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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Summary of Structural Alloy Compatibility in Supercritical CO2 at 450°-800°C

Supercritical CO2 (sCO2) is of interest as a working fluid for several concepts including the direct- fired Allam cycle as a low-emission fossil energy power cycle. Over the past 10 years, laboratory exposures at 300 bar sCO2 have found reasonably good compatibility for Ni-based alloys at <800°C, including an assessment of the sCO2 impact on room temperature mechanical properties after 750°C exposures. However, initial screening tests at 1 and 20 bar CO2 at 900°-1100°C showed poor compatibility for Ni-based alloys. In an open cycle, the introduction of 1%O2 and 0.1- 0.25%H2O impurities at 300 bar increased the reaction rates ≥2X at 750°C. At lower temperatures, steels are susceptible to C ingress and embrittlement. Creep-strength enhanced ferritic steels may be limited to <550°C and conventional stainless steels to <600°C. Two strategies to increase those temperatures are higher Ni and Cr alloying additions and Al- or Cr-rich coatings. Alloy 709 (Fe- 20Cr-25Ni) shows some promising results at 650°C in sCO2 but reaction rates were accelerated with the addition of O2 and H2O impurities. Pack aluminized and chromized Gr.91 (Fe-9Cr-1Mo) and type 316H stainless steel show some promise at 600°-650°C but further coating optimization is needed.

Pint, Bruce↗

Idaho National Laboratory Ten-Year Site Plan Project / Activity Description Document

This document describes the currently active and proposed infrastructure projects and activities listed in Appendix B of the Idaho National Laboratory 2015 2023 Ten-Year Site Plan (DOE/ID-11488) with project statuses as of August 2013. This document was produced in accordance with Contract Data Requirements List I.06.

99 GENERAL AND MISCELLANEOUS↗

Fusion Materials Research at Oak Ridge National Laboratory in Fiscal Year 2023

The materials science challenge of providing a suite of suitable materials to satisfy the technology to achieve fusion energy is addressed in this ORNL program. The inability of currently available materials and components to withstand the harsh fusion nuclear environment requires development of new materials, and an understanding of their response to the fusion environment. The overarching goal of the ORNL Fusion Materials program is to provide the applied materials science support and materials understanding to underpin the ongoing DOE Office of Science—Fusion Energy Sciences program, in parallel with developing the materials for fusion power systems. In this effort the program continues to be integrated both with the larger U.S. and international fusion materials communities and with the U.S. and international fusion design and technology communities. The excitement of this program comes from the priorities given to this subject in the two recent fusion reviews, by the FESAC and NAS committees. An important element of those recommendations is the support for pivoting the national R&D emphasis to the Fusion Materials and Technologies (FM&T), the long-advocated Fusion Prototypic Neutron Source, and for the Fusion Pilot Plant study that will help focus program direction and efforts. Furthermore, the surge of venture capital investment into the private fusion industry start-ups over the last few years is anticipated to help accelerate all aspects of the fusion energy development. This twelfth annual report of the ORNL (Oak Ridge National Laboratory) Fusion Reactor Materials Program summarizes the accomplishments in Fiscal Year 2023 (FY2023). The year was the first to return to full post-COVID-restriction operations, with students and international assignees no longer impacted by COVID restrictions, as in FY20-21-22. Following the pattern of planning used in this program, work for the year FY2023 focused on having the data and productivity to support a strong presence at the International Conference on Fusion Reactor Materials (ICFRM) 21, organized by Spain and occurred in October 2023. Twenty-nine ORNL-led abstracts were submitted, with all accepted. Four were invited presentations, nine contributed oral, fourteen posters, and two withdrawn due to unforeseen circumstances. Additionally, nine external abstracts with ORNL contributing authors were presented. These will be reported in the FY24 report next year.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Long-Term Evaluation of Remedial Technology Performance in the Laboratory: Multi-year Experimental Test Plan

