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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Optimization of thermal protection systems for the space shuttle vehicle. Volume 1: Final report

A study performed to continue development of computational techniques for the Space Shuttle Thermal Protection System is reported. The resulting computer code was used to perform some additional optimization studies on several TPS configurations. The program was developed in Fortran 4 for the CDC 6400, and it was converted to Fortran 5 to be used for the Univac 1108. The computational methodology is developed in modular fashion to facilitate changes and updating of the techniques and to allow overlaying the computer code to fit into approximately 131,000 octal words of core storage. The program logic involves subroutines which handle input and output of information between computer and user, thermodynamic stress, dynamic, and weight/estimate analyses of a variety of panel configurations. These include metallic, ablative, RSI (with and without an underlying phase change material), and a thermodynamic analysis only of carbon-carbon systems applied to the leading edge and flat cover panels. Two different thermodynamic analyses are used. The first is a two-dimensional, explicit precedure with variable time steps which is used to describe the behavior of metallic and carbon-carbon leading edges. The second is a one-dimensional implicity technique used to predict temperature in the charring ablator and the noncharring RSI. The latter analysis is performed simply by suppressing the chemical reactions and pyrolysis of the TPS material.

Source record↗

Mass loss of TEOS-coated RCC subjected to the environment at the shuttle wing leading edge

Coated, reinforced carbon-carbon (RCC) is used for the leading edges of the Space Shuttle. The mass loss characteristics of RCC specimens coated with tetra-ethyl-ortho-silicate (TEOS) were determined for conditions which simulated the entry environment expected at the stagnation area of the wing leading edge. Maximum specimen temperature was 1632 K. Specimens were exposed for up to 100 missions. Stress levels up to 8.274 MPa caused an average increase in oxidation of 6 percent over unstressed specimens. Experimentally determined mass losses were compared with those predicted by an existing empirical analysis.

Stroud, C. W.↗

Nondestructive Evaluation for the Space Shuttle's Wing Leading Edge

The loss of the Space Shuttle Columbia highlighted concerns about the integrity of the Shuttle's thermal protection system, which includes Reinforced Carbon-Carbon (RCC) on the leading edge. This led NASA to investigate nondestructive evaluation (NDE) methods for certifying the integrity of the Shuttle's wing leading edge. That investigation was performed simultaneously with a large study conducted to understand the impact damage caused by errant debris. Among the many advanced NDE methods investigated for applicability to the RCC material, advanced digital radiography, high resolution computed tomography, thermography, ultrasound, acoustic emission and eddy current systems have demonstrated the maturity and success for application to the Shuttle RCC panels. For the purposes of evaluating the RCC panels while they are installed on the orbiters, thermographic detection incorporating principal component analysis (PCA) and eddy current array scanning systems demonstrated the ability to measure the RCC panels from one side only and to detect several flaw types of concern. These systems were field tested at Kennedy Space Center (KSC) and at several locations where impact testing was being conducted. Another advanced method that NASA has been investigating is an automated acoustic based detection system. Such a system would be based in part on methods developed over the years for acoustic emission testing. Impact sensing has been demonstrated through numerous impact tests on both reinforced carbon-carbon (RCC) leading edge materials as well as Shuttle tile materials on representative aluminum wing structures. A variety of impact materials and conditions have been evaluated including foam, ice, and ablator materials at ascent velocities as well as simulated hypervelocity micrometeoroid and orbital debris impacts. These tests have successfully demonstrated the capability to detect and localize impact events on Shuttle's wing structures. A first generation impact sensing system has been designed for the next Shuttle flight and is undergoing final evaluation for deployment on the Shuttle's first return to flight. This system will employ wireless accelerometer sensors that were qualified for other applications on previous Shuttle flights. These sensors will be deployed on the wing's leading edge to detect impacts on the RCC leading edge panels. The application of these methods will help to insure the continued integrity of the Shuttle wing's leading edge system as the Shuttle flights resume and until their retirement.

