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At least 55 records · Page 3

Battery metal recycling by flash Joule heating

The staggering accumulation of end-of-life lithium-ion batteries (LIBs) and the growing scarcity of battery metal sources have triggered an urgent call for an effective recycling strategy. However, it is challenging to reclaim these metals with both high efficiency and low environmental footprint. We use here a pulsed dc flash Joule heating (FJH) strategy that heats the black mass, the combined anode and cathode, to >2100 kelvin within seconds, leading to ~1000-fold increase in subsequent leaching kinetics. There are high recovery yields of all the battery metals, regardless of their chemistries, using even diluted acids like 0.01 M HCl, thereby lessening the secondary waste stream. The ultrafast high temperature achieves thermal decomposition of the passivated solid electrolyte interphase and valence state reduction of the hard-to-dissolve metal compounds while mitigating diffusional loss of volatile metals. Life cycle analysis versus present recycling methods shows that FJH significantly reduces the environmental footprint of spent LIB processing while turning it into an economically attractive process

36 MATERIALS SCIENCE↗

Acceleration of runaway electrons and Joule heating in solar flares

The electric field acceleration of electrons out of a thermal plasma and the simultaneous Joule heating of the plasma are studied. Acceleration and heating timescales are derived and compared, and upper limits are obtained on the acceleration volume and the rate at which electrons can be accelerated. These upper limits, determined by the maximum magnetic field strength observed in flaring regions, place stringent restrictions upon the acceleration process. The role of the plasma resistivity in these processes is examined, and possible sources of anomalous resistivity are summarized. The implications of these results for the microwave and hard X-ray emission from solar flares are examined.

Holman, G. D.↗

Acceleration of runaway electrons and Joule heating in solar flares

The electric field acceleration of electrons out of a thermal plasma and the simultaneous Joule heating of the plasma are studied. Acceleration and heating timescales are derived and compared, and upper limits are obtained on the acceleration volume and the rate at which electrons can be accelerated. These upper limits, determined by the maximum magnetic field strength observed in flaring regions, place stringent restrictions upon the acceleration process. The role of the plasma resistivity in these processes is examined, and possible sources of anomalous resistivity are summarized. The implications of these results for the microwave and hard X-ray emission from solar flares are examined.

Holman, G. D.↗

Rapid synthesis of phase-engineered tungsten carbide electrocatalysts via flash joule heating for high-current-density hydrogen evolution

Fabricating durable and high-performance electrocatalysts operating at high current densities for industrial acidic hydrogen evolution remains a daunting challenge. Tailoring the phase composition of electrocatalysts is a promising strategy to harness synergistic effects and improve charge transfer, thereby optimizing their performance. Here, this work presents a fast, green method based on flash joule heating (FJH) to synthesize phase-engineered tungsten carbide electrocatalysts for the acidic hydrogen evolution reaction (HER) at high current densities. Tungsten carbide electrodes with varying FJH treatment durations (3, 10, 30, and 60 s) are fabricated to fine-tune the mixture of tungsten monocarbide (WC) and tungsten semicarbide (W 2 C) phases. Results show that samples with a 30-s treatment (TC-3) exhibit an optimal balance between these phases, leading to a low overpotential of 180.97 and 387 mV at current densities of 10 mA/cm 2 and 4 A/cm 2 , respectively. TC-3 exhibits significantly lower charge transfer resistance compared to the other electrocatalysts, which can be attributed to its optimal phase ratio. Notably, the TC-3 electrocatalyst remains stable for over 9 days at 4 A/cm 2 due to their controlled phases and excellent corrosion-resistant properties. This work highlights a new method to fabricate cost-effective, high-performance tungsten carbide electrocatalysts with well-controlled phase compositions.

Acidic hydrogen evolution reaction↗

Circulation in the high-latitude thermosphere due to electric fields and Joule heating

Electric fields in the earth's upper atmosphere are capable of setting the neutral atmosphere in motion via ion-neutral collisions as well as pressure gradients from resultant Joule heating. By means of simple models for the high-latitude thermosphere and electric fields a simplified set of coupled equations is solved which show that moderate electric fields, when present for a period of several hours, are capable of displacing the neutral atmosphere of the order of 50 km in the vertical, a few hundred kilometers in the north-south direction and over 1000 km in the east-west direction.

