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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
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NASA NTRS1997

Structure and Stability of Burke-Schumann Diffusion Flames

The general goal of this NASA Grant is twofold: to improve our understanding of (1) the influence of buoyancy on the stability and structure of Burke-Schumann type diffusion flames, and (2) the effects of buoyancy on vortex-flame interactions in co-flow diffusion flames. A numerical code with a higher order accuracy for spatial discretization is developed in this project for simulation of time-dependent diffusion flames by Sheu and Sheu and Chen, and an extended reduced mechanism is incorporated for prediction of methane oxidation and NO(x)(NO, NO2, and N2O) formation and emission from methane Burke-Schumann diffusion flame (BSDF) as reported in Sheu, and Sheu and Chen. Initial investigation of vortex and flame interaction within the context of fast chemistry is reported. Experiments are conducted in reduced pressure to study the lift-off and stabilization of methane-fueled BSDF in reduced buoyancy environments due to reduced pressure. Measurements of temperature and species concentrations are made in normal and reduced pressure environments to study the effects of buoyancy on the structure of BSDF, and will be reported in this paper. To study the buoyancy effects on the lift-off and stabilization of methane-fueled jet diffusion flames in coflowing air, a glovebox investigation, Enclosed Laminar Flames (ELF), has been proposed and approved for space-based testing on the fourth United States Microgravity Payload (USMP-4) mission, scheduled for October 1997. A brief description of the ELF investigation is also presented.

Lee, Yong G.↗
NASA NTRS2002

The Effect of Transport and Circulation Differences on Stratospheric Ozone Recovery in Two 35-year Three-dimensional Simulations

The NASA Global Modeling Initiative (GMI) has completed two 35-year simulations with WMO future baseline boundary conditions that simulate increasing N2O and CH4 emissions and decreasing organic chlorine and bromine emissions. Simulations were done with the GMI offline chemistry and transport model using 1) 1 year of winds from the Finite-Volume General Circulation Model (FV-GCM), repeated for the 35 years, and 2) 1 year of winds from the Finite-Volume Data Assimilation System (FV-DAS), repeated for 35-years. The simulations have full stratospheric chemistry. To understand differences in simulated ozone recoveries, basic transport and circulation differences between these models are evaluated. The distribution of mean age of stratospheric air in the FV-GCM run agrees well with observations in the lower stratosphere but the FV-DAS ages are generally too low. This implies circulation and mixing differences that will affect the distributions of other trace species such as CH4, NO, and the organic halogens, all of which are responding to changing boundary conditions and are involved in ozone loss. Realism of model transport is evaluated, with particular attention given to regions and seasons where ozone recovery is expected. Preliminary results indicate increasing ozone trends in the lowermost stratosphere in summer and in the Antarctic and Arctic lower stratosphere in winter and spring.

Bhartia, P. K.↗
NASA NTRS1985

Continental sources of halocarbons and nitrous oxide

Estimates of continental sources of CFC-11, CFC-12, CCl4, CH3CCl3 and N2O are derived from the atmospheric lifetime experiment in Adrigole, Ireland, and anthropogenic emissions of CCl4 and N2O from Europe have been identified. Relative source strengths are consistent with global budgets for the halocarbons and N2O. Different industrial release patterns for halocarbons are observed for Europe, the western United States and Australia.

Prather, M. J.↗
NASA NTRS1988

The effects of biomass burning on the concentration of trace gases in the atmosphere

Over the past several years, there has been considerable interest concerning the global effects of biomass burning on concentrations of trace gases in the atmosphere. The paucity of reported studies and investigations into the effects of the Greenhouse Gases such as carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O), up until about a decade ago, would suggest that the topic was not then one of universal concern. Efforts are now being made to understand the biogenic, anthropogenic and photochemical sources of atmospheric trace gases. Biomass burning which includes the burning of forests for clearing, the burning of vegetative stubble after harvesting, and lightning and human-induced wildfires is but one consideration under the general paradigm of atmospheric perturbations. A team of researchers from the Langley Research Center, along with the Canadian Forest Ministry, Ontario, Canada collaborated in an experiment in a deforestration effort through a prescribed burn. Through a specially designed experimental modeling and instrumentation, a substantial pre-burn data set was collected. The primary focus of the pre-burn experimental activities was the emission of nitrous oxide (N2O) gas from selected sites.

