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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

An improved detailed chemical kinetic model for C3-C4 linear and iso-alcohols and their blends with gasoline at engine-relevant conditions

Propanol and butanol isomers have received significant research attention as promising fuel additives or neat biofuels. Robust chemical kinetic models are needed that can provide accurate and efficient predictions of combustion performance across a wide range of engine relevant conditions. Herein, this study seeks to improve the understanding of ignition and combustion behavior of pure C3-C4 linear and iso-alcohols, and their blends with gasoline at engine-relevant conditions. In this work, a kinetic model with improved thermochemistry and reaction kinetics was developed based on recent theoretical calculations of H-atom abstraction and peroxy radical reaction rates. Kinetic model validations are reported, and the current model reproduces the ignition delay times of the C3 and C4 alcohols well. Variations in reactivity over a wide range of temperatures and other operating conditions are also well predicted by the current model. Recent ignition delay time measurements from a rapid compression machine of neat iso-propanol and iso-butanol [Cheng et al., Proc. Combust Inst. (2020)] and blends with a research grade gasoline [Goldsborough et al., Proc. Combust Inst. (2020)] at elevated pressure (20–40 bar) and intermediate temperatures (780–950 K) were used to demonstrate the accuracy of the current kinetic model at conditions relevant to boosted spark-ignition engines. The effects of alcohol blending with gasoline on the autoignition behavior are discussed. The current model captures the suppression of reactivity in the low-temperature and negative-temperature-coefficient (NTC) region when either isopropanol and isobutanol are added to a research grade gasoline. Sensitivity and reaction flux analysis were performed to provide insights into the relevant fuel chemistry of the C3-C4 alcohols.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Distribution Market-Clearing and Pricing Considering Coordination of DSOs and ISO: An EPEC Approach

Distribution-level electricity market provides a platform for trading energy and grid services from large-amount of small-scale distributed energy resources (DERs) located on distribution grids. The behavior of the DERs in the distribution electricity market may ultimately impact the market-clearing and locational marginal prices (LMPs) in the wholesale market. This paper proposes a bi-level optimization model for distribution market clearing and distribution locational marginal pricing (DLMP) considering the interactions between distribution and transmission wholesale markets. In the proposed model, the upper-level model represents the distribution system operator (DSO) market-clearing and the lower-level model represents the wholesale market-clearing by the independent system operator (ISO). The LMP at the substation will impact the DER dispatch and power demands of the DSO as well as the DLMP. In turn, the power demands of the DSO will further impact the ISO market and its LMPs. The equilibrium problem with equilibrium constraints (EPEC) approach is applied to find the equilibria of multiple DSOs and the ISO. The EPEC problem is transformed into a single-level mixed-integer convex problem in order to allow for efficient solving. Finally, the effectiveness of the proposed model and solution method are demonstrated through case studies.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

PMK 1000 cone-socket ventilator fittings force testing to ISO 5356-1:2015 Standard

This memo summarizes the results of verification tests on a cone-socket fitting to the ISO 5356-1:2015 standard, annexes B and F. The components were found to meet requirements holding 50N tensile force and more than 35 N-cm of torque for 10 seconds without separating at 35°C with a fresh socket. Humidity control was unavailable; consequently, humidity was significantly lower than the values in the ISO standard. Several repeat tests of the fitting with force, torque, and time excursions give us confidence that the fittings perform suitably to the ISO standard. Force overload tests suggest that the samples will disengage under tension at around 69 N, while torque overload tests under a force of 50 N will fail at 79 N-cm of torque. If repeated tests are performed on the same component, the socket can deform and lead to the connection failing the standard requirements. However, such failures only occur with repeated testing, and the gripping of such units can be modified so that they pass the standard. This observation demonstrates that socket gripping is responsible for those failures and would not be a problem in application.

