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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Abundances of the elements in the intergalactic medium

A summary of the X-ray and optical spectroscopic data on emission lines from elements in clusters of galaxies is presented. The best data exists for Fe. For the about 30 well-observed clusters, the mean Fe abundance is about 0.4 solar, but there appears to be a real variation of at least a factor of 2. X-ray emission lines from O, Mg, Si and S have been detected, and their abundances are within a factor of a few of solar. Analysis of optical emission lines from cooling gas due to O, N, and S also indicates abundances not too far from solar values. The implications of the presence of heavy elements in the intergalactic medium of clusters for the evolution of the chemical abundances of galaxies are discussed.

Mushotzky, Richard↗
NASA NTRS1985

Ignition of mixtures of SiH sub 4, CH sub 4, O sub 2, and Ar or N sub 2 behind reflected shock waves

Ignition delay times in mixtures of methane, silane, and oxygen diluted with argon and nitrogen were measured behind reflected shock waves generated in the chemical kinetic shock tube at Langley Research Center. The delay times were inferred from the rapid increase in pressure that occurs at ignition, and the ignition of methane was verified from the emission of infrared radiation from carbon dioxide. Pressures of 1.25 atm and temperatures from 1100 K to 1300 K were generated behind the reflected shocks; these levels are representative of those occurring within a supersonic Ramjet combustor. Expressions for the ignition delay time as a function of temperature were obtained from least squares curve fits to the data for overall equivalence ratios of 0.7 and 1.0. The ignition delay times with argon as the diluent were longer than those with nitrogen as the diluent. The infrared wavelength observations at 4.38 microns for carbon dioxide indicated that silane and methane ignited simultaneously (i.e., within the time resolution of the measurement). A combined chemical kinetic mechanism for mixtures of silane, methane, oxygen, and argon or nitrogen was assembled from one mechanism that accurately predicted the ignition of methane and a second mechanism that accurately predicted silane hydrogen ignition. Comparisons between this combined mechanism and experiment indicated that additional reactions, possibly between silyl and methyl fragments, are needed to develop a good silane methane mechanism.

Mclain, A. G.↗
NASA NTRS2024

Inverse Modeling of the Initial Stage of the 1991 Pinatubo Volcanic Cloud Accounting for Radiative Feedback of Volcanic Ash

The way volcanic clouds evolve is very sensitive to the initial spatial 3D distributions of volcanic materials, which are often unknown. In this study, we conducted inverse modeling of the Mt. Pinatubo cloud using TOMS 2D mapping of Aerosol Index and SO 2 loading during the first three post-eruption days to estimate the time-dependent emissions profiles and initial 3D spatial distributions of volcanic ash and SO 2 . We account for aerosol radiative feedback and dynamic lofting of volcanic ash in the inversion calculations for the first time. This resulted in a lower ash injection height (by 1.5 km for ash) than without ash radiative feedback. The Pinatubo eruption ejected ≈77% of fine ash at 12 to 23 km, ≈65% of SO 2 at 18–25 km. In contrast with previous studies, which suggested that all volcanic materials were emitted above the tropopause, a significant fraction of SO 2 (5.1 of 15.5 Mt) and fine ash (37.2 of 66.5 Mt) were ejected in the troposphere, where SO 2 quickly oxidized into sulfate aerosol that is short-lived in the troposphere. This explains the early presence of sulfate aerosols in the plume and why the models can reproduce the observed volcanic aerosols' optical depth (AOD), assuming lower-than-observed SO 2 emission in the stratosphere. Despite the quicker than in observations build-up of sulfate AOD, in a month after the eruption, the evolution of the Pinatubo AOD simulated using the obtained ash and SO 2 initial distributions converges with the available stratospheric aerosol and gas experiment (SAGE) observations.

