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At least 55 records · Page 3

Ion and water adsorption to graphene and graphene oxide surfaces

Graphene and graphene oxide (GO) are two particularly promising nanomaterials for a range of applications including energy storage, catalysis, and separations. Understanding the nanoscale interactions between ions and water near graphene and GO surfaces is critical for advancing our fundamental knowledge of these systems and downstream application success. Here this minireview highlights the necessity of using surface-specific experimental probes and computational techniques to fully characterize these interfaces, including the nanomaterial, surrounding water, and any adsorbed ions, if present. Key experimental and simulation studies considering water and ion structures near both graphene and GO are discussed. The major findings are: water forms 1–3 hydration layers near graphene; ions adsorb electrostatically to graphene under an applied potential; the chemical and physical properties of GO vary considerably depending on the synthesis route; and these variations influence water and ion adsorption to GO. Lastly, we offer outlooks and perspectives for these research areas.

36 MATERIALS SCIENCE↗

Machine Learning Analysis of Hydrologic Exchange Flows and Transit Time Distributions in a Large Regulated River

Hydrologic exchange between river channels and adjacent subsurface environments is a key process that influences water quality and ecosystem function in river corridors. High-resolution numerical models were often used to resolve the spatial and temporal variations of exchange flows, which are computationally expensive. In this study, we adopt Random Forest (RF) and Extreme Gradient Boosting (XGB) approaches for deriving reduced order models of hydrologic exchange flows and associated transit time distributions, with integrated field observations (e.g., bathymetry) and hydrodynamic simulation data (e.g., river velocity, depth). The setup allows an improved understanding of the influences of various physical, spatial, and temporal factors on the hydrologic exchange flows and transit times. The predictors also contain those derived using hybrid clustering, leveraging our previous work on river corridor system hydromorphic classification. The machine learning-based predictive models are developed and validated along the Columbia River Corridor, and the results show that the top parameters are the thickness of the top geological formation layer, the flow regime, river velocity, and river depth; the RF and XGB models can achieve 70% to 80% accuracy and therefore are effective alternatives to the computational demanding numerical models of exchange flows and transit time distributions. Each machine learning model with its favorable configuration and setup have been evaluated. The transferability of the models to other river reaches and larger scales, which mostly depends on data availability, is also discussed.

97 MATHEMATICS AND COMPUTING↗

Linking Hydrology and Dissolved Organic Matter Characteristics in a Subtropical Wetland: A Long-Term Study of the Florida Everglades

Dissolved organic matter (DOM) acts as an important biogeochemical component of aquatic ecosystems that controls nutrient cycling, influences water quality, and links terrestrial and oceanic carbon pools, yet long-term studies of how changing environmental drivers alter its abundance and composition are rare. Using a ten-year, spatially explicit dataset from Everglades National Park (ENP), a globally significant wetland, we investigated the relationships between DOM quality/quantity and hydrologic/climatic drivers along two contrasting marsh-estuarine transects based on generalized linear modeling and a cumulative sums analysis. Analyses revealed distinct spatial, seasonal, and interannual patterns in variability of DOC and optical properties. Landscape-scale seasonal patterns showed an enrichment in microbial-like and protein-like DOM during the dry season relative to the wet season. We found that, while some compositional constituents varied with the solar calendar, responsive to temperature and photoperiod, others varied with the hydrologic calendar. Independent water level and discharge effects indicated strong hydrologic control on DOM quality that differed between the two transects, evidencing differences in their connectivity to areas of high agricultural activity. Across all sites, a significant long-term increasing trend in the fluorescence index was observed, associated with a positive correlation with precipitation and also potential changes in agricultural inputs, with other features associated with drought and hurricanes. Lastly, the cumulative sums analysis revealed differences between the two transects in the sensitivity of DOM composition to decreased water levels associated with 30-year climate scenarios, with the less hydrologically dynamic transect exhibiting greater potential sensitivity.

