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At least 55 records · Page 3

Features of ion trajectories in the polar magnetosphere

In the present polar magnetosphere model, which includes the effects of convection electric fields and gravitation, the trajectories of mainly low energy ionospheric ions injected near the polar cusp into the polar magnetosphere display the ion mass and energy differentiation seen in recent satellite observations of low energy ionospheric ions. Two interesting trajectory classes are noted for low energy heavy ions: parabolic trajectories, in which ions injected into the polar cusp at small pitch angles rise, and then fall, into the polar cap atmosphere, and 'hopping' trajectories, in which heavy ions injected at large pitch angles at the polar cusp will mirror as they convect at low to medium altitudes across the polar cap.

Horwitz, J. L.↗

Observations of the artificially injected Porcupine xenon ion beam in the ionosphere

Results are given of ion beam injection experiments performed in the auroral ionosphere in connection with the German Sounding Rocket Project Porcupine. A heavy (xenon) ion beam was injected into the collisionless ionospheric plasma approximately perpendicular to the ambient magnetic field at altitudes from 190 km to about 450 km. The beam propagates nearly undistorted across the plasma because it is essentially depolarized; at the same time the beam is not current neutralized. This unexpected behavior poses the interconnected problems of how the beam manages to become charge neutralized, how current closure is maintained, and what is the mechanism of depolarization.

Haeusler, B.↗

Low-energy ion acceleration at quasi-perpendicular shocks: Transverse diffusion

The problem of ion injection and acceleration at quasi perpendicular shocks has been the subject of some debate over the past two decades. It is widely known that these shocks efficiently accelerate particles that are well in the high-energy tail of the distribution. However, the issue of injection, or the acceleration of low-energy ions, has yet to reach a consensus. The fundamental issue is whether there is enough diffusion normal to the magnetic field for the particles to remain near the shock. Since transverse diffusion is a physical process that is not well understood in space plasmas, this is an important, and difficult issue to address. In this report, we will investigate the ion injection problem by performing test particle orbit integrations using synthesized turbulent fields. These fields are fully three-dimensional so that transverse diffusion is possible (cross-field diffusion is not possible in geometries where the electromagnetic fields are less than three dimensional). The synthesized fields are produced by superimposing a three-dimensional wave field on a background field. For completeness, we will compare the results from this model with the more well-established theories, such as the diffusive approximation and scatter-free shock drift acceleration. We will also compare these results with other numerical simulation techniques such as the well known hybrid simulation, and other test-particle calculations in which the shock fields are specified to have less than three dimensions. We will also discuss some recent relevant observations and how these compare with our results.

Giacalone, J.↗

A Dual-Gated Structures for Lossless Ion Manipulations-Ion Mobility Orbitrap Mass Spectrometry Platform for Combined Ultra-High-Resolution Molecular Analysis

High-resolution ion mobility spectrometry-mass spectrometry (HR-IMS-MS) instruments have enormously advanced the ability to characterize complex biological mixtures. Unfortunately, HR-IMS and HR-MS measurements are typically performed independently due to mismatches in analysis time scales. Here we overcome this limitation by using a dual-gated ion injection approach to couple an 11-meter path length structures for lossless ion manipulations (SLIM) module to a Q-Exactive Plus Orbitrap MS. The dual-gate setup was implemented by placing one ion gate before the SLIM module and a second ion gate after. The dual-gated ion injection approach allowed the new SLIM-Orbitrap platform to simultaneously perform an 11-meter SLIM separation, Orbitrap mass analysis using the highest selectable mass resolution setting (up to 140k), and high-energy collision induced dissociation (HCD) in ~25 minutes over an $m/z$ range of ~1500 amu. The SLIM-Orbitrap was initially characterized using a mixture of standard phosphazene cations and demonstrated an average SLIM CCS resolving power (Rp CCS ) of ~218 and SLIM peak capacity of ~156 while simultaneously obtaining high mass resolutions. SLIM-Orbitrap analysis with fragmentation was then performed on mixtures of standard peptides and two reverse peptides (SDGRG 1+ , GRGDS 1+ , Rp CCS = 305) to demonstrate the utility of combined HR-IMS-MS/MS measurements for peptide identification. Our new HR-IMS-MS/MS capability was further demonstrated by analyzing a complex lipid mixture and showcasing SLIM separations on isobaric lipids. In conclusion, this new SLIM-Orbitrap platform demonstrates a critical new capability for proteomics and lipidomics applications, and the high-resolution multimodal data obtainable with this system establishes the foundation for reference-free identification of unknown ion structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Low-altitude signatures of the cusp and flux transfer events

Cusp-like ion injection was studied using DE-2 satellite data obtained during strongly southward IMF. Although magnetosheath ion injection signatures are detected, the satellite motion and convection are opposed, and it is suggested that the observed falling energy dispersion of the precipitating ions may have arisen from a static moving or growing source. The spatial scale of the flux is found to be typical of that of a flux transfer event (FTE). A simple model of the ionospheric signature of an FTE is able to reproduce the observed electric and magnetic field perturbations. Precipitating electrons with peak energies of about 100 eV lie on the predicted boundary of the newly opened tube and are similar to those noted on the edges of FTEs at the magnetopause.

