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NASA NTRSDate not supplied

Mineralogy and Spectroscopy of Mount Etna Lava Flows as an Analogue to Venus

Reports of geologically recent volcanism at Venus [1–3] raise the question of whether Venus is actively resurfacing. Observing the venusian surface is difficult due to the planet’s thick, relatively opaque atmosphere, but emission from the surface is detectable via a few atmospheric windows in the near-infrared (NIR) around 1 μm [4]. Spectroscopy of rocks at these wavelengths varies due to its primary composition and the presence of secondary weathering products [2, 5, 6]. If degree of alteration can be tied to the spectroscopic response, then the weathering of the venusian surface can reveal its age and extent of recent volcanism [2, 7]. Mount Etna on Earth is a potential analogue to Venus that can aid our understanding. The composite volcano is currently active and exhibits a progression of dated lava flows with a range of textures (‘a‘¯a versus p¯ahoehoe flows) and degrees of alteration [8]. While not a perfect analogue due to differing weathering environments, Mount Etna represents a natural age progression of altered basaltic rock [8] that can provide a useful comparison to volcanic structures on Venus. Here we will determine if spectroscopy can determine the alteration state of these flows as a proxy for their age. Future missions to Venus such as VERITAS, En- Vision, and DAVINCI will observe the surface in NIR emissivity. Kirchhoff’s Law holds that e = 1−r, where e is the emissivity and r is the reflectance. NIR emissivity can be reliably calculated from reflectance measurements of rocks [9], so laboratory reflectance spectroscopy is useful to rapidly test potential Venus analogue materials.

Gabriel L. Eggers↗
NASA NTRS1986

Composition of the lunar highland crust from near-infrared spectroscopy

An attempt is made to synthesize NIR reflectance spectra of the lunar highlands to obtain global information about the composition of the lunar near-side crust. Major rock types identified include noritic, anorthositic, gabbric, and troctolitic compositions. Seventy-five percent of the areas that represent samples from the upper 1-2 km of lunar crust exhibit noritic compositions with different amounts of pyroxene and/or brecciation alteration. The data demonstrate that the lunar near-side crust is clearly mineralogically heterogeneous, both laterally and vertically, and not well mixed below 1-2 km.

Pieters, C. M.↗
NASA NTRS2003

Surface Material Analysis of the S-type Asteroids: Removing the Space Weathering Effect from Reflectance Spectrum

Recent years, many researchers have been observing a lot of asteroid reflectance spectra in the UV, visible to NIR at wavelength region. Reflectance spectroscopy of asteroid at this range should bring us a lot of information about its surface materials. Pyroxene and olivine have characteristic absorption bands in this wavelength range. Low-Ca pyroxene has two absorption bands around 0.9 microns and 1.9 microns. The more Ca and Fe content, the longer both absorption band centers. On the other hand, reflectance spectrum of olivine has three complicated absorption bands around 1 m, and no absorption feature around 2 microns. In general, reflectance spectra of many asteroids that are considered to be silicate rich (i.e., S- and A type asteroids) show redder slope and more subdued absorption bands than those of terrestrial minerals and meteorites. These features are now believed to be caused by the space weathering effect, which is probably caused by micrometeorite bombardment and/or solar wind. This process causes nanophase reduced iron (npFe(sup 0)) particles near the surface of mineral grains, which leads the optical change. Therefore, the space weathering effect should be removed from asteroid reflectance spectra to compare with those of meteorite and terrestrial minerals. In this report, we will apply the expanded modified Gaussian model (MGM) to the reflectance spectra of S-type asteroids 7 Iris and 532 Herculina and compare them with those of meteorites.

