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Vibrational-rotational motion effect on electric and magnetic properties of diatomic molecules, calculating magnetic susceptibility and rotational magnetic moment
The ambiguities about geophysical implications based on the correlation of scalar magnetic anomalies and geological features were investigated. A method was developed to convert scalar magnetic anomalies into a map of the lateral variations of magnetic susceptibility of the lithosphere. This map is directly correlated with the causative sources. The method is based on spherical harmonic analysis of lateral variations seen on the scalar magnetic anomaly map and those of the lithospheric magnetic susceptibility. The harmonic coefficients are related through the fundamental causality relationship governing a magnetized body and its associated scalar magnetic anomaly. The main features of the resulting magnetic susceptibility anomalies are outlined.
The field-induced force density on a magnetic fluid is proportional to the magnetic susceptibility times the gradient of the magnetic field squared. The direction of the force is towards increasing magnetic field (positive gradient). Applying a magnetic field to a magnetic fluid will result in a force from all directions towards the location of peak field. Since the magnetic field is conservative and there are no magnetic monopoles, the net field-induced force on any fluid of constant susceptibly will be zero. The only manner to obtain a nonzero net field-induced force is to vary the susceptibility of the fluid. At the gas/liquid interface of liquid oxygen, the susceptibility varies drastically, and the exploitation of the resultant large net forces. An alternative method of varying the magnetic susceptibility is to vary the temperature of the fluid. The magnetic susceptibility of paramagnetic liquid oxygen obeys the Curie-Weiss law: it is inversely proportional to temperature. By applying a temperature gradient in the presence of a symmetric magnetic field, a nonzero net force results. Much of the theory of the so-called Magnetocaloric Effect has previously been developed for and applied to ferromagnetic fluids, or ferrofluids, but is readily applied to paramagnetic liquid oxygen.
The effect of spaceflight on starch development in soybean (Glycine max L., BRIC-03) and potato (Solanum tuberosum, Astroculture-05) was compared with ground controls by biophysical and biochemical measurements. Starch grains from plants from both flights were on average 20-50% smaller in diameter than ground controls. The ratio delta X/delta rho (delta X --difference of magnetic susceptibilities, delta rho--difference of densities between starch and water) of starch grains was ca. 15% and 4% higher for space-grown soybean cotyledons and potato tubers, respectively, than in corresponding ground controls. Since the densities of particles were similar for all samples (1.36 to 1.38 g/cm3), the observed difference in delta X/delta rho was due to different magnetic susceptibilities and indicates modified composition of starch grains. In starch preparations from soybean cotyledons (BRIC-03) subjected to controlled enzymatic degradation with alpha-amylase for 24 hours, 77 +/- 6% of the starch from the flight cotyledons was degraded compared to 58 +/- 12% in ground controls. The amylose content in starch was also higher in space-grown tissues. The good correlation between the amylose content and delta X/delta rho suggests, that the magnetic susceptibility of starch grains is related to their amylose content. Since the seedlings from the BRIC-03 experiment showed elevated post-flight ethylene levels, material from another flight experiment (GENEX) which had normal levels of ethylene was examined and showed no difference to ground controls in size distribution, density, delta X/delta rho and amylose content. Therefore the role of ethylene appears to be more important for changes in starch metabolism than microgravity. c2001 COSPAR. Published by Elsevier Science Ltd. All rights reserved.
The physical properties of the stone meteorites provide important clues to understanding the formation and physical evolution of material in the Solar protoplanetary disk as well providing indications of the properties of their asteroidal parent bodies. Knowledge of these properties is essential for modeling a number of Solar System processes, such as bolides in planetary atmospheres, the thermal inertia of atmosphereless solid body surfaces, and the internal physical and thermal evolution of asteroids and rock-rich icy bodies. In addition, insight into the physical properties of the asteroids is important for the design of robotic and crewed reconnaissance, lander, and sample return spacecraft missions to the asteroids. One key property is meteorite porosity, which ranges from 0% to more than 40%, similar to the range of porosities seen in asteroids. Porosity affects many of the other physical properties including thermal conductivity, speed of sound, deformation under stress, strength, and response to impact. As a result of the porosity, the properties of most stone meteorites differ significantly from those of compact terrestrial rocks, whose physical properties have been used in many models of asteroid behavior. A few physical properties, such as grain density, magnetic susceptibility, and heat capacity are not functions of porosity. Taken together, the grain density and the magnetic susceptibility can be used to classify unweathered or minimally weathered ordinary chondrites. This provides a rapid screening technique to identify heterogeneous samples, classify new samples, and identify misclassified meteorites or interlopers in strewn fields.
