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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

HL-2A's ELM cycle simulations by integrating BOUT++'s drift MHD and transport code

A new integrating model has been developed to couple tokamak edge multiscale magnetohydrodynamic (MHD) events and transport simulations, such as edge-localized mode (ELM) cycles. As a proof of principle, we first start from a set of three-field two-fluid model equations, which includes the pressure, current, and vorticity. Here, the equations are separated into the slowly evolving part of the axisymmetric component by taking a time average of the axisymmetric component. The time-averaged fluxes, which are quadratic in fluctuating quantities, act as driven terms for the time-averaged axisymmetric quantities that determine the plasma transport, and therefore the large-scale evolution of the plasma profiles. Then the HL-2A's ELM cycles are simulated using the model. Good agreements of ELM size and pedestal recovery time have been achieved for the solutions obtained from the coupled simulation compared with experiment. For one ELM cycle simulation, the coupled code can achieve a speedup of a factor of up to 30 over standalone code.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1995

Probabilistic Fatigue And Flaw-Propagation Analysis

Probabilistic Failure Assessment for Fatigue and Flaw Propagation (PFAFAT II) package of software utilizing probabilistic failure-assessment (PFA) methodology to model flaw-propagation and low-cycle-fatigue modes of failure of structural components. Comprises one program for performing probabilistic crack-growth analysis and two programs for performing probabilistic low-cycle-fatigue analysis. These programs perform probabilistic fatigue and crack-propagation analysis by means of Monte Carlo simulation. PFAFAT II is extension of, rather than replacement for, PFAFAT software (NPO-18965). Written in FORTRAN 77.

Moore, Nicholas↗
DOE OSTI2022

Methods and system for a battery

Systems and methods for operating a redox flow battery system may include switching the redox flow battery system to an idle mode, wherein the idle mode includes operation of the redox flow battery system outside of a charging mode and outside of a discharge mode; in response to switching to the idle mode, repeatedly cycling operation of an electrolyte pump between an idling threshold flow rate less than a charging threshold flow rate and a deactivation threshold flow rate; and in response to switching to the charging mode, maintaining operation of the electrolyte pump at the charging threshold flow rate greater than the idling threshold flow rate. In this way, a responsiveness of the redox flow battery system to charging and discharging commands can be maintained while in idle, while reducing parasitic pumping losses due to pumping and heating, and reducing shunt current losses.

Song, Yang↗
DOE OSTI2024

Electrochemical and Chemical Reactivities of Titanium Oxide-Based Materials with a Chloroaluminate Ionic Liquid Electrolyte for Aluminum Batteries

Here, by selecting three different types of electrode materials, we intended to better understand the Al 3+ intercalation chemistry of titanium oxide-based frameworks with an acidic chloroaluminate electrolyte. In agreement with previous reports, we confirmed that the native interstitial sites of anatase TiO 2 are less prone to accommodate Al 3 + than Li + or Na + ions, while introducing cationic vacancies largely increases the electrochemical storage capacity. Upon the first cycle, the highest reversible capacity, up to 277 mAh/g, was obtained for a hydrated layered structure featuring cationic vacancies. Total scattering data showed that the insertion of Al 3+ ions induced a strong distortion of the framework. In addition, combined 27 Al MAS NMR and DFT calculations revealed that in oxy-hydroxylated vacant sites, the coordination mode of Al 3+ ions depends on the arrangement of anions around vacancies inducing the occurrence of 4-, 5-, and 6-fold coordination modes. Further cycling experiments revealed a progressive capacity fading for all electrode materials. Using cyclic voltammetry on the used electrolyte, we evidenced that a partial dissolution has occurred, which is more pronounced for the layered hydrate compound, and that solubilized species are electrochemically active, giving rise to specific signatures in both CVs and galvanostatic experiments. Raman spectroscopy enabled us to characterize these species, which are derived from the Ti-Cl system. The solubilized species, however, eventually precipitated, as shown by a purple deposit observed on the separator and tentatively assigned to TiCl 3 , known to be insoluble in this medium. By providing further information on the Al 3+ intercalation chemistry and a better understanding of the electrochemical and chemical reactivities of electrode materials, this work will enable progress to be made in the development of aluminum-ion batteries.

