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NASA NTRS1992

A reduced atmosphere for early Mars?

One-dimensional, radiative-convective climate calculations indicate that the old model of a warm, dense, CO2 atmosphere on early Mars is no longer viable. The magnitude of the greenhouse effect in a CO2/H2O atmosphere is limited by condensation of CO2 clouds; this phenomenon is not important for Mars today, but has a pronounced cooling effect at the low solar luminosities thought to apply during early solar system history. The failure of this model indicates one of four things: (1) the new climate calculations are incorrect; (2) current solar evolution models are incorrect; (3) the idea that early Mars was warm and wet is incorrect; or (4) the atmosphere of early Mars contained other greenhouse gases (or particles) in addition to CO2 and H2O. Of these explanations, the most plausible is number (4) and the rest of the investigation is a further explanation of number (4).

Kasting, J. F.↗

NASA NTRS2010

Cryogenic Carbonate Formation on Mars: Clues from Stable Isotope Variations Seen in Experimental Studies

Discoveries of large deposits of sedimentary materials on the planet Mars by landers and orbiters have confirmed the widely held hypothesis that water has played a crucial role in the development of the martian surface. Recent studies have indicated that both water ice and liquid water may have been present and in the case of water ice perhaps is still present on or near the surface of Mars. However, there remains much controversy about the prevailing atmospheric conditions and climate of Mars during its history and whether liquid water existed on the martian surface simply during discrete geological events or whether this water was present over relatively much longer geologic time periods. The recent identification of Ca-rich carbonate by the Phoenix lander as well as its measurement of the isotopic composition of atmospheric CO2 has shown the importance of understanding the carbonates on Mars as an important sink of atmospheric carbon. This work compliments that of our past experiments where we produced cryogenic calcite in open containers, as analogs for terrestrial aufeis formation, and as a means for evaluating the fractionation of C-13 in CO2 during bicarbonate freezing [13]. Unlike our previous experiments in which carbonates were grown in ambient laboratory condition in open containers (atmospheric pressure and composition), this work attempts to quantify the amount of delta C-13 enrichment possible in both fluids and secondary carbonates formed from freezing of bicarbonate fluids under martian-like atmospheric conditions. Morphologic textures of produced carbonates in these experiments are also examined under SEM in order to identify the effect that the cryogenic freezing process has on the mineral's mineralogy. Understanding the role of kinetic isotope fractionation during formation of carbonates under martian-like conditions will aid in our ability to quantify the isotopic composition of the carbonate sink furthering our ability to model the climate history of Mars.

Socki, Richard A.↗

NASA NTRS1982

Mars - The regolith-atmosphere-cap system and climate change

A model is derived for the prediction of the Martian regolith-atmosphere-cap CO2 regime's behavior, as well as for the description of the roly of the regime in climate change, through descriptions of the time-temperature histories of 90 regolith 'chunks' on a latitude-depth grid. The influence of differences in regolith adsorption laws for basalt and clay, and the influence of variations in regolith depth with (1) latitude, (2) regolith thermal diffusivity, and (3) total exchangeable CO2 inventory on predicted variations in atmospheric pressure and cap mass, are examined. It is found that the atmosphere acts as a low capacity conduit between two reservoirs through which 10-100 times the current atmospheric mass of CO2 flows. The exchange between the reservoirs is driven by obliquity variations, with the polar cap the dominant CO2 sink at low obliquity and the regolith dominating at high obliquity.

Fanale, F. P.↗

NASA NTRS2015

Mineralogical Indicators for Climate Change on Mars: Evidence from Landed Missions

Mineralogical and geochemical data returned by a flotilla of Mars orbiters and landers over the past 10 years has substantially enhanced our understanding on the evolution of the atmosphere and climate. Instruments onboard Mars Express and MRO discovered widespread deposits of phyllosilicates that formed during the Noachian followed by formation of sulfates into the Hesperian. The formation of extensive valley networks along with these layered deposits of phyllosilicates and sulfates during the late Noachian/ early Hesperian indicate a past martian climate that was capable of maintaining liquid water at the surface. The planet's climate changed substantially after these early 'episodes' of water and very little aqueous alteration has occurred over the past 3.5 Gyrs . A key to understanding Mars past climate is to identify, characterize, and age date secondary minerals that have formed by reaction with volatile compounds, e.g., H2O, CO2, SO2. Here, we summarize the detection of secondary minerals at the four landing sites visited over the past 10 years. We also provide potential pathways for their formation and implications for past climate change on Mars.

