Search NASA⌕ Search

SEARCH · Search NASA

Results for “KNaCK”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3

The abundances of CH4, CH3D, NH3, and PH3 in the troposphere of Jupiter derived from high-resolution 1100-1200/cm spectra

High-resolution spectra of the 1100-1200/cm region of the central part of Jupiter obtained in March 1980 and April 1981 are analyzed. The best fit NH3 distribution curve reveals a higher than solar mixing ratio, the abundance of NH3 to that of H2 being (3.3 + or - 1.7) x 10 to the -4th, below the 147 K layer (greater than 0.6 atmosphere). If NH3 ice particles are introduced as an opacity source, the NH3 mixing ratio below the 147 K layer can be lowered, but the fit is worse than that given by the model that excludes NH3 ice particles. The best fit PH3 distribution curve exhibits a PH3/H2 mixing ratio of (8.3 + or - 2.0) x 10 to the -7th in the troposphere. In addition, a CH4/H2 mixing ratio of (2.5 + or - 0.4) x 10 to the -3rd is found in the troposphere.

Knacke, R. F.↗

Infrared spectrophotometry of Comet IRAS-Araki-Alcock (1983d) - A bare nucleus revealed?

Spectra of the central core and surrounding coma of Comet IRAS-Araki-Alcock (1983d) were obtained at 8-13 microns on May 11 and 2-4 microns on May 12, 1983. Spatially resolved measurements at 10 microns with a 4-arcsec beam showed that the central core was more than 100 times brighter than the inner coma only 8 arcsec away; for radially outflowing dust, the brightness ratio would be a factor of 8. The observations of the central core are consistent with direct detection of a nucleus having a radius of approximately 5 km. The temperature of the sunlit hemisphere was greater than 300 K. Spectra of the core are featureless, while spectra of the coma suggest weak silicate emission. The spectra show no evidence for icy grains. The dust production rate on May 11.4 was about 100,000 g/sec, assuming that the gas flux from the dust-producing areas on the nucleus was about 0.00001 g/sq cm per sec.

Hanner, M. S.↗

Interstellar dust spectra between 2.5 and 3.3 microns - A search for hydrated silicates

Spectra in the 2.5-3.3 micron wavelength region of VI Cyg 12, AFGL 2205, and AFGL 2885 were obtained in a search for bound water, hydroxyl groups, and hydrated minerals in interstellar dust. No new absorption bands were found. Comparison of expected strengths of bands of serpentine and chlorite-like minerals with the data suggests that less than 25 percent and 50 percent, respectively, of the silicate in the grains is composed of these materials.

Knacke, R. F.↗

Dark grains in comet Crommelin

Comet P/Crommelin (1983n) was observed at 1-20 microns at the NASA IRTF March 29-April 1, 1984. The thermal emission spectrum fits a black body of about 290 K, cooler than other comets observed at 1 AU. The ratio of thermal to scattered radiation indicates that these grains were extremely dark with a geometric albedo of about 0.015 at J(1.25 microns) and 0.02 at K(2.25 microns). The 10 micron flux distribution on April 1 was very asymmetric, decreasing rapidly on the sunward side, less than 6000 km from the nucleus, and extended in the north and east. The spatial distribution and photometric data suggest that large grains emitted from the nucleus at very low velocity were viewed.

Hanner, M. S.↗

The abundances of ethane and acetylene in the atmospheres of Jupiter and Saturn

The present determination of the stratospheric abundances of ethane and acetylene on Jupiter and Saturn on the basis of IR spectra near 780/cm uses atmospheric models whose thermal and density profiles have constant mixing ratios. The ratio of ethane to acetylene is noted to be insensitive to model atmosphere assumptions; it is 55 + or - 31 for Jupiter and 23 + or - 12 where model mixing ratios are uniform. Atmospheric model density profiles adapted from theoretical photochemical models are noted to also yield a higher ethane/acetylene ratios for Jupiter.

