Search NASA⌕ Search

SEARCH · Search NASA

Results for “Mass loading”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Ultrahigh Mass Loading Batteries with Holey Graphene-Enabled Dry-Pressed Cathode Architectures

Holey graphene is a structural derivative of graphene with arrays of nanometer-sized, through-thickness holes across the lateral surface of the atomically thin nanosheet. It has been widely acknowledged that the presence of holes improves ion transport through the graphene planes, making holey graphene an ideal electrode material for electrochemical energy storage. We recently discovered another unique attribute of holey graphene in that it can be directly compressed from powder into electrode in a single step without the use of solvent or binder. In addition to neat holey graphene electrodes, composite electrodes with holey graphene as an ultralightweight scaffold host filled with various active materials can also be readily prepared in a similar solvent-free and binder-free fashion. The active materials can be metal-containing catalysts for lithium-oxygen batteries, lithium-ion battery electrode materials, or high energy density components such as sulfur. Compared to the conventional slurry-based process, the dry-press method is comparably much more suitable toward the facile and scalable preparation of ultrahigh mass loading electrodes with ultrahigh areal capacities.

holey graphene, cathode scaffold, lithium metal, h↗
NASA NTRS1997

Mass Loading Characteristics of Crystal Clock Oscillators

The 10-MHz piezoelectric quartz-crystal microbalance (QCM) has been used extensively for stratospheric aerosol sampling. We have undertaken laboratory studies of the QCM response to mass loading by trace gases. However, this device requires dual oscillator circuitry and the mass sensitivity can often be affected by the electronics. The coatings on the quartz crystals are sometimes difficult to remove after they have reacted with a particular gas and a disposable crystal system would be desirable. The cost of the dual oscillator-based QCM makes this a prohibitive option. Since our goal is to develop a cost-effective microbalance system with stable electronics we have begun testing of crystal clock oscillators, which are assembled with their own circuitry. We have been using chemically specific coatings for ozone to determine if the sensitivity and mass-frequency ratios are comparable to that of the 10-MHz QCM.

Cobb, Janel↗
NASA NTRS1961

Effects of Mass-Loading Variations and Applied Moments on Motion and Control of a Manned Rotating Space Vehicle

An analytical study has been made to determine the effects of mass-loading variations and onboard rotating machinery on a hypothetical earth-satellite space station, rotating to provide an artificial gravity equal to one-fourth of that at the earth's surface. Attempts were also made to damp out or minimize undesirable motions by using mass shifts, constant-rate inertia wheels, or jet-reaction moments. Results obtained indicate that the shifting of masses within the rotating space station could bring about large roll oscillations (plus or minus 100 degrees) or even continuous rolling motions if the craft is rotating about the axis of intermediate moment of inertia. The pitch angles obtained were generally small (less than plus or minus 1 degree). The amplitudes of the roll and pitch oscillations are dependent upon the angle of displacement of the greatest principal axis of inertia from the initial spin axis. In attempting to damp out or minimize undesirable motions, it was found that a constant-rate inertia wheel located on and rotating about the axis about which the craft is rotating (Z-axis) was beneficial in keeping the roll angles relatively small, provided it had a sufficient amount of angular momentum. It was also found that the use of jet-reaction moments was very satisfactory for damping undesirable motions in that the roll oscillations could be damped.

Grantham, William D.↗
NASA NTRS1978

Direct evaluation of aerosol-mass loadings from multispectral extinction data

A formula is derived for the evaluation of the total volume of aerosol in a column, and hence for the aerosol columnar mass loading, from multispectral extinction data. This formula is exact in the 'anomalous diffraction' approximation, and reasonably accurate for Mie scattering, over a fairly wide range of refractive indices typical of real aerosols.

Box, M. A.↗
NASA NTRS1992

Comparison of the impact of volcanic eruptions and aircraft emissions on the aerosol mass loading and sulfur budget in the stratosphere

Data obtained by the Stratospheric Aerosol and Gas Experiment (SAGE) 1 and 2 were used to study the temporal variation of aerosol optical properties and to assess the mass loading of stratospheric aerosols from the eruption of volcanos Ruiz and Kelut. It was found that the yearly global average of optical depth at 1.0 micron for stratospheric background aerosols in 1979 was 1.16 x 10(exp -3) and in 1989 was 1.66 x 10(exp -3). The eruptions of volcanos Ruiz and Kelut ejected at least 5.6 x 10(exp 5) and 1.8 x 10(exp 5) tons of materials into the stratosphere, respectively. The amount of sulfur emitted per year from the projected subsonic and supersonic fleet is comparable to that contained in the background aerosol particles in midlatitudes from 35 deg N to 55 deg N.