Ming, D. W.↗

NASA NTRS1999

Modeling the Atmospheric Structure and Dynamics of the Martian Atmosphere

Models of the general circulation and climate system of Mars have reached a high level of maturity, but observations to validate them have lacked the kind of global and temporal coverage required. However, we are now on the verge of a new era in Mars exploration as Mars Global Surveyor, and the now enroute Mars Climate Orbiter, will provide daily global coverage of the atmosphere for two Mars years. In the coming years, data from these missions will test the predictions of general circulation models (GCM's) whose results have perhaps become too accepted as truth. This talk will review what GCM's tell us about Mars, what their weaknesses are, and what the latest results imply for their future. Additional information is contained in the original extended abstract.

Haberle, R. M.↗

NASA NTRS1992

An ion mass spectrometer for measuring isotopic adundances and loss rates of O, C and H in Mars' upper atmosphere

The history of Mars' climate is clearly intimately linked to the evolution of its store of volatiles, particularly H2O, and CO2. The global CO2-H2O system is complex, with a number of production, loss, exchange, and buffering mechanisms operating between the atmosphere and the surface. For example, loss of these volatiles takes place through solar wind interaction with the upper atmosphere/ionosphere, ionospheric chemistry, and thermal escape. The atmospheric water inventory is, in turn, influenced by the exchange with polar water ice deposits and high latitude ground-ice. Atmospheric CO2, on the other hand, can be lost through adsorption in the regolith and in the formation of carbonates. Finally, oxygen is exchanged between atmospheric CO2 and H2O.

Elphic, R. C.↗

NASA NTRS2017

Synoptic Traveling Weather Systems on Mars: Effects of Radiatively-Active Water Ice Clouds

Atmospheric aerosols on Mars are critical in determining the nature of its thermal structure, its large-scale circulation, and hence the overall climate of the planet. We conduct multi-annual simulations with the latest version of the NASA Ames Mars global climate model (GCM), gcm2.3+, that includes a modernized radiative-transfer package and complex water-ice cloud microphysics package which permit radiative effects and interactions of suspended atmospheric aerosols (e.g., water ice clouds, water vapor, dust, and mutual interactions) to influence the net diabatic heating. Results indicate that radiatively active water ice clouds profoundly affect the seasonal and annual mean climate. The mean thermal structure and balanced circulation patterns are strongly modified near the surface and aloft. Warming of the subtropical atmosphere at altitude and cooling of the high latitude atmosphere at low levels takes place, which increases the mean pole-to-equator temperature contrast (i.e., "baroclinicity"). With radiatively active water ice clouds (RAC) compared to radiatively inert water ice clouds (nonRAC), significant changes in the intensity of the mean state and forced stationary Rossby modes occur, both of which affect the vigor and intensity of traveling, synoptic period weather systems.Such weather systems not only act as key agents in the transport of heat and momentum beyond the extent of the Hadley circulation, but also the transport of trace species such as water vapor, water ice-clouds, dust and others. The northern hemisphere (NH) forced Rossby waves and resultant wave train are augmented in the RAC case: the modes are more intense and the wave train is shifted equatorward. Significant changes also occur within the subtropics and tropics. The Rossby wave train sets up, combined with the traveling synoptic period weather systems (i.e., cyclones and anticyclones), the geographic extent of storm zones (or storm tracks) within the NH. A variety of circulation features will be presented which indicate contrasts between the RAC and nonRAC cases, and which highlight key effects radiatively-active clouds have on physical and dynamical processes active in the current climate of Mars.

GCM-global climate model↗

NASA NTRSDate not supplied

Simulating the Martian Middle and Upper Atmosphere with the NASA Ames Mars GCM.

The NASA Ames Mars Global Climate Model (MGCM) continues to be utilized to examine the dynamical coupling between the lower atmosphere and middle/upper atmosphere. This coupling impacts the transport of water, dust, and chemistry which augments the thermal structure and circulation. The interactions and coupling within the atmosphere are important for understanding the present-day and past atmosphere and climate. MGCM simulations are compared with observations from recent Mars missions to provide model constraints, and in turn, the simulations can then provide context to the observations. This cycle is important to move us forward in our understanding of planetary atmospheres. We will present on one of the fundamental atmospheric features, the thermal structure, and how the physics in the MGCM can elucidate the observed diurnal and seasonal behavior. Additionally, we will focus on the distribution of chemical species which influences the thermal structure and provides additional information on the coupling between the lower and middle/upper atmosphere. Lastly, we will provide a summary of the model capabilities, as the MGCM continues to be improved upon to properly simulate Mars’ atmosphere from the ground to ~250 km.