Eric I Madaras↗

The determination of aluminum, copper, iron, and lead in glycol formulations by atomic absorption spectroscopy

Initial screening tests and the results obtained in developing procedures to determine Al, Cu, Fe, and Pb in glycol formulations are described. Atomic absorption completion was selected for Cu, Fe and Pb, and after comparison with emission spectroscopy, was selected for Al also. Before completion, carbon, iron, and lead are extracted with diethyl dithio carbamate (DDC) into methyl isobutyl ketone (MIBK). Aluminum was also extracted into MIBK using 8-hydroxyquinoline as a chelating agent. As little as 0.02 mg/l carbon and 0.06 mg/l lead or iron may be determined in glycol formulations. As little as 0.3 mg/l aluminum may be determined.

Source record↗

Advanced X-Ray Inspection of Reinforced Carbon Composite Materials on the Orbiter Leading Edge Structural Subsystem (LESS)

The post return-to-flight (RTF) inspection methodology for the Orbiter Leading Edge Structural Subsystem (LESS) is currently being defined. Numerous NDT modalities and techniques are being explored to perform the flight-to-flight inspections of the reinforced carbon/carbon (RCC) composite material for impact damage, general loss of mass in the bulk layers, or other anomalous conditions that would pose risk to safe return upon re-entry. It is possible to have an impact upon ascent that is not visually observable on the surface, yet causes internal damage. Radiographic testing may be a useful NDT technique for such occurrences. The authors have performed radiographic tests on full-sized mock samples of LESS hardware with embedded image quality phantoms. Digitized radiographic film, computed radiography and flat panel digital real-time radiography was acquired using a GE Eresco 200 x-ray tube, and Se-75 and Yb-169 radioisotopes.

Hernandez, Jose M.↗

Implications of Climate Mitigation for Future Agricultural Production

Climate change is projected to negatively impact biophysical agricultural productivity in much of the world. Actions taken to reduce greenhouse gas emissions and mitigate future climate changes, are thus of central importance for agricultural production. Climate impacts are, however, not unidirectional; some crops in some regions (primarily higher latitudes) are projected to benefit, particularly if increased atmospheric carbon dioxide is assumed to strongly increase crop productivity at large spatial and temporal scales. Climate mitigation measures that are implemented by reducing atmospheric carbon dioxide concentrations lead to reductions both in the strength of climate change and in the benefits of carbon dioxide fertilization. Consequently, analysis of the effects of climate mitigation on agricultural productivity must address not only regions for which mitigation is likely to reduce or even reverse climate damages. There are also regions that are likely to see increased crop yields due to climate change, which may lose these added potentials under mitigation action. Comparing data from the most comprehensive archive of crop yield projections publicly available, we find that climate mitigation leads to overall benefits from avoided damages at the global scale and especially in many regions that are already at risk of food insecurity today. Ignoring controversial carbon dioxide fertilization effects on crop productivity, we find that for the median projection aggressive mitigation could eliminate approximately 81% of the negative impacts of climate change on biophysical agricultural productivity globally by the end of the century. In this case, the benefits of mitigation typically extend well into temperate regions, but vary by crop and underlying climate model projections. Should large benefits to crop yields from carbon dioxide fertilization be realized, the effects of mitigation become much more mixed, though still positive globally and beneficial in many food insecure countries.

Mueller, Christoph↗

Isolating the Impacts of Soil Moisture Initialization on Land Carbon Fluxes at the Sub-Seasonal to Seasonal Scale

Soil moisture, through its impact on transpiration, plays a significant role in controlling the productivity of terrestrial vegetation. Initial soil moisture conditions in a seasonal forecast may therefore affect the forecast of land carbon uptake. Here we investigate the relative impacts of soil moisture initialization and carbon reservoir initialization on forecasts of land carbon fluxes at the sub-seasonal to seasonal (S2S) scale. The bias-corrected, retrospective meteorology of NASA Global Modeling and Assimilation Office (GMAO)’s S2S ensemble forecast was used to force the stand-alone Catchment-CN model and thereby estimate terrestrial carbon responses out to nine lead months. Our results show that soil moisture initialization is a major contributor (approximately 44%) to the high global carbon uptake forecast skill seen during the first three lead months. The carbon reservoir initialization explains roughly another half of the monthly carbon forecast skill during this period and becomes relatively more important at longer leads (while the overall forecast skill decreases after the 3 lead month), suggesting a slower but longer-lasting influence of carbon reservoir initialization on carbon fluxes. Our results highlight the significance of a good soil moisture initialization for improved forecasts of carbon fluxes at leads of several months, further support for the usefulness of assimilating the satellite based soil moisture information into terrestrial biosphere models and of a short term carbon forecast to understand current events with often a lag in the availability of flux estimates.