54 ENVIRONMENTAL SCIENCES↗

Atmospheric Rivers in the Eastern and Midwestern United States Associated With Baroclinic Waves

Atmospheric rivers (ARs) significantly impact the hydrological cycle and associated extremes in western continental regions. Recent studies suggest ARs also influence water resources and extremes in continental interiors. AR detection tools indicate that AR conditions are relatively frequent in areas east of the Rocky Mountains. The origin of these ARs, whether from synoptic-scale waves or mesoscale processes, is unclear. This study uses meteorological composite maps and transects of AR conditions during the four seasons. The analysis reveals that ARs east of the Rockies are associated with long-wave, baroclinic Rossby waves. This result demonstrates that eastern North American ARs are dynamically similar to their western coastal counterparts, though mechanisms for vertical moisture flux differ between the two. These findings provide a foundation for understanding future climate change and ARs in this region and offer new methods for evaluating climate model simulations.

58 GEOSCIENCES↗

A novel construct for scaling groundwater–river interactions based on machine-guided hydromorphic classification

Hydrologic exchange between river channels and adjacent subsurface environments is a key process that influences water quality and ecosystem function in river corridors. Predictive numerical models are needed to understand responses of river corridors to environmental change and to support sustainable watershed management. We posit that systematic hydromorphic classification provides a scaling construct that facilitates extrapolation of outputs from local-scale mechanistic models to reduced-order models applicable at reach and watershed scales. This in turn offers the potential to improve large-scale predictions of river corridor hydrobiogeochemical processes. Here we present a new machine-guided hydromorphic classification methodology that addresses the key requirements of this objective, and we demonstrate its application to a segment of the Columbia River in the northwestern United States. The resulting hydromorphic classes form spatially coherent and physically interpretable hydromorphic units that exhibit distinct behaviors in terms of distributions of subsurface residence times (a primary control on critical biogeochemical reactions). This approach forms the basis of ongoing research that is evaluating the formulation of reduced-order models and transferability of results to other river reaches and larger scales.

54 ENVIRONMENTAL SCIENCES↗

The Ice Particle and Aggregate Simulator (IPAS). Part III: Verification and Analysis of Ice–Aggregate and Aggregate–Aggregate Collection for Microphysical Parameterization

Abstract The Ice Particle and Aggregate Simulator (IPAS) is used to theoretically represent the aggregation process of ice crystals. Aggregates have a variety of formations based on initial ice particle size, shape, and falling orientation, all of which influence water phase partitioning. Aggregate dimensional properties and density changes are calculated for monomer–monomer (MON–MON), monomer–aggregate (MON–AGG), and aggregate–aggregate (AGG–AGG) collection to be used by ice-microphysical models for improvement in aggregation parameterizations. Aggregates are chosen from a database of 9 744 000 preformed combinations to be further collected (see Part II). AGG–AGG collection results in more extreme and a smaller range of aggregate aspect ratios than MON–AGG collection. A majority of aggregates are closer to prolate than oblate spheroids, regardless of collection type, except for quasi-horizontally oriented particles that have extreme aspect ratios to begin with. MON–AGG collection frequently results in an increase in density upon collection, whereas MON–MON and AGG–AGG collection almost always result in particle density decreases, with extreme reductions near 99% for MON–MON collection. MON–MON collection results in the greatest decreases in density but then quickly becomes unaffected by the addition of more monomers due to inherent size differences between monomers and aggregates. Finally, a holistic analysis to in situ observations of cloud particle images is presented. IPAS 2D aspect ratios surround a median value of 0.6 and closely follow that of previous studies while varying by no more than ≈12% on average from observed aggregates.