Al3+-ion insertion chemistry↗
NASA NTRS2010

Supersonic Free-Jet Combustion in a Ramjet Burner

A new dual-mode ramjet combustor concept intended for operation over a wide flight Mach number range is described. Subsonic combustion mode is similar to that of a traditional ram combustor which allows operation at higher efficiency, and to lower flight Mach numbers than current dual-mode scramjets. High speed mode is characterized by supersonic combustion in a free-jet that traverses the subsonic combustion chamber to a variable nozzle. The maximum flight Mach number of this scheme is governed largely by the same physics as its classical counterpart. Although a variable combustor exit aperture is required, the need for fuel staging to accommodate the combustion process is eliminated. Local heating from shock-boundary-layer interactions on combustor walls is also eliminated. Given the parallel nature of the present scheme, overall flowpath length is less than that of present dual-mode configurations. Cycle analysis was done to define the flowpath geometry for computational fluid dynamics (CFD) analysis, and then to determine performance based on the CFD results. CFD results for Mach 5, 8, and 12 flight conditions indicate stable supersonic free-jet formation and nozzle reattachment, thereby establishing the basic feasibility of the concept. These results also reveal the structure of, and interactions between the free-jet and recirculating combustion chamber flows. Performance based on these CFD results is slightly less than that of the constant-pressure-combustion cycle analysis primarily due to these interactions. These differences are quantified and discussed. Additional CFD results at the Mach 8 flight condition show the effects of nozzle throat area variation on combustion chamber pressure, flow structure, and performance. Calculations with constant temperature walls were also done to evaluate heat flux and overall heat loads. Aspects of the concept that warrant further study are outlined. These include diffuser design, ramjet operation, mode transition, loss mechanisms, and the effects of secondary flow for wall cooling and combustion chamber pressurization. Also recommended is an examination of system-level aspects such as weight, thermal management and rocket integration as well as alternate geometries and variable geometry schemes.

Trefny, Charles J.↗
DOE OSTI2025

Deciphering the local structure of Prussian blue analogue cathodes with Raman spectroscopy for sodium-ion batteries

Iron-based Prussian blue analogues (PBAs) have gained attention as low-cost, relatively higher-potential cathodes for sodium-ion batteries, due to their open 3D-framework structures. However, understanding the local structural changes is critical to unveiling the intercalation pathways and degradation mechanisms. We employ here operando Raman spectroscopy to probe the changes in the cyanide vibrational modes during cycling and degradation after cycling, which are not adequately resolved by X-ray diffraction due to the low structure factor and limited X-ray sensitivity of the cyanide groups. Vibrational spectroscopy has thus proven essential for deciphering these complex materials. Additionally, we implement pre-sodiation strategies to assess the impact of sodium inventory loss by pairing PBAs with a hard carbon anode in a full-cell configuration. Operando galvanostatic electrochemical impedance spectroscopy (EIS) and ex situ X-ray photoelectron spectroscopy (XPS) further elucidate the interface evolution and the role of water molecules in forming the cathode-electrolyte interphase (CEI) and solid-electrolyte interphase (SEI). The insights gained advance the understanding of PBAs and enhance their practical viability.

25 ENERGY STORAGE↗
DOE OSTI2022

Dispatch Optimization, System Design and Cost Benefit Analysis of a Nuclear Reactor with Molten Salt Thermal Storage

Variable renewable energy availability has increased the volatility in energy prices in most markets. Nuclear power plants, with a large ratio of capital to variable costs, have historically operated as base load energy suppliers but the need for more flexible operation is increasing. We simulate the techno-economic performance of a 950 MWt nuclear power plant, based on the Westinghouse lead-cooled fast reactor, coupled with molten salt thermal storage as a method for flexible energy dispatch. We use the System Advisor Model to model the nuclear reactor thermal power input and power cycle operating modes. We combine this robust engineering model with a mixed-integer linear program model for optimized dispatch scheduling. We then simulate the coupled nuclear and thermal storage system under different market scenarios with varying price volatility. We find that the coupled plant outperforms the base plant under markets where energy price peaks fluctuate by a factor of two or more about the mean price. We show that a calculated power purchase agreement price for the plant improves by up to 10% when operating under California energy market conditions. Sensitivity analysis on the thermal storage cost shows that the optimal design remains unchanged even when doubling costs.

25 ENERGY STORAGE↗
NASA NTRS1970

Load cell for thermionic converter tests

Stable, low duty cycle transistorized emitter follower load cell controls and absorbs large currents at low voltages. The use of energy storage in capacitors reduces auxiliary power source requirements. Low duty cycle pulse mode of operation reduces the average power handling requirement of all components.