Amanda Susanne Brecht↗

NASA NTRS2017

Synoptic Traveling Weather Systems on Mars: Effects of Radiatively-Active Water Ice Clouds

Atmospheric aerosols on Mars are critical in determining the nature of its thermal structure, its large-scale circulation, and hence the overall climate of the planet. We conduct multi-annual simulations with the latest version of the NASA Ames Mars global climate model (GCM), gcm2.3+, that includes a modernized radiative-transfer package and complex water-ice cloud microphysics package which permit radiative effects and interactions of suspended atmospheric aerosols (e.g., water ice clouds, water vapor, dust, and mutual interactions) to influence the net diabatic heating. Results indicate that radiatively active water ice clouds profoundly affect the seasonal and annual mean climate. The mean thermal structure and balanced circulation patterns are strongly modified near the surface and aloft. Warming of the subtropical atmosphere at altitude and cooling of the high latitude atmosphere at low levels takes place, which increases the mean pole-to-equator temperature contrast (i.e., "baroclinicity"). With radiatively active water ice clouds (RAC) compared to radiatively inert water ice clouds (nonRAC), significant changes in the intensity of the mean state and forced stationary Rossby modes occur, both of which affect the vigor and intensity of traveling, synoptic period weather systems. Such weather systems not only act as key agents in the transport of heat and momentum beyond the extent of the Hadley circulation, but also the transport of trace species such as water vapor, water ice-clouds, dust and others. The northern hemisphere (NH) forced Rossby waves and resultant wave train are augmented in the RAC case: the modes are more intense and the wave train is shifted equatorward. Significant changes also occur within the subtropics and tropics. The Rossby wave train sets up, combined with the traveling synoptic period weather systems (i.e., cyclones and anticyclones), the geographic extent of storm zones (or storm tracks) within the NH. A variety of circulation features will be presented which indicate contrasts between the RAC and nonRAC cases, and which highlight key effects radiatively-active clouds have on physical and dynamical processes active in the current climate of Mars.

Atmospheric aerosols↗

NASA NTRS2007

Proceedings of the Seventh International Conference on Mars

The oral and poster sessions of the SEVENTH INTERNATIONAL CONFERENCE ON MARS included; The Distribution and Context of Water-related Minerals on Mars; Poster Session: Mars Geology; Geology of the Martian Surface: Lithologic Variation, Composition, and Structure; Water Through Mars' Geologic History; Poster Session: Mars Water and the Martian Interior; Volatiles and Interior Evolution; The Martian Climate and Atmosphere: Variations in Time and Space; Poster Session: The Martian Climate and Current Processes; Modern Mars: Weather, Atmospheric Chemistry, Geologic Processes, and Water Cycle; Public Lecture: Mars Reconnaissance Orbiter's New View of the Red Planet; The North and South Polar Layered Deposits, Circumpolar Regions, and Changes with Time; Poster Session: Mars Polar Science, Astrobiology, Future Missions/Instruments, and Other Mars Science; Mars Astrobiology and Upcoming Missions; and Martian Stratigraphy and Sedimentology: Reading the Sedimentary Record.

Source record↗

NASA NTRS1974

Climatic variations on Mars. II - Evolution of carbon dioxide atmosphere and polar caps

The long-term variations in the atmospheric pressure and the polar cap temperature of Mars resulting from the obliquity oscillations are discussed. In performing these calculations, the assumption is made that the atmosphere is in equilibrium with perennial CO2 ice deposits at the north pole, as is proposed by Leighton and Murray (1966). If heat transport by the atmosphere is neglected, the temperature of CO2 ice at the poles ranges from about 130 K to about 160 K, the corresponding atmospheric pressure rising from a few tenths of a millibar to about 30 mbar, respectively. The neglect of atmospheric heat transport probably underestimates the peak pressure. Because the altitude of the south cap is about 2 km higher than that of the north cap, CO2 ice is unstable there and will migrate to the north cap at a rate of about 10 g/sq cm yr, the implication being that the south residual cap is water ice. A simplified model of the annual polar caps and pressure fluctuations is also presented.

Ward, W. R.↗

NASA NTRS1987

Climatic effects of enhanced CO2 levels in Mars early atmosphere

Results are presented of one-dimensional radiation convection modeling of the early Mars atmosphere. Up to 5 bars of CO2 would have been required to raise the surface temperature (orbitally and globally averaged) above the freezing point, although at the equator at perihelion, 1 bar would have sufficed. Such an atmospheric CO2 invertory, the author argued, is not inconsistent with any known constraint on Mars' degassed volatile inventory.