Land carbon↗

Shuttle Wing Leading Edge Root Cause NDE Team Findings and Implementation of Quantitative Flash Infrared Thermography

Comparison metrics can be established to reliably and repeatedly establish the health of the joggle region of the Orbiter Wing Leading Edge reinforced carbon carbon (RCC) panels. Using these metrics can greatly reduced the man hours needed to perform, wing leading edge scanning for service induced damage. These time savings have allowed for more thorough inspections to be preformed in the necessary areas with out affecting orbiter flow schedule. Using specialized local inspections allows for a larger margin of safety by allowing for more complete characterizations of panel defects. The presence of the t-seal during thermographic inspection can have adverse masking affects on ability properly characterize defects that exist in the joggle region of the RCC panels. This masking affect dictates the final specialized inspection should be preformed with the t-seal removed. Removal of the t-seal and use of the higher magnification optics has lead to the most effective and repeatable inspection method for characterizing and tracking defects in the wing leading edge. Through this study some inadequacies in the main health monitoring system for the orbiter wing leading edge have been identified and corrected. The use of metrics and local specialized inspection have lead to a greatly increased reliability and repeatable inspection of the shuttle wing leading edge.

Burke, Eric R.↗

Quasi-Static 3-Point Reinforced Carbon-Carbon Bend Test and Analysis for Shuttle Orbiter Wing Leading Edge Impact Damage Thresholds

Static 3-point bend tests of Reinforced Carbon-Carbon (RCC) were conducted to failure to provide data for additional validation of an LS-DYNA RCC model suitable for predicting the threshold of impact damage to shuttle orbiter wing leading edges. LS-DYNA predictions correlated well with the average RCC failure load, and were good in matching the load vs. deflection. However, correlating the detectable damage using NDE methods with the cumulative damage parameter in LS-DYNA material model 58 was not readily achievable. The difficulty of finding internal RCC damage with NDE and the high sensitivity of the mat58 damage parameter to the load near failure made the task very challenging. In addition, damage mechanisms for RCC due to dynamic impact of debris such as foam and ice and damage mechanisms due to a static loading were, as expected, not equivalent.

Fasanella, Edwin L.↗

Carbon Dioxide Removal via Passive Thermal Approaches

A paper describes a regenerable approach to separate carbon dioxide from other cabin gases by means of cooling until the carbon dioxide forms carbon dioxide ice on the walls of the physical device. Currently, NASA space vehicles remove carbon dioxide by reaction with lithium hydroxide (LiOH) or by adsorption to an amine, a zeolite, or other sorbent. Use of lithium hydroxide, though reliable and well-understood, requires significant mass for all but the shortest missions in the form of lithium hydroxide pellets, because the reaction of carbon dioxide with lithium hydroxide is essentially irreversible. This approach is regenerable, uses less power than other historical approaches, and it is almost entirely passive, so it is more economical to operate and potentially maintenance- free for long-duration missions. In carbon dioxide removal mode, this approach passes a bone-dry stream of crew cabin atmospheric gas through a metal channel in thermal contact with a radiator. The radiator is pointed to reject thermal loads only to space. Within the channel, the working stream is cooled to the sublimation temperature of carbon dioxide at the prevailing cabin pressure, leading to formation of carbon dioxide ice on the channel walls. After a prescribed time or accumulation of carbon dioxide ice, for regeneration of the device, the channel is closed off from the crew cabin and the carbon dioxide ice is sublimed and either vented to the environment or accumulated for recovery of oxygen in a fully regenerative life support system.

