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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Development of a kinetic-thermodynamic model for lime-stabilization of Na-bentonite

This study presents the first kinetic model to predict the solid and pore solution composition of Na-bentonite clay reacting with slaked lime over a period of 720 days. The model successfully accounts for most experimental data using a single kinetic rate constant. The following sequence of reactions was predicted by the model: initial rapid dissolution of portlandite within the first 7 days, leading to a decrease in pH and dissolved calcium, and concurrent formation of calcium silicate hydrates (C-S-H: jennite), calcium aluminate hydrate (C-A-H: C₄AH₁₃), calcium aluminosilicate hydrates (stratlingite) and hydrotalcite. After 7 days, jennite and stratlingite are predicted to transform into tobermorite-II, contributing to strength development up to 28 days. From 28 to 90 days, continued montmorillonite dissolution is predicted, along with minor formation of ettringite, partial tobermorite-II dissolution, and precipitation of secondary phases such as albite and talc. Experimentally, portlandite dissolution was confirmed by TGA and XRD and found to be complete within 7 days, in agreement with model predictions. However, other predicted solid-phase transformations (e.g., tobermorite-II formation and dissolution, ettringite, albite, and talc formation) could not be conclusively verified through experimental techniques. Aqueous phase measurements confirmed that the pH and Ca trends in solution, and that equilibrium was reached by 90 days.

Chemical kinetics↗
DOE OSTI2012

Energy Efficient Microwave Hybrid Processing of Lime for Cement, Steel, and Glass Industries

In this study, the microwave materials interactions were studied through dielectric property measurements, process modeling, and lab scale microwave hybrid calcination tests. Characterization and analysis were performed to evaluate material reactions and energy usage. Processing parameters for laboratory scale and larger scale calcining experiments were developed for MAT limestone calcination. Early stage equipment design concepts were developed, with a focus on microwave post heating treatment. The retrofitting of existing rotary calcine equipment in the lime industry was assessed and found to be feasible. Ceralink sought to address some of the major barriers to the uptake of MAT identified as the need for (1) team approach with end users, technology partners, and equipment manufacturers, (2) modeling that incorporates kiln materials and variations to the design of industrial microwave equipment.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Optical Response of Soda-Lime Glass Shocked to 14 GPa

To investigate the potential use of soda-lime glass (SLG) as an optical window in shock wave experiments, laser interferometry (VISAR) was used to determine the window correction and the refractive index in SLG samples subjected to plane shock wave compression. Symmetric plate impact experiments were conducted at peak stresses varying between 4 and 14 GPa and laser interferometry ($λ_0$ = 532$\textit {nm}$ wavelength) measurements were used to monitor the particle velocity histories at the impact surface. The higher stress experiments displayed a constant state prior to stress unloading. In contrast, the lower stress experiments (4.3 and 7.8 GPa) displayed an initial constant state followed by weakly time-dependent response prior to stress unloading. Because the actual particle velocities were independently known from the projectile velocity measurements, the window correction factor and the refractive index changes were determined over the stress range examined. Above 7.5 GPa, our window correction and refractive index results show significant differences with previously published data for the same material. Potential reasons for these differences are indicated.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Influence of acid leaching surface treatment on indentation cracking of soda lime silicate glass

Past work has shown that water or acid soaking treatments can increase the mechanical strength of soda lime silicate (SLS) glasses. In this work, we show that acid leaching treatments result in an increase in the apparent crack resistance of the acid-leached surface of SLS glass during indentation. Vickers indentation tests in controlled environments show a humidity dependence of radial cracking, suggesting that the transport of water through the leached layer plays a critical role in the propagation of cracks to the glass surface. Here, molecular dynamics simulations with reactive force fields indicate that the leached surface layer can undergo pressure-induced mechanochemical reactions during indentation, which increases the bridging oxygen connectivity in the silica network of the leached layer. Such structural changes can hinder transport of water molecules from the environment to the subsurface crack tip. Based on experimental observations and simulation results, a new hypothesis is proposed that mechanochemical restructuring in the leached layer in response to the applied load may lower the transport kinetics of molecular water to critical flaws, resulting in an apparent enhancement in the crack resistance of the acid-leached surface of SLS glass.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Nonlinear relationship between the Product Consistency Test (PCT) response and the Al/B ratio in a soda-lime aluminoborosilicate glass

We have investigated the effect of A1/B ratio on the Product Consistency Test (PCT) response. In an aluminoborosilicate soda-lime glass based on a modified International Simple Glass, ISG-3, the A1/B ratio varied from 0 to 0.55 (in mole fractions). In agreement with various models of the PCT response as a function of glass composition, we observed a monotonic increase of B and Na releases with decreasing A1/B mole ratio, but only when the ratio was higher than 0.05. Below this value (A1/B < 0.05), we observed a sharp decrease that we attribute to B in tetrahedral coordination.