Yue, Glenn K.↗
NASA NTRS1988

To what extent is mass loading responsible for the Venus bowshock precursor?

Significant ion and electron flux enhancements immediately upstream of the Venus bow shock were observed by the Electron Temperature Probe on the Pioneer Venus Orbiter. It is shown that mass loading of the solar wind by oxygen ions accounts for only about 10 percent of the observed effect.

Fontheim, Ernest G.↗
NASA NTRS1989

A modified VAPEPS method for predicting vibroacoustic response of unreinforced mass loaded honeycomb panels

VAPEPS (VibroAcoustic Payload Environment Prediction System) is a computer program used to predict the vibroacoustic response of a structure. An alternate VAPEPS modeling technique, the Modified NASA Lewis Method, is an improvement for modeling unreinforced mass loaded honeycomb panels. The Modified NASA Lewis Method prediction is compared to the standard ASMS VAPEPS prediction, and the acoustic test data for three spacecraft panels. An analytical method of computing variance is presented and used to compute 95 percent confidence levels. These levels are compared to the standard VAPEPS confidence levels and to the envelope of the test data. As a result of using the new methodology suggested in the paper, both the mean prediction and the 95 percent confidence level prediction agree well with the test data in both spectral shape and magnitude. Therefore, the Modified NASA Lewis Method prediction methodology may be used to define more realistic random vibration test levels.

Mcnelis, Mark E.↗
NASA NTRS1989

A modified VAPEPS method for predicting vibroacoustic response of unreinforced mass loaded honeycomb panels

VAPEPS (vibroAcoustic Payload Environment Prediction System) is a computer program used to predict the vibroacoustic response of a structure. An alternate VAPEPS modeling technique, the Modified NASA Lewis Method, is an improvement for modeling unreinforced mass loaded honeycomb panels. The Modified NASA Lewis Method prediction is compared to the standard ASMS VAPEPS prediction, and the acoustic test data for three spacecraft panels. An analytical method of computing variance is presented and used to compute 95 percent confidence levels. These levels are compared to the standard VAPEPS confidence levels and to the envelope of the test data. As a result of using the new methodology suggested in the paper, both the mean prediction and the 95 percent confidence level prediction agree well with the test data in both spectral shape and magnitude. Therefore, the Modified NASA Lewis Method prediction methodology may be used to define more realistic random vibration test levels.

Mcnelis, Mark E.↗
NASA NTRS1984

SAGE and SAM II measurements of global stratospheric aerosol optical depth and mass loading

Several volcanic eruptions between November 1979 and April 1981 have injected material into the stratosphere. The SAGE and SAM II satellite systems have measured, with global coverage, the 1-micron extinction produced by this material, and examples of the data product are shown in the form of global maps of stratospheric optical depth and altitude-latitude plots of zonal mean extinction. These data, and that for the volcanically quiet period in early 1979, have been used to determine the changes in the total stratospheric mass loading. Estimates have also been made of the contribution to the total aerosol mass from each eruption. It has been found that between 1979 and mid-1981, the total stratospheric aerosol mass increased from a background level of approximately 570,000 metric tons to a peak of approximately 1,300,000 metric tons.

Kent, G. S.↗
NASA NTRS1994

Observation of mass loading in the Io plasma torus

Ground-based high-resolution spectra of emission from the Io plasma torus obtained during 53 nights of observation over a seven month period are used to measure the torus rotation speed and discern regions of the torus that are slowed by mass loading of newly ionized materials. The amount of torus slowing implies that between 2000 and 3000 kg/sec are being ionized by the torus. The slowing is spread azimuthally throughout the orbit of Io, suggesting that neutral materials emanating from Io are distributed around Jupiter much more uniformly than currently believed.