Heaps, M. G.↗

Sensitivity of magnetohydrodynamic simulations of Joule-heated conductors to the vaporization curve in equations of state

Magnetohydrodynamic (MHD) simulations of electrically exploded aluminum and copper rods demonstrate a technique to validate equations of state (EOS) for rapidly Joule-heated conductors. The balance of internal and magnetic forces at the conductor-insulator interface drives the metal there along the vaporization phase boundary. Variations between critical points and vaporization curves in existing models predict differing densities and temperatures in MHD simulations for these models. Here, the inclusion of Maxwell constructs in the liquid-vapor biphase region of the EOS caused the rod surface to vaporize earlier in time than unmodified tables with van der Waals loops. Velocimetry of recent experiments is used to validate the location of the vaporization curve in existing EOS models and differentiate between the vapor dome treatments. Dielectric coatings applied to the metal surface restricted the conductor’s expansion and diverted the metal into the warm dense matter regime.

36 MATERIALS SCIENCE↗

Joule heating and runaway electron acceleration in a solar flare

The hard and soft x ray and microwave emissions from a solar flare (May 14, 1980) were analyzed and interpreted in terms of Joule heating and runaway electron acceleration in one or more current sheets. It is found that all three emissions can be generated with sub-Dreicer electric fields. The soft x ray emitting plasma can only be heated by a single current sheet if the resistivity in the sheet is well above the classical, collisional resistivity of 10(exp 7) K, 10(exp 11)/cu cm plasma. If the hard x ray emission is from thermal electrons, anomalous resistivity or densities exceeding 3 x 10(exp 12)/cu cm are required. If the hard x ray emission is from nonthermal electrons, the emissions can be produced with classical resistivity in the current sheets if the heating rate is approximately 4 times greater than that deduced from the soft x ray data (with a density of 10(exp 10)/cu cm in the soft x ray emitting region), if there are at least 10(exp 4) current sheets, and if the plasma properties in the sheets are characteristic of the superhot plasma observed in some flares by Lin et al., and with Hinotori. Most of the released energy goes directly into bulk heating, rather than accelerated particles.

Holman, Gordon D.↗

Polar thermospheric Joule heating, and redistribution of recombination energy in the upper mesosphere

Kellogg (1961), suggested that transport of atomic oxygen from the summer into the winter hemisphere and subsequent release of energy by three body recombination, O+O+N2 yields O2+N2+E, may contribute significantly to the so-called mesopause temperature anomaly. Earlier model calculations have shown that Kellogg's mechanism produces about a 10-percent increase in the temperature from summer to winter at 90 km. This process, however, is partly compensated by differential heating from absorption of UV radiation associated with dissociation of O2. In the auroral region of the thermosphere, there is a steady energy dissipation by Joule heating causing a redistribution and depletion of atomic oxygen due to wind-induced diffusion. With the removal of O, latent chemical energy normally released by three body recombination is also removed, and the result is that the temperature decreases by almost 2 percent near 90 km. Through dynamic feedback, this process reduces the depletion of atomic oxygen by about 25 percent and the temperature perturbation in the exosphere from 10 to 7 percent at polar latitudes. Under the influence of the internal dynamo interaction, the prevailing zonal circulation in the upper thermosphere changes direction when the redistribution of recombination energy is considered.

Mayr, H. G.↗

Joule heating and field-aligned currents: Preliminary results from DE-2

There are three main processes by which energy is transferred from the magnetosphere to the thermosphere: (1) charge exchange of the ring current particles; (2) precipitation of charged particles; and (3) joule dissipation by the magnetosphere-ionosphere current systems. The importance of this last process has been recognized and the rate of joule heating has been estimated by many workers. Observations of the electric (E) and magnetic (B) fields from Dynamics Explorer Satellite 2 are providing a new set of data on field-aligned currents. One of the remarkable features found in these observations is the high correlation between an orthogonal pair of the E and B field components. In recent years, observational data have accrued concerning the relationship between the interplanetary magnetic field and the size of the polar cap and also about the evolution of a substorm or a magnetic storm. It is suggested that these findings be incorporated in future model calculations.