Lockwood, Mike↗

Observations of the plasma environment during an active ionospheric ion beam injection experiment

Several sounding rocket flights have been used to clarify the electrodynamics of neutral beam releases of Ar ions in the upper ionosphere, by varying the Ar's point of release with respect to the diagnostic payload. A volume of 10-m radius centered on the Ar release payload is measured for broadband wave activity; the superthermal neutralizing beam electrons become magnetized in this volume for across-field plasma releases, and ambient electrons are accelerated to energies of several hundred eV. This is speculated to be due to wave turbulence rather than payload-neutralization.

Arnoldy, R. L.↗

Charge states of substorm particle injections

The charge states of ions injected during substorms are discussed. Observations from the Medium Energy Particle Analyzer (McEntire et al., 1985) are used to time the arrival of peak proton, helium, and oxygen fluxes at the Charge Composition Explorer satellite. In addition, the dominant ion charge states of these species in the energy range 72-1000 keV are determined. It is found that the freshly-injected heluim (72-240 keV) and oxygen (137-365 keV) are singly ionized, but that more energetic oxygen (greater than 365 keV) is multiply charged. It is suggested that this result implies either a dominant ionospheric source at the lower energies with a solar-wind source at the higher energies, or an energization of the preexisting ring-current population.

Sibeck, D. G.↗

Theoretical Coupling of Free-Flowing Ions and Magnetically Insulated Electrons

Magnetic insulation of electrons prevents losses and can be applied to generating radiation or electron sources for high current and high power applications. Ion emission from the anode may degrade magnetic insulation. We develop equilibrium theory, self-consistently coupling magnetically insulated electron flow with free-flowing injected ions. Generally, ion injection is self-limiting from space charge; however, once insulation strength drops below about 1.2x the magnetic insulation threshold, ion space-charge limits vanish. Further, the gap effectively short-circuits and the electron flow layer asymptotically approaches the anode. In this regime a quasineutral, nonthermal plasma manifests, effectively reducing gap distance and suggesting quasiequilibrium gap closure evolution.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Semiconducting Small Molecules as Active Materials for p-Type Accumulation Mode Organic Electrochemical Transistors

A series of semiconducting small molecules with bithiophene or bis-3,4-ethylenedioxythiophene cores are designed and synthesized. The molecules display stable reversible oxidation in solution and can be reversibly oxidized in the solid state with aqueous electrolyte when functionalized with polar triethylene glycol side chains. Evidence of promising ion injection properties observed with cyclic voltammetry is complemented by strong electrochromism probed by spectroelectrochemistry. Blending these molecules with high molecular weight polyethylene oxide (PEO) is found to improve both ion injection and thin film stability. The molecules and their corresponding PEO blends are investigated as active layers in organic electrochemical transistors (OECTs). For the most promising molecule:polymer blend (P4E4:PEO), p-type accumulation mode OECTs with µA drain currents, μS peak transconductances, and a µC* figure-of-merit value of 0.81 F V -1 cm -1 s -1 are obtained.

36 MATERIALS SCIENCE↗

Thermal fluctuations from an artificial ion beam injection into the ionosphere

Simulations of argon beam experiments flown on two sounding rocket flights (ARCS 1, 2) reveal two bands of electrostatic wave emissions, one at high frequencies around the upper hybrid mode, the other at low frequencies around the lower hybrid mode. The latter is significantly enhanced by the argon beam in the simulations, and the enhancement was clearly observed on ARCS 2. This enhancement at phase velocities greater than the beam velocity is suggested to be due to an increase in the thermal fluctuation level of the plasma when the argon beam is present. Inclusion of electron dynamics and oblique angles of wave propagation with respect to B allows investigation of electron heating. Electron tail heating is observed parallel to B for k-parallel/k-perpendicular proportional to the square root of m(e)/m(0), while background ions are heated perpendicular to B.