Al↗
DOE OSTI2018

The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent

This study focuses on the use of raw fly ash (FA) and modified fly ash – activated by lime (MFA), as effective and low-cost adsorbents for the removal of heavy metals (Zn2+, Pb2+and As(V)), followed by the revalorization of the exhausted adsorbent. The granulometric, elemental analysis, point of zero charge (pHPZC), radiochemical and structural characterization were conducted using X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and gamma spectrometry techniques. The optimal conditions and key factors influencing the adsorption process were assessed using the response surface method (RSM). The adsorption capacity of the MFA adsorbent for Zn2+, Pb2+and As(V) removal, calculated by the Langmuir model, was found to be 33.13, 26.06, and 29.71 mg g−1, respectively. The kinetic and thermodynamic parameters indicated that the adsorption process is spontaneous and endothermic. Due to their low desorption potential of the exhausted adsorbents, their effective reuse was established to be feasible. For this reason, the valorization of this material as an additive in construction materials was thereafter studied, where testing its toxicity leaching (TCLP) as well as the mechanical properties of construction material containing exhausted MFA confirmed its safe use. Hence, this study points to a possible “two-in-one” reuse of coal ash, initially as an adsorbent and later as an additive in a construction material.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2012

Formation of silver nanoparticles inside a soda-lime glass matrix in the presence of a high intensity Ar{sup +} laser beam

Formation and motion of the silver nanoparticles inside an ion-exchanged soda-lime glass in the presence of a focused high intensity continuous wave Ar{sup +} laser beam (intensity: 9.2 x 10{sup 4} W/cm{sup 2}) have been studied in here. One-dimensional diffusion equation has been used to model the diffusion of the silver ions into the glass matrix, and a two-dimensional reverse diffusion model has been introduced to explain the motion of the silver clusters and their migration toward the glass surface in the presence of the laser beam. The results of the mentioned models were in agreement with our measurements on thickness of the ion-exchange layer by means of optical microscopy and recorded morphology of the glass surface around the laser beam axis by using a Mirau interferometer. SEM micrographs were used to extract the size distribution of the migrated silver particles over the glass surface.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Improvement in hardness of soda-lime-silica glass

Hardness is a key design parameter for structural application of brittle solids like glass. Here we report for the first time the significant improvement of about 10% in Vicker's hardness of a soda-lime-silica glass with loading rate in the range of 0.1-10 N.s{sup -1}. Corroborative dark field optical and scanning electron microscopy provided clue to this improvement through evidence of variations in spatial density of shear deformation band formation as a function of loading rate.

36 MATERIALS SCIENCE↗
DOE OSTI2013

A comparison of ZnO films deposited on indium tin oxide and soda lime glass under identical conditions

ZnO films have been grown via a vapour phase transport (VPT) on soda lime glass (SLG) and indium-tin oxide (ITO) coated glass. ZnO film on ITO had traces of Zn and C which gives them a dark appearance while that appears yellowish-white on SLG. X-ray photoelectron spectroscopy studies confirm the traces of C in the form of C-O. The photoluminescence studies reveal a prominent green luminescence band for ZnO film on ITO.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Generation of alkali-free and high-proton concentration layer in a soda lime glass using non-contact corona discharge

Formation mechanisms of alkali-free and high-proton concentration surfaces were investigated for a soda lime glass using a corona discharge treatment under an atmospheric pressure. Protons produced by high DC voltage around an anode needle electrode were incorporated into a sodium ion site in the anode side glass. The sodium ion was swept away to the cathode side as a charge carrier. Then it was discharged. The precipitated sodium was transformed to a Na{sub 2}CO{sub 3} powder when the surface contacted with air. The sodium ion in the glass surface layer of the anode side was replaced completely by protons. The concentration of OH groups in the layer was balanced with the amount of excluded sodium ions. The substitution reaction of sodium ions with protons tends to be saturated according to a square root function of time. The alkali depletion layer formation rate was affected by the large difference in mobility between sodium ions and protons in the glass.