Ueda, Y.↗
NASA NTRS2010

Polycyclic Aromatic Hydrocarbons

Carbonaceous materials play an important role in space. Polycyclic Aromatic Hydrocarbons (PAHs) are a ubiquitous component of the carbonaceous materials. PAHs are the best-known candidates to account for the IR emission bands. They are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge is to reproduce in the laboratory the physical conditions that exist in the emission and absorption interstellar zones. The harsh physical conditions of the ISM -low temperature, collisionless, strong UV radiation fields- are simulated in the laboratory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions and radicals are formed from the neutral precursors in an isolated environment at low temperature and probed with high-sensitivity cavity ringdown spectroscopy in the NUV-NIR range. Carbon nanoparticles are also formed during the short residence time of the precursors in the plasma and are characterized with time-offlight mass spectrometry. These experiments provide unique information on the spectra of large carbonaceous molecules and ions in the gas phase that can now be directly compared to interstellar and circumstellar observations (IR emission bands, DIBs, extinction curve). These findings also hold great potential for understanding the formation process of interstellar carbonaceous grains. We will review recent progress in the experimental and theoretical studies of PAHs, compare the laboratory data with astronomical observations and discuss the global implications.

Salama, Farid↗
NASA NTRS1987

Star formation in the Magellanic irregular galaxy NGC 4449

New NIR and FIR maps and J = 1-0 CO spectroscopy of the Magellanic irregular galaxy NGC 4449 are presented. The brighter 150-micron emission is concentrated along the central visual ridge of the galaxy, although there is lower intensity extended emission throughout the visible extent of the object. The maximum FIR emission is coincident, within the uncertainties, with the visual and NIR maxima, identified as the galactic nucleus. It is estimated that the IR luminosity of the 1-kpc-diameter central region in NGC 4449 is comparable to that for a similar-sized region at the center of the Galaxy. A large fraction of the 150-micron emission may arise from warm dust distributed throughout the galaxy and heated by the diffuse radiation field. Active star formation follows the NIR emission in part of the galaxy, but no coincidence is found in another region.

Thronson, Harley A., Jr.↗
NASA NTRS1988

Infrared spectroscopy, imaging, and 10 micron photometry of Giclas 29-38

An NIR spectrum and several images of Giclas 29-38, a white dwarf suspected to have a brown dwarf in orbit around it, are presented. There is no absorption feature in the spectrum that is deeper than 5 percent in the wavelength range 1.95-2.45 microns, from which it is inferred that there is no feature deeper than 10 percent at 2.4 microns from any brown dwarf companion. The IR spectrum does not yield any strong constraint on whether or not the thermal emission observed from G29-38 comes from a brown dwarf or dust. The 1.6- and 2.2-micron images of G29-38 appear indistinguishable from a point source with an upper limit of 0.4 arcsec for the separation of the white dwarf and the source of the excess IR emission. This corresponds to a projected linear separation of 5.6 AU. A 2sigma limit at 10 microns of 10 mJy constrains possible alternative models for the IR excess by emission from dust grains. While the present results do not show evidence for the suspected brown dwarf companion around G29-38, the presence of such an object cannot be ruled out.

Tokunaga, A. T.↗
NASA NTRS2016

Degradation of Beta Cloth Covering for a Battery Orbital Replacement Unit in Low Earth Orbit

Samples from the beta cloth cover for a battery orbit replaceable unit from the International Space Station (ISS) were characterized using optical and electron microscopy, UV-vis-NIR spectrophotometry, and x-ray energy dispersive spectroscopy. Results showed that in areas where the fabric was exposed to solar radiation the absorptance increased by as much as 20 percent, and the peak difference was in the ultraviolet, indicating that the increased absorptance may have been due to radiation. The emissivity of the material over a temperature range of 300 to 700 K was essentially unchanged.

Solar Physics↗
NASA NTRS2016

Degradation of Beta-Cloth Covering for a Battery Orbital Replacement Unit in Low Earth Orbit

Samples from the B-cloth cover for a battery orbit replaceable unit from the International Space Station were characterized using optical and electron microscopy, UV-vis-NIR spectrophotometry, and x-ray energy dispersive spectroscopy. Results showed that in areas where the fabric was exposed to solar radiation the absorptance increased by as much as 20 percent, and the peak difference was in the ultraviolet, indicating that the increased absorptance may have been due to radiation. The emissivity of the material over a temperature range of 300 - 700 K was essentially unchanged.