Noll, K. S.↗

Infrared spectroscopy of Jupiter and Saturn

The origin of carbon monoxide has been a puzzle for some time, and it has become apparent that CO serves as a tracer of disequilibrium processes in the Jovian atmosphere. High resolution spectra with a Fabry-Perot spectrometer was obtained. From a detailed synthetic spectral analysis of the CO line profiles, it was established that the CO is located in the troposphere of Jupiter. It must therefore be a product of convection upward from hotter levels in the deep atmosphere, and is not a product of infall of material from above the stratosphere. Six lines of CO in Saturn was detected, a surprising result because disequilibrium models predicted that the CO mixing ratio would be too low to be observable if upward convection is the dominant mechanism. Therefore several possibilities for the origin of the CO now exist, none completely satisfactory at this time.

Knacke, R. F.↗

The abundances of ethane to acetylene in the atmospheres of Jupiter and Saturn

The present determination of the stratospheric abundances of ethane and acetylene on Jupiter and Saturn on the basis of IR spectra near 780/cm uses atmospheric models whose thermal and density profiles have constant mixing ratios. The ratio of ethane to acetylene is noted to be insensitive to model atmosphere assumptions; it is 55 + or - 31 for Jupiter and 23 + or - 12 where model mixing ratios are uniform. Atmospheric model density profiles adapted from theoretical photochemical models are noted to also yield a higher ethane/acetylene ratios for Jupiter.

Noll, K. S.↗

Ground-based detection of water in Comet Halley

Gaseous water was detected in the coma of comet Halley. Emission was observed in the upsilon 1 + upsilon 3 band at 1.4 microns, and the upsilon 2 + upsilon 3 band at 1.9 microns. Based on the upsilon 1 + upsilon 3 band intensity, the mass loss rate is 2 times 10 to the 29th power molecules/sec (with an uncertainty of a factor of 2) on 29 Oct. 1985, marginally consistent with other detections. The method is applicable to observations of H2O in other fast-moving comets.

Knacke, R. F.↗

Detection of carbon monoxide in Saturn

The detection of CO in the atmosphere of Saturn is reported. Six spectral regions containing lines of the CO 1-0 vibration-rotation band near 4.7 microns are studied; three of the lines are free of blending and in effect attest to the presence of this molecule in Saturn's atmosphere. Consideration is given to the following CO sources: (1) rapid convection from the hot interior, and (2) the infall of oxygen-bearing material from outside.

Noll, Keith S.↗

The origin and vertical distribution of carbon monoxide in Jupiter

Six clearly-resolved lines of the CO 1-0 vibration-rotation band near 4.7 microns have been observed in Jupiter at a resolution of 0.07/cm. CO is not found to be concentrated in the stratosphere, but is shown to be present in the troposphere at a mole fraction of 1.6 + or - 0.3 x 10 to the -9th, suggesting that rapid vertical mixing is the source of CO. Results indicate that the global oxygen abundance in Jupiter's gaseous envelope below the cloud-forming regions must be near the solar value, and that intervening clouds with an optical depth of 0.5-4 are present above the line-forming region.

Noll, Keith S.↗

The ice band in IRAS 09371 + 1212

Spectra from 2 to 4 microns of the unusual IRAS source 09371 + 1212, a bipolar nebula, reveal a deep H2O ice absorption band near 3.1 microns. No long-wavelength wing is present, implying that the absorbing grain mantles are of high purity. The structure of the absorption feature is reasonably well modeled by a mixture of amorphous and crystalline H2O ice mantles on silicate grains, but discrepancies remain that could indicate other absorbers also.

Geballe, T. R.↗

Evidence for germane in Saturn

Observations in Saturn have prompted the development of an 0.4 + or - 0.2 ppb mole fraction for germane (GeH4) on the basis of the P- and R-branch lines' spectra. The presence of germane in Saturn implies a disequilibrium of the upper atmosphere by rapid vertical convection. It is suggested that future, more realistic radiative transfer models that include the effects of scattering within a cloud layer will probably only reduce the mole fraction presently derived for germane, by increasing the effective path length in a given atmospheric layer.

Noll, Keith S.↗

The 3.4 micrometer emission feature in Comet Halley

Several teams of ground based observers reported observations of the emission feature centered at 3.36 micrometers in comet Halley following its discovery by the Vega 1 spacecraft. The position and shape of the band indicate a superposition of emissions by C-H groups. But the mechanism for the excitation of these C-H3 groups is still not agreed upon. Three possibilities are summarized. Elucidation of the emission mechanism is needed to determine whether the source is predominately solid or gas. In addition, is it shown that the derived carbon abundance in Halley depends strongly on the assumed mechanism.