Pinatubo volcanic ash and SO2 emissions↗
NASA NTRS2013

An Archival Chandra and XMM-Newton Survey of Type 2 Quasars

In order to investigate obscuration in high-luminosity type 2 active galactic nuclei (AGNs), we analyzed Chandra and XMM-Newton archival observations for 71 type 2 quasars detected at 0.05 < z < 0.73, which were selected based on their [O III] lambda5007 emission lines. For 54 objects with good spectral fits, the observed hard X-ray luminosity ranges from 2 × 10(exp 41) to 5.3 × 10(exp 44) erg s(exp −1), with a median of 1.1 × 10(exp 43) erg s(exp −1). We find that the means of the column density and photon index of our sample are log N(sub H) = 22.9 cm(exp −2) and gamma = 1.87, respectively. From simulations using a more physically realistic model, we find that the absorbing column density estimates based on simple power-law models significantly underestimate the actual absorption in approximately half of the sources. Eleven sources show a prominent Fe K alpha emission line (EW>100 eV in the rest frame) and we detect this line in the other sources through a joint fit (spectral stacking). The correlation between the Fe K alpha and [O III] fluxes and the inverse correlation of the equivalent width of the Fe Kα line with the ratio of hard X-ray and [O III] fluxes is consistent with previous results for lower luminosity Seyfert 2 galaxies. We conclude that obscuration is the cause of the weak hard X-ray emission rather than intrinsically low X-ray luminosities. We find that about half of the population of optically selected type 2 quasars are likely to be Compton thick. We also find no evidence that the amount of X-ray obscuration depends on the AGN luminosity (over a range of more than three orders of magnitude in luminosity).

quasars: general↗
NASA NTRS1980

Forbidden lines of np/q/ ions. I - Detailed balance and line intensity ratios

The detailed balance equations are solved in the ground state terms of 37 ions of C, N, O, Ne, Mg, Si, S and Fe; atomic data for 235 transitions of these ions are tabulated, and 14 line ratios of q = 2,4 ions and eight line ratios of q = 3 ions are graphed. Forbidden emission lines of these ions are in the far and near UV, visible, and near and far IR regions of the spectrum. In addition, detailed calculations of the relative populations of the levels of the ground state are presented as a function of temperature and density.

Kafatos, M.↗
NASA NTRS1996

Microwave Observations andf Modeling of O(sub 2) ((sup 1)delta-(sub g)) and O(sub 3) Diurnal Variation in the Mesosphere

The first microwave measurements of an electronically excited molecular species in the Earth's atmosphere are presented. Local thermodynamic equilibrium (LTE) rotational line emission from mesopheric O(sub 2) ((sup 1)delta-(sub g)) was observed at a frequency of 255.01794 GHz (Lambda approx. 1.2mm), employing the National Radio Astronomy Observatory (NRAO) millimeter facility at Kitt Peak, Arizona (32(deg)N, 111(deg)W).

photolysis ozone↗
NASA NTRS1989

Utraviolet observations of the planetary nebula NGC 2242

IUE observations of NGC 2242 reveal strong emission lines of C IV, He II, semi-forbidden C III, and forbidden Ne IV, along with weaker emissions from O IV and N IV. It is found that the oxygen abundance is about 1/6 of the solar value for T(e) = 25,000 K, and that the N/H and Ar/H ratios are down by a factor of 2-3 from typical disk PN values. The present abundance pattern resembles that observed in the halo planetary DDDM-1, except for the unusually low C/O ratio in DDDM-1.

Garnett, Donald R.↗
NASA NTRS1995

Near-infrared and optical spectroscopy of FSC 10214+4724

New infrared and optical spectroscopic observations, obtained with the W. M. Keck Telescope, are reported for the highly luminous infrared source FSC 10214+4724. The rest frame optical spectrum shows new emission lines of (Ne III), (Ne V), (O I), (O II), (S II), and He(+), while the rest frame ultraviolet spectrum shows new lines of O IV) + Si IV, N III, N IV), Si II, Ne IV, and possibly N II and (Ne III), as well as clearly showing that Ly-alpha is self-absorbed. The emission-line spectrum is most characteristic of a Seyfert 2 nucleus. The preponderance of spectroscopic evidence strengthens the case for a dust-enshrouded Active galactic nuclei (AGN) powering much or most of the observed luminosity. The various spectral lines lead to a wide range in the inferred reddening and ionization parameter for this system, suggesting that we are viewing several environments through differing extinctions.