An understanding of the long-term effectiveness of remediation technologies is central to sustainable environmental cleanup. Long-term experiments are valuable for reducing uncertainty and predicting remediation outcomes at scales required for regulatory compliance. However, these types of tests can be costly and challenging to interpret. Therefore, contaminated sites often rely on short-term laboratory experiments that may not account for the potentially significant effects of gradual, time- dependent processes governing contaminant retention, release, and species transformation. For example, short-term lab experiments (from months to a year) conducted with sediments from the unsaturated and saturated zones at the Hanford Site play an important role in initial evaluations of remediation technologies but cannot capture the full extent of time-dependent reactions, leaving uncertainties in field-scale deployment. Here, long-term testing will be conducted on select technologies based on their performance in short-term testing. The overall objective is to directly address the challenges described above by generating and analyzing data on long-term (2–10 years) efficacy of selected remediation technologies, integrating this understanding into models, and providing critical input for remediation planning, monitoring, and 5-year review cycles for field-implemented remedies. Specific objectives include: 1. Evaluating long-term efficiency of promising remedies under site-specific conditions. 2. Generating robust parameters for modeling, reducing uncertainty in predictive simulations. 3. Advancing integrated monitoring by combining geochemical and geophysical observations. 4. Informing field-scale implementation by incrementally advancing technologies, identifying failure mechanisms early, and prioritizing robust, cost-effective remedies. Through systematic evaluation of technologies in laboratory-scale column experiments, integrated monitoring, and modeling support, this project is designed to bolster confidence in the long-term robustness of selected technologies. The ultimate outcome is the identification and deployment of more reliable, cost-effective remedies that safeguard human health and the environment while reducing the uncertainties that have historically hindered cleanup progress at Hanford Site. An experimental approach was developed and initiated for long-term testing potentially up to 10 years. The table below summarizes the experimental approach developed for testing select technologies and presented in this multi-year experimental test plan.

54 ENVIRONMENTAL SCIENCES↗

Fusion Materials Research at Oak Ridge National Laboratory in Fiscal Year 2015

The realization of fusion energy is a formidable challenge with significant achievements resulting from close integration of the plasma physics and applied technology disciplines. Presently, the most significant technological challenge for the near-term experiments such as ITER, and next generation fusion power systems, is the inability of current materials and components to withstand the harsh fusion nuclear environment. The overarching goal of the Oak Ridge National Laboratory (ORNL) fusion materials program is to provide the applied materials science support and understanding to underpin the ongoing Department of Energy (DOE) Office of Science fusion energy program while developing materials for fusion power systems. In doing so the program continues to be integrated both with the larger United States (US) and international fusion materials communities, and with the international fusion design and technology communities.This document provides a summary of Fiscal Year (FY) 2015 activities supporting the Office of Science, Office of Fusion Energy Sciences Materials Research for Magnetic Fusion Energy (AT-60-20-10-0) carried out by ORNL. The organization of this report is mainly by material type, with sections on specific technical activities. Four projects selected in the Funding Opportunity Announcement (FOA) solicitation of late 2011 and funded in FY2012-FY2014 are identified by “FOA” in the titles. This report includes the final funded work of these projects, although ORNL plans to continue some of this work within the base program.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Metastable Radioxenon Verification Laboratory (MRVL) Year-End Report

This is the year end report that is due to the client. The MRVL system is designed to measure multiple radioxenon isotopes ( 135 Xe, 133 Xe, 133 mXe and 133 mXe) simultaneously. The system has 12 channels to load samples and make nuclear measurements. Although the MRVL system has demonstrated excellent stability in measurements of Xe-133 and Xe-135 over the year of evaluation prior to delivery, there has been concern about system stability over measurements performed on samples with orders of magnitude different radioactivity, and samples containing multiple isotopes. To address these concerns, a series of evaluation test have been performed at the end-user laboratory. The evaluation was performed in two separate phases. Phase 1 made measurements on isotopically pure Xe-133 from high radioactivity down to the system background levels of activity, addressing the potential count rate dependencies when activities change from extreme high to very low. The second phase performed measurements on samples containing multiple isotopes (Xe-135, Xe-133 and Xe-133m), and addressed concerns about the dependence of isotopic concentrations on the presence of additional isotopes. The MRVL showed a concentration dependence on the Xe-133 due to the amount of Xe-133m that was in the sample. The dependency is due to the decay of Xe-133m into Xe-133. This document focuses on the second phase and will address the analysis used to account for ingrowth of Xe-133 from Xe-133m.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Idaho National Laboratory 2015-2023 Ten-Year Site Plan

