DOE OSTI2017
SiAlON ceramics, solid solutions based on the Si 3 N 4 structure, are important, lightweight structural materials with intrinsically high strength, high hardness, and high thermal and chemical stability. Described by the chemical formula β-Si 6–z Al z O z N 8–z , from a compositional viewpoint, these materials can be regarded as solid solutions between Si 3 N 4 and Al 3 O 3 N. A key aspect of the structural evolution with increasing Al and O (z in the formula) is to understand how these elements are distributed on the β-Si 3 N 4 framework. The average and local structural evolution of highly phase-pure samples of β-Si 6–z Al z O z N 8–z with z = 0.050, 0.075, and 0.125 are studied here, using a combination of X-ray diffraction, NMR studies, and density functional theory calculations. Synchrotron X-ray diffraction establishes sample purity and indicates subtle changes in the average structure with increasing Al content in these compounds. Solid-state magic-angle-spinning 27Al NMR experiments, coupled with detailed ab initio calculations of NMR spectra of Al in different AlO q N 4–q tetrahedra (0 ≤ q ≤ 4), reveal a tendency of Al and O to cluster in these materials. Independently, the calculations suggest an energetic preference for Al–O bond formation, instead of a random distribution, in the β-SiAlON system.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