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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Effects of nonequilibrium and surface catalysis on Shuttle heat transfer - A review

It is pointed out that the Space Shuttle Orbiter is a hypersonic glide reentry vehicle which spends much of its entry time at relatively tenuous altitudes in which chemical nonequilibrium predominates in the shock layer. On the windward side, dissociation nonequilibrium exists in the inviscid layer and recombination nonequilibrium exists in the boundary layer. The present investigation is concerned with an evaluation of various flowfield predictions, taking into account a comparison of equilibrium and nonequilibrium flowfields coupled with reacting axisymmetric analog boundary-layer solutions and the results of viscous-shock-layer solutions with flight temperature/heat-flux measurements near the windward centerline for the Shuttle flights STS-2, STS-3, and STS-5.

Scott, C. D.↗
NASA NTRS1985

Chemical and thermal nonequilibrium heat transfer analysis for hypervelocity, low Reynolds number flow

Chemical and thermal nonequilibrium phenomena are studied in the stagnation region of a hypervelocity blunt body. This investigation is motivated by the need to predict the heat transfer rate to the leading edge of Aeromaneuvering Orbital Transfer Vehicles. Flight speeds of approximately 10 km/s at altitudes of approximately 80 km are considered for body radii of 1 to 50 cm. The analysis is based on continuum theory and is applicable to the viscous-layer and incipient-merged-layer rarefied-flow regimes. A two-species, two-temperature gas model is assumed. Comparisons are made with previous theories, experimental data, and results based on the thermodynamic equilibrium assumption. The equation accounting for vibrational nonequilibrium is presented and its effects on flow properties are discussed. Parameters which require further investigation are identified. Preliminary results indicate that the inclusion of vibrational relaxation has little effect on heat transfer rate for a catalytic surface. However, vibrational nonequilibrium may increase the heat transfer rate to a noncatalytic surface, depending on the degree of nonequilibrium.

Brown, K. G.↗
NASA NTRS1988

Viscous shock-layer solutions with nonequilibrium chemistry for hypersonic flows past slender bodies

Laminar nonequilibrium heat transfer to slender vehicles is discussed, with heating-rate results presented as a ratio of the noncatalytic to the corresponding fully catalytic value to illustrate the maximum potential for a heating reduction in dissociated nonequilibrium flow at a given flight condition. Larger blunted cone half-angles are shown to produce the most significant nonequilibrium effects at distances beyond 100 nose radii, except in the fore-cone region. Increasing nose bluntness is found to produce large reductions in the ratio for the smaller cone angles at relatively large downstream surface lengths. It is noted that the nose radius and freestream density are not independent scaling parameters in nonequilibrium flow.

Zoby, E. V.↗
NASA NTRS1991

Recent improvements in the nonequilibrium VSL scheme for hypersonic blunt-body flows

The nonequilibrium viscous shock-layer (VSL) solution scheme is revisited to improve its solution accuracy in the stagnation point region and also to minimize and control the errors in the conservation of elemental mass. The stagnation-point solution is improved by using a second-order expansion for the normal velocity and the elemental mass conservation is improved by directly imposing the element conservation equations as solution constraints. These modifications are such that the general structure and computational efficiency of the nonequilibrium VSL scheme is not affected. This revised nonequilibrium VSL scheme is used to study the Mach 20 flow over a 7-deg sphere-cone vehicle under zero and 20-deg angle-of-attack conditons. Comparisons are made with the corresponding predictions of Navier-Stokes and Parabolized Navier-Stokes solution schemes. The results of these tests show that the nonequilibrium blunt-body VSL scheme is indeed an accurate, fast and extremely efficient means for generating the blunt-body flowfield over spherical nosetips at small-to-large angles of attack.