42 ENGINEERING↗

An Imaging Spectrometric Observatory (ISO)

The Imaging Spectrometric Observatory (ISO) is designed for low light level spectroscopy of both the day and night side of the earth. The instrument is composed of five spectrometers, each of which covers part of the total wavelength range of 30 to 1300 nm spanned by the instrument. Wavelength resolution varies between 0.2 and 0.6 nm over the spectral range. The five spectrometers are each optimized for a portion of the spectrum by the choice of mirror reflective coatings and detector photocathode materials. The full spectral range for each spectrometer is covered in a total of 11 grating steps. The Imaging Spectrometric Observatory was flown for the first time on the Spacelab 1 mission during which it acquired almost 40 hr of observations. The ISO investigation to be flown on the Atmospheric Laboratory for Applications and Science (ATLAS 1) mission will draw on the experience gained from the data gathered on Spacelab 1. The detector system in each spectrometer was upgraded to provide both higher sensitivity at low light levels and simultaneous imaging over larger spectral segments than was achieved on Spacelab 1. In addition, the instrument and the observing sequences were modified to allow observation of the sun in the extreme ultraviolet. A summary of ISO parameters for ATLAS 1 (scheduled for late 1990) is given.

Torr, M. R.↗

Introduction to the Infrared Space Observatory (ISO)

The Infrared Space Observatory (ISO) is an astronomical satellite, which will operate at infrared wavelengths (2.5 to 200 microns) for a period of at least 18 months. Imaging, spectroscopic, photometric and polarimetric observations will be obtained by four scientific instruments in the focal plane of its 60-cm diameter, cryogenically-cooled telescope. Two-thirds of ISO's observing time will be available to the astronomical community. ISO is a fully approved and funded project of the European Space Agency (ESA) with a foreseen launch date of May 1993.

Kessler, M. F.↗

IAL SPACE: A test laboratory for the ISO cryogenic payload

The ESA Infrared Space Observatory (ISO) satellite is a 3 axes pointed platform designed to make accurate pointed observations of astronomical objects and sources in the wavelength range between 2.5 and 200 microns. ISO is composed of a service module and a payload module which is a large cylindrical vacuum vessel. The vessel is in fact a cryostat (capacity of 2250 l of liquid He II) which contains the telescope and the four focal scientific instruments. The latter being cooled up to a temperature less than 4 K. The qualification of the payload requires the measurement respectively of: the image quality of the telescope through wave front error (WFE) measurements; and the optical alignment of the scientific instruments with respect to the telescope axis and the telescope focus, and this under cryogenic conditions. Consequently, since 1988, the FOCAL 5 IAL Space facility has been upgraded in order to perform the cryogenic optical tests of the ISO optical subsystems.

Cucchiaro, A.↗

Infrared Space Observatory (ISO) Key Project: the Birth and Death of Planets

This program was designed to continue to analyze observations of stars thought to be forming protoplanets, using the European Space Agency's Infrared Space Observatory, ISO, as one of NASA Key Projects with ISO. A particular class of Infrared Astronomy Satellite (IRAS) discovered stars, known after the prototype, Vega, are principal targets for these observations aimed at examining the evidence for processes involved in forming, or failing to form, planetary systems around other stars. In addition, this program continued to provide partial support for related science in the WIRE, SOFIA and Space Infrared Telescope Facility (SIRTF) projects, plus approved ISO supplementary time observations under programs MCREE1 29 and VEGADMAP. Their goals include time dependent changes in SWS spectra of Long Period Variable stars and PHOT P32 mapping experiments of recognized protoplanetary disk candidate stars.

Stencel, Robert E.↗

The ISO View of Star Forming Galaxies

ISO studies of normal galaxies in the local Universe have revealed basic new properties whose significant implications for the star formation process and cosmology are only starting to be understood. This review will touch on the general results of a statistical nature, and provide a quick summary of the profusion of exciting results on individual objects. In the mid-infrared, PHT-S has established that the spectra of star forming galaxies between 6 and-13microns are dominated by the Aromatic Features in Emission (AFE), and show little variation as a function of the heating intensity. The Carriers of the AFE (CAFE) are thus a universal component of dust with standard properties, and contribute between 10 and 25% of the total dust luminosity. In addition to AFE, the spectra show a low-level continuum detectable at wavelengths longer than 3.5microns whose origin is still under investigation. The mid-infrared colors formed as the ratio of flux densities in the 6.75micron and the 15micron bands of ISO-CAM remain essentially constant and near unity for quiescent and mildly active galaxies. As dust heating increases further, the 15micron flux increases steeply compared to 6.75microns, indicating that dust heated to 100K<T<200K becomes a significant component. Such hot dust is presumably located within or just outside HII regions. At the other end of the spectrum, photometry at 120-200microns using ISO-PHOT is starting to constrain the distribution of dust temperatures at the low end of the temperature scale. From LWS data, the far-infrared fine-structure lines of [CII] and [OI], which provide most of the cooling for warm atomic gas, show variations that have remained controversial in their interpretation. In particular, as the galaxy become more active in star formation, its [CII] flux weakens relative to total dust emission while the [OI] does not. This behavior has attracted much interest because it extrapolates to the most active galaxies, making them weaker in [CII] than previously expected. Several explanations for the effect have been advanced, and will be discussed in this review. Spectroscopy with SWS has measured molecular hydrogen in galaxies, providing a powerful handle on the warm molecular gas content. SWS and CAM-CVF studies targeting ionic fine-structure lines have demonstrated their value as diagnostics of the radiation field.