This Idaho National Laboratory (INL) Ten-Year Site Plan (TYSP) describes the strategy for accomplishing the long-term objective of sustaining the INL infrastructure to meet the Department of Energy Office of Nuclear Energy (DOE-NE) mission: to promote nuclear power as a resource capable of making major contributions in meeting the nation’s energy supply, environmental and energy security needs. This TYSP provides the strategy for INL to accomplish its mission by: (1) linking R&D mission goals to core capabilities and infrastructure requirements; (2) establishing a ten-year end-state vision for INL facility complexes; (3) identifying and prioritizing infrastructure needs and capability gaps; (4) establishing maintenance and repair strategies that allow for sustainment of mission-critical (MC) facilities; and (5) applying sustainability principles to each decision and action. The TYSP serves as the infrastructure-planning baseline for INL; and, though budget formulation documents are informed by the TYSP, it is not itself a budget document.

42 ENGINEERING↗

Sandia National Laboratories Ten-Year Site Plan (Fiscal Year 2016)

During the next 10 years, Sandia’s most critical investments are as follows: 1) Complete the Sandia Silicon Fabrication Revitalization (SSiFR) initiative to replace outdated microelectronics production tools, capital equipment, and processes at the Microsystems and Engineering Sciences Applications (MESA) Complex. 2) Plan, design, and construct the Rad Hard Foundry to sustain the microelectronics-trusted foundry capability in support of critical microsystems science and technology (S&T) for NNSA and SPP. 3) Plan, design, and construct the Weapons Engineering Facility (WEF) to recapitalize core NW capabilities in R&D facilities and excess major buildings that are at the end of their designed service lives. 4) Plan, design, and construct the Emergency Operations and Response Center (EORC) to provide emergency incident management from a modern facility that serves and supports both local and national response teams. 5) Continue to facilitate the deactivation and eventual renovation or demolition of Building 892, a 60-year old facility that is rapidly approaching functional obsolescence.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Fusion Materials Research at Oak Ridge National Laboratory in Fiscal Year 2014

The realization of fusion energy is a formidable challenge with significant achievements resulting from close integration of the plasma physics and applied technology disciplines. Presently, the most significant technological challenge for the near-term experiments such as ITER, and next generation fusion power systems, is the inability of current materials and components to withstand the harsh fusion nuclear environment. The overarching goal of the ORNL fusion materials program is to provide the applied materials science support and understanding to underpin the ongoing DOE Office of Science fusion energy program while developing materials for fusion power systems. In doing so the program continues to be integrated both with the larger U.S. and international fusion materials communities, and with the international fusion design and technology communities.

36 MATERIALS SCIENCE↗

Fusion Materials Research at Oak Ridge National Laboratory in Fiscal Year 2017

Achieving fusion energy presents a formidable challenge to the field of materials science, to provide a suite of suitable materials in close integration to the plasma physics and other applied technologies. The technological challenge presented by the planned fusion power systems is the inability of current materials and components to withstand the harsh fusion nuclear environment. The overarching goal of the ORNL fusion materials program is to provide the applied materials science support and materials understanding to underpin the ongoing DOE Office of Science fusion energy program in parallel with developing materials for fusion power systems. In this effort the program continues to be integrated both with the larger U.S. and international fusion materials communities and with the international fusion design and technology communities. This long-running ORNL program continues to pursue development of low activation structural materials such as the Reduced Activation Ferritic/Martensitic Steels, higher strength/higher creep resistant/coolant compatible/radiation tolerant advanced steels, and Silicon Carbide Composites. Focus tasks within the steels portfolio are development of Castable Nanostructured Alloys, exploratory work on Bainitic steels and liquid metal compatibility evaluations. Parallel to this is the increased emphasis on radiation effects, high heat flux testing and the development of refractory metals. This includes the use of an ORNL Plasma Arc Lamp facility adapted for the thermal testing of irradiated materials, the development and evaluation of new tungsten materials, and the study and understanding of the irradiation performance of tungsten. In each case the materials are being developed in a design-informed fashion where properties improvements are led by fusion-relevant design studies and directed at advancing the Technology Readiness Level of the material systems.