Solar Physics↗
NASA NTRS2005

Experimental Near Infrared Spectroscopy of Polycyclic Aromatic Hydrocarbons Between 0.7 to 2.5 microns

The near infrared (NIR) spectra and absolute band strengths of 27 polycyclic aromatic hydrocarbon (PAH) cations and anions ranging in size from C14H10 to C50H22, are reported. The spectra from 0.7 to 2.5 microns (14,000 to 4000/cm) are presented for the fifteen PAHs ranging in size from C40H18 to C50H22 whereas the spectra of the remaining twelve span the narrower range from 0.7 to 1.1 microns (14,000 to 9000/cm). The spectra of all the ionized PAHs we have studied to date have strong, broad absorption bands in the NIR arising from electronic transitions. This work shows that ionized PAHs have significant absorption bands at longer wavelengths than predicted by the current astronomical models which consider PAHs in their treatment of the radiation balance of the interstellar medium. Two implications are 1)-ionized interstellar PAHs should add weak, broad band structure to the NIR portion of the interstellar extinction curve and 2)- UV poor radiation fields can pump the PAH emission bands provided ionized PAHs are present.

Mattioda, A. L.↗
NASA NTRS2019

Texas Spectroscopic Search for Lyα Emission at the End of Reionization. II. The Deepest Near-infrared Spectroscopic Observation at z ≳ 7

Realizing the utility of Lyα emission to trace the evolution of the intergalactic medium (IGM) during the epoch of reionization requires deep spectroscopy across the boundary of optical and near-infrared (NIR) spectrographs at z ∼ 7.2 when Lyα emission is at ∼1 μm. Our Texas Spectroscopic Search for Lyα Emission at the End of Reionization includes 18 nights of deep spectroscopic observations using the Keck DEIMOS (optical) and MOSFIRE (NIR) spectrographs. Within this data set we observe Lyα emission from 183 photometric-redshift-selected galaxies at z = 5.5–8.3 from the Cosmic Assembly Near infrared Deep Extragalactic Legacy Survey. Our overlapping MOSFIRE observations, over 84 galaxies in total, provide the deepest NIR spectroscopic data yet obtained for Lyα from galaxies z > 7, with >16 hr integration time for four observed galaxies. Here we analyze these four targets, and we report the discovery of a new z = 7.60 Lyα detection as well as provide an updated observation of the previously confirmed z = 7.51 Lyα emission from Finkelstein et al. with a ∼3× longer exposure time. Our analysis of these Lyα emission-line profiles reveals a significant asymmetric shape. The detection of Lyα from two out of three bright sources (MUV < −20.25) could imply that these bright galaxies inhabit ionized bubbles in a partially neutral IGM, although deeper exposures may reveal Lyα emission in the fainter source.

Intae Jung↗
NASA NTRS1993

Groundbased imaging spectroscopy of Mars in the near-infrared - Preliminary results

The initial results of a NIR spectral imaging study conducted from Mauna Kea Observatory during the 1990 opposition are presented. The study's main goals were to determine whether it is possible to map and monitor subtle variations in surface and atmospheric components on Mars from ground-based observations and to constrain Mars surface and airborne dust composition. Small variations near 2.3 microns include both atmospheric (CO) and surface/dust mineral absorption, although the data cannot yet accurately discriminate these components or assess their relative contributions. The present data set, even after preliminary calibration steps, demonstrates the potential of the Mars imaging spectroscopic observations in the near-IR. Focused ground-based telescopic studies in selected wavelength regions accompanied by detailed high spectral resolution atmospheric modeling will allow the mapping and monitoring of surface minerals, atmospheric aerosols, and atmospheric trace gases.