54 ENVIRONMENTAL SCIENCES↗

wmpy-power: A Python package for process-based regional hydropower simulation

Hydropower is an important source of renewable energy in many parts of the world. The generation potential for a hydropower facility can vary greatly due to fluctuations in precipitation and snowmelt patterns impacting streamflow and reservoir storage. Human activities such as irrigation, manufacturing, and hydration can also influence water availability at nearby and downstream facilities. wmpy-power--the hydropower model described in this work--is process-based, leveraging explicit reservoir storage and release data to address impacts on hydropower from climate change and human adaptive behaviors to inform long-term planning and resource-adequacy considerations.

13 HYDRO ENERGY↗

Infrared thermometry in high temperature materials processing: influence of liquid water and steam

Here, the capability of four infrared thermometry techniques (2-colour and 1-colour pyrometers, Pyrolaser and IR camera) was evaluated with respect to the impact of water or steam in the line of sight to determine temperature from two heat sources (blackbody calibration source and steel block inside the furnace). The influence of liquid water on the temperature readings was minimal when using 2-colour pyrometry due to comparable absorption coefficients of water for the measured wavelengths. The signals measured using both the Pyrolaser and the 1-colour pyrometer were decreased due to the partial absorption and resulted in an apparent temperature lower than the actual. Water readily absorbed the IR signal in the range of the IR camera operation, resulting in no signal whenever liquid water was present in the line of sight. Steam caused the most deviation and fluctuation of temperature readings for all techniques due to the large level of light scattering in addition to the absorption of the radiant energy. A technique was developed to determine the transmissivity (apparent emissivity) when water or steam is in the line of sight of measurement. An approximate correction to the measurements based on Planck’s law is discussed for both 2-colour and 1-colour pyrometers.

2-colour and 1-colour pyrometry↗

δ 2 H isotopic offsets in xylem water measurements under cryogenic vacuum distillation: Quantifying and correcting wood‐water hydrogen exchange influences

Stable isotopes δ 18 O and δ 2 H are used to infer vegetation water sources. In some studies, significant xylem water δ 2 H offsets from potential source waters have been observed. The offsets appear to be more prevalent with cryogenic vacuum distillation (CVD) of plant water. Hypothesized mechanisms for these offsets include changes during plant water uptake and transport, and methodological problems. We propose that a large portion of the offsets are due to hydrogen isotope exchange between xylem water and non-crystalline hydroxyl groups of wood cellulose and hemicellulose during CVD. We present a method for estimating the hypothesized isotopic exchange between wood tissues and water, which is the result of Rayleigh and equilibrium fractionation. To estimate the exchange, we use published wood properties for North American tree species and isotope chemical relationships as a function of moisture content, CVD temperature and water extraction efficiency. A simple model of exchange between xylem water and hydroxyl groups captures the range of observations in studies in which CVD and non-CVD methods were compared. To evaluate the model, we compared observed δ 2 H offsets (sw-excess) values from two field datasets (90°C, n = 364, and 170°C, n = 43) to δ 2 H offsets estimated with our chemical model. We found good agreement between observed and estimated δ 2 H offsets for samples extracted at 90°C (r 2 = 0.69) but not for samples extracted at 170°C (r 2 = 0.20). The offset may be eliminated by increasing the extraction temperature to 229°C or by adding a standard sufficient to raise the moisture content to >150%. A correction can also be approximated by applying a theoretical calculation based on the extraction temperature, moisture content and water extraction efficiency.

54 ENVIRONMENTAL SCIENCES↗

Aerosol Influences on Cloud Water: Insights From ARM EPCAPE Observations With Explainable Machine Learning

This study employs an explainable machine learning (ML) framework (XGBoost-SHapley Additive exPlanations analysis) to investigate controlling factors on cloud liquid water path (LWP) using EPCAPE observations near the California coast. Aerosols are found to be the dominant factor explaining LWP variability, surpassing meteorological factors (MFs). By isolating aerosol effects from meteorological influences, the ML reveals a negative linear relationship between LWP and cloud droplet number concentration (Nd) in log space, likely driven by entrainment drying via evaporation-entrainment feedback. This aligns with the negative regime of the inverted-V relationship reported in previous studies, while no positive LWP responses are found due to a limited number of precipitating cases in EPCAPE. Furthermore, the sensitivity of LWP to Nd shows a non-linear dependence on MFs like moisture contrast between surface and free troposphere and lower-tropospheric stability. This occurs due to the interplay between the MFs' direct effects on entrainment drying and indirect effects through LWP adjustments.