Donaldson, Leon M.↗
NASA NTRS2009

Infrared Heterodyne Spectroscopy and its Unique Application to Planetary Studies

Since the early 1970's the infrared heterodyne technique has evolved into a powerful tool for the study of molecular constituents, temperatures, and dynamics in planetary atmospheres. Its extremely high spectral resolution (Lambda/(Delta)Lambda/>10(exp 6)) and highly accurate frequency measurement (to 1 part in 10(exp 8)) enabled the detection of nonthermal/natural lasing phenomena on Mars and Venus; direct measurements of winds on Venus, Mars, and Titan; study of mid-infrared aurorae on Jupiter; direct measurement of species abundances on Mars (ozone, isotopic CO2), hydrocarbons on Jupiter, Saturn., Neptune, and Titan, and stratospheric composition in the Earth's stratosphere (O3, CIO, N2O, CO2 ....). Fully resolved emission and absorption line shapes measured by this method enabled the unambiguous retrieval of molecular abundances and local temperatures and thermal structure in regions not probed by other techniques. The mesosphere of Mars and thermosphere of Venus are uniquely probed by infrared heterodyne spectroscopy. Results of these studies tested and constrained photochemical and dynamical theoretical models describing the phenomena measured. The infrared heterodyne technique will be described. Highlights in its evolution to today's instrumentation and resultant discoveries will be presented, including work at Goddard Space Flight Center and the University of Koln. Resultant work will include studies supporting NASA and ESA space missions and collaborations between instrumental and theoretical groups.

Kostiuk, Theodore↗
NASA NTRS1991

Emissions of nitrous oxide from biomass burning

A study has been conducted which compared N2O results obtained over large prescribed fires or wildfires, in which 'grab-sampling' with storage had been used with N2O measurements made in near-real time. CO2-normalized emission ratios obtained initially from the laboratory fires are substantially lower than those obtained over large-scale biomass fires. Combustion may not be the only source of N2O in large fire smoke plumes; physical, chemical, and biochemical processes in the soil may be altered by large biomass fires, leading to large N2O releases.

Winstead, Edward L.↗
NASA NTRSDate not supplied

Validation of the Aeroplanets Model in a Present-Day Earth Simulation

We present a validation of the Aeroplanets/Aerochemistry model (Gronoff et al. 2012; Airapetian et al. 2016), a one-dimensional photochemistry model, with another one-dimensional photochemistry model implemented in Hu et al. 2016. Results from a simulation of the atmosphere of present-day Earth from both models were used in the validation. Realistic initial conditions and concentrations were used in the validation, including surface emissions of CO, CH4, NH3, N2O, NO, SO2, OCS, H2S, and H2SO4. As part of the validation, we compare the vertical profile of concentration of key chemical species, including O3, N2O, NO, NO2, HNO3, HO2, OH, and CH4. Our model was able to create vertical concentration profiles of these species that closely matched the results from Hu et al. 2016. With the successful validation, we plan to use the Aeroplanets model to explore the role of ions and aerosols, formed the interaction of solar energetic particles and the atmosphere of early Earth, in generating key greenhouse gas species and gas species that support the formation of molecules crucial for life.

Bradley Michael Hegyi↗
NASA NTRS2021

Effective radiative forcing from emissions of reactive gases and aerosols - a multi-model comparison