Bell, James F., III↗
NASA NTRS2021

SOFIA/FLITECAM 3-5.4 Micron Spectroscopy of PAHs in Planetary Nebulae

We present stratospheric observations of the ~3-5.4 micron spectra of young planetary nebulae by the SOFIA instrument FLITECAM. The goal of this study was to characterize the NIR emission of Polycyclic Aromatic Hydrocarbons (PAHs) in planetary nebulae and study the evolution of PAH features within these objects. Using airborne 3-5.4 micron grism spectroscopy of three young, Carbon-rich planetary nebulae: IC 5117, PNG 093.9-00.1, and BD +30 3639, we investigated the spectral variation of the 3.3 micron PAH feature, its associated aliphatic features (3.4-3.6 microns), characterized the weak 5.25 PAH emission feature, and set limits on the theoretical contribution of the 4.4-4.8 micron deuterated-PAH features. All features, including atomic emission lines, were fit with a series of Gaussians to determine their flux. We further characterized the 3.3 micron PAH feature using equivalent width and central wavelength, and classified the shape of the emission. We also determined the PAH/Aliphatic ratio for each target. The 3.3 micron PAH emission feature is observed in all three objects, as is PAH emission at 5.25 microns. PNG 093.9-00.1 exhibits NGC 7027-like aliphatic emission in the 3.4–3.6 micron region while aliphatic emission in IC 5117 and BD +30 3639 is weaker, and exhibits less structure.

Erin C Smith↗
NASA NTRS2005

Spectroscopy of Jet-Cooled Neutral and Ionized PAHs: Implications for Interstellar Dust

We present the gas-phase spectroscopy of neutral and ionized polycyclic aromatic hydrocarbons (PAHs) measured in the W-Visible-NIR range in an astrophysically relevant environment. These measurements provide data on PAHs and nanometer sized particles that can now be directly compared to astronomical observations. The harsh physical conditions of the IS medium - characterized by a low temperature, an absence of collisions and strong VUV radiation fields - are simulated in the laborat'ory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions are formed from the neutral precursors in an isolated environment at low temperature ($\sim lOO$-K). The spectra of neutral and ionized PAHs are measured using the high sensitivity methods of cavity ring down spectroscopy (CRDS) and multiplex integrated cavity output spectroscopy (MICOS). These experiments provide unique information on the spectra of free, cold large carbon molecules and ions in the gas phase. The electronic bands measured for ionized PAH are found to be intrinsically broad ($\geq$20 cm$^{-l}$) while the bands associated with the neutral precursors are narrower (of the order of 2 - 10 cm$^{-l}$). The laboratory data are discussed and compared with recent astronomical spectra of large and narrow DIBs and with the spectra of circumstellar environments of selected carbon stars (see contribution of Cami et al.) and the implications for the interstellar PAH population are derived. Preliminary results also show that carbon nanoparticles are formed during the short residence time of the precursors in the plasma. This finding holds great potential for understanding the formation process of interstellar grains.

Salama, F.↗
NASA NTRS2019

Optical Instrument Thermal Control on the Large Ultraviolet/Optical/Infrared Surveyor

The Large Ultraviolet/Optical/Infrared Surveyor (LUVOIR) is a multi-wavelength observatory commissioned by NASA as one of four large mission concept studies for the Astro2020 Decadal Survey. Two concepts are under study which bound a range of cost, risk, and scientific return: an 8-meter diameter unobscured segmented aperture primary mirror and a 15-meter segmented aperture primary mirror. Each concept carries with it an accompanying suite of instruments. The Extreme Coronagraph for Living Planetary Systems (ECLIPS) is a near-ultraviolet (NUV) / optical / near-infrared (NIR) coronagraph; the LUVOIR Ultraviolet Multi-object Spectrograph (LUMOS) provides multi-object imaging spectroscopy in the 100-400 nanometer ultraviolet (UV) range; and the High Definition Imager (HDI) is a wide field-of-view near-UV / optical / near-IR camera that can also perform astrometry. The 15-meter concept also contains an additional instrument, Pollux, which is a high-resolution UV spectro-polarimeter. While the observatory is nominally at a 270 Kelvin operational temperature, the requirements of imaging in both IR and UV require separate detectors operating at different temperature regimes, each with stringent thermal stability requirements. The change in observatory size requires two distinct thermal designs per instrument. In this current work, the thermal architecture is presented for each instrument suite. We describe here the efforts made to achieve the target operational temperatures and stabilities with passive thermal control methods. Additional discussion will focus on how these instrument thermal designs impact the overall system-level architecture of the observatory and indicate the thermal challenges for hardware implementation.