Kasting, James F.↗

NASA NTRS2013

Carbonate Mineral Formation on Mars: Clues from Stable Isotope Variation Seen in Cryogenic Laboratory Studies of Carbonate Salts

The geologic history of water on the planet Mars is intimately connected to the formation of carbonate minerals through atmospheric CO2 and its control of the climate history of Mars. Carbonate mineral formation under modern martian atmospheric conditions could be a critical factor in controlling the martian climate in a means similar to the rock weathering cycle on Earth. The combination of evidence for liquid water on the martian surface and cold surface conditions suggest fluid freezing could be very common on the surface of Mars. Cryogenic calcite forms readily when a rise in pH occurs as a result of carbon dioxide degassing quickly from freezing Ca-bicarbonate-rich water solutions. This is a process that has been observed in some terrestrial settings such as arctic permafrost cave deposits, lakebeds of the Dry Valleys of Antarctica, and in aufeis (river icings) from rivers of N.E. Alaska. We report here the results of a series of laboratory experiments that were conducted to simulate potential cryogenic carbonate formation on the planet Mars. These results indicate that carbonates grown under martian conditions (controlled atmospheric pressure and temperature) show enrichments from starting bicarbonate fluids in both carbon and oxygen isotopes beyond equilibrium values with average delta13C(DIC-CARB) values of ~20.5%0 which exceed the expected equilibrium fractionation factor of [10(sup 3) ln alpha = ~13%0] at 0 degC. Oxygen isotopes showed a smaller enrichment with delta18O(H2O-CARB) values of ~35.5%0, slightly exceeding the equilibrium fractionation factor of [10(sup 3) ln alpha = ~34%0 ] at 0degC. Large kinetic carbon isotope effects during carbonate precipitation could substantially affect the carbon isotope evolution of CO2 on Mars allowing for more efficient removal of 13C from the Noachian atmosphere enriched by atmospheric loss. This mechanism would be consistent with the observations of large carbon isotope variations in martian materials despite the relative paucity of carbonate minerals in the martian crust.

Socki, Richard↗

NASA NTRS1992

Microcraters on Mars: Evidence of past climatic variations

On Mars, we do not expect to see the full spectrum of crater sizes that we see on the Moon, because the Martian atmosphere decelerates smaller incoming meteorites. Mars climate models predict thirty-fold variations in Mars' atmospheric pressure due to large amplitude quasi-periodic variations in Mars' obliquity. More recent studies have shown that uncertainties in Mars' moment of inertia may have resulted in an underestimation of this range. In this study, we find that potential variations in the mass of the Martian atmosphere should have dramatic effects on the production rates of centimeter sized craters on the surface of Mars, and suggest that observations of the densities of Martian microcraters would provide an important validation of the astronomical theory for Martian climate change.

Vasavada, A. R.↗

NASA NTRS2022

Mars Climate Sounder Observations of Gravity Wave Activity throughout Mars’s Lower Atmosphere

Gravity waves are one way Mars’s lower atmospheric weather can affect the circulation and even composition of Mars’s middle and upper atmosphere. A recent study showed how on-planet observations near the center of the 15 micron CO2band by the A3 channel(635–665 cm−1)of the Mars Climate Sounder on board Mars Reconnaissance Orbiter (MRO-MCS) could sense horizontally short, vertically broad gravity waves at≈25 km above the surface by looking at small-scale radiance variability in temperature-sensitive channels. This approach is extended here to two additional channels closer to the wings of the 15 micron CO2band,A1 (595–615 cm−1) and A2 (615–645 cm−1), to sense gravity waves throughout the lower atmosphere. Using information from all three channels demonstrates that gravity wave activity in Mars’s lowermost atmosphere is dominated by orographic sources, particularly over the extremely rough terrain of Valles Marineris. Much of this orographic population is either trapped or filtered in the lowest two scale heights, such that variations in filtering and non-orographic sources shape the gravity wave population observed at 25 km above the surface. During global dust storms, however, gravity wave activity in the first scale height decreases by approximately a factor of two, yet trapping/filtering of what activity remains in the tropics substantially weakens. Exceptionally high radiance variability at night in the tropics during the less dusty part of the year is the result of observing mesospheric clouds rather than gravity waves.