This paper quantifies the pre-industrial (1850) to present-day (2014) effective radiative forcing (ERF) of anthropogenic emissions of NOX, volatile organic compounds (VOCs; including CO), SO2, NH3, black carbon, organic carbon, and concentrations of methane, N2O and ozone-depleting halocarbons, using CMIP6 models. Concentration and emission changes of reactive species can cause multiple changes in the composition of radiatively active species: tropospheric ozone, stratospheric ozone, stratospheric water vapour, secondary inorganic and organic aerosol, and methane. Where possible we break down the ERFs from each emitted species into the contributions from the composition changes. The ERFs are calculated for each of the models that participated in the AerChemMIP experiments as part of the CMIP6 project, where the relevant model output was available. The 1850 to 2014 multi-model mean ERFs (± standard deviations) are −1.03 ± 0.37 W/sq.m for SO2 emissions, −0.25 ± 0.09 W/sq.m for organic carbon (OC), 0.15 ± 0.17 W/sq.m for black carbon (BC) and −0.07 ± 0.01 W/sq.m for NH3. For the combined aerosols (in the piClim-aer experiment) it is −1.01 ± 0.25 W/sq.m. The multi-model means for the reactive well-mixed greenhouse gases (including any effects on ozone and aerosol chemistry) are 0.67 ± 0.17 W/sq.m for methane (CH4), 0.26 ± 0.07 W/sq.m for nitrous oxide (N2O) and 0.12 ± 0.2 W/sq.m for ozone-depleting halocarbons (HC). Emissions of the ozone precursors nitrogen oxides (NOx), volatile organic compounds and both together (O3) lead to ERFs of 0.14 ± 0.13, 0.09 ± 0.14 and 0.20 ± 0.07 W/sq.m respectively. The differences in ERFs calculated for the different models reflect differences in the complexity of their aerosol and chemistry schemes, especially in the case of methane where tropospheric chemistry captures increased forcing from ozone production.

radiative forcing↗
NASA NTRS1988

Enhanced biogenic emissions of nitric oxide and nitrous oxide following surface biomass burning

Recent measurements indicate significantly enhanced biogenic soil emissions of both nitric oxide (NO) and nitrous oxide (N2O) following surface burning. These enhanced fluxes persisted for at least six months following the burn. Simultaneous measurements indicate enhanced levels of exchangeable ammonium in the soil following the burn. Biomass burning is known to be an instantaneous source of NO and N2O resulting from high-temperature combustion. Now it is found that biomass burning also results in significantly enhanced biogenic emissions of these gases, which persist for months following the burn.

Anderson, Iris C.↗
NASA NTRS1974

Infrared heterodyne spectroscopy of astronomical and laboratory sources at 8.5 micron

The first infrared heterodyne spectrometer using tuneable semiconductor (PbSe) diode lasers has been constructed and was used near 8.5 micron to measure absorption line profiles of N2O in the laboratory and black body emission from the Moon and from Mars. Spectral information was recorded over a 200 MHz bandwidth using an 8-channel filter bank. The resolution was 25 MHz and the minimum detectable (black body) power was 1 x 10 to the minus 16th power watts for 8 minutes of integration. The results demonstrate the usefulness of heterodyne spectroscopy for the study of remote and local sources in the infrared.

Mumma, M.↗
NASA NTRS1988

Trace gas emissions from a mid-latitude prescribed chaparral fire

Smoke-plume gas samples were collected at altitudes from 35-670 m above the ground over the San Dimas Experimental Forest during a 400-acre prescribed chaparral fire. Mean emission ratios relative to CO2 for CO, H2, CH4, and total nonmethane hydrocarbons were lower than previous values obtained for large biomass-burning field experiments. Comparison of samples from vigorously flaming and mixed stages of combustion revealed little differences in CO2 normalized emission ratios for these gases (except for N2O).

Cofer, Wesley R., III↗
NASA NTRS1988

European sources of halocarbons and nitrous oxide - Update 1986

New information on seasonal and secular trends in the releases of CFCl3, CF2Cl2, CCl4, CH3CCl3, and N20 from Europe was obtained as part of the Atmospheric Lifetime Experiment. Semicontinuous measurements of these pollutants were made at Adrigole, Ireland, using lean air from the Atlantic Ocean as a baseline. The results obtained include unambiguous evidence for elevated levels of N2O occurring concurrent with halocarbon pollution events; the detection of trends in the relative emission of different halocarbons; the discovery of seasonal variations in emission of CF2Cl2, CCl4, and CH3Cl3; the characterization of typical summer and winter pollution episodes; and the identification of weather patterns over Europe that are associated with high concentrations of chlorofluorocarbons at Adrigole. It was estimated that the European source of N2O represents 25 percent of the global emissions associated with combustion and 10 percent of the integrated stratospheric losses.