Decadal Study↗
NASA NTRS2019

Optical Instrument Thermal Control on the Large Ultraviolet/Optical/Infrared Surveyor

The Large Ultraviolet/Optical/Infrared Surveyor (LUVOIR) is a multi-wavelength observatory commissioned by NASA as one of four large mission concept studies for the Astro2020 Decadal Survey. Two concepts are under study which bound a range of cost, risk, and scientific return: an 8-meter diameter unobscured segmented aperture primary mirror and a 15-meter segmented aperture primary mirror. Each concept carries with it an accompanying suite of instruments. The Extreme Coronagraph for Living Planetary Systems (ECLIPS) is a near-ultraviolet (NUV) / optical / near-infrared (NIR) coronagraph; the LUVOIR Ultraviolet Multi-object Spectrograph (LUMOS) provides multi-object imaging spectroscopy in the 100-400 nanometer ultraviolet (UV) range; and the High Definition Imager (HDI) is a wide field-of-view near-UV / optical / near-IR camera that can also perform astrometry. The 15-meter concept also contains an additional instrument, Pollux, which is a high-resolution UV spectro-polarimeter. While the observatory is nominally at a 270 Kelvin operational temperature, the requirements of imaging in both IR and UV require separate detectors operating at different temperature regimes, each with stringent thermal stability requirements. The change in observatory size requires two distinct thermal designs per instrument. In this current work, the thermal architecture is presented for each instrument suite. We describe here the efforts made to achieve the target operational temperatures and stabilities with passive thermal control methods. Additional discussion will focus on how these instrument thermal designs impact the overall system-level architecture of the observatory and indicate the thermal challenges for hardware implementation.

LUVOIR↗
NASA NTRS2011

PING Gamma Ray and Neutron Measurements of a Meter-Sized Carbonaceous Asteroid Analog

Determining the elemental composition of carbonaceous (spectral type C) asteroids is still one of the basic problems when studying these objects. The only main source of elemental composition information for asteroids is from their optical, NIR and IR properties, which include their spectral reflectance characteristics, albedo, polarization, and the comparison of optical spectroscopy with meteorite groups corresponding to asteroids of every spectral type. Unfortunately, these sources reflect observations from widely contrasting spatial scales that presently yield a void in the continuum of microscopic and macroscopic evidence, a lack of in situ measurement confirmation, and require deeper sensing techniques to discern the nature of these asteroids. The Probing In situ with Neutrons and Gamma rays (PING) instrument is ideally suited to address this problem because it can be used to determine the bulk elemental composition, H and C content, the average atomic weight and density of the surface and subsurface layers of C-type asteroids, and can provide measurements used to determine the difference between and distinguish between different types of asteroids. We are currently developing the PING instrument that combines gamma ray and neutron detectors with a 14 Me V pulsed neutron generator to determine the in-situ bulk elemental abundances and geochemistry of C-type asteroids with a spatial resolution of 1 m down to depths of tens of cm to 1 m. One aspect of the current work includes experimentally testing and optimizing PING on a known meter-sized Columbia River basalt C-type asteroid analog sample that has a similar composition and the same neutron response as that of a C-type asteroid. An important part of this effort focuses on utilizing timing measurements to isolate gamma rays produced by neutron inelastic scattering, neutron capture and delayed activation processes. Separating the gamma ray spectra by nuclear processes results in higher precision and sensitivity elemental composition measurements. Using gated data acquisition techniques allows for the unambiguous identification of gamma ray lines from different isotopes and nuclear processes, especially in situations when limited detector resolution results in overlapping gamma ray lines that cannot be individually resolved. In this paper, we will present the PING basalt layering experimental data, taken at the test facility at NASA Goddard Space Flight Center using the time tagged event-by-event data analysis technique, compared to our MCNPX computer simulation results for the C-type asteroid and basalt layering simulant models. Comparison of these data will show the advantages, validity, and measurement sensitivity of PING's nuclear interrogation methods to obtain more precise and sensitive in situ bulk elemental composition and density measurements of the subsurface of asteroids.