Breitwieser, R.↗
NASA NTRS1972

Pioneer F/G feed movement mechanism

The Pioneer F/G spacecraft achieves the desired earth-pointing direction through a system requiring the shifting of the main antenna feed 1 in. off axis. The feed is pivoted to this position by an electrically heated thermal actuator consisting of an electroless nickel bellows in a copper housing and filled with Freon 21. The actuator overtravels and maintains the feed in the offset position in a thermostatic limit cycle operation mode until commanded off. The mechanism is expected to operate in a -240 F environment near Jupiter and was successfully tested at such temperatures.

R. M. Acker↗
NASA NTRS1971

Combustion dynamics in liquid rocket engines

A chemical analysis of the emission and absorption spectra in the combustion chamber of a nitrogen tetroxide/aerozine-50 rocket engine was conducted. Measurements were made under conditions of preignition, ignition, and post combustion operating periods. The cause of severe ignition overpressures sporadically observed during the vacuum startup of the Apollo reaction control system engine was investigated. The extent to which residual propellants or condensed intermediate reaction products remain after the engine has been operated in a pulse mode duty cycle was determined.

Mclain, W. H.↗
NASA NTRS1976

Emissions of an AVCO Lycoming 0-320-DIAD air cooled light aircraft engine as a function of fuel-air ratio, timing, and air temperature and humidity

A carbureted aircraft engine was operated over a range of test conditions to establish the exhaust levels over the EPA seven-mode emissions cycle. Baseline (full rich production limit) exhaust emissions at an induction air temperature of 59 F and near zero relative humidity were 90 percent of the EPA standard for HC, 35 percent for NOx, and 161 percent for CO. Changes in ignition timing around the standard 25 deg BTDC from 30 deg BTDC to 20 deg BTDC had little effect on the exhaust emissions. Retarding the timing to 15 deg BTDC increased both the HC and CO emissions and decreased NOx emissions. HC and CO emissions decreased as the carburetor was leaned out, while NOx emissions increased. The EPA emission standards were marginally achieved at two leanout conditions. Variations in the quantity of cooling air flow over the engine had no effect on exhaust emissions. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased.

Meng, P. R.↗
NASA NTRS1989

Pulse modulated control synthesis for a flexible spacecraft

The describing function method is employed for the nonlinear control analysis and design of a flexible spacecraft equipped with pulse modulated reaction jets. The method provides a means of characterizing the pulse modulator in terms of its gain and phase for structural mode limit cycle analysis. Although the describing function method is inherently inexact and is not widely used in practice, a new way of utilizing it for practical control design problems is presented. It is shown that the approximations inherent in the method can be accounted as a modeling uncertainty for the nonlinear control robustness analysis. The pulse modulated control system of the Intelsat 5 spacecraft is used as an example to illustrate the concept and methodology developed in the paper. The nonlinear stability margins predicted by the describing function analysis are verified from nonlinear simulations.

Anthony, Tobin C.↗
NASA NTRS1992

NSTS Orbiter auxiliary power unit turbine wheel cracking risk assessment

The present investigation of turbine-wheel cracking problems in the hydrazine-fueled APU turbine wheel of the Space Shuttle Orbiter's Main Engines has indicated the efficacy of systematic probabilistic risk assessment in flight certification and safety resolution. Nevertheless, real crack-initiation and propagation problems do not lend themselves to purely analytical studies. The high-cycle fatigue problem is noted to generally be unsuited to probabilistic modeling, due to its extremely high degree of intrinsic scatter. In the case treated, the cracks appear to trend toward crack arrest in a low cycle fatigue mode, due to a detuning of the resonance model.

Cruse, T. A.↗
NASA NTRS1995

Probabilistic Failure Assessment For Fatigue

Probabilistic Failure Assessment for Fatigue (PFAFAT) package of software utilizing probabilistic failure-assessment (PFA) methodology to model high- and low-cycle-fatigue modes of failure of structural components. Consists of nine programs. Three programs perform probabilistic fatigue analysis by means of Monte Carlo simulation. Other six used for generating random processes, characterizing fatigue-life data pertaining to materials, and processing outputs of computational simulations. Written in FORTRAN 77.