36 MATERIALS SCIENCE↗
DOE OSTI2015

On how differently the quasi-harmonic approximation works for two isostructural crystals: Thermal properties of periclase and lime

Harmonic and quasi-harmonic thermal properties of two isostructural simple oxides (periclase, MgO, and lime, CaO) are computed with ab initio periodic simulations based on the density-functional-theory (DFT). The more polarizable character of calcium with respect to magnesium cations is found to dramatically affect the validity domain of the quasi-harmonic approximation that, for thermal structural properties (such as temperature dependence of volume, V(T), bulk modulus, K(T), and thermal expansion coefficient, α(T)), reduces from [0 K-1000 K] for MgO to just [0 K-100 K] for CaO. On the contrary, thermodynamic properties (such as entropy, S(T), and constant-volume specific heat, C{sub V}(T)) are described reliably at least up to 2000 K and quasi-harmonic constant-pressure specific heat, C{sub P}(T), up to about 1000 K in both cases. The effect of the adopted approximation to the exchange-correlation functional of the DFT is here explicitly investigated by considering five different expressions of three different classes (local-density approximation, generalized-gradient approximation, and hybrids). Computed harmonic thermodynamic properties are found to be almost independent of the adopted functional, whereas quasi-harmonic structural properties are more affected by the choice of the functional, with differences that increase as the system becomes softer.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Hugoniot states and optical response of soda lime glass shock compressed to 120 GPa

In contrast to relatively pure silica glass (fused silica-FS), commercial silica-rich glasses contain significant fractions of additional oxide components. In particular, soda-lime glass (SLG) consists of approximately 71% SiO 2 by weight, which raises the question: what is the effect of additional cations on the shock compression response of silica-rich glasses? To address this concern, plate impact experiments were conducted to determine the high-pressure Hugoniot states for shocked SLG (37 to 120 GPa) and compared with recently reported results on FS. Using laser interferometry, particle velocity profiles were measured at the impact surface and the SLG/LiF window interface. In all experiments, the transmitted profiles show a single shock wave, with no features indicative of a phase transformation. The Hugoniot states determined from the wave profiles are described well using a linear shock velocity–particle velocity relation. Interferometry measurements (using 1550-nm wavelength laser) at the impact surface show that SLG is transparent when shocked to 55 GPa, transparent for tens of nanoseconds after impact between 55 and 81 GPa, and opaque beyond 81 GPa. From impact surface measurements, a linear relationship between the apparent and true particle velocity was observed, resulting in a linear relationship between the refractive index (at 1550 nm) and density. At 120 GPa, the SLG density is nearly twice its ambient value, indicating that SLG can achieve highly dense amorphous states. When compared to FS, shocked SLG is much less compressible and likely does not transform to a crystalline phase. A plausible explanation for this difference is indicated.

58 GEOSCIENCES↗
DOE OSTI2021

Probing the properties and mechanisms of failure waves in soda-lime glass

Soda-lime glass (SLG) and other silica glasses exhibit the failure wave phenomenon under shock compression. The mechanism responsible for this peculiar behavior of glasses is still unresolved. In this study, a series of plate impact experiments was performed at three different impact stresses of 6.4, 8.3, and 10.8 GPa to better understand the mechanisms underlying the failure wave phenomenon. Specifically, spall experiments were conducted to probe the speed and existence of failure waves at different stresses in SLG. A layered glass target was used to probe the possibility of a “renucleation” of the wave at the SLG–SLG interface. When it existed, the failure wave was inferred to propagate at a speed of 1.3 km/s. However, it was observed that the failure wave phenomenon ceases to exist for impact stresses higher than 10 GPa. In experiments with a 6.4 GPa impact stress, the peak free surface velocity was significantly less than what is predicted by stress-Hugoniot calculations. This velocity deficit and other important features of the measured free surface velocity profiles were simulated using finite element analysis by incorporating an abrupt densification of SLG at a critical stress in the equation of state. Furthermore, this densification feature is similar to what would be expected of a phase transition. Although unable to unambiguously reveal the mechanism causing the failure wave phenomenon, the results of the present work clearly indicate that the failure wave causes a secondary compression and densification in SLG.

36 MATERIALS SCIENCE↗
DOE OSTI2022

An investigation of shock-induced phase transition in soda-lime glass

There exists a large body of evidence from experiments and molecular dynamics simulations to suggest the occurrence of phase transitions in soda-lime glass (SLG) and other silica glasses subject to shock compression to pressures above 3 GPa. In light of these findings, the current work investigated the existence of phase transition in SLG using shock and release experiments. The experiments employed symmetric SLG–SLG impact to achieve complete unloading to zero stress after shock compression to stresses in the range of 3–7 GPa. The stress–strain response and the Lagrangian release wave speed behavior of SLG obtained from these experiments are seen to reveal a mismatch between the loading and unloading paths of the pressure–strain curve for the material, which serves as compelling evidence for the occurrence of a shock-induced phase transition in the material at relatively low pressures. Furthermore, the release wave speed vs strain data obtained from experiments were used to construct a methodology for modeling the shock and release behavior of SLG. Lastly, this scheme implemented in numerical simulations was able to capture the release behavior of shock compressed SLG, for which a robust and satisfactory model was previously unavailable.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Behavior of soda-lime silicate glass under laser-driven shock compression up to 315 GPa