Bhutta, Bilal A.↗
NASA NTRS1992

Improved nonequilibrium viscous shock-layer scheme for hypersonic blunt-body flowfields

The nonequilibrium viscous shock-layer (VSL) solution scheme is revisited to improve its solution accuracy in the stagnation region and also to minimize and control errors in the conservation of elemental mass. The stagnation-point solution is improved by using a second-order expansion for the normal velocity, and the elemental mass conservation is improved by directly imposing the element conservation equations as solution constraints. These modifications are such that the general structure and computational efficiency of the nonequilibrium VSL scheme is not affected. This revised nonequilibrium VSL scheme is used to study the Mach 20 flow over a 7-deg sphere-cone vehicle under 0- and 20-deg angle-of-attack conditions. Comparisons are made with the corresponding predictions of Navier-Stokes and parabolized Navier-Stokes solution schemes. The results of these tests show that the nonequilibrium blunt-body VSL scheme is indeed an accurate, fast, and extremely efficient means for generating the blunt-body flowfield over spherical nose tips at zero-to-large angles of attack.

Bhutta, Bilal A.↗
NASA NTRS1991

Application of program LAURA to thermochemical nonequilibrium flow through a nozzle

Program LAURA (Langley Aerothermodynamic Upwind Relaxation Algorithm) is an upwind-biased, point-implicit relaxation algorithm for obtaining the numerical solution to the governing equations for 3D viscous hypersonic flows in chemical and thermal nonequilibrium. The algorithm is derived using a finite-volume formulation in which the inviscid components of flux across cell walls are described with a modified Roe's averaging and with second-order corrections based on Yee's Symmetric Total Variation Diminishing scheme. The code has been applied to Problem 8.2 of this workshop for the case of thermochemical nonequilibrium flow through a nozzle. Chemical reaction rates are defined with the model of Park (1987). Thermal nonequilibrium is modeled using a two-temperature approximation in which the vibrational energies of all molecules are assumed to be in equilibrium at a single temperature which is generally different from the translational-rotational temperature. Two grids were used to define the flow for the original problem, with a stagnation temperature of 6500 K. A third case with a stagnation temperature of 10,000 K is also presented. The solution domain includes the converging nozzle, subsonic flow domain in which the gas is substantially in thermochemical equilibrium and the diverging nozzle, hypersonic flow domain in which the gas is substantially in thermochemical nonequilibrium.

Gnoffo, Peter A.↗
NASA NTRS1994

Observational tests for nonequilibrium ionization in the solar corona

Nonequilibrium ionization may be produced by a variety of processes in the solar corona, for example, by mass flows through the large temperature gradients of the transition region or by impulsive heating and cooling. Any deviation from equilibrium ionization would have a strong effect on the radiation from the corona and on the interpretation of solar observations; hence, it is important to determine observational signatures of nonequilibrium. The temperature-sensitive line ratios can be used as such signatures. We examine the line ratios: C IV I(1548.2 A)/I(312.4 A), O IV I(789.4 A)/I(554.4 A), O V I(629.7 A)/I(172.2 A), O VI I(1031.9 A)/I(173.0 A) and O VI I(1031.9 A)/I(150.1 A). These line ratios are calculated for four coronal loop models that have a steady flow and that are known to have significant departures from equilibrium ionization. Our results indicate that, in general, nonequilibrium causes a considerable reduction in the line ratios, more than an order of magnitude in the downflowing leg of the loop model with the largest mass flows. We find that the C IV line ratio is the most sensitive to nonequilibrium. We discuss the implications of our results for observations, specifically, the observations expected from the upcoming SOHO mission.