Moore, Nicholas↗
NASA NTRS2012

Adhesive Wear of Rollers in Vacuum

This work was done to support NASA's James Webb Space Telescope that is equipped with a Near Infrared Camera and Spectrograph and Micro Shutter Assembly (MSA). A MSA mechanism's qualification test in cryogenic vacuum at 30deg K for 96K cycles resulted in roller wear and formation of some debris. Lab tests in vacuum were conducted at NASA Glenn Research Center (GRC) to understand the wear of Ti6Al4V mated with 440F steel rollers. Misalignment angle was found to have the most significant effect on debris formation. At misalignment angle of 1.4deg, significant amount of wear debris were formed within 50,000 cycles. Very few wear particles were found for a zero misalignment angle, and the total wear was small even after 367,000 cycles. The mode of wear in all the tests was attributed to adhesion, which was clearly evident from video records as well as the plate-like amalgamated debris material from both rollers. The adhesive wear rate was found to be approximately proportional to the misalignment angle. The wear is a two-way phenomenon, and the mixing of both roller materials in wear debris was confirmed by x-ray fluorescence (XRF) and EDX spectra. While there was a net loss of mass from the steel rollers, XRF and energy dispersive x-ray (EDX) spectra showed peaks of Ti on steel rollers, and peaks of Fe on Ti rollers. These results are useful for designers in terms of maintaining appropriate tolerances to avoid misalignment of rolling elements and the resulting severe wear

Shaeef, Iqbal↗
DOE OSTI2024

Research Highlight - Dispatch Optimization, System Design and Cost Benefit Analysis of a Nuclear Reactor with Molten Salt Thermal Storage

We highlight our work from our previous publication titled "Dispatch Optimization, System Design, and Cost Benefit Analysis of a Nuclear Reactor with Molten Salt Thermal Storage" published in MDPI Energies 2022 (doi.org/10.3390/en15103599). Variable renewable energy availability has increased the volatility in energy prices in most markets. Nuclear power plants, with a large ratio of capital to variable costs, have historically operated as base load energy suppliers but the need for more flexible operation is increasing. We simulate the techno-economic performance of a 950 MWt nuclear power plant, based on the Westinghouse lead-cooled fast reactor, coupled with molten salt thermal storage as a method for flexible energy dispatch. We use the System Advisor Model to model the nuclear reactor thermal power input and power cycle operating modes. We combine this robust engineering model with a mixed-integer linear program model for optimized dispatch scheduling. We then simulate the coupled nuclear and thermal storage system under different market scenarios with varying price volatility. We find that the coupled plant outperforms the base plant under markets where energy price peaks fluctuate by a factor of two or more about the mean price. We show that a calculated power purchase agreement price for the plant improves by up to 10% when operating under California energy market conditions. Sensitivity analysis on the thermal storage cost shows that the optimal design remains unchanged even when doubling costs.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS2013

Advanced Shock Position Control for Mode Transition in a Turbine Based Combined Cycle Engine Inlet Model

A dual flow-path inlet system is being tested to evaluate methodologies for a Turbine Based Combined Cycle (TBCC) propulsion system to perform a controlled inlet mode transition. Prior to experimental testing, simulation models are used to test, debug, and validate potential control algorithms. One simulation package being used for testing is the High Mach Transient Engine Cycle Code simulation, known as HiTECC. This paper discusses the closed loop control system, which utilizes a shock location sensor to improve inlet performance and operability. Even though the shock location feedback has a coarse resolution, the feedback allows for a reduction in steady state error and, in some cases, better performance than with previous proposed pressure ratio based methods. This paper demonstrates the design and benefit with the implementation of a proportional-integral controller, an H-Infinity based controller, and a disturbance observer based controller.

Csank, Jeffrey T.↗
DOE OSTI2023

Longwave infrared (6.6–11.4 µm) dual-comb spectroscopy with 240,000 comb-mode-resolved data points at video rate

Using sub-3-cycle pulses from mode-locked Cr:ZnS lasers at λ ≈ 2.4 µm as a driving source, we performed high-resolution dual-frequency-comb spectroscopy in the longwave infrared (LWIR) range. A duo of highly coherent broadband (6.6–11.4 µm) frequency combs were produced via intrapulse difference frequency generation in zinc germanium phosphide (ZGP) crystals. Fast (up to 0.1 s per spectrum) acquisition of 240,000 comb-mode-resolved data points, spaced by 80 MHz and referenced to a Rb clock, was demonstrated, resulting in metrology grade molecular spectra of N 2 O (nitrous oxide) and CH 3 OH (methane). The key to high-speed massive spectral data acquisition was low intensity and phase noise of the LWIR combs and high (7.5%) downconversion efficiency, resulting in a LWIR power of 300 mW for each comb.

Vasilyev, Sergey (ORCID:0000000225203547)↗