Shock experiments give a unique insight into the behavior of matter subjected to extremely high pressures and temperatures. Understanding the behavior of materials under such extreme conditions is key to modeling material failure and deformation dynamics under impact. While studies on pure silica are extensive, the shock behavior of other commercial silicates that contain additional oxides has not been systematically investigated. To better understand the role of composition in the dynamic behavior of silicates, we performed laser-driven dynamic compression experiments on soda-lime glass (SLG) up to 315 GPa. Using the accurate pulse shaping offered by the long pulse laser system at the Matter in Extreme Conditions end-station at the Linac Coherent Light Source, SLG was shock compressed along the Hugoniot to multiple pressure-temperature points. Velocity Interferometer System for Any Reflector was used to measure the velocity and determine the pressure inside the SLG. The U s –u p relationship obtained agrees well with the previous parallel plate impact studies. Within the error bars, no transformation to the crystalline phase was observed up to 70 GPa, which is in contrast to the behavior of pure silica under shock compression. Our studies show that the glass composition strongly influences the shock compression behavior of the silicate glasses.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Sound velocities in shock-compressed soda lime glass: Melting and liquid-state response

Longitudinal sound velocities (and elastic moduli) were determined in soda lime glass (SLG) at peak shock stresses ranging between 40 and 90 GPa. Laser interferometry was used to obtain particle velocity histories and sound velocities by impacting SLG samples on lithium fluoride (LiF) optical windows. In all experiments, the SLG response consists of a sharp jump to a constant state followed by a release wave. The measured longitudinal sound velocities and moduli showed a marked decrease between 52 and 58 GPa, providing experimental evidence for the transformation from an amorphous solid to a liquid in shock-compressed SLG. Furthermore, the stress threshold (~55 GPa) for melting in SLG is considerably lower than the threshold reported in shock-compressed fused silica (~72 GPa), showing the effect of network-modifying cations on the onset of melting. The relative values of sound velocities, shock velocities, and the Hugoniot slopes—between 58 and 90 GPa—are fully consistent with the thermodynamic response of a shock-compressed liquid. Using the experimental results, the Grüneisen parameter (Γ) values were determined for liquid SLG to 90 GPa and then used to provide the Mie-Grüneisen equation of state for liquid SLG.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Analysis of Potential-Induced Degradation in Soda-Lime Glass and Borosilicate-Glass Cu(In,Ga)Se 2 Samples

In this study, potential-induced degradation (PID) is investigated in small-size Cu(In,Ga)Se 2 (CIGS) submodules of individual cells. Samples with conventional soda-lime glass (SLG) and low-alkaline glass (borosilicate glass, BSG) were analyzed applying positive and negative 1000 V bias at 85 degrees C and low relative humidity after a heat-soaking phase. During the heat-soaking phase, BSG samples showed degradation, with variations in their dark current-voltage (I-V) curve parameters compared with the stability of SLG samples. During the PID stress phase, back-grounded SLG samples with -1000 V applied to the cell experienced fast degradation, with complete failure in 25 h, whereas, BSG samples only showed changes because of the dark heat environment. When grounded on their front face, SLG samples remained stable during more than 150 h of PID testing, beginning degradation after longer applications of stress. The analysis of the dark I-V curves of SLG samples through the single-diode model showed that an increase in saturation current J 0 occurs first, attributed to Na + ions migrating into the CdS/ZnO layer; later, a decrease in shunt resistance occurs. Lastly, the application of the model in BSG samples showed an increase in series resistance evaluated at 25 degrees C. When the bias is reversed, SLG samples gradually recover their performance.

14 SOLAR ENERGY↗
DOE OSTI2018

Strategies for Lime Treatment Of D-Area Coal Storage Area (484-17D) Vadose Zone Soil

Sixty years of coal storage operations in the DCSA (484-17D, Figure 1) have resulted in vadose zone soils with a total acidity level typical of acid mine drainage soils. Field measurements from June 2018 show soil pH values ranging from 3 to 4.5 to water-table depth (10 to 12 feet). Best estimates for treatment of the acidic soils with dolomitic (agricultural) limestone suggest a required application rate ranging from 8 to 10 tons per acre per foot of soil depth to raise the soil pH from 3.5 to 5.5. The model predicts a lower bound of 3 tons per acre per foot for high-quality limestone with a particle size less than 60-mesh and an upper bound of 19 tons per acre per foot for lower-quality limestone. This compares to typical residential and agricultural lime application rates of one to four tons per acre per foot of depth.

01 COAL, LIGNITE, AND PEAT↗