Sugiura, M.↗

Joule heating of Io's ionosphere by unipolar induction currents

Electrical induction in Io's ionosphere, due to the corotating plasma bound to the Jovian magnetosphere, is one possible source for the attainment of the high temperatures suggested by the large scale height of Io's ionosphere. Unipolar induction models are constructed to calculate ionospheric joule heating numerically, whose heating rates lie between 10 to the -9th and 10 to the -8th W/cu m. The binding and coupling of the ionosphere is due to the dense, and possibly ionized, neutral SO2 atmosphere, and there appears to be no need to postulate the existence of an intrinsic Ionian magnetic field in order to retain the observed ionnosphere.

Herbert, F.↗

Energy-efficient generation of skyrmion phases in Co/Ni/Pt-based multilayers using Joule heating

We have studied the effects of electrical current pulses on skyrmion formation in a series of Co/Ni/Pt-based multilayers. Transmission x-ray microscopy reveals that by applying electrical current pulses of duration and current density on the order of 50 μs and 1.7 × 10 10 A/m 2 , respectively, in an applied magnetic field of 50 mT, stripe-to-skyrmion transformations are attained. The skyrmions formed by such pulses remain stable across a wide range of magnetic fields, including zero field. We attribute the transformation primarily to current-induced Joule heating on the order of ~128 K. Reducing the magnetic moment and perpendicular anisotropy using thin rare-earth spacers reduces the pulse duration, current density, and magnetic field necessary to 25 µs, 2.4 × 10 9 A/m 2 , and 27 mT, respectively. Finally, these findings show that energetic inputs allow for the formation of skyrmion phases in a broad class of materials, and that material properties can be tuned to yield more energy-efficient access to skyrmion phases.

36 MATERIALS SCIENCE↗

Ultrafast (1‐5 sec) Lamination of Perovskite Solar Cells With Self‐Encapsulation Using Rapid Joule Heating

Perovskite solar cells (PSCs) are traditionally fabricated using sequential layer‐by‐layer deposition, in which each layer of the device is processed on top of the preceding layer. This constrains the processing techniques and selection of transport layer materials that can be used in the solar cell. To overcome these challenges, two half‐cells can be processed independently and then diffusion‐bonded through a lamination process. However, current lamination processes for perovskite solar cells suffer from relatively long process times, which can limit throughput when moving toward high‐volume manufacturing. In this study, a custom platform was designed for rapid‐joule heating of perovskite materials and devices. This enabled more than a 99% reduction in lamination time from 26 min to 1 s. Perovskite samples that were laminated in 1 s exhibited comparable values of percent bonded area, interfacial toughness, grain domain size, and X‐ray diffraction spectra to those laminated in greater than 10 min. As a proof‐of‐concept, 18.3% efficient devices were successfully laminated in 5 s. A transient heat transfer model was developed to describe the relationship between the perovskite temperature and the electrical power supplied to the heaters, establishing a baseline for predicting processing conditions in large‐scale manufacturing systems. Ultra‐fast lamination provides a pathway toward scalable roll‐to‐roll or sheet‐to‐sheet manufacturing of PSCs.

heat transfer↗

Joule heating in the high-latitude mesosphere

The contribution made by Joule dissipation to heating of the daytime high-latitude upper mesosphere is discussed. During solar proton precipitation events in regions of large electric fields, Joule dissipation can be substantially larger than the local solar heating rate. Altitude profiles of Joule dissipation are presented for the polar cleft region for the August 4, 1972, solar proton event.

Banks, P. M.↗

Numerical modeling of Joule heated ceramic melter

Computational fluid dynamics and heat transfer models of waste glass melters are being developed to support the vitrification campaign at the Waste Treatment and Immobilization Plant (WTP) as part of the United States nuclear waste stewardship and environmental protection programs. The WTP mission aims to achieve the stable and durable processing of vitrified waste in the safest, most efficient, and economical manner possible. Hanford’s tank waste is far more complex and varied than the waste treated by other vitrification facilities and both startup and long-term operational challenges are likely to be even greater than prior experience has shown. There are thousands of different waste compositions, which makes processing the waste a complex and challenging task. Models of test melters, pilot-scale, and full-scale melters have been developed to provide understanding and insight into the various physical and chemical phenomena occurring during vitrification. So the results of these modeling activities will be used to support the WTP operations to process legacy nuclear waste into a stable form for disposal.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