Hudson, M. K.↗

IMF By-dependent plasma flow and Birkeland currents in the dayside magnetosphere. I - Dynamics Explorer observations

Plasma, magnetic-field, and dc electric-field observations from Dynamics Explorers 1 and 2 are used to investigate the morphology of solar-wind ion injection, Birkeland currents, and plasma convection in the morning sector for both positive and negative interplanetary magnetic field (IMF) By components. The results of the study are used to construct a By-dependent global convection model for southward IMF. A significant element of the model is the coexistence of three types of convection cells ('merging cells', 'viscous cells', and 'lobe cells'). This model can account for observations of a nearly stationary (in local time) convection 'throat', a sunward-antisunward convection reversal zone at the polar-cap boundary in both the morning and afternoon quadrants, the morphology of solar-wind ion injection and transport in the mid-altitude polar cusp, and the By-dependent dawn-dusk asymmetry of polar-cap electron fluxes.

Burch, J. L.↗

Picosecond laser generated plasma as a source of singly charged ions for external injection into an EBIS

The focus of this paper is on practical aspects of ion generation by picosecond lasers as a source of low charge state ions for external injection of ions into an electron beam ion source (EBIS). For a ps-laser, compared to a ns-laser currently used at Relativistic Heavy Ion Collier Electron Beam Ion Source (RHIC EBIS), the influence of heat conductivity in the solid target is almost negligible, which results in a lower target consumption rate and less vacuum pressure rise. By using a laser with high repetition rate, it is possible to produce quasi continuous 1+ ion beams for periods of tens of milliseconds, making it possible to take advantage of the ability of the EBIS to accumulate ions in the “slow” injection capture mode. Producing such an ion pulse train is now feasible since ps-lasers with pulse energy up to 10 mJ and rep-rate up to 10 kHz have recently become commercially available. The advantages of this lower current accumulation scheme include: (1) easier beam transport due to lower space charge of lower beam currents required compared to the present single pulse fast injection scheme, (2) better EBIS pulse to pulse ion output stability since pulse to pulse ion variations of the laser source are averaged over a long train of laser pulses, and (3) the possible addition of an isotope separator in which rare beams could be produced and selected at run time from less expensive (unenriched) targets. We studied the properties of plasmas generated by a ps-laser with 1.27 mJ energy within an 8 ps pulse and a repetition rate up to 400 Hz at Argonne National Laboratory to investigate feasibility and specify parameters for a laser ion source for RHIC EBIS using a “slow” injection mode. Al, Ti, Cu, Nb, and Ta targets were tested with various target translation speeds. Here, we demonstrated that a both “slow” and “fast” injection modes are accessible with a single ion source geometry and single injection line, providing the most attractive option for an ion source for external injection into RHIC EBIS trap based on a ps-laser.

43 PARTICLE ACCELERATORS↗

Magnetosheath-ionospheric plasma interactions in the cusp/cleft. 1: Observations of modulated injections and upwelling ion fluxes

In situ observations of the cusp/cleft are important as they allow a direct investigation of coupling solar wind energy to the ionosphere, plus they provide an opportunity for the remote sensing of the magnetopause. High time resolution observations from Dynamic Explorer 1 are used to investigate these processes. It is shown that in the spacecraft frame the injection is modulated or pulsating with a period of approximately 18-30 s with the injection duration possibly being as short as 6 s. This modulation indicates that there may be fast time scale and/or short scale length processes modulating the injection of the magnetosheath plasma across the magnetopause. In addition, the pulsating injection is seen to modulate the outflow of upwelling ionospheric ions to the magnetosphere. These upwelling ions are seen prior to the magnetosheath ion injection and therefore are not directly created by the injection. During the injection itself, the intensity of the upwelling ions is seen to dramatically decrease but their average energy increases. At end of the magnetosheath injections, the intensity of the upwelling ion flux is seen to increase to levels comparable to levels prior to the magnetosheath injection. On two occasions during the encounter, the particle fluxes are sufficiently high that enhanced downward flows of perpendicularly heated ions, of presumably ionospheric origin, are observed in association with a reduction in the intensity of the upwelling ions. These observations are probably the first detection of downward conics and suggest that there is momentum transfer between the magnetosheath and ionospheric ions. This momentum transfer eventually leads to an enhanced outflow of heated ionospheric plasma where their energy has been raised from a few tens of eV to a few hundred eV.

