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Isotope effects in Lyman and Werner systems of molecular hydrogen, HD and molecular deuterium, calculating band strengths, oscillator strengths and Franck-Condon factors
The suggestion that a claimed 30 Myr period in the geologic past resulted from cometary impacts following encounters with molecular clouds as the solar system oscillates about the galactic plane poses a well-defined problem in the theory of shot noise. All recent CO surveys of the Galaxy clearly indicate that the concentration of molecular clouds in the galactic plane is not sufficient to allow a statistically significant period to be extracted from the small number of dated events. Of the order of 1000 events is probably required to obtain a credible period.
A 980-nm-ridge waveguide pseudomorphic InGaAs/GaAs/AlGaAs single-quantum-well laser with a maximum single-ended output power of 240 mW from a facet-coated device is fabricated from a graded-index separate-confinement heterostructure grown by molecular-beam epitaxy. The laser oscillates in the fundamental spatial mode, allowing 22 percent coupling efficiency into a 1.55-micron single-mode optical fiber. Life testing at an output power of 30 mW per facet from uncoated devices reveals a superior reliability to GaAs/AlGaAs quantum-well lasers but also the need for protective facet coatings for long term reliability at power levels required for pumping Er-doped fiber amplifiers.
Fluidic oscillator, incorporating piezoelectric transducer to sense molecular weight of gas mixture, is used to continuously monitor ratio of a mixture of two gases in a flowing system. Device is lightweight, compact, reliable, easy to install, and also produces a simple output signal for controller. Frequency of oscillation is measured and signal converted to ac output.
Improvements to the Yale Rotating Stellar Evolution Code (YREC) by incorporating the Mihalas-Hummer-Daeppen equation of state, an improved opacity interpolation routine, and the effects of molecular opacities, calculated at Los Alamos, have been made. the effect of each of the improvements on the standard solar model has been tested independently by computing the corresponding solar nonradial oscillation frequencies. According to these tests, the Mihalas-Hummer-Daeppen equation of state has very little effect on the model's low l p-mode oscillation spectrum compared to the model using the existing analytical equation of state implemented in YREC. On the other hand, the molecular opacity does improve the model's oscillation spectrum. The effect of molecular opacity on the computed solar oscillation frequencies is much larger than that of the Mihalas-Hummer-Daeppen equation of state. together, the two improvements to the physics reduce the discrepancy with observations by 10 microHz for the low l modes.
Changes in surface layers cause oscillations in RHEED measurements. Specular RHEED Beam intensity measured before, during, and after deposition of seven to eight monomolecular layers of gallium during 1.5 seconds. Arsenic pressure was 1.7x10 to the negative seventh power torr (2.3x10 to the negative fifth power Pa) throughout measurements.
Molecular nitrogen plays a central role in the energetics of the earth's upper atmosphere and is the major constituent of the atmospheres of the planetary satellites Titan and Triton. This paper reports a new set of absorption oscillator strengths measured at higher resolution for seven bands in the 95.8-99.4 nm region. The results are compared with earlier, lower resolution absorption measurements, electron scattering measurements, and calculations based on a deperturbation analysis of the excited states.
The effects of light absorption on the wave functions of gas-phase molecules and atoms are investigated by high resolution spectral measurements of radiation emerging from a sample. A Stark-modulated sample of methyl fluoride was irradiated at the 102 GHz rotational transition and the emergent radiation was resolved by means of a spectrum analyzer. For signal oscillator frequencies below or above the molecular resonance by one modulation frequency, the amplitudes of the upper and lower modulation sidebands are found to be of nonuniform intensity, which is inconsistent with amplitude modulation. Emission due to polarization is, however, calculated to be consistent with the results observed, indicating that light absorption should be considered as a subtractive stimulated emission.
In a microgravity environment, molecular diffusion is the primary mechanism by which fuel and oxidizer that are initially separated are brought together to the reaction zone. Combustion systems in microgravity are therefore primed to diffusive-thermal instabilities. One such instability appears in the form of spontaneous oscillations. Oscillations were observed in condensed-phase fuels and gas-jet diffusion flames, and in microgravity jet-flames, candle flames and spherical flames surrounding large fiber-supported fuel droplets. The nature of oscillations is quite different in each of these cases: the droplet flame exhibits radial oscillations, the edge of the candle flame is seen to move back and forth along the hemispherical flame surface and the jet-flame oscillations are primarily up and down along the axis. Despite these differences, associated mainly with the mode of oscillation, one may identify some common factors: in all cases the flame exhibits low-frequency oscillations, oscillations are only observed in special mixtures and their onset occur only at near-extinction conditions.