Soifer, B. T.↗
NASA NTRS2002

C-H Hot Bands in the Near-IR Emission Spectra of Leonids

The reported infrared (IR) emission spectra from 1999 Leonid fireballs show a 3.4 micron C-H emission band and unidentified bands at longer wavelengths. Upon atmospheric entry, the Leonid meteorites were flash-heated to temperatures around 2400K, which would destroy any organics on the surface of the meteorite grains. We propose that the nu(sub )CH emission band in the Leonid emission spectra arises from matrix-embedded C(sub n)-H-O entities that are protected from instant pyrolysis. Our model is based on IR absorption nu(sub )CH bands, which we observed in laboratory-grown MgO and natural olivine single crystals, where they arise from C(sub n)-H-O units imbedded in the mineral matrix, indicative of aliphatic -CH2- and -CH3 organics. Instead of being pyrolyzed, the C(sub n)-H-O entities in the Leonid trails become vibrationally excited to higher levels n = 1, 2, 3 etc. During de-excitation they emit at 3.4 microns, due to the (0 => 1) transition, and at longer wavelengths, due to hot bands. As a first step toward verifying this hypothesis we measured the C-H vibrational manifold of hexane (C6H14). The calculated positions of the (2 => l ) , (3 => 2), and possibly (4 => 3) hot bands agree with the Leonid emission bands at 3.5, 3.8 and 4.l microns.

Freund, F. T.↗
NASA NTRS1977

The chemical composition of three planetary nebulae in the Magellanic Clouds

The paper studies the detailed spectral characteristics of the planetary nebulae N97 and N153 in the Large Magellanic Cloud (LMC), the planetary nebula N67 in the Small Magellanic Cloud (SMC), and the small H II regions N9, N61, and N81 in the SMC. Electron temperatures and densities for each nebula are derived from emission-line strengths determined by photographic spectrophotometry, and relative abundances are estimated for H, He, N, O, Ne, Ar, and S. The results show that: (1) N67 has a 60% overabundance in He/H while N97 and N153 have approximately normal He/H values; (2) all three planetaries have N/H values comparable to those of galactic planetaries but substantially higher than found in the H II regions of their respective Cloud; (3) the O/H values in the planetaries are similar to or lower than those in the H II regions of the respective Cloud; (4) the O/Ne, O/S, and O/Ar ratios in the two LMC planetaries are comparable to those in galactic planetaries; (5) the compositions of the small H II regions in the SMC are nearly identical to those of previously studied large H II regions in the same Cloud; and (6) the He/H ratio of the interstellar gas in the SMC is about 25% less than that in the Galaxy. It is concluded that most of the N abundance in both Clouds arose from nucleosynthesis sources other than planetary nebulae.