Helou, George↗

A Consolidated Block Grant Proposal to Carry Out the Analysis of Data from the ISO Satellite

This block grant covers the activities of three research groups at STScI: search for cold molecular hydrogen in the galaxy; dust characterization in circumstellar shells around evolved massive stars; and the relationship between dust absorption and emission in galaxies. We proposed to group the efforts and resources available to several approved ISO projects in order to more efficiently deal with the data reduction and analysis. We give a brief description of primary objectives and scope of each project, along with the final status of the project as of the expiration date of the grant. Owing to many delays on the part of the ISO Project, the calibrated data was received very late, which resulted in significant delays in deriving the results. In addition, for one of the components of this project, the ISO data was finally determined to be of too low a quality to be useful.

Allen, Ron↗

ISO Spectroscopy of Proto-Planetary Nebulae

The goal of this program was to determine the chemical properties of the dust shells around protoplanetary nebulae (PPNs) through a study of their short-wavelength (6-45 micron) infrared spectra. PPNs are evolved stars in transition from the asymptotic giant branch to the planetary nebula stages. Spectral features in the 10 to 20 gm region indicate the chemical nature (oxygen- or carbon-rich), and the strengths of the features relate to the physical properties of the shells. A few bright carbon-rich PPNs have been observed to show PAH features and an unidentified 21 micron emission feature. We used the Infrared Space Observatory (ISO) to observe a sample of IRAS sources that have the expected properties of PPNs and for which we have accurate positions. Some of these have optical counterparts (proposal SWSPPN01) and some do not (SWSPPN02). We had previously observed these from the ground with near-infrared photometry and, for those with visible counterparts, visible photometry and spectroscopy, which we have combined with these new ISO data in the interpretation of the spectra. We have completed a study of the unidentified emission feature at 21 micron in eight sources. We find the shape of the feature to be the same in all of the sources, with no evidence of any substructure. The ratio of the emission peak to continuum ranges from 0.13 to 1.30. We have completed a study of seven PPNs and two other carbon-rich objects for which we had obtained ISO 2-45 micron observations. The unidentified emission features at 21 and 30 micron were detected in six sources, including four new detections of the 30 micron feature. This previously unresolved 30 micron feature was resolved and found to consist of a broad feature peaking at 27.2 micron (the "30 micron" feature) and a narrower feature peaking at 25.5 micron (the "26 micron" feature). This new 26 micron feature is detected in eight sources and is particularly strong in IRAS Z02229+6208 and 16594-4656. The unidentified features at 3.3, 6,2, 7.7, and 11.3 micron, which are commonly observed in planetary nebulae and HII regions, are also seen in these PPNs. However, their strengths relative to the continuum plateaus at 8 and 12 micron are weaker than in planetary nebulae. The 6.9 micron feature, seen almost exclusively in PPNs, is strong. The spectral energy distributions of these PPNs were fitted with a radiative-transfer model, taking into account the emission features at 21, 26, and 30 micron. A significant fraction of the total energy output is emitted in these features: as high as 20% in the 30 micron feature and 8% in the 21 micron feature. The fact that so much energy is carried in these features suggests that the material responsible for this feature must be made of abundant elements, and most likely involves carbon. The change in the in feature strengths from stronger aliphatic bonds in PPNs to stronger aromatic bonds in PNs suggests a chemical and physical evolution in the carbonaceous circumstellar dust during this transition time scale of a few thousand years.

