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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Plasmon and exciton superconductivity mechanisms in layered structures

Plasmon and exciton superconductivity mechanisms are discussed. Superconductivity in a three layer metal semiconductor metal and insulator semimetal insulator sandwich structure was described in terms of the temperature dependent Green function of the longitudinal (Coulomb) field. The dependences of the superconducting transition temperature on structure parameters were obtained. In a semiconducting film, as a result of interactions of degenerate free carriers with excitons, superconductivity exists only in a certain range of parameter values, and the corresponding critical temperature is much lower than in the plasmon mechanism of superconductivity.

Gabovich, A. M.↗

Magnetic and Superconducting Properties of the Heterogeneous Layered Structures V/Fe{sub 0.7}V{sub 0.3}/V/Fe{sub 0.7}V{sub 0.3}/Nb and Nb/Ni{sub 0.65(0.81)}Cu{sub 0.35(0.19)}

The heterogeneous ferromagnetic–superconducting layered heterostructures V/Fe{sub 0.7}V{sub 0.3}/V/Fe{sub 0.7}V{sub 0.3}/Nb and Nb/Ni{sub 0.65(0.81)}Cu{sub 0.35(0.19)}, which contain magnetic clusters and ferromagnetic domains, are studied. The magnetic and superconducting properties of the structures depend on the magnetic-layer thickness, the magnetic field, and the time elapsed from structure preparation. We detected the interaction of clusters with a domain structure, diamagnetism and magnetization reversal of the magnetic layer during the superconducting transition in a ferromagnetic–superconducting heterostructure, and a superconducting transition in the magnetic layer. The magnetic and resistive properties of the heterostructures changed in several weeks and months.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Cone transitional boundary-layer structure at Me = 14.

Experimental results suggest that the boundary-layer mean profiles in hypersonic flows may be highly transitional in the outer part of the boundary layer before the transition process is detected at the surface. Means of determining the initial location where the transition process begins in the outer part of the boundary layer are considered.

Fischer, M. C.↗

Additive engineering for robust interphases to stabilize high-Ni layered structures at ultra-high voltage of 4.8 V

Nickel-rich layered cathode materials promise high energy density for next-generation batteries when coupled with lithium metal anodes. However, the practical capacities accessible are far less than the theoretical values due to their structural instability during cycling, especially when charged at high voltages. Here we demonstrate that stable cycling with an ultra-high cut-off voltage of 4.8 V can be realized by using an appropriate amount of lithium difluorophosphate in a common commercial electrolyte. The Li||LiNi 0.76 Mn 0.14 Co 0.10 O 2 cell retains 97% of the initial capacity (235 mAh g -1 ) after 200 cycles. The cycling stability is ascribed to the robust interphase on the cathode. It is formed by lithium difluorophosphate decomposition, which is facilitated by the catalytic effect of transition metals. The decomposition products (Li 3 PO 4 and LiF) form a protective interphase. This suppresses transition metal dissolution and cathode surface reconstruction. It also facilitates uniform Li distribution within the cathode, effectively mitigating the strain and crack formation.

25 ENERGY STORAGE↗

Remote sensing of seasonal distribution of precipitable water vapor over the oceans and inference of boundary layer structure

Over the ocean satellite infrared spectral measurements in the 18 micrometer water vapor band and the 11 micrometer window region were used to derive precipitable water vapor, w, in the atmosphere and the sea surface temperature, SST. Seasonal maps of w on the oceans derived from these data reveal the dynamical influence of the large scale atmospheric circulation. With the help of a model for the vertical distribution of water vapor, the configuration of the atmospheric boundary layer over the oceans can be inferred from w when the information of SST is combined. The gross seasonal mean structure of the boundary layer inferred in this fashion reveals the broad areas of the trade wind inversion and the convectively active areas such as the intertropical convergence zones.

Prabhakara, C.↗

Remote sensing of seasonal distribution of precipitable water vapor over the oceans and the inference of boundary-layer structure

From the depth of the water vapor spectral lines in the 8-9 micron window region, measured by the Nimbus 4 Infrared Interferometer Spectrometer (IRIS) with a resolution of about 3/cm, the precipitable water vapor over the oceans is remotely sensed. In addition the IRIS spectral data in the 11-13 micron window region have been used to derive the sea surface temperature (SST). Seasonal maps of w on the oceans deduced from the spectral data reveal the dynamical influence of the large-scale atmospheric circulation. With the help of a model for the vertical distribution of water vapor, the configuration of the atmospheric boundary layer over the oceans can be inferred from these remotely sensed w and SST. The gross seasonal mean structure of the boundary layer inferred in this fashion reveals the broad areas of trade wind inversion and the convectively active areas such as the ITCZ. The derived information is in reasonable agreement with some observed climatological patterns over the oceans.