An effort is underway to develop a method of pumping small amounts of liquid oxygen by use of pulsed magnetic fields. This development is motivated by a desire to reduce corrosion and hazards of explosion and combustion by eliminating all moving pump parts in contact with the pumped oxygen. The method exploits the known paramagnetism of liquid oxygen. Since they both behave similarly, the existing theory of ferrofluids (liquids with colloidally suspended magnetic particles) is directly applicable to paramagnetic liquid oxygen. In general, the force density of the paramagnetic interaction is proportional to the magnetic susceptibility multiplied by the gradient of the square of the magnitude of the magnetic field. The local force is in the direction of intensifying magnetic field. In the case of liquid oxygen, the magnetic susceptibility is large enough that a strong magnetic-field gradient can lift the liquid in normal Earth gravitation.
The character of magnetic interactions in La-Sr-Cu-O and Y-Ba-Cu-O systems is of primary importance for analysis of high-T(sub c) superconductivity in these compounds. Neutron diffraction experiments showed the antiferromagnetic ground state for nonsuperconducting La2CuO4 and YBa2Cu3O6 with the strongest antiferromagnetic superexchange being in the ab plane. The nonsuperconducting '1-2-3' system has two Neel temperatures T sub N1 and T sub N2. The first one corresponds to the ordering of Cu atoms in the CuO2 planes; T sub N2 reflects the antiferromagnetic ordering of magnetic moments in CuO chains relatively to the moments in the planes T sub N1 and T sub N2 depend strongly on the oxygen content. Researchers describe magnetic interactions in high-T superconductors based on the Linear Muffin-Tin Orbitals (LMTO) band structure calculations. Exchange interaction parameters can be defined from the effective Heisenberg hamiltonian. When the magnetic moments are not too large, as copper magnetic moments in superconducting oxides, J sub ij parameters can be defined through the non-local magnetic susceptibility of spin restricted solution for the crystal. The results of nonlocal magnetic susceptibility calculations and the values of exchange interaction parameters for La CuO and YBa2Cu3O7 systems are given in tabular form. Strong anisotropy of exchange interactions in the ab plane and along the c axis in La2CuO4 is obviously seen. The value of Neel temperature found agrees well with the experimental data available. In the planes of '1-2-3' system there are quite strong antiferromagnetic Cu-O and O-O interaction which appear due to holes in oxygen subbands. These results are in line with the magnetic model of oxygen holes pairing in high-T(sub c) superconductors.
The character of magnetic interactions in La-Sr-Cu-O and Y-Ba-Cu-O systems is of primary importance for analysis of high-T(sub c) superconductivity in these compounds. Neutron diffraction experiments showed the antiferromagnetic ground state for nonsuperconducting La2CuO4 and YBa2Cu3O6 with the strongest antiferromagnetic superexchange being in the ab plane. The nonsuperconducting '1-2-3' system has two Neel temperatures T(sub N1) and T(sub N2). The first one corresponds to the ordering of Cu atoms in the CuO2 planes; T(sub N2) reflects the antiferromagnetic ordering of magnetic moments in CuO chains relatively to the moments in the planes T(sub N1) and T(sub N2) which depend strongly on the oxygen content. Researchers describe magnetic interactions in high-T superconductors based on the Linear Muffin-Tin Orbitals (LMTO) band structure calculations. Exchange interaction parameters can be defined from the effective Heisenberg Hamiltonian. When the magnetic moments are not too large, as copper magnetic moments in superconducting oxides, J(sub ij) parameters can be defined through the non-local magnetic susceptibility of spin restricted solution for the crystal. The results of nonlocal magnetic susceptibility calculations and the values of exchange interaction parameters for La CuO and YBa2Cu3O7 systems are given in tabular form. Strong anisotropy of exchange interactions in the ab plane and along the c axis in La2CuO4 is obviously seen. The value of Neel temperature found agrees well with the experimental data available. In the planes of '1-2-3' system there are quite strong antiferromagnetic Cu-O and O-O interaction which appear due to holes in oxygen subbands. These results are in line with the magnetic model of oxygen holes pairing in high-T(sub c) superconductors.