EPCAPE observations↗

Understanding the Influence of Water-Soluble Compounds from Unpretreated Corn Stover Pellets on Enzymatic Hydrolysis of Cellulose

Aqueous extractives are minor and non-structural compounds in biomass that can be extracted using solvents, while contributing significantly to lignocellulose characteristics. Yet their roles in enzyme-mediated processing of lignocellulosic biomass remain elusive. Here, we examine the composition and features of extractives derived from untreated pelleted corn stover as well as their effects on enzymatic hydrolysis. Unlike the observations described in previous reports, we find that water extractable material improves the enzymatic hydrolysis of extractive-free stover by 67% with a glucose yield increase from 12% to 20% with 6 FPU cellulase per g glucan, whereas the enzyme activities are diminished when using microcrystalline cellulose as a substrate. The different behavior of corn stover and microcrystalline cellulose is likely attributed to the presence of lignin, which may interact with inhibitory compounds such as phenolics, mitigating the detrimental impacts of soluble inhibitors or insoluble lignin or both. These findings advance our fundamental understanding of the intrinsic behavior of extractives and help to optimize the schemes for efficient and cost-competitive enzymatic conversion of lignocellulose.

09 BIOMASS FUELS↗

Influence of Local Water Vapor Analysis Uncertainty on Ensemble Forecasts of Tropical Cyclogenesis Using Hurricane Irma (2017) as a Testbed

Abstract Tropical cyclone formation is known to require abundant water vapor in the lower to middle troposphere within the incipient disturbance. In this study, we assess the impacts of local water vapor analysis uncertainty on the predictability of the formation of Hurricane Irma (2017). To this end, we reduce the magnitude of the incipient disturbance’s water vapor perturbations obtained from an ensemble-based data assimilation system that constrained moisture by assimilating all-sky infrared and microwave radiances. Five-day ensemble forecasts are initialized two days before genesis using each set of modified analysis perturbations. Growth of convective differences and intensity uncertainty are evaluated for each ensemble forecast. We observe that when initializing an ensemble forecast with only moisture uncertainty within the incipient disturbance, the resulting intensity uncertainty at every lead time exceeds half that of an ensemble containing initial perturbations to all variables throughout the domain. Although ensembles with different initial moisture uncertainty amplitudes reveal a similar pathway to genesis, uncertainty in genesis timing varies substantially across ensembles since moister members exhibit earlier spinup of the low-level vortex. These differences in genesis timing are traced back to the first 6–12 h of integration, when differences in the position and intensity of mesoscale convective systems across ensemble members develop more quickly with greater initial moisture uncertainty. In addition, the rapid growth of intensity uncertainty may be greatly modulated by the diurnal cycle. Ultimately, this study underscores the importance of targeting the incipient disturbance with high spatiotemporal water vapor observations for ingestion into data assimilation systems. Significance Statement Hurricanes form from clusters of thunderstorms that organize into a coherent system. One of the key ingredients for the formation process is an abundance of moisture. In this study, we test the sensitivity of hurricane formation to the initial moisture content in the vicinity of the cluster of thunderstorms that would become Hurricane Irma (2017). To do so, we initialize sets of forecasts each having a different variability of initial moisture content within the embryonic disturbance. Our results show that the predictability of hurricane formation is highly dependent on the uncertainty of the moisture content within the initial disturbance. Consequently, more high-quality observations of the moisture within the precursor disturbances to hurricanes are expected to improve forecasts of their formation.