Nicholas G Heavens↗

NASA NTRS2012

The Mars Dust Cycle: Investigating the Effects of Radiatively Active Water Ice Clouds on Surface Stresses and Dust Lifting Potential with the NASA Ames Mars General Circulation Model

The dust cycle is a critically important component of Mars' current climate system. Dust is present in the atmosphere of Mars year-round but the dust loading varies with season in a generally repeatable manner. Dust has a significant influence on the thermal structure of the atmosphere and thus greatly affects atmospheric circulation. The dust cycle is the most difficult of the three climate cycles (CO2, water, and dust) to model realistically with general circulation models. Until recently, numerical modeling investigations of the dust cycle have typically not included the effects of couplings to the water cycle through cloud formation. In the Martian atmosphere, dust particles likely provide the seed nuclei for heterogeneous nucleation of water ice clouds. As ice coats atmospheric dust grains, the newly formed cloud particles exhibit different physical and radiative characteristics. Thus, the coupling between the dust and water cycles likely affects the distributions of dust, water vapor and water ice, and thus atmospheric heating and cooling and the resulting circulations. We use the NASA Ames Mars GCM to investigate the effects of radiatively active water ice clouds on surface stress and the potential for dust lifting. The model includes a state-of-the-art water ice cloud microphysics package and a radiative transfer scheme that accounts for the radiative effects of CO2 gas, dust, and water ice clouds. We focus on simulations that are radiatively forced by a prescribed dust map, and we compare simulations that do and do not include radiatively active clouds. Preliminary results suggest that the magnitude and spatial patterns of surface stress (and thus dust lifting potential) are substantial influenced by the radiative effects of water ice clouds.

Kahre, Melinda A.↗

NASA NTRS2003

Electrochemical approaches for chemical and biological analysis on Mars

Obtaining in situ chemical data from planetary bodies such as Mars or Europa can present significant challenges. The one analytical technique that has many of the requisite characteristics to meet such a challenge is electroanalysis. Described here are three electroanalytical devices designed for in situ geochemical and biological analysis on Mars. The Mars Environmental Compatibility Assessment (MECA) was built and flight qualified for the now cancelled NASA Mars 2001 Lander. Part of MECA consisted of four "cells" containing arrays of electrochemical based sensors for measuring the ionic species in soil samples. A next-generation MECA, the Robotic Chemical Analysis Laboratory (RCAL), uses a carousel-type system to allow for greater customization of analytical procedures. A second instrument, proposed as part of the 2007 CryoScout mission, consists of a flow-through inorganic chemical analyzer (MICA). CryoScout is a torpedo-like device designed for subsurface investigation of the stratigraphic climate record embedded in Mars' north polar cap. As the CryoScout melts its way through the ice cap, MICA will collect and analyze the meltwater for a variety of inorganics and chemical parameters. By analyzing the chemistry locked in the layers of dust, salt, and ice, geologists will be able to determine the recent history of climate, water, and atmosphere on Mars and link it to the past. Finally, electroanalysis shows its abilities in the detection of possible microorganism on Mars or elsewhere in the solar system. To identify an unknown microorganism, one that may not even use Earth-type biochemistry, requires a detection scheme which makes minimal assumptions and looks for the most general features. Recent work has demonstrated that the use of an array of electrochemical sensors which monitors the changes in a solution via electrical conductivity, pH, and ion selective electrodes, can be used to detect minute chemical perturbations caused by the growth of bacteria and with the correct methodology provide unamibiguous detection of such life forms.

Non-NASA Center↗

NASA NTRS1999

Investigating Atmospheric Effects on Impact Ejecta Morphology: Possible Tool for Determining Past Climate Conditions on Mars?

The combined use of impact crater morphology and mechanics provides important information on the physical conditions of both planetary atmospheres and planetary and asteroid surfaces present during crater formation, while an understanding of the rate of crater production on the surface of asteroids provides information of their surface and spin rate evolution. The research performed with support from this project improves our understanding of (1) the mechanics of impact cratering in order to gain insights on the evolution of these physical surface conditions on planets with atmospheres and asteroids, and (2) how impact flux across an asteroid surface may vary due to anisotropic distribution of impactors in the solar system. As part of this project, we have undertaken three studies. In the first study, we investigate atmospheric effects on the morphology of ejecta excavated during a cratering event in order to determine the atmospheric and target conditions from observed crater morphologies. In the second study, we use the physical and morphological consequences of oblique impacts on an asteroid to understand how the asteroid Mathilde (recently imaged by the Near Earth Asteroid Rendezvous - NEAR- spacecraft) could have survived the formation of five giant craters. In a third study, we use a Monte Carlo method to calculate the impact flux on an asteroid given a distribution of impactors on elliptical orbits. In the following section, we present the result obtained from all three studies.

Appleby, John F.↗