An improved readout scheme has been proposed for high-resolution thermometers, (HRTs) based on the use of superconducting quantum interference devices (SQUIDs) to measure temperature- dependent magnetic susceptibilities. The proposed scheme would eliminate counting ambiguities that arise in the conventional scheme, while maintaining the superior magnetic-flux sensitivity of the conventional scheme. The proposed scheme is expected to be especially beneficial for HRT-based temperature control of multiplexed SQUIDbased bolometer sensor arrays. SQUID-based HRTs have become standard for measuring and controlling temperatures in the sub-nano-Kelvin temperature range in a broad range of low-temperature scientific and engineering applications. A typical SQUIDbased HRT that utilizes the conventional scheme includes a coil wound on a core made of a material that has temperature- dependent magnetic susceptibility in the temperature range of interest. The core and the coil are placed in a DC magnetic field provided either by a permanent magnet or as magnetic flux inside a superconducting outer wall. The aforementioned coil is connected to an input coil of a SQUID. Changes in temperature lead to changes in the susceptibility of the core and to changes in the magnetic flux detected by the SQUID. The SQUID readout instrumentation is capable of measuring magnetic-flux changes that correspond to temperature changes down to a noise limit .0.1 nK/Hz1/2. When the flux exceeds a few fundamental flux units, which typically corresponds to a temperature of .100 nK, the SQUID is reset. The temperature range can be greatly expanded if the reset events are carefully tracked and counted, either by a computer running appropriate software or by a dedicated piece of hardware.
It is found that the thermal treatment of nontronite in air, for long periods at 700 C or short periods at 900 C, results in the destruction of the nontronite structure, a distinct reddening in color, and a large increase in magnetic susceptibility and saturation magnetization. Measurements and calculations of the magnetic properties suggest that the magnetism is due to the presence of ultrafine particles of alpha or gamma Fe2O3. The highly magnetic thermally treated nontronite is amorphous to X-rays consistent with an ultrafine grain size. Prolonged heating results in the growth of alpha Fe2O3, while reflectivity spectra of a sample heated for 1 hr at 900 C indicate the presence of an opaque, magnetite-like phase in addition to alpha Fe2O3. It is found that the thermally treated nontronite has chemical, color, and magnetic properties similar to those found by Viking on Mars. It is concluded that these results indicate an origin for the fine grained Martian surface material by repeated impacts into an Fe-rich smectite-charged regolith (Weldon et al., 1980).
An explanation for the magnetic properties of Martian surface material is discussed, specifically that the surface particles were composed primarily of smectite clay (nontronite) pigmented throughout by a red magnetic phase. The thermal treatment of nontronite in air, for long periods at 700 deg C or short periods at 900 deg C, results in destruction of the nontronite structure, a distinct reddening in color, and a spectacular increase in magnetic susceptibility and saturation magnetization (up to 4.4 Am squared/kg). Magnetic property measurements suggest that the magnetism is due to the presence of ultrafine particles of alpha or gamma Fe2O3; the precise identify was not resolved. Thermally treated nontronite has chemical, color and magnetic properties akin to those found by Viking on Mars. These results favor an origin for the fine grained Martian surface material by repeated impacts into an Fe-rich smectite-charged regolith, the smectite having resulted from hydrothermal alteration of volcanic or impact generated glass, the magnetic phase having resulted from the pressure or thermal shocked nontronite.
The effect of convection during the crystallization of proteins is not very well understood. In a gravitational field, convection is caused by crystal sedimentation and by solutal buoyancy induced flow and these can lead to crystal imperfections. While crystallization in microgravity can approach diffusion limited growth conditions (no convection), terrestrially strong magnetic fields can be used to control fluid flow and sedimentation effects. In this work, a theory is presented on the stability of solutal convection of a magnetized fluid in the presence of a magnetic field. The requirements for stability are developed and compared to experiments performed within the bore of a superconducting magnet. The theoretical predictions are in good agreement with the experiments and show solutal convection can be stabilized if the surrounding fluid has larger magnetic susceptibility and the magnetic field has a specific structure. Discussion on the application of the technique to protein crystallization is also provided.