Hartman, Christopher M.↗

Evaluating the combined effects of light and water availability on the early growth and physiology of Tamarindus indica : Implications for restoration

Abstract Premise The tamarind tree (Tamarindus indica) is a species of significant cultural, economic, and ecological value, with a pantropical distribution. However, the tamarind is experiencing a decline in wild populations in its native range, but the reasons for its decline remain unknown. Methods We examined the critical early life‐history stages for tamarind establishment to understand how varying levels of light and water availability and watering frequency affect its regeneration. Through three greenhouse experiments, we assessed the impact of these resources on the germination, survival, growth, and physiological responses of tamarind seedlings and saplings. Results Water availability was critical for seed germination, but not light levels or pre‐germination treatments. Light was the primary limiting factor for seedling growth. Tamarinds in high light availability grew taller, had more biomass and larger diameter, but the effect of light was modulated by water availability, indicating that there was an interaction between both resources. Water and light affected specific leaf area and leaf dry matter content but not biomass allocation, root‐to‐shoot ratio, or stomatal conductance. Water availability influenced sapling growth, but watering frequency did not, indicating a resilience of tamarind saplings to changes in rainfall periodicity but a sensitivity to total rainfall amounts. Conclusions Our study underscores the importance of considering both light and water availability in tamarind restoration efforts and contribute to understanding plant responses and trade‐offs under different levels of critical resources. Our findings will inform conservation strategies to support the regeneration and long‐term survival ofTamarindus indicain its native habitats.

Plant Sciences↗

Water availability modulates maximum canopy heights of low-elevation Amazonian second-growth forests

Tropical second-growth forests of the Amazon sequester large amounts of carbon and are important carbon sinks, contributing substantially to climate change mitigation, biodiversity conservation, and providing crucial ecosystem services. Deforestation due to selective logging and shifting cultivation is expanding second-growth forest areas in tropical forest regions, which if well managed, regenerate rapidly over time. Maximum forest canopy height is an important metric of biomass and carbon accumulation in second-growth forests and is strongly influenced by water availability. The water limitation hypothesis explains the positive influence of water availability on maximum tree heights and has been examined and demonstrated at a small-scale using field data, and at a global scale, with limited accuracy, using remote sensing data in tropical ecosystems. However, this hypothesis concerning maximum canopy height has not been much studied at regional and national scales for tropical second-growth forests. In this study, we leveraged NASA GEDI spaceborne lidar data across the Brazilian Amazon and derived second-growth forest relative height metrics for delineating the influence of water availability, second-growth forest age, and topographic elevation on maximum canopy height. Water availability was found to significantly influence the maximum canopy height of second-growth forest trees, of age range from 30 to 35 years, at elevations less than 500 m and maximum precipitation thresholds of 1500 mm. Our results indicate that changing precipitation patterns or increased drought conditions under different climate change regimes could impact forest structure, plant communities, ecosystem functioning, and carbon sequestration capabilities of tropical second-growth forests in the Amazon.

Carbon sequestration↗

Earth's water reservoirs in a changing climate

Progress towards achieving a quantitative understanding of the exchanges of water between Earth's main water reservoirs is reviewed with emphasis on advances accrued from the latest advances in Earth Observation from space. These exchanges of water between the reservoirs are a result of processes that are at the core of important physical Earth-system feedbacks, which fundamentally control the response of Earth's climate to the greenhouse gas forcing it is now experiencing, and are therefore vital to understanding the future evolution of Earth's climate. The changing nature of global mean sea level (GMSL) is the context for discussion of these exchanges. Different sources of satellite observations that are used to quantify ice mass loss and water storage over continents, how water can be tracked to its source using water isotope information and how the waters in different reservoirs influence the fluxes of water between reservoirs are described. The profound influence of Earth's hydrological cycle, including human influences on it, on the rate of GMSL rise is emphasized. The many intricate ways water cycle processes influence water exchanges between reservoirs and thus sea-level rise, including disproportionate influences by the tiniest water reservoirs, are emphasized.