Spadaro, D.↗
NASA NTRS1995

Nozzle flow with vibrational nonequilibrium

This research concerns the modeling and numerical solutions of the coupled system of compressible Navier-Stokes equations in cylindrical coordinates under conditions of equilibrium and nonequilibrium thermodynamics. The problem considered was the modeling of a high temperature diatomic gas N2 flowing through a converging-diverging high expansion nozzle. The problem was modeled in two ways. The first model uses a single temperature with variable specific heats as functions of this temperature. For the second model we assume that the various degrees of freedom all have a Boltzmann distribution and that there is a continuous redistribution of energy among the various degrees of freedom as the gas passes through the nozzle. Each degree of freedom is assumed to have its own temperature and, consequently, each system state can be characterized by these temperatures. This suggests that formulation of a second model with a vibrational degree of freedom along with a rotational-translation degree of freedom, each degree of freedom having its own temperature. Initially the vibrational degree of freedom is excited by heating the gas to a high temperature. As the high temperature gas passes through the nozzle throat there is a sudden drop in temperature along with a relaxation time for the vibrational degree of freedom to achieve equilibrium with the rotational-translation degree of freedom. That is, we assume that the temperature change upon passing through the throat is so great that the changes in the vibrational degree of freedom occur at a much slower pace and consequently lags behind the rotational-translational energy changes. This lag results in a finite relaxation time. In this context the term nonequilibrium is used to denote the fact that the energy content of the various degrees of freedom are characterized by two temperatures. We neglect any chemical reactions which could also add nonequilibrium effects. We develop the energy equations for the nonequilibrium model from first principles. The resulting equations, which model the nozzle flow, can be expressed in various forms. In most forms the resulting equations are coupled systems of nonlinear partial differential equations subject to certain boundary conditions. To solve the resulting coupled system of nonlinear partial differential equations, several numerical techniques were investigated: (1) the explicit MacCormack method, (2) the explicit-implicit MacCormack method, (3) the method of operator splitting, (4) factorization schemes, and (5) the Steger-Warming scheme.

Heinbockel, J. H.↗
NASA NTRS1986

Chemical and Thermal Nonequilibrium Heat-Transfer Analysis for Hypervelocity, Low Reynolds Number Flow

Chemical and thermal nonequilibrium phenomena are studied in the stagnation region of a hypervelocity blunt body. This investigation is motivated by the need to predict the heat-transfer rate to the leading edge of aeromaneuvering orbital transfer vehicles. Flight speeds of approximately 10 km/s at altitudes of approximately 80 km are considered for body radii of 1-50 cm. The analysis is based on continuum theory and is applicable to the viscous and incipient merged layer regimes of rarefied flow. A two-species, two-temperature gas model is assumed. Comparisons are made with previous theories, experimental data, and results based on the thermodynamic equilibrium assumption. The equation accounting for vibrational nonequilibrium is presented and its effects on flow properties are discussed. Parameters requiring further investigation are identified. Preliminary results indicate that the inclusion of vibrational relaxation has little effect on the heat-transfer rate for a fully catalytic surface. However, vibrational nonequilibrium may increase the heat-transfer rate to a noncatalytic surface, depending on the degree of nonequilibrium.

Brown, Kevin G.↗
NASA NTRS1995

The Development of a Nonequilibrium Radiative Heat Transfer Computational Model for High Altitude Entry Vehicle Flowfield Methods

This final report will attempt to concisely summarize the activities and accomplishments associated with NASA Grant and to include pertinent documents in an appendix. The project initially had one primary and several secondary objectives. The original primary objective was to couple into the NASA Johnson Space Center (JSC) nonequilibrium chemistry Euler equation entry vehicle flowfield code, INEQ3D, the Texas A&M University (TAMU) local thermodynamic nonequilibrium (LTNE) radiation model. This model had previously been developed and verified under NASA Langley and NASA Johnson sponsorship as part of a viscous shock layer entry vehicle flowfield code. The secondary objectives were: (1) to investigate the necessity of including the radiative flux term in the vibrational-electron-electronic (VEE) energy equation as well as in the global energy equation, (2) to determine the importance of including the small net change in electronic energy between products and reactants which occurs during a chemical reaction, and (3) to study the effect of atom-atom impact ionization reactions on entry vehicle nonequilibrium flowfield chemistry and radiation. For each, of these objectives, it was assumed that the code would be applicable to lunar return entry conditions, i.e. altitude above 75 km, velocity greater, than 11 km/sec, where nonequilibrium chemistry and radiative heating phenomena would be significant. In addition, it was tacitly assumed that as part of the project the code would be applied to a variety of flight conditions and geometries.

Carlson, Leland A.↗
NASA NTRS1994

Rotational Relaxation in Nonequilibrium Freejet Expansions of Heated