To support long-duration manned missions in space such as a permanent lunar base, Mars transit, or Mars Surface Mission, improved methods for the treatment of solid wastes, particularly methods that recover valuable resources, are needed. The ability to operate under microgravity and hypogravity conditions is essential to meet this objective. The utilization of magnetic forces to manipulate granular magnetic media has provided the means to treat solid wastes under variable gravity conditions by filtration using a consolidated magnetic media bed followed by thermal processing of the solid wastes in a fluidized bed reactor. Non-uniform magnetic fields will produce a magnetic field gradient in a bed of magnetically susceptible media toward the distributor plate of a fluidized bed reactor. A correctly oriented magnetic field gradient will generate a downward direct force on magnetic media that can substitute for gravitational force in microgravity, or which may augment low levels of gravity, such as on the Moon or Mars. This approach is termed Gradient Magnetically Assisted Fluidization (G-MAFB), in which the magnitude of the force on the fluidized media depends upon the intensity of the magnetic field (H), the intensity of the field gradient (dH/dz), and the magnetic susceptibility of the media. Fluidized beds based on the G-MAFB process can operate in any gravitational environment by tuning the magnetic field appropriately. Magnetic materials and methods have been developed that enable G-MAFB operation under variable gravity conditions.
With allowance for the discussion of classification of enstatite chondrites and their relation to aubrites, the obtained magnetic and thermoanalytical data is submitted to be considered as additive arguments. Our study covered the Adhi Kot (EH4) and Atlanta (EL6). meteorites belonging to two distinct groups of enstatite chondrites. Applying AF demagnetization the intensity of natural remanent magnetization (NRM) was measured and the mean magnetic susceptibility of the samples was determined. The differential thermal (DTA) and thermogravimetric (TG) curves were obtained for meteorites under study. For measurements of the intensity of NRM, a superconducting cryomagnetometer SQUID (2 G Enterprise, USA), while magnetic susceptibility Kappabridge KLY-2 (Czechoslovakia) were used. The abbreviated magnetic data sheets are given. The values 786 x 10(exp -4)A/mkg and 196.1 x 10(exp -4)A/mkg were obtained as NRM intensities for Atlanta and Adhi Kot respectively, while 17.4 x 10(exp -6) SIu/kg and 43.4 x 10(exp -6) SIu/kg for their susceptibilities. Both meteorites proved to be strongly magnetized. The demagnetization down to 3.2 percent of NMR was received for Atlanta at AF field intensity of 250 Oe. For Adhi Kot at this level rested 13.2 percent of NRM intensity, this sample being demagnetized without change of direction till 750 Oe field. The demagnetization curves are similar to those obtained for Abee (EL4) chondrite by Sugiura and Strangway. Against Abee the Adhi Kot exhibited a little bit steeper downfall, and in both cases dominate one component of magnetization. The DTA and TG curves were obtained with Rigaku-Denki thermoanalytical instrument. The DTA curves exhibit striking similarity in their shape and relatively close temperature values for various features. The same is valid for TG curves. The higher values for TG for Adhi Kot express its higher content of oxydable (Fe, Ni) whose oxidation in air is reached at 1000-1200 C.
Static and dynamic magnetic fields have been used to control convection in many materials processing applications. In most of the applications, convection control (damping or enhancement) is achieved through the Lorentz force that can be tailored to counteract/assist dominant system flows. This technique has been successfully applied to liquids that are electrically conducting, such as high temperature melts of semiconductors, metals and alloys, etc. In liquids with low electrical conductivity such as ionic solutions of salts in water, the Lorentz force is weak and hence not very effective and alternate ways of flow control are necessary. If the salt in solution is paramagnetic then the variation of magnetic susceptibility with temperature and/or concentration can be used for flow control. For thermal buoyancy driven flows this can be accomplished in a temperature range below the Curie point of the salt. The magnetic force is proportional to the magnetic susceptibility and the product of the magnetic field and its gradient. By suitably positioning the experiment cell in the magnet, system flows can be assisted or countered, as desired. A similar approach can be extended to diamagnetic substances and fluids but the required magnetic force is considerably larger than that required for paramagnetic substances. The presentation will provide an overview of work to date on a NASA fluid physics sponsored project that aims to test the hypothesis of convective flow control using strong magnetic fields in protein crystal growth. The objective is to understand the nature of the various forces that come into play, delineate causative factors for fluid flow and to quantify them through experiments, analysis, and numerical modeling. The seminar will report specifically on the experimental results using paramagnetic salts and solutions in magnetic fields and compare them to analytical predictions. Applications of the concept to protein crystallization studies will be discussed. The use of strong magnetic fields for terrestrially simulating variable gravity environments and applications supporting the NASA Exploration Initiative will also be briefly discussed.