36 MATERIALS SCIENCE↗

Fusion Materials Research at Oak Ridge National Laboratory in Fiscal Year 2018

Achieving fusion energy presents a formidable challenge to the field of materials science, to provide a suite of suitable materials in close integration to the plasma physics and other applied technologies. The technological challenge presented by the conceptual future fusion power systems is the inability of current materials and components to withstand the harsh fusion nuclear environment.The overarching goal of the ORNL fusion materials program is to provide the applied materials science support and materials understanding to underpin the ongoing DOE Office of Science - Fusion Energy Sciences program, in parallel with developing materials for fusion power systems. In this effort the program continues to be integrated both with the larger U.S. and international fusion materials communities and with the international fusion design and technology communities.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Environmental Monitoring Report, Calendar year 2020. Knolls Laboratory and Kesselring Site

The results of the effluent and environmental monitoring programs at the Knolls Laboratory and Kesselring Site are summarized and assessed in this report. Tables 1 - 4 summarize the major elements of the environmental monitoring programs at each site. Information regarding the U.S. Department of Energy – Office of Environmental Management (DOE-EM) Separations Process Research Unit (SPRU) Disposition Project (SPRU DP), is also included in this report; however, the project was completed in 2020 and will no longer be reported in subsequent reports. DOE-EM will be continuing to perform other Decontamination & Decommissioning (D&D) work at Knolls Laboratory and Kesselring Site, which may require environmental monitoring, and will be included in this report, as warranted. Operations at the Knolls Laboratory, which includes SPRU and other DOE-EM activities, and the Kesselring Site continue to have no adverse effect on human health and the quality of the environment.

54 ENVIRONMENTAL SCIENCES↗

A Curious Year on Mars - Long-Term Thermal Trends for Mars Science Laboratory Rover's First Martian Year

By the time of this writing, Curiosity, the Mars Science Laboratory (MSL) Rover, has weathered four seasons in Gale Crater, just south of and approaching the foothills of the 5-km high Aeolis Mons, known as "Mount Sharp," at 4.59 deg south latitude. The mission design included a much broader latitude range of 30 deg north to 30 deg south constraining some of the Rover environmental requirements and operations. To date, Curiosity has relayed over 150 MB of thermal telemetry. Curiosity has relayed over 150 MB of thermal telemetry through four seasons. The trends and idiosyncrasies revealed through four seasons of telemetry from Mars are discussed. The better-characterized thermal environment allows for less conservatism in operational models and increases the amount of science data collection. Examples include: the elimination of overheating concerns for some cameras and the use of the previous sol's temperature telemetry along with the conservative soak temperature curve from the winter thermal model, to produce a custom heating prescription for the upcoming weeks thus increasing operation time and reducing heating times. This paper discusses the lessons learned for Rover operation as well as general idiosyncrasies discovered about the local environment-such as the effect of orientation on subsystem temperature variation, a regular morning and afternoon wind, ground and air microclimates with distinct temperature differences from other terrain, and how the Rover affects the local environment. This paper further documents and explains some of the interesting highs and lows of the temperature telemetry data as well as offers explanations for sudden temperature changes on board the Rover.

HRS↗

Mars Science Laboratory Observations of the 2018/Mars Year 34 Global Dust Storm

Mars Science Laboratory Curiosity rover observations of the 2018/Mars year 34 global/planet-encircling dust storm represent the first in situ measurements of a global dust storm with dedicated meteorological sensors since the Viking Landers. The Mars Science Laboratory team planned and executed a science campaign lasting approximately 100 Martian sols to study the storm involving an enhanced cadence of environmental monitoring using the rover's meteorological sensors, cameras, and spectrometers. Mast Camera 880-nanometer optical depth reached 8.5, and Rover Environmental Monitoring Station measurements indicated a 97 percent reduction in incident total ultraviolet solar radiation at the surface, 30 degrees Kelvin reduction in diurnal range of air temperature, and an increase in the semidiurnal pressure tide amplitude to 40 pascals. No active dust-lifting sites were detected within Gale Crater, and global and local atmospheric dynamics were drastically altered during the storm. This work presents an overview of the mission's storm observations and initial results.

Guzewich, Scott D.↗