Brown, Michael E.↗
NASA NTRS2012

Correlation Results for a Mass Loaded Vehicle Panel Test Article Finite Element Models and Modal Survey Tests

High-fidelity Finite Element Models (FEMs) were developed to support a recent test program at Marshall Space Flight Center (MSFC). The FEMs correspond to test articles used for a series of acoustic tests. Modal survey tests were used to validate the FEMs for five acoustic tests (a bare panel and four different mass-loaded panel configurations). An additional modal survey test was performed on the empty test fixture (orthogrid panel mounting fixture, between the reverb and anechoic chambers). Modal survey tests were used to test-validate the dynamic characteristics of FEMs used for acoustic test excitation. Modal survey testing and subsequent model correlation has validated the natural frequencies and mode shapes of the FEMs. The modal survey test results provide a basis for the analysis models used for acoustic loading response test and analysis comparisons

Maasha, Rumaasha↗
NASA NTRS1987

A new computational model for the prediction of mass loading phenomena for solar wind interactions with cometary and planetary ionospheres

The modified gasdynamic convected-magnetic-field MHD model developed by Spreiter and Stahara (1980) to simulate the supersonic flow of the solar wind past planetary magnetoionospheres is extended to account for cases (such as Venus and comets) in which significant numbers of neutral atmospheric atoms become ionized in the surrounding flow and add to its momentum, energy, and mass. The mathematical model and the solution procedures for the nose and tail regions are explained; typical computational grids are shown; and numerical results for a comet and for the Venus ionosheath and bow shock are presented graphically. It is found that the bow shock weakens and moves further upstream of the obstacle as mass loading is increased and the flow upstream of the bow shock becomes more compressed.

Stahara, Stephen S.↗
DOE OSTI2024

Upcycling Linear Low-Density Polyethylene Waste into Graphene for High Mass Loading Supercapacitors

Polyethylene is notoriously difficult to upcycle because it decomposes into light gases at approximately 350-400 °C which prevents processing it at higher temperatures to convert it into electrode materials. We address this challenge by using an air-based, thermos-oxidative process, which heats linear low-density polyethylene (LLDPE) just below the decomposition point to initiate oxidation and cross-linking of LLDPE alkyl chains. These molecular transformations allow LLDPE to be graphenized at 950 °C without decomposing. The LLDPE-derived graphene (LLDPE-G) has a BET specific surface area up to 1,800 m2/g and Raman ID/IG ratio of 0.85. When used as electrode material for a symmetric supercapacitor with the 1 M H2SO4 electrolyte, LLDPE-G possesses an specific capacitance up to 175 F/g at mass loading of 20 mg/cm2, yielding an areal capacitance of 3.5 F/cm2. The cycling stability with capacitance demonstrates a retention of 95.8% after 100,000 cycles at high current density of 4.0 A/g.

Gao, Yuan↗
DOE OSTI2024

Upcycling Low Linear Density Polyethylene Waste into Turbostratic Graphene for High Mass Loading Supercapacitors

In this work, LLDPE was upcycled into a high quality turbostratic graphene using a pre-treatment step to oxidatively crosslink the polymer with the assistance of solid additives (KCl and K2CO3) that improve crosslinking by increasing the effective surface area of the polymer melt during processing. After this pretreatment step, the crosslinked polymer could then be carbonized and catalytically graphenized between 400-950 °C without complete decomposition of the material. The LLDPE derived graphene (LLDPE-G) obtained from this process has a Brunauer–Emmett–Teller (BET) specific surface area, up to 1800 m2g-1 and average Raman ID/IG and I2D/IG ratios of 0.85 and 0.57, respectively, indicating high quality graphene. When used as an electrode material in symmetric supercapacitors, LLDPE-G possesses an outstanding specific capacitance up to 175 Fg-1 at a mass loading of 20 mgcm-2, which is two times the commercial requirement, yielding an excellent areal capacitance of 3.5 Fcm-2. Moreover, LLDPE-G exhibits exceptional cycling stability with a capacitance retention of 95.8% after 100,000 cycles at a current density of 4.0 Ag-1. Additionally, the KCl and K2CO3 were recycled and reused over 3 complete cycles to make new LLDPE-G with the material quality and electrocapacitive performance retained and verified after each cycle. Our approach creates new opportunities for upcycling not only waste LLDPE but also other varieties of PE to high value graphene materials.