54 ENVIRONMENTAL SCIENCES↗

Compositional changes of dissolved organic molecules along water flow and their influencing factors in the Three Gorges Reservoir

Molecular composition of dissolved organic matter (DOM) and its influencing factors in river reservoirs remains elusive. Here, molecular compositions of DOM, bacterial community structures, and water physiochemistry were investigated in the field and microcosm samples of the Three Gorges Reservoir (TGR). The results showed that DOM molecular compositions were significantly (R 2 = 0.245, p < 0.001) correlated with bacterial community structures in the studied field samples, suggesting that bacteria may actively interact with DOM molecules. In this study, the molecular compositions of DOM in the studied field samples were significantly (p < 0.05) affected by the distance between the sample sites and the Three Gorges Dam and by bacterial groups of Actinobacteria and Alphaproteobacteria, suggesting that both hydrological and bacterial processes may contribute to the variation in DOM molecular composition in the TGR water. Furthermore, microcosm experiments demonstrated that both microbial and abiotic processes may transform and/or produce DOM in the TGR, thereby affecting DOM molecular composition. Microbial process increased the average aromaticity index and decreased the carbon number of DOM molecules with increasing incubation duration; whereas average oxygen number, double bond equivalent, and oxidation state of carbon of DOM molecules increased during the first 14 days of incubation and began to decrease thereafter. Taken together, this study expands our understanding of the impact of microbial process on the DOM molecular composition in reservoir ecosystems, and has great implications for carbon cycling in major rivers.

58 GEOSCIENCES↗

BAWLD-CH 4 : a comprehensive dataset of methane fluxes from boreal and arctic ecosystems

Methane (CH 4 ) emissions from the boreal and arctic region are globally significant and highly sensitive to climate change. There is currently a wide range in estimates of high-latitude annual CH 4 fluxes, where estimates based on land cover inventories and empirical CH 4 flux data or process models (bottom-up approaches) generally are greater than atmospheric inversions (top-down approaches). A limitation of bottom-up approaches has been the lack of harmonization between inventories of site-level CH 4 flux data and the land cover classes present in high-latitude spatial datasets. Here we present a comprehensive dataset of small-scale, surface CH 4 flux data from 540 terrestrial sites (wetland and non-wetland) and 1247 aquatic sites (lakes and ponds), compiled from 189 studies. The Boreal–Arctic Wetland and Lake Methane Dataset (BAWLD-CH 4 ) was constructed in parallel with a compatible land cover dataset, sharing the same land cover classes to enable refined bottom-up assessments. BAWLD-CH 4 includes information on site-level CH 4 fluxes but also on study design (measurement method, timing, and frequency) and site characteristics (vegetation, climate, hydrology, soil, and sediment types, permafrost conditions, lake size and depth, and our determination of land cover class). The different land cover classes had distinct CH 4 fluxes, resulting from definitions that were either based on or co-varied with key environmental controls. Fluxes of CH 4 from terrestrial ecosystems were primarily influenced by water table position, soil temperature, and vegetation composition, while CH 4 fluxes from aquatic ecosystems were primarily influenced by water temperature, lake size, and lake genesis. Models could explain more of the between-site variability in CH 4 fluxes for terrestrial than aquatic ecosystems, likely due to both less precise assessments of lake CH 4 fluxes and fewer consistently reported lake site characteristics. Analysis of BAWLD-CH 4 identified both land cover classes and regions within the boreal and arctic domain, where future studies should be focused, alongside methodological approaches. Overall, BAWLD-CH 4 provides a comprehensive dataset of CH 4 emissions from high-latitude ecosystems that are useful for identifying research opportunities, for comparison against new field data, and model parameterization or validation.

54 ENVIRONMENTAL SCIENCES↗