Prather, Michael↗
NASA NTRS1974

Determination of the rate constant for the reaction O + NO yields N + O2

A shock-tube technique was used to determine the rate constant for the reaction O + NO yields N + O2 in the 2500-4100 K range. Mixtures of NO, N2O, and an inert gas (Ar or Kr) were shock-heated, and the decay of infrared emission from the fundamental vibration-rotation band of NO at 5.3 microns was monitored. The N2O dissociates quickly to provide a source of O atoms for the above reaction. An expression for the rate constant is derived which fits these data and previous data at higher and lower temperatures.

Hanson, R. K.↗
NASA NTRS1987

Interpretation of the N2 LBH glow observed on the S3-4 spacecraft

Emissions in the vacuum ultraviolet Lyman-Birge-Hopfield (LBH) bands of N2 were observed at night from the S3-4 spacecraft and from the Space Shuttle. No atmospheric source of this emission was identified. Conway et al. have reported that the intensity of the S3-4 LBH emission varied as the cube power of the N2 or N2O concentration. A vehicle-atmosphere interaction was suggested as the source but it was found that the needed excitation cross section would have to be unacceptably large. Recent models of the gas concentration build-up around large space vehicles predict concentrations that may be consistent with the observe LBH intensity variation with altitude. The emission in the model is generated primarily by secondary collisional excitation by ambient N2 and/or O of desorbed metastable molecular constituents. A Chapman-like production function in the induced gaseous environment results in the observed cube power of the N2 concentration altitude variation. A cross section of approximately 2.5 x 10(-18) sq cm is required for excitation of desorbed metastable N2(A) to the N2 (a 1 Pi g) state to account for the observed intensities.

Torr, D. G.↗
NASA NTRS1983

Radio searches for additional interstellar molecules

Observations in the 2-mm wavelength range are reported which yield new interstellar molecular transitions of NH2CHO, SO2, H2CCO, U150820.5, and U150850.0 toward Sgr B2, and SO2, CH2CHCN, HCOOCH3, and U153513.0 toward Orion A. The first interstellar searches for HOCl, CH3CH2CCH, and CH3SiH3 were conducted, but these species were not detected. During these observations limits were also obtained on 2-mm wave transitions of N2O and NaOH toward several galactic sources of molecular emission.

Hollis, J. M.↗
NASA NTRS1990

Gaseous emissions from Canadian boreal forest fires

CO2-normalized emission ratios for carbon monoxide (CO), hydrogen (H2), methane (CH4), total nonmethane hydrocarbons (TNMHC), and nitrous oxide (N2O) were determined from smoke samples collected during low-altitude helicopter flights over two prescribed fires in northern Ontario, Canada. The emission ratios determined from these prescribed boreal forest fires are compared to emission ratios determined over two graminoid (grass) wetlands fires in central Florida and are found to be substantially higher (elevated levels of reduced gas production relative to CO2) during all stages of combustion. These results argue strongly for the need to characterize biomass burning emissions from the major global vegetation/ecosystems in order to couple combustion emissions to their vegetation/ecosystem type.

Cofer, Wesley R., III↗
NASA NTRS1991

New estimates of nitrous oxide emissions from biomass burning

The recent discovery of an artifact producing increased levels of N2O in combustion gas samples collected and stored in grab bottles before chemical analysis has resulted in the downgrading of fossil-fuel combustion and the questioning of biomass burning as important sources of N2O. As almost all reported analyses of N2O produced from biomass burning have involved essentially the same collection and analysis protocols as used in the fossil-fuel studies, this source of N2O must also be reexamined. Here, measurements of N2O made over a large prescribed fire using a near real-time in situ measurement technique are reported and compared with measurements of N2O from simultaneously collected grab-bottle samples. The results from 27 small laboratory biomass test fires are also used to help clarify the validity of earlier assessments. It is concluded that biomass burning contributes about seven percent of atmospheric N2O, as opposed to earlier estimates of several times this value.

Cofer, W. R., III↗