Gao, Yuan [NETL Site Support Contractor, National ↗
NASA NTRS1992

Latitudinal survey of spectral optical depths of the Pinatubo volcanic cloud - Derived particle sizes, columnar mass loadings, and effects on planetary albedo

Airborne measurements are examined of spectral optical depths, radiative fluxes, and scattered radiation fields during the NASA Caribbean mission (July 7-14, 1991) to characterize the Pinatubo volcanic cloud. The latitudinal and spectral dependence are reported of the volcanic cloud's optical depth. From these measurements moments of the particle-size distribution are determined. The change in planetary albedo induced by the volcanic cloud is calculated for the range of measured optical depths with the objective of assessing the impact on the solar radiation budget. Mid-visible optical depths higher than 0.4 were observed, placing the Pinatubo stratospheric cloud among the thickest ever measured. The latitudinal distribution of extinction shows that by July 7, 1991 the volcanic cloud had extended to 30 deg N. The effective particle radius was determined to be between 0.18 and 0.35 micron with a corresponding columnar mass loading between 35 and 80 mag/sq m.

Valero, Francisco P. J.↗
DOE OSTI2021

Biota Modeling in EPA’s Preliminary Remediation Goal and Dose Compliance Concentration Calculators for Use in EPA Superfund Risk Assessment: Explanation of Intake Rate Derivation, Transfer Factor Compilation, and Mass Loading Factor Sources

The Preliminary Remediation Goal (PRG) and Dose Compliance Concentration (DCC) calculators are screening level risk assessment tools that set forth the Environmental Protection Agency’s (EPA) recommended approaches and currently available risk assessment guidance for response actions at Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites, commonly known as Superfund. The environmental screening levels derived by the PRG and DCC calculators are used to identify isotopes contributing the highest risk and dose as well as establish preliminary remediation goals. Each calculator has residential gardening and subsistence farmer exposure scenarios that model transfer of contaminants from soil and water into various types of biota (crops and animal products). New publications of human intake rates of biota; farm animal intakes of water, soil, and fodder; and soil to plant interactions require updates be implemented into the PRG and DCC calculators. Recent improvements in the biota modeling for these calculators include newly derived biota intake rates, enhanced soil mass loading factors (MLFs), and more comprehensive soil to plant transfer factors (BV’s) and soil to tissue transfer factors (TFs) for animals. New biota have been added in both the produce and animal products categories that greatly improve the accuracy and utility of the PRG and DCC calculators and encompass greater geographic diversity on a national and international scale.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Upcycling linear low-density polyethylene waste to turbostratic graphene for high mass loading supercapacitors

Linear low-density polyethylene (LLDPE) waste is difficult to upcycle into more valuable carbon materials because it tends to completely decompose into small molecules during thermal processing. In this work, LLDPE is upcycled into a high quality turbostratic graphene using a pre-treatment step to oxidatively crosslink the polymer with the assistance of solid additives (KCl and K 2 CO 3 ) that improve crosslinking by increasing the effective surface area of the polymer melt during processing. After this pretreatment step, the crosslinked polymer could then be carbonized and catalytically graphenized between 400–950°C without decomposition of the polymer feedstock. The LLDPE derived graphene (LLDPE-G) obtained from this process has a Brunauer–Emmett–Teller (BET) specific surface area, up to 1800m 2 g -1 and average Raman I D /I G and I 2D /I G ratios of 0.85 and 0.57, respectively, indicating high quality graphene. When used as an electrode material in symmetric supercapacitors, LLDPE-G possesses a specific capacitance up to 175Fg -1 at a mass loading of 20mgcm -2 , which is two times the commercial requirement, yielding an areal capacitance of 3.5 Fcm -2 . Moreover, LLDPE-G exhibits exceptional cycling stability with a capacitance retention of 95.8 % after 100,000 cycles at a current density of 4.0 Ag -1 . Additionally, the KCl and K 2 CO 3 solids are recycled and reused over 3 complete reaction cycles to make new LLDPE-G with the material quality and electrocapacitive performance retained and verified after each cycle. Our approach creates new opportunities for upcycling waste LLDPE and other varieties of polyethylene into a higher value graphene used for electrochemical energy storage applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