Dufour, R. J.↗
NASA NTRS1996

Results of Detailed Modeling of the Narrow-Line Region of Seyfert Galaxies

We present model line profiles of [O II] lambda3727, [Ne III] lambda3869, [O I] lambda5007, [Fe VII] lambda6087, [Fe X] lambda6374, [O I] lambda6300, H(alpha) lambda6563, and [S 2] lambda6731. The profiles presented here illustrate explicitly the pronounced effects that collisional de-excitation, and that spatial variations in both the ionization parameter and cloud column density, have on Narrow-Line Region (NLR) model profiles. The above effects were included only qualitatively in a previous analytical treatment by Moore and Cohen. By making a direct correspondence between these model profiles and the analytical model profiles of Moore and Cohen, and by comparing with the observed profiles presented in a companion paper and also with those presented elsewhere in the literature, we strengthen some of the conclusions of Moore and Cohen. Most notably, we argue for constant ionization parameter, uniformly accelerated outflow of clouds that are individually stratified in ionization, and the interpretation of emission-line width correlations with ionization potential as a column density effect. For comparison with previous observational studies, such as our own in a companion paper, we also calculate profile parameters for some of the models, and we present and discuss the resulting line width correlations with critical density (n(sub cr)) and Ionization Potential (IP). Because the models we favor are those that produce extended profile wings as observed in high spectral resolution studies, the line width correlations of our favoured models are of particular interest. Line width correlations with n(sub cr) and/or IP result only if the width parameter is more sensitive to extended profile wings than is the Full Width at Half-Maximum (FWHM). Correlations between FWHM and n(sub cr) and/or IP result only after convolving the model profiles with a broad instrumental profile that simulates the lower spectral resolution used in early observational studies. The model in agreement with the greatest number of observational considerations has electron density decreasing outward from n(sub e) approx. equals 10(exp 6)/cu cm to n(sub e) approx. equals 10(exp 2)/cu cm and, due to collisional de-excitation effects in the lowest velocity clouds, it generates broad flat-topped profile peaks in the lines of lowest critical density (e.g., [O II] lambda3727 and [S II] lambda(lambda)6716, 6731). Because the observed profile peaks of both low and high critical density lines are often very similar, our favored model requires a contribution to NLR emission-line spectra from low-velocity, low-density, and low-ionization gas not included in the model NLR.

Moore, David↗
NASA NTRS2005

Variations in the Peak Position of the 6.2 micron Interstellar Emission Feature: A Tracer of N in the Interstellar Polycyclic Aromatic Hydrocarbon Population

This paper presents the results of an investigation of the molecular characteristics that underlie the observed peak position and profile of the nominal 6.2 micron interstellar emission band generally attributed to the CC stretching vibrations of polycyclic aromatic hydrocarbons (PAHs). It begins with a summary of recent experimental and theoretical studies ofthe spectroscopic properties of large (>30 carbon atoms) PAH cations as they relate to this aspect of the astrophysical problem. It then continues with an examination of the spectroscopic properties of a number of PAH variants within the context of the interstellar 6.2 micron emission, beginning with a class of compounds known as polycyclic aromatic nitrogen heterocycles (PANHs; PAHs with one or more nitrogen atoms substituted into their carbon skeleton). In this regard, we summarize the results of recent relevant experimental studies involving a limited set of small PANHs and their cations and then report the results of a comprehensive computational study that extends that work to larger PANH cations including many nitrogen-substituted variants of coronene(+) (C24H12(+)), ovalene(+) (C32H14(+)), circumcoronene(+) (C54H18(+)), and circum-circumcoronene(+) (C96H24(+)). Finally, we report the results of more focused computational studies of selected representatives from a number of other classes of PAH variants that share one or more of the key attributes of the PANH species studied. These alternative classes of PAH variants include (1) oxygen- and silicon-substituted PAH cations; (2) PAH-metal ion complexes (metallocenes) involving the cosmically abundant elements magnesium and iron; and (3) large, asymmetric PAH cations. Overall, the studies reported here demonstrate that increasing PAH size alone is insuEcient to account for the position of the shortest wavelength interstellar 6.2 micron emission bands, as had been suggested by earlier studies. On the other hand, this work reveals that substitution of one or more nitrogen atoms within the interior of the carbon skeleton of a PAH cation induces a significant blueshift in the position of the dominant CC stretching feature of these compounds that is suf6cient to account for the position of the interstellar bands. Subsequent studies of the effects of substitution by other heteroatoms (O and Si), metal ion complexation (Fe(+), Mg(+), and Mg(2+)), and molecular symmetry variation-all of which fail to reproduce the blueshift observed in the PANH cations-indicate that N appears to be unique in its ability to accommodate the position of the interstellar 6.2 micron bands while simultaneously satisfying the other constraints of the astrophysical problem. This result implies that the peak position of the interstellar feature near 6.2 micron traces the degree of nitrogen substitution in the population, that most of the PAHs responsible for the interstellar IR emission features incorporate nitrogen within their aromatic networks, and that a lower limit of 1%-2% of the cosmic nitrogen is sequestered within the interstellar PAH population. Finally, in view of the ubiquity and abundance of interstellar PAHs and the permanent dipoles and distinctive electronic structures of these nitrogen-substituted variants, this work impacts a wide range of observational phenomena outside of the infrared region of the spectrum including the forest of unidentified molecular rotational features and the anomalous Galactic foreground emission in the microwave, and the diffuse interstellar bands (DIBs) and other structure in the interstellar extinction curve in the ulhviolet/visible. These astrophysical ramifications are discussed, and the dipole moments and rotational constants are tabulated to facilitate further investigations of the astrophysical role of nitrogen-substituted aromatic compounds.