Bodnarik, J.↗
NASA NTRSDate not supplied

Spectroscopy of Mount Etna Lava Flows as A Proxy for Age: A Potential Analogue to Recent Volcanism on Venus

There is growing evidence of geologically recent volcanism at Venus [1–3], a question that may be resolved by forthcoming missions to our sister planet that will make spectroscopic measurements of the surface. The thick, relatively opaque atmosphere of Venus makes observation difficult, but a few key atmospheric windows in the near-infrared (NIR) around 1 μm make emission from the surface detectable [4]. At these wavelengths, the spectroscopic signature of rocks are due to its primary mineralogy and chemistry, as well as the presence of secondary weathering minerals [2, 5, 6]. If the degree of alteration can be tied to the spectroscopy of Venus analogue materials, then spectroscopy of venusian lava flows can potentially reveal their degree of weathering and thus their age, which in turn gives an estimate of the extent of recent volcanism [2, 7]. A potential Earth analogue to volcanoes on Venus is Mount Etna in Sicily, Italy [8]. This composite volcano is among the most active in the world and features mafic lava flows with definitive ages that exhibit varying degrees of alteration [9]. While Mount Etna is not a perfect analogue due to its different weathering environment, the natural age progression of altered basaltic rock can be a useful comparison. Here, we will investigate how weathering at Mount Etna affects spectroscopic measurements and if this can be used as a proxy for Venus. While planned missions to Venus such as DAVINCI, VERITAS, and EnVision will measure NIR emissivity from the surface, Kirchhoff’s Law states that e = 1 − r, where e is emissivity and r is reflectance, meaning that NIR emissivity can be estimated from reflectance measurements [10]. Given its relative ease, laboratory reflectance spectroscopy is a useful tool to efficiently test potential Venus analogue materials.

Gabriel L Eggers↗
NASA NTRS2012

Near-Infrared Photon-Counting Camera for High-Sensitivity Observations

The dark current of a transferred-electron photocathode with an InGaAs absorber, responsive over the 0.9-to-1.7- micron range, must be reduced to an ultralow level suitable for low signal spectral astrophysical measurements by lowering the temperature of the sensor incorporating the cathode. However, photocathode quantum efficiency (QE) is known to reduce to zero at such low temperatures. Moreover, it has not been demonstrated that the target dark current can be reached at any temperature using existing photocathodes. Changes in the transferred-electron photocathode epistructure (with an In- GaAs absorber lattice-matched to InP and exhibiting responsivity over the 0.9- to-1.7- m range) and fabrication processes were developed and implemented that resulted in a demonstrated >13x reduction in dark current at -40 C while retaining >95% of the approximately equal to 25% saturated room-temperature QE. Further testing at lower temperature is needed to confirm a >25 C predicted reduction in cooling required to achieve an ultralow dark-current target suitable for faint spectral astronomical observations that are not otherwise possible. This reduction in dark current makes it possible to increase the integration time of the imaging sensor, thus enabling a much higher near-infrared (NIR) sensitivity than is possible with current technology. As a result, extremely faint phenomena and NIR signals emitted from distant celestial objects can be now observed and imaged (such as the dynamics of redshifting galaxies, and spectral measurements on extra-solar planets in search of water and bio-markers) that were not previously possible. In addition, the enhanced NIR sensitivity also directly benefits other NIR imaging applications, including drug and bomb detection, stand-off detection of improvised explosive devices (IED's), Raman spectroscopy and microscopy for life/physical science applications, and semiconductor product defect detection.

Jurkovic, Michael↗