Particle sizing by weighted measurements of scattered light
A description is given of a measurement method, applicable to a poly-dispersion of particles, in which the intensity of scattered light at any angle is weighted by a factor proportional to that angle. Determination is then made of four angles at which the weighted intensity is four fractions of the maximum intensity. These yield four characteristic diameters, i.e., the diameters of the volume/area mean (D sub 32 the Sauter mean) and the volume/diameter mean (D sub 31); the diameters at cumulative volume fractions of 0.5 (D sub v0.5 the volume median) and 0.75 (D sub v0.75). They also yield the volume dispersion of diameters. Mie scattering computations show that an average diameter less than three micrometers cannot be accurately measured. The results are relatively insensitive to extraneous background light and to the nature of the diameter distribution. Also described is an experimental method of verifying the conclusions by using two microscopic slides coated with polystyrene microspheres to simulate the particles and the background.