The magnetic properties of black Beloc glass have been measured. The Curie constant, the magnetization, and the magnetic susceptibility of the Beloc glass fall within the known ranges observed for tektites. However, the temperature-independent component of the magnetic susceptibility is slightly higher than that found for tektites. Moreover, it is not possible to match the experimental magnetic data for the Beloc glass with the calculated values using the previously reported Fe(3+)/Fe(2+) ratio of 0.7. The oxidation state of Fe was therefore redetermined by Mossbauer measurements, and the Fe(3+)/Fe(2+) ratio was found to be 0.024 plus or minus 0.015. Using the redetermined value of the ratio, the magnetic parameters were again calculated using formulas that are applicable to tektites, and good agreement was found between the calculated and experimental values. The experimental magnetic measurements and the redetermined Fe(3+)/Fe(2+) ratio of the Beloc glass specimens are essentially the same as those found for tektite glass.
An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular crystals for diffraction analyses has been the central focus for biochemists, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitants, other possible phases of the protein, foreign particles, the walls of the container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and sedimentation, as is achieved in 'microgravity', researchers have been able to dramatically affect the movement and distribution of macromolecules in the fluid, and thus their transport, formation of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. Whether this limited convection in a magnetic field will provide the environment for the growth of high quality crystals is still a matter of conjecture that our research will address. The approach exploits the variation of fluid magnetic susceptibility with concentration for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteracts terrestrial gravity. The general objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. Once the basic understanding is obtained, the study will focus on testing the hypothesis on proteins of pyruvate dehydrogenase complex (PDC), proteins E1 and E3. Obtaining high crystal quality of these proteins is of great importance to structural biologists since their structures need to be determined.
An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular crystals for diffraction analyses has been the central focus for biochemists, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitants, other possible phases of the protein, foreign particles, the walls of the container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and sedimentation, as is achieved in "microgravity", researchers have been able to dramatically affect the movement and distribution of macromolecules in the fluid, and thus their transport, formation of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. Whether this limited convection in a magnetic field will provide the environment for the growth of high quality crystals is still a matter of conjecture that our research will address. The approach exploits the variation of fluid magnetic susceptibility with concentration for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteracts terrestrial gravity. The general objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. Once the basic understanding is obtained, the study will focus on testing the hypothesis on proteins of pyruvate dehydrogenase complex (PDC), proteins E1 and E3. Obtaining high crystal quality of these proteins is of great importance to structural biologists since their structures need to be determined. Specific goals for the investigation are: 1. To develop an understanding of convection control in diamagnetic fluids with concentration gradients through experimentation and numerical modeling. Specifically solutal buoyancy driven convection due to crystal growth will be considered. 2. To develop predictive measures for successful crystallization in a magnetic field using analyses and numerical modeling for use in future protein crystal growth experiments. This will establish criteria that can be used to estimate the efficacy of magnetic field flow damping on crystallization of candidate proteins. 3. To demonstrate the understanding of convection damping by high magnetic fields to a class of proteins that is of interest and whose structure is as yet not determined. 4. To compare quantitatively, the quality of the grown crystals with and without a magnetic field. X-ray diffraction techniques will be used for the comparative studies. In a preliminary set of experiments, we studied crystal dissolution effects in a 5 Tesla magnet available at NASA Marshall Space Flight Center (MSFC). Using a Schlieren setup, a 1mm crystal of Alum (Aluminum-Potassium Sulfate) was introduced in a 75% saturated solution and the resulting dissolution plume was observed. The experiment was conducted both in the presence and absence of a magnetic field gradient. The magnet produces a gradient field of approx. 1 Tesla2/cm. Image analysis of the recorded images indicated an enhanced plume velocity that was of the order of the measurement limit. For this experiment, both the gradient and gravity fields are in the same direction resulting in an enhanced effective gravity that tends to accelerate the observed plume velocity. While the results are not conclusive, pending further tests, it clearly points out the inadequacy of the MSFC magnet for conducting protein crystallization experiments and the need for a stronger magnet. In spacebased experiments, however, where the gravitational effects are small, only a weak magnetic field will be required to control or mitigate the effects of convective contamination.