Brooke, Timothy Y.↗

The near-infrared polarization and color of Comet Halley: What can we learn about the grains

The near infrared polarization and JHK colors of light scattered by dust grains in comet Halley were measured over a wide range in phase angle and heliocentric distance. Colors were redder than solar with no statistically significant variation with phase angle, heliocentric distance, or pre- and post-perihelion. This suggests that the grain population did not change drastically over time and that the data may be combined and modeled. However, short term variations in visible polarization and dust albedo were seen in Halley. Also, near infrared colors became systematically bluer after the observations were completed. The near infrared colors of Halley fall in the range of those of other comets. The near infrared polarization is similar to the visible polarization of Halley and other comets in showing a negative branch at small phase angles and an approximately linear rise toward positive values at larger phase angles. Mie theory calculations and a size distribution based on spacecraft data were used to model the near infrared polarization and color of comet Halley. Numerous lines of evidence point to the presence of dark, absorbing, probably carbonaceous materials in comets.

Brooke, Timothy Y.↗

Infrared spectroscopy of Jupiter and Saturn

High resolution infrared spectoscopy provides unique insights into the chemistry and dynamics of the atmospheres of Jupiter and Saturn. The 5 micrometer spectral region, which is transparent to deep levels, is particularly useful for the identification of molecules that are present at very low (parts per billion) concentrations. These are tracers of convective and strongly non-equilibrium processes in the atmosphere. High resolution ground-based spectroscopy complements Voyager and Galileo measurements. Spectroscopy is sensitive to lower mixing levels for selected molecules, while the on-board mass spectrometers probe molecules that are spectroscopically inaccessible. Analysis and modeling of the 4.7 micrometer carbon monoxide in Jupiter was completed. CO is present at a mole fraction of 1.6 plus or minus 0.3 x 10 to the 9th power and concentrated in the troposphere. At this abundance, it must be convected upward from much deeper levels in Jupiter where the temperature is near 1100 K. Thus CO is a tracer of the deep atmosphere which is otherwise unobservable. The oxygen abundance in Jupiter (as measured by the CO abundance) is near solar. Chemical or physical process must deplete the major oxygen carrier, water. Germane, GeH4, was discovered on Saturn at amole fraction of 4 plus or minus 2 x 10 to the 10th power.

Knacke, Roger↗

Evidence for interstellar H2O in the Orion molecular cloud

A search for interstellar gas phase H2O in the infrared spectrum of the BN object in Orion is reported. There is absorption (S/N = 2-4) at the position of the nu3 1(01)-2(02) line of H2O at 3801.42/cm, the strongest expected H2O line. Statistical analysis of the spectrum provides corroborating evidence for other H2O lines. With an assumed H2O excitation temperature of 150 K, N(H2O) of 2.3 x 10 to the 17th/sq cm or less toward the BN object is derived. The H2O column density implies abundance ratios of (H2O)/(CO) = 0.01-0.08 or less and (HDO)/(H2O) = 0.8-3.0 x 10 to the -3rd or more. The gas-to-ice ratio is (H2O gas)/(H2O ice) = 0.06 with an estimated uncertainty of a factor of 5.

Knacke, R. F.↗

Arsine in Saturn and Jupiter

New spectra of Saturn and Jupiter are reported that show a prominent, heretofore unidentified absorption near 2126/cm. The observation is interpreted as unambiguous evidence for the presence of arsine, AsH3. The abundance of AsH3 appears to be almost a factor of two higher in Saturn than in Jupiter. The observed enrichments are consistent with the core instability model for the formation of giant planets. Models of arsenic chemistry that predict strong depletions of AsH3 at temperatures below 370 K are not consistent with the observations, suggesting that vertical convection or perhaps some other mechanism inhibits depletion. Arsenic is the first new element identified in a planetary atmosphere since germanium was found in Jupiter a decade ago.

Noll, Keith S.↗