Hrivnak, Bruce J.↗

ISO Key Project: Exploring the Full Range of Quasar/AGN Properties

The origin of the infrared emission in Active Galactic Nuclei (AGN), whose strength is comparable to the optical/ultra-violet (OUV) emission, is generally thought to be a combination of thermal emission from dust and non-thermal, synchrotron emission. Although data are sparse, particularly in the far-infrared, the broad wavelength range of this emission suggests a wide range of temperatures and a combination of AGN and starburst heating mechanisms. The strength of the non-thermal emission is expected to be related to the radio emission. While this scenario is well-established, basic questions, such as the spatial and temperature distribution of the dust, the relative importance of AGN and starburst heating, and the significance of the non-thermal contribution, remain largely undetermined. The wide wavelength range of the Infrared Space Observatory (ISO) combined with its arcmin spatial resolution and increased sensitivity facilitated the observation of a larger subset of the AGN population than previously covered, allowing these questions to be investigated in more detail. This paper will review the spectral energy distributions (SED) of AGN with particular emphasis on the infrared emission and on ISO contributions to our knowledge. Preliminary results from ISO observations of X-ray selected and high-redshift AGN will be described.

Wilkes, B.↗

Intra-seasonal Oscillations (ISO) of Zonal-Mean Meridional Winds and Temperatures as Measured by UARS

Based on an empirical analysis of measurements with the High Resolution Doppler Imager (HRDI) on the UARS spacecraft in the upper mesosphere (95 km), persistent and regular intra-seasonal oscillations (ISO) with periods of about 2 to 4 months have recently been reported in the zonal-mean meridional winds. Similar oscillations have also been discussed independently in a modeling study, and they were attributed to wave-mean-flow interactions. The observed and modeled meridional wind ISOs were largely confined to low latitudes. We report here an analysis of concurrent temperature measurements on UARS, which produces oscillations similar to those seen in the meridional winds. Although the temperature oscillations are observed at lower altitudes (55 km), their phase variations with latitude are qualitatively consistent with the inferred properties seen in the meridional winds and thus provide independent evidence for the existence of ISOs in the mesosphere.

Huang, Frank T.↗

First Results from the ISO-IRAS Faint Galaxy Survey

We present the first result from the ISO-IRAS Faint Galaxy Survey (IIFGS), a program designed to obtain ISO observations of the most distant and luminous galaxies in the IRAS Faint Source Survey by filling short gaps in the ISO observing schedule with pairs of 12um ISOCAM AND 90um ISOPHOT observation.

Galaxy Survey luminous galaxies↗

ISO 15859 Propellant and Fluid Specifications: A Review and Comparison with Military and NASA Specifications

This work presents an overview of the International Organization for Standardization (ISO) 15859 International Standard for Space Systems Fluid Characteristics, Sampling and Test Methods Parts 1 through 13 issued in June 2004. These standards establish requirements for fluid characteristics, sampling, and test methods for 13 fluids of concern to the propellant community and propellant characterization laboratories: oxygen, hydrogen, nitrogen, helium, nitrogen tetroxide, monomethylhydrazine, hydrazine, kerosene, argon, water, ammonia, carbon dioxide, and breathing air. A comparison of the fluid characteristics, sampling, and test methods required by the ISO standards to the current military and NASA specifications, which are in use at NASA facilities and elsewhere, is presented. Many ISO standards composition limits and other content agree with those found in the applicable parts of NASA SE-S-0073, NASA SSP 30573, military performance standards and details, and Compressed Gas Association (CGA) commodity specifications. The status of a current project managed at NASA Johnson Space Center White Sands Test Facility (WSTF) to rewrite these documents is discussed.