Hudgins, Douglas M.↗
NASA NTRS1982

The ionization structure of the Ring Nebula. II - Ultraviolet observations

Good agreement is found for O and N abundances, and the importance of charge-transfer reactions to the ionization of Ne is confirmed, in UV observations of emission line intensities for four positions in the Ring Nebula that have been previously studied optically. It is noted that the C(2+) abundance inferred from the optical 4267 A recombination line is as much as 10 times brighter than that measured from the UV lines, and that this discrepancy is greatest near the central star. The most attractive explanation for this phenomenon is the resonance fluorescence due to light from the central star. Both Ne/O and C/H abundances are in good agreement with previously measured average values for planetary nebulae.

Barker, T.↗
NASA NTRS1976

H2CO emission at 2 millimeters in dark clouds

The paper reports the detection of the 2-mm emission line due to the 2(12)-1(11) transition of H2CO at two positions in the Taurus dark cloud and one position in the dark cloud L134 N. The profiles of the observed emissions are plotted, and peak radiation temperatures at 2 mm are determined for the three positions. These radiation temperatures are used along with data on the 2-mm H2CO absorption line and computed cross sections for H2-H2CO collisions to deduce the molecular hydrogen density and the ortho-H2CO column density in the two clouds. The results are shown to support previous theoretical estimates of the H2CO/H2 and the H2(C-12)O/H2(C-13)O ratios. It is concluded that if the abundances of CS and HCN in the clouds are equal to that of H2CO, emissions from these molecules should be easily detectable.

Evans, N. J., II↗
NASA NTRS2023

The Mid-Infrared Molecular Inventory Towards Orion IRc2

We present the first high spectral resolution mid-infrared survey in the Orion BN/KL region, covering 7.2 to 28.3μm. With SOFIA/EXES we target the enigmatic source Orion IRc2. While this is in the most prolifically studied massive star-forming region, longer wavelengths and molecular emission lines dominated previous spectral surveys. The mid-infrared observations in this work access different components and molecular species in unprecedented detail. We unambiguously identify two new kinematic components, both chemically rich with multiple molecular absorption lines. The “blue clump” has ν LSR = −7.1 ± 0.7 km s −1 and the “red clump” 1.4 ± 0.5 km s −1 . While the blue and red clump shave similar temperatures and line widths, molecular species in the blue clump have higher column densities. They are both likely linked to pure rotational H 2 emission also covered by this survey. This work provides evidence for the scenario that the blue and red clumps are distinct components unrelated to the classic components in the Orion BN/KL region. Comparison to spectroscopic surveys towards other infrared targets in the region show that the blue clump is clearly extended. We analyze, compare, and present in depth findings on the physical conditions of C 2 H 2 , 13 CCH 2 , CH 4 , CS, H 2 O, HCN, H 13 CN, HNC, NH 3 , and SO 2 absorption lines and an H 2 emission line associated with the blue and red clumps. We also provide limited analysis of H 2 O and SiO molecular emission lines towards Orion IRc2 and the atomic forbidden transitions [FeII], [SI], [SIII], and [NeII].