Lawson, Michael↗

Enhanced Weathering Strategies for Stabilizing Climate and Averting Ocean Acidification

Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m(exp -2) yr (exp -1)) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.

Taylor, Lyla L.↗

Enhanced Weathering Strategies for Stabilizing Climate and Averting Ocean Acidification - Supplementary Information

Chemical breakdown of rocks, weathering, is an important but very slow part of the carbon cycle that ultimately leads to CO2 being locked up in carbonates on the ocean floor. Artificial acceleration of this carbon sink via distribution of pulverized silicate rocks across terrestrial landscapes may help offset anthropogenic CO2 emissions. We show that idealized enhanced weathering scenarios over less than a third of tropical land could cause significant drawdown of atmospheric CO2 and ameliorate ocean acidification by 2100. Global carbon cycle modelling driven by ensemble Representative Concentration Pathway (RCP) projections of twenty-first-century climate change (RCP8.5, business-as-usual; RCP4.5, medium-level mitigation) indicates that enhanced weathering could lower atmospheric CO2 by 30-300 ppm by 2100, depending mainly on silicate rock application rate (1 kg or 5 kg m(exp. -2) yr (exp -1)) and composition. At the higher application rate, end-of-century ocean acidification is reversed under RCP4.5 and reduced by about two-thirds under RCP8.5. Additionally, surface ocean aragonite saturation state, a key control on coral calcification rates, is maintained above 3.5 throughout the low latitudes, thereby helping maintain the viability of tropical coral reef ecosystems. However, we highlight major issues of cost, social acceptability, and potential unanticipated consequences that will limit utilization and emphasize the need for urgent efforts to phase down fossil fuel emissions.

Taylor, Lyla L.↗

Results of the TTF-TCNQ and the calcium carbonate crystallization on the Long Duration Exposure Facility

Experiment A0139A on the Long Duration Exposure Facility (LDEF) carried four large containers into orbit five years with crystal growth solutions for lead sulfide, calcium carbonate, and TTF-TCNQ. Although temperature data was lost, the experimental program had been working since the valves in all containers had been opened. All four experiments produced crystals of varying quality. The calcium carbonate crystals had the best appearance. The TTF-TCNQ crystals were packed together near the valve openings of the container. When taken apart, the single crystals showed some unusual morphological properties. X ray investigations as well as conductivity measurements on long duration space grown TTF-TCNQ crystals will be presented. Comparisons will be made with our previous space solution growth experiments. The TTF-TCNQ crystals are no longer of the highest interest, so this activity has been terminated in favor of calcium carbonate and calcium phosphate crystallizations.

Nielsen, Kjeld Flemming↗

Results of the TTF-TCNQ- and the calcium carbonate-crystallization on the Long Duration Exposure Facility

Experiment AO139A on the Long Duration Exposure Facility (LDEF) carried four large containers into orbit for five years with crystal growth solutions for lead sulfide, calcium carbonate, and tetra thiafulvalene- tetra cyanoquino methane (TTF-TCNQ). The LDEF was in excellent condition after the long orbital stay, and although the temperature data was lost, the experiment program had been working since the valves in all containers were opened. All four experiments produced crystals; however, they were of varying quality. The calcium carbonate crystals had the best appearance. The TTF-TCNQ crystals were packed together near the valve openings of the container. When taken apart, the single crystals showed some unusual morphological properties. X-ray investigations as well as conductivity measurements on the long duration space grown TTF-TCNQ crystals are presented, and pictures of the calcium carbonate are shown. Comparisons are made with previous space solution growth experiments on the European Spacelab Mission and the Apollo-Soyuz Test Project.