Prabhakara, C.↗

Evaluation of Planetary Boundary Layer Structure from NASA Global Modeling and Assimilation Office’s Next Retrospective Analysis Product MERRA-21C

The Planetary Boundary Layer (PBL) is a complex interface between Earth’s surface and the atmosphere with high spatiotemporal variability in its characteristics, and accurate simulation and observation of the PBL has proven to be a challenge. In this study, we evaluate PBL structures from NASA Global Modeling and Assimilation Office (GMAO)’s next retrospective analysis product: the Goddard Earth Observing System Retrospective Analysis of the early 21st Century (GEOS-R21C), with 25-km horizontal resolution. The GEOS-R21C incorporates a wide range of observing systems and various improvements over previous GMAO reanalysis. We compare the PBL thermodynamic structure as well as PBL Height (PBLH) from GEOS-R21C with various PBL observations. For PBLH, definitions are different depending on each observing system. PBLHs derived from radiosonde observations and Global Navigation Satellite System Radio Occultation (GNSS RO) are based on bulk Richardson number and refractivity gradient, respectively. The results of the evaluation of PBL structure from GMAO’s next retrospective analysis product will be presented. In addition, comparison between near-real-time (NRT) commercial and NASA commercial GNSS RO PBLH will also be discussed.

Eun-Gyeong Yang↗

Boundary Layer Structures Over the Northwest Atlantic Derived From Airborne High Spectral Resolution Lidar and Dropsonde Measurements During the ACTIVATE Campaign

The Planetary Boundary Layer height (PBLH) is essential for studying PBL and ocean-atmosphere interactions. Marine PBL is usually defined to include a mixed layer (ML) and a capping inversion layer. The ML height (MLH) estimated from the measurements of aerosol backscatter by a lidar was usually compared with PBLH determined from radiosondes/dropsondes in the past, as the PBLH is usually similar to MLH in nature. However, PBLH can be much greater than MLH for decoupled PBL. Here, in this study, we evaluate the retrieved MLH from an airborne lidar (HSRL-2) by utilizing 506 co-located dropsondes during the ACTIVATE field campaign over the Northwest Atlantic from 2020 to 2022. First, we define and determine the MLH and PBLH from the temperature and humidity profiles of each dropsonde, and find that the MLH values from HSRL-2 and dropsondes agree well with each other, with a coefficient of determination of 0.66 and median difference of 18 m. In contrast, the HSRL-2 MLH data do not correspond to dropsonde-derived PBLH, with a median difference of -47 m. Therefore, we modify the current operational and automated HSRL-2 wavelet-based algorithm for PBLH retrieval, decreasing the median difference significantly to -8 m. Further data analysis indicates that these conclusions remain the same for cases with higher or lower cloud fractions, and for decoupled PBLs. These results demonstrate the potential of using HSRL-2 aerosol backscatter data to estimate both marine MLH and PBLH and suggest that lidar-derived MLH should be compared with radiosonde/dropsonde-determined MLH (not PBLH) in general.

54 ENVIRONMENTAL SCIENCES↗

A Superconducting Praseodymium Nickelate with Infinite Layer Structure

A variety of nickel oxide compounds have long been studied for their manifestation of various correlated electron phenomena. Recently, superconductivity was observed in nanoscale infinite layer nickelate thin films of Nd 0.8 Sr 0.2 NiO 2 , epitaxially stabilized on SrTiO 3 substrates via topotactic reduction from the perovskite precursor phase. In this paper, we present the synthesis and properties of PrNiO 2 thin films on SrTiO 3 . Upon doping in Pr 0.8 Sr 0.2 NiO 2 , we observe superconductivity with a transition temperature of 7–12 K and robust critical current density at 2 K of 334 kA/cm 2 . These findings indicate that superconductivity in the infinite layer nickelates is relatively insensitive to the details of the rare earth 4 f configuration. Furthermore, they motivate the exploration of a broader family of compounds based on two-dimensional NiO 2 planes, which will enable systematic investigation of the superconducting and normal state properties and their underlying mechanisms.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A Study of Layered Structural Configurations as Thermal and Impact Shielding of Lunar Habitats

The focus of this study is the analysis of a proposed multilayer material configuration as lunar habitat shielding so as to assess its ability to resist temperature extremes and impact. In order to resist this environmental hazard, the analysis will compare various configurations of potential shielding layers using both in-situ resource utilization (ISRU) and Earth-based materials. The technology for implementation of in-situ resources in construction is developing, though not yet able to produce a functional lunar habitat. As the lunar infrastructure is developed, ISRU techniques for manufacturing and construction may become more viable. Therefore, both types of materials are considered due to potential for application towards both near-term and long-term commencements of habitat construction. The thermal analysis in this paper utilizes the nonlinear heat equation to produce a depth-dependent temperature gradient from the habitat exterior to the interior that changes continuously with time during the lunar diurnal cycle. Static loading conditions meant to simulate the impact force of a 77.9 g meteorite were used to analyze the ability of a proposed multilayer shielding configuration to resist impact. A thermal stress analysis was performed to observe the effects of heat transfer through the proposed multilayer configuration. The results of this study should be useful in determining the potential for implementation of efficient shielding layers for the initial lunar base.