Atomic spectroscopy↗
NASA NTRSDate not supplied

Radiative Emission in Incident Air Shocks from 3-7 km/s

This paper reports experimental characterization of shock layer radiation in Air at low velocities (3-7 km/s) measured in the Electric Arc Shock Tube at NASA Ames Research Center. This included shock conditions from 3-5 km/s and 2-10 Torr to measure ultraviolet and mid-infrared radiation from NO and two nominal equilibrium conditions of 6 km/s, 2.0 Torr and 7 km/s, 1.4 Torr which were intended to produce 1 bar post-shock conditions and produced atomic N and O radiation along with the UV NO bands. The latter conditions are compared to similar measurements in the Oxford T6 facility and shown to have good agreement, however do not agree with measurements and simulations in equilibrium.

Radiation↗
NASA NTRS1994

ASCA observations of the coronal X-ray emission of Algol

We report a 1.7 day ASCA X-ray observation of the 2.87 day binary Algol (Beta Per), centered on the secondary eclipse. Spectra accumulated for different intensity states show a prominent He-like iron K line at 6.7 keV. A two-temperature variable abundance plasma model applied to the spectra yielded temperatures of approximately 8 and approximately 30 MK. The modeled coronal abundances of Fe, O, Mg, Si, S, Ar, and Ca were a factor of 2-3 below the solar photospheric value, and N less than 0.1. These model abundance anomalies are similar to those found from the ASCA spectra of other late-type stars and may indicate either true deviations from solar abundances or problems with the assumptions and atomic physics of the plasma models. The X-ray light curve shows a factor of 2 increase in flux over 13 hr beginning in the middle of the secondary eclipse, with a shallow eclipse centered on phase 0.45. The orbital light curve is similar to that observed by ROSAT 1 year earlier. The rise in flux is caused by an increase in the emission measure of the higher temperature component. The intensity variation is not associated with any major change in the abundances or temperature of the two components.

Antunes, A.↗
NASA NTRS2003

Temperature Measurements in the Solar Transition Region Using N III Line Intensity Ratios

UV emission from B-like N and O ions a rather rare opportunity for recording spectral lines in a narrow wavelength range that can potentially be used to derive temperatures relevant to the solar transition region. In these ions, the line intensity ratios of the type (2s2p(sup 2) - 2p(sup 3)) / (2s(sup 2)2p - 2s2p(sup 2)) are very sensitive to the electron temperature. Additionally, the lines involving the ratios fall within a range of only - 12 A; in N III the lines fall in the 980 - 992 A range and in O IV in the 780 - 791 A range. In this work, we explore the use of these atomic systems, primarily in N III, for temperature diagnostics of the transition region by analyzing UV spectra obtained by the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) spectrometer flown on the Solar and Heliospheric Observatory (SOHO). The N III temperature-sensitive line ratios are measured in more than 60 observations. Most of the measured ratios correspond to temperatures in the range 5.7x10(exp 4) - 6.7x10(exp 4) K. This range is considerably lower than the calculated temperature of maximum abundance of N III, which is approx. 7.6x10(exp 4) K. Detailed analysis of the spectra further indicates that the measured ratios are probably somewhat overestimated due to resonant scattering effects in the 2s(sup 2)2p - 2s2p(sup 2) lines and small blends in the 2s2p(sup 2) - 2p3 lines. Actual lower ratios would only increase the disagreement between the ionization balance calculations and present temperature measurements based on a collisional excitation model. In the case of the O IV spectra, we determined that due to the close proximity in wavelength of the weak line (2s2p(sup 2)-2p3 transitions) to a strong Ne VIII line, sufficiently accurate ratio measurements cannot be obtained. Subject headings: atomic data --- atomic processes --- Sun: transition region --- Sun: U V radiation --- techniques: spectroscopic

Doron, R.↗