Winglee, R. M.↗

Stochastic acceleration of energetic ions in Jupiter's magnetosphere

An equation governing the combined radial diffusion and stochastic acceleration of super-Alfvenic ions by magnetohydrodynamic waves in Jupiter's outer magnetosphere is derived. The formulation is based upon a total energy invariant of the adiabatic transport which applies to an isotropic distribution undergoing rapid pitch angle scattering by waves. An analytic solution to the double diffusion equation is obtained and numerical results are presented for two models of ion injection. The first model assumes S(+) and O(+) are injected throughout a broad region of space through photoionization of Jupiter's magnetospheric neutral wind and obtain an initial energy corresponding to the local corotation energy after pickup by the planetary magnetic field. The second model assumes a monoenergetic distribution of energetic protons is implanted in the middle magnetosphere by the action of field-aligned potential drops in Jupiter's auroral ionosphere. For both light and heavy ions the injection process creates a seed population of particles which are further accelerated nonadiabatically by the MHD waves and adiabatically through radial diffusion. A comparison of the theoretical results with a recent data analysis of Voyager low-energy charged particle measurements is made with very good agreement, thus providing a rigorous quantitative account of and definitive explanation for the high-energy ion component of Jupiter's magnetosphere.

Barbosa, D. D.↗

Energetic ion beam magnetosphere injection and solar power satellite transport

The effects of ion beam injection in the magnetosphere are considered. The beam's parameters are those characteristic of the ion propulsion engines envisioned for use in solar power satellite placement (Hanley and Guttman, 1978). Specifically, from a detailed analysis of the beam's propagation through the magnetosphere it is shown that the bulk of the ion beam is not stopped in the magnetosphere. However, the relatively small fraction of the beam which is deposited via the beam's sheath loss may give rise to a large distortion in the magnetospheric plasma population. Possible loss mechanisms from the magnetosphere for this artificial energetic ion component are evaluated. Electron Coulomb scattering yields the shortest lifetime throughout most of the plasmasphere provided that plasmasphere heating by beam ions is not too intense. Charge exchange dominates beyond the plasmasphere. The effects of pitch angle scattering due to beam ion turbulence may appreciably shorten beam ion lifetimes throughout the magnetosphere

Curtis, S. A.↗

An Improved Boosting to Amplify Signal with Isobaric Labeling (iBASIL) Strategy for Precise Quantitative Single-cell Proteomics

Mass spectrometry (MS)-based proteomics has great potential for overcoming the limitations of antibody-based immunoassays for antibody-independent, comprehensive, and quantitative proteomic analysis of single cells. Indeed, recent advances in nanoscale sample preparation have enabled effective processing of single cells. In particular, the concept of using boosting/carrier channels in isobaric labeling to increase the sensitivity in MS detection has also been increasingly used for quantitative proteomic analysis of small-sized samples including single cells. However, the full potential of such boosting/carrier approaches has not been significantly explored, nor has the resulting quantitation quality been carefully evaluated. Herein, we have further evaluated and optimized our recent boosting to amplify signal with isobaric labeling (BASIL) approach, originally developed for quantifying phosphorylation in small number of cells, for highly effective analysis of proteins in single cells. This improved BASIL (iBASIL) approach enables reliable quantitative single-cell proteomics analysis with greater proteome coverage by carefully controlling the boosting-to-sample ratio (e.g. in general <100×) and optimizing MS automatic gain control (AGC) and ion injection time settings in MS/MS analysis (e.g. 5E5 and 300 ms, respectively, which is significantly higher than that used in typical bulk analysis). By coupling with a nanodroplet-based single cell preparation (nanoPOTS) platform, iBASIL enabled identification of ~2500 proteins and precise quantification of ~1500 proteins in the analysis of 104 FACS-isolated single cells, with the resulting protein profiles robustly clustering the cells from three different acute myeloid leukemia cell lines. This study highlights the importance of carefully evaluating and optimizing the boosting ratios and MS data acquisition conditions for achieving robust, comprehensive proteomic analysis of single cells.

59 BASIC BIOLOGICAL SCIENCES↗

Heavy ion beam probe measurements of radial potential profiles in the modified Penning discharge

A heavy ion beam probe was used to examine the radial potential profile of a plasma in the modified Penning discharge. The plasma has strong (approximately kV) electrostatic potentials near the anode ring which can be a large fraction of the injected ion beam energy. A primary (singly ionized) thallium ion beam is injected through the plasma in the midplane of a double Penning anode ring. After passage through the plasma, primary and secondary (doubly ionized) ions are detected with either a set of flat probes or an electrostatic energy analyzer. A calculation of the primary orbit through the plasma is performed to obtain an approximation to the measured primary beam trajectory. As the real radial potential profile is unknown, an adjustable model is used in the computer program. The adjustable potential profile is varied until the best agreement between measured and calculated trajectories is obtained. Secondary orbits are also predicted using the best fitting adjustable profile. The calculations indicate that secondary beams originating at more than one point in the plasma can be simultaneously observed at the electrostatic analyzer with certain primary beam initial conditions.

Kambic, G. X.↗