared (IR) spectra of complex systems, which combines the fragment-based Coupled Cluster method and anharmonic vibrational quasi-degenerate perturbation theory, and demonstrate its accuracy towards the complete and accurate assignment of the IR spectrum of the H + (H 2 O) 21 cluster. The site-specific IR spectral signatures reveal two distinct structures for the internal and surface four-coordinated water molecules, which are ice-like and liquid-like, respectively. The effect of inter-molecular interaction between water molecules is addressed, and the vibrational resonance is found between the O-H stretching fundamental and the bending overtone of the nearest neighboring water molecule. The revelation of the spectral signature of the excess proton offers deeper insight into the nature of charge accommodation in the extended hydrogen-bonding network underpinning this aqueous cluster.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1995

The 5-8 Micron Infrared Spectrum of the Galactic Center and the Composition of Interstellar Dust

Interstellar dust is an important component of the interstellar medium which dominates the opacity and, hence, regulates radiative transfer, molecule formation, and thermal balance of the ISM. Much of our knowledge on the composition of interstellar dust results from infrared spect,oscopy. The extinction along the line of sight towards the galactic center is believed to be dominated by dust in the diffuse ISM. Because of the high extinction and high IR flux, IR spectra of galactic center sources have been a prime sampling ground for the characteristics of interstellar dust. We have obtained 5-8 micrometer spectra of the galactic center using the KAO. These spectra show absorption features at 5.5, 5.8, 6.1, and 6.8 micrometers. Together with features in the 3 micrometer region previously observed by us using the IRTF, these features are compared to laboratory spectra of candidate materials. We conclude that the 3.0 and 6.1 micrometer feature are carried by H2O, likely in the form of water of hydration in interstellar silicates. The 3.4, 5.5, 5.8, and 6.8 micrometer features are due to CH2, CH3 and C=O stretching and deformation modes in a hydrocarbon grain component. Comparing derived dust abundances, we conclude that silicates dominate the interstellar dust volume. Hydrocarbon and (small) graphite grains contribute each about 0.1. The remainder of the interstellar dust volume does not show strong IR absorption features and is likely in the form of large graphite, amorphous, carbon, or diamond grains.

Tielens, A. G. G. M.↗
NASA NTRS1981

The infrared spectrum of Rhea

The reflectance spectrum of the leading side of the Saturnian satellite Rhea in the 0.65 to 2.5 micron range is reported and used to quantify the amount of water and other materials present on the surface. Data were obtained with 1.5% spectral resolution and 3 to 5% precision by the 3.0-m Infrared Telescope Facility at Mauna Kea Observatory with a continuously scanning circular variable filter spectrometer. Water ice absorptions previously identified at 2.02, 1.65 and 1.55 microns are confirmed, and additional absorptions at 1.25 and probably 1.04 microns are identified. The spectrum of Rhea is noted to be very similar to that of the leading side of Ganymede in the 0.6 to 2.5 micron region and to laboratory spectra of water frost on ice blocks rather than an optically thick frost. Results indicate that the leading side of Rhea is at least 90 wt % water ice, and may be as much as 98 wt %. Of the remaining material, neither clathrates nor minerals is excluded.

Clark, R. N.↗
NASA NTRS2012

Climate Change Detection and Attribution of Infrared Spectrum Measurements

Climate change occurs when the Earth's energy budget changes due to natural or possibly anthropogenic forcings. These forcings cause the climate system to adjust resulting in a new climate state that is warmer or cooler than the original. The key question is how to detect and attribute climate change. The inference of infrared spectral signatures of climate change has been discussed in the literature for nearly 30 years. Pioneering work in the 1980s noted that distinct spectral signatures would be evident in changes in the infrared radiance emitted by the Earth and its atmosphere, and that these could be observed from orbiting satellites. Since then, a number of other studies have advanced the concepts of spectral signatures of climate change. Today the concept of using spectral signatures to identify and attribute atmospheric composition change is firmly accepted and is the foundation of the Climate Absolute Radiance and Refractivity Observatory (CLARREO) satellite mission being developed at NASA. In this work, we will present an overview of the current climate change detection concept using climate model calculations as surrogates for climate change. Any future research work improving the methodology to achieve this concept will be valuable to our society.

Phojanamongkolkij, Nipa↗