Nielsen, Kjeld Flemming↗

Sedimentology and geochemistry of a perennially ice-covered epishelf lake in Bunger Hills Oasis, East Antarctica

A process-oriented study was carried out in White Smoke lake, Bunger Hills, East Antarctica, a perennially ice-covered (1.8 to 2.8 m thick) epishelf (tidally-forced) lake. The lake water has a low conductivity and is relatively well mixed. Sediments are transferred from the adjacent glacier to the lake when glacier ice surrounding the sediment is sublimated at the surface and replaced by accumulating ice from below. The lake bottom at the west end of the lake is mostly rocky with a scant sediment cover. The east end contains a thick sediment profile. Grain size and delta 13C increase with sediment depth, indicating a more proximal glacier in the past. Sedimentary 210Pb and 137Cs signals are exceptionally strong, probably a result of the focusing effect of the large glacial catchment area. The post-bomb and pre-bomb radiocarbon reservoirs are c. 725 14C yr and c. 1950 14C yr, respectively. Radiocarbon dating indicates that the east end of the lake is >3 ka BP, while photographic evidence and the absence of sediment cover indicate that the west end has formed only over the last century. Our results indicate that the southern ice edge of Bunger Hills has been relatively stable with only minor fluctuations (on the scale of hundreds of metres) over the last 3000 years.

Non-NASA Center↗

Tracing the Path of Carbon Export in the Ocean though DNA Sequencing of Individual Sinking Particles

Surface phytoplankton communities were linked with the carbon they export into the deep ocean by comparing 18 S rRNA gene sequence communities from surface seawater and individually isolated sinking particles. Particles were collected in sediment traps deployed at locations in the North Pacific subtropical gyre and the California Current. DNA was isolated from individual particles, bulk-collected trap particles, and the surface seawater. The relative sequence abundance of exported phytoplankton taxa in the surface water varied across functional groups and ecosystems. Of the sequences detected in sinking particles, about half were present in large (>300 μm), individually isolated particles and primarily belonged to taxa with small cell sizes (<50 μm). Exported phytoplankton taxa detected only in bulk trap samples, and thus presumably packaged in the smaller sinking size fraction, contained taxa that typically have large cell sizes (>500 m). The effect of particle degradation on the detectable 18 S rRNA gene community differed across taxa, and differences in community composition among individual particles from the same location largely reflected differences in relative degradation state. Using these data and particle imaging, we present an approach that incorporates genetic diversity into mechanistic models of the ocean's biological carbon pump, which will lead to better quantification of the ocean’s carbon cycle.

Carbon Expert↗

Accreting white dwarf models for type 1 supernovae. 1: Presupernova evolution and triggering mechanisms

As a plausible explosion model for a Type I supernova, the evolution of carbon-oxygen white dwarfs accreting helium in binary systems was investigated from the onset of accretion up to the point at which a thermonuclear explosion occurs. The relationship between the conditions in the binary system and the triggering mechanism for the supernova explosion is discussed, especially for the cases with relatively slow accretion rate. It is found that the growth of a helium zone on the carbon-oxygen core leads to a supernova explosion which is triggered either by the off-center helium detonation for slow and intermediate accretion rates or by the carbon deflagration for slow and rapid accretion rates. Both helium detonation and carbon deflagration are possible for the case of slow accretion, since in this case the initial mass of the white dwarf is an important parameter for determining the mode of ignition. Finally, various modes of building up the helium zone on the white dwarf, namely, direct transfer of helium from the companion star and the various types and strength of the hydrogen shell flashes are discussed in some detail.

Nomoto, K.↗

Test-Analysis Correlation for Space Shuttle External Tank Foam Impacting RCC Wing Leading Edge Component Panels

The Space Shuttle Columbia Accident Investigation Board recommended that NASA develop, validate, and maintain a modeling tool capable of predicting the damage threshold for debris impacts on the Space Shuttle Reinforced Carbon-Carbon (RCC) wing leading edge and nosecap assembly. The results presented in this paper are one part of a multi-level approach that supported the development of the predictive tool used to recertify the shuttle for flight following the Columbia Accident. The assessment of predictive capability was largely based on test analysis comparisons for simpler component structures. This paper provides comparisons of finite element simulations with test data for external tank foam debris impacts onto 6-in. square RCC flat panels. Both quantitative displacement and qualitative damage assessment correlations are provided. The comparisons show good agreement and provided the Space Shuttle Program with confidence in the predictive tool.

Lyle, Karen H.↗