Greene, Ben↗

ISO 50001-Based Energy Management Systems as a Practical Path for Decarbonization: Initial Findings from a Survey of Technical Assistance Cohort Participants

Organizations face rising pressure to take action to reduce their climate-affecting emissions (i.e., decarbonize). While many responses are possible, an essential approach—strategically managing their energy consumption as an essential business practice via an ISO 50001-based energy management system—is not yet widely recognized as a framework for decarbonization. This study analyzes interim survey results from 24 organizations (a 48% response rate) implementing a rigorous energy management system, one deployed by the U.S. Department of Energy as “50001 Ready”, to test whether participating organizations perceive the energy management system under development as an essential aspect of their decarbonization efforts. The results are preliminary in nature, given the ongoing nature of the program and associated data collection; however, they are sufficient to refute our hypothesis that energy management systems are perceived by organizations participating in 50001 Ready cohorts to primarily affect energy performance with little-to-no connection regarding decarbonization efforts. Major findings include that participants’ decarbonization targets and commitments are driven by market imperatives (highlighting the importance of ISO 50001 as a management system tool) and that they see energy efficiency as vital to decarbonizing. We conclude by suggesting future research directions to further establish the premise that energy management systems are an effective, efficient, and long-lasting decarbonization strategy.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Incorporating ISO Metadata Using HDF Product Designer

The need to store in HDF5 files increasing amounts of metadata of various complexity is greatly overcoming the capabilities of the Earth science metadata conventions currently in use. Data producers until now did not have much choice but to come up with ad hoc solutions to this challenge. Such solutions, in turn, pose a wide range of issues for data managers, distributors, and, ultimately, data users. The HDF Group is experimenting on a novel approach of using ISO 19115 metadata objects as a catch-all container for all the metadata that cannot be fitted into the current Earth science data conventions. This presentation will showcase how the HDF Product Designer software can be utilized to help data producers include various ISO metadata objects in their products.

metadata↗

Wind turbine main bearing rating lives as determined by IEC 61400‐1 and ISO 281: A critical review and exploratory case study

Abstract This paper studies the rating lives of wind turbine main bearings, as determined by the IEC 61400‐1 and ISO 281 standards. A critical review of relevant bearing life theory and turbine design requirements is provided, including discussion on possible shortcomings such as the existence (or not) of the bearing fatigue load limit and the validity of assuming linear damage accumulation. A detailed exploratory case study is then undertaken to determine rating lives for two models of main bearing in a 1.5 MW wind turbine. Rating life assessment is carried out under different conditions, including various combinations of main bearing temperature, wind field characteristics, lubricant viscosity, and contamination levels. Rating lives are found to be sufficiently above the desired 20‐year design life for both bearing models under expected operating conditions. For the larger bearing, operational loads are shown to be below or close to the bearing fatigue load limit a vast majority of the time. Key sensitivities for rating life values are temperature and contamination. Overall, the results of this study suggest that an ISO 281 rating life assessment does not account for reported rates of main bearing failures in 1 to 3 MW wind turbines. It is recommended that a similar analysis be undertaken for ISO/TS 16281 rating lives, along with further efforts to identify principal root causes of main bearing failures in future work, possibly leading to a new application standard specific to this component. It is also recommended that the impacts of partial wake impingement on main bearing rating lives are investigated.

17 WIND ENERGY↗

Upcycling disposable face masks into fuel range iso-alkanes through hydropyrolysis coupled with vapor-phase hydrocracking

The COVID-19 pandemic has resulted in an alarming accumulation of plastic waste. Herein, an integrated hydropyrolysis and hydrocracking process was performed to upcycle disposable masks into fuel-range iso-alkanes over carbon supported ruthenium (Ru/C). Experimental results indicated that catalyst type significantly affected product distribution during the hydropyrolysis and vapor-phase hydrocracking of disposable masks. Compared with zeolites-induced catalytic cascade process where up to ~25.9 wt% yield of aromatic hydrocarbons such as toluene and xylenes were generated, a ~82.7 wt% yield of desirable iso-alkanes with a high C 5 –C 12 gasoline selectivity of 95.5% was obtained over Ru/C under 550 °C hydropyrolysis temperature and 300 °C hydrocracking temperature at 0.2 MPa H 2 . Further, the cascade hydropyrolysis and hydrocracking process also exhibited high adaptability and flexibility in upcycling single-use syringes, food packaging, and plastic bags, generating 79.1, 81.6, and 80.3 wt% yields of fuel range iso/n-alkanes, respectively. This catalytic cascade hydrotreating process provides an efficient and effective approach to convert pandemic-derived plastic waste into gasoline-range fuel products.

09 BIOMASS FUELS↗