Layered systems↗

Derivation of generalized transition/boundary conditions for planar multiple-layer structures

Infinite-order generalized impedance boundary conditions (GIBCs) and generalized sheet transition conditions (GSTCs) for planar multilayer configurations are developed via the Taylor series expansion method. The conditions are derived in a matrix product form where each matrix corresponds to a specific layer. An overall composite boundary/transition condition is obtained by making finite-order approximations to the elements of each matrix for the cases of 'low-contrast' and 'high-contrast' material layers. The accuracy of the truncated boundary conditions is examined by comparing their implied reflection and transmission coefficients with the corresponding exact coefficients. Design curves are also given which relate the maximum order of the conditions required to simulate a coating or layer of specific thickness and contrast. Expressions are then derived for the reflection and transmission coefficients of the GIBC/GSTC sheets, and these are compared to exact coefficients to demonstrate the validity of the derived GIBCs/GSTCs.

Ricoy, M. A.↗

High Mobility Transport Layer Structures for Rhombohedral Si/Ge/SiGe Devices

An electronic device includes a trigonal crystal substrate defining a (0001) C-plane. The substrate may comprise Sapphire or other suitable material. A plurality of rhombohedrally aligned SiGe (111)-oriented crystals are disposed on the (0001) C-plane of the crystal substrate. A first region of material is disposed on the rhombohedrally aligned SiGe layer. The first region comprises an intrinsic or doped Si, Ge, or SiGe layer. The first region can be layered between two secondary regions comprising n+doped SiGe or n+doped Ge, whereby the first region collects electrons from the two secondary regions.

Choi, Sang Hyouk↗

Inference of the boundary layer structure over the oceans from satellite infrared measurements

Remote infrared spectral measurements in the 8-13 micron m window region, at a resolution about 3 cm/1, contain useful information about the water vapor and temperature stratification of the atmosphere within the first few kilometers above the water surface. Two pieces of information are retrieved from the spectral measurements: precipitable water vapor in the atmosphere, from the depth of the line structure between 8 and 9 micron m due to water vapor lines; and sea surface temperature, from the variation of brightness temperature between 11 and 13 micron m. Together, these two pieces of information can signify either the presence of a deep moist convective layer or the prevalence of stable conditions, such as caused by temperature inversions, which inhibit moist convection. A simple infrared radiative transfer model of the 9 micron m water vapor lines was developed to validate the method. With the help of this model and the Nimbus 4 infrared interferometer spectrometer data, a gross picture of the planetary boundary layer for different seasons over the global oceans is deduced. The important regions of the trade wind inversion and the intertropical convergence zones over all the oceans are clearly identified with this method. The derived information is in reasonable agreement with some observed climatological patterns over the oceans.

Prabhakara, C.↗

Study of the Atmospheric Boundary Layer Structure during AWAKEN (Final Report)

The American Wake Experiment (AWAKEN, https://openei.org/wiki/AWAKEN) is a collaborative, international field campaign funded by the Department of Energy (DOE) to study the dynamic and turbulent properties of wind farm wakes. The scope of the project ranges from studying individual turbine wakes, wake interactions within wind farms, to downstream wake effects of wind farms on the atmospheric boundary layer (ABL) and mesoscale environment. The latter effects influence the performance of wind farms deployed downwind and modify the weather and climate in the region. The focus of our project is on studying the mesoscale and boundary-layer effects of wind farms in more detail using advanced boundary-layer profiling facilities.

17 WIND ENERGY↗

Dropwindsonde observations of the mean boundary layer structure in the low-latitude Pacific during SOP-1

The low-level mean thermodynamic and wind profiles in the transition between the trade winds and the ICZ are described using the FGGE level II-b dropwindsonde data set collected during the period of SOP-1 (January 15-February 20, 1979). The results illustrate the influence of decaying midlatitude frontal systems in the northwesternmost region, the general tradelike nature of the eastern regions, and the highly convective nature of a region near the equator. Contrary to the results obtained with the traditional approach to the tropical boundary layer, the FGGE data indicate a trade inversion that remains quasi-horizontal in the north-south direction despite an equatorward decrease in its frequency of occurrence, indicating that subsidence may be more important in equatorial regions than was previously thought.

Firestone, James K.↗

Transient variation of martian ground-atmosphere thermal boundary layer structure.

Results of a numerical simulation of the diurnal redistribution of temperature by radiative and molecular-conductive processes in the Martian soil-atmosphere system. An attempt is made to assess the importance of atmospheric molecular conduction near the surface and to estimate the characteristic depth of the diurnal temperature wave. The computational results are found to indicate a dual structure in the diurnal temperature wave propagation pattern, with a diffusive-type wave in the lowest 150 m superimposed on a radiatively induced disturbance with a characteristic scale of 1.8 km. Atmospheric molecular thermal conduction typically accounts for about 15% of the total heating/cooling in the lowest 25 m. Thermal conduction in both the soil and atmosphere appears to be an important factor in the thermal coupling of these subsystems. A free-convection regime in the conduction layer is predicted by the model for about five hours of the Martian day.

Pallmann, A. J.↗