Values of band oscillator strengths and rotational line widths for the Schumann-Runge band system have been used to derive interpolation constants from which the transmittance and rate of dissociation of molecular oxygen can be calculated. These constants, valid for temperatures between 150 and 300 K and for column densities between 1 x 10 to the 17th power/cm sq and 7 x 10 to the 24th power/cm sq, cover the wavelength range 1750 and 2050A.
Use of recently obtained band oscillator strengths and predissociation line widths, for the Schumann-Runge band system to calculate the photodissociation rate of molecular oxygen as a function of column density and temperature by solar radiation between 1025 and 2500 A. Data are presented from which the mean transmission and photodissociation rates for given wavelength intervals between 1750 and 2025 A can be calculated for column densities between 10 to the 17th and 10 to the 23rd molecules/sq cm and for temperatures between 150 and 300 K. Also, the production of vibrationally excited oxygen molecules as a result of fluorescence in the Schumann-Runge bands is discussed.
A hydrogen gas sensor that can replace catalytic combustion sensors used to detect leaks in the liquid hydrogen transfer systems at Kennedy Space Center was developed. A fluidic sensor concept, based on the principle that the frequency of a fluidic oscillator is proportional to the square root of the molecular weight of its operating fluid, was utilized. To minimize sensitivity to pressure and temperature fluctuations, and to make the sensor specific for hydrogen, two oscillators are used. One oscillator operates on sample gas containing hydrogen, while the other operates on sample gas with the hydrogen converted to steam. The conversion is accomplished with a small catalytic converter. The frequency difference is taken, and the hydrogen concentration computed with a simple digital processing circuit. The output from the sensor is an analog signal proportional to hydrogen content. The sensor is shown to be accurate and insensitive to severe environmental disturbances. It is also specific for hydrogen, even with large helium concentrations in the sample gas.
Optical observations of molecules in diffuse interstellar clouds are discussed. The role of oscillator strengths in determining cloud properties such as densities, temperatures, and particle and photon fluxes is examined. The use of an emission technique, molecular and atomic lifetime measurements, and absorption measurements to estimate oscillator strengths is described. It is noted that the lifetime and absorption measurements are more advantageous than the emission technique to estimate oscillator strengths.
Argon ion laser passing through iodine molecular beam inducing resonance fluorescence usable for oscillation frequency stabilization of laser
Photodissociation via discrete line absorption into predissociating Rydberg and valence states is the dominant destruction mechanism of CO and other molecules in the interstellar medium and molecular clouds. Accurate values for the rovibronic oscillator strengths of these transitions and predissociation yields of the excited states are required for input into the photochemical models that attempt to reproduce observed abundances. We report here on our latest experimental results of the electron collisional properties of CO and N2 obtained using the 3-meter high resolution single-scattering spectroscopic facility at JPL.
Interstellar molecular oxygen should be detectable in interstellar clouds through observation of its absorption lines in the spectra of background stars. This paper describes and presents the results of measurements of oscillator strengths for some lines in the vacuum ultraviolet (VUV) spectrum of O2. Lines of the (13, 0) through (16, 0) bands of the B 3Sigma(-)u - X 3Sigma(-)g, Schumann-Runge system between 1760 A and 1790 A will be the most suitable for searches for absorption by interstellar O2 with the High Resolution Spectrograph on Space Telescope. The strongest lines in these bands have oscillator strengths of about 3 x 10 to the -5th.
The semiclassical approximation is applied to anharmonic diatomic oscillators in excited initial states. Multistate numerical solutions giving the vibrational transition probabilities for collinear collisions with an inert atom are compared with equivalent, exact quantum-mechanical calculations. Several symmetrization methods are shown to correlate accurately the predictions of both theories for all initial states, transitions, and molecular types tested, but only if coupling of the oscillator motion and the classical trajectory of the incident particle is considered. In anharmonic heteronuclear molecules, the customary semiclassical method of computing the classical trajectory independently leads to transition probabilities with anomalous low-energy resonances. Proper accounting of the effects of oscillator compression and recoil on the incident particle trajectory removes the anomalies and restores the applicability of the semiclassical approximation.
The semiclassical approximation (quantum oscillator, classical path) is applied to anharmonic diatomic oscillators in excited initial states. Multistate numerical solutions giving the vibrational transition probabilities for collinear collisions with an inert atom are compared with equivalent, exact quantum-mechanical calculations. Several symmetrization methods are shown to correlate accurately the predictions of both theories for all initial states, transitions, and molecular types tested, but only if coupling of the oscillator motion and the classical trajectory of the incident particle is considered. In anharmonic heteronuclear molecules, the customary semiclassical method of computing the classical trajectory independently leads to transition probabilities with anomalous low-energy resonances. Proper accounting of the effects of oscillator compression and recoil on the incident particle trajectory removes the anomalies and restores the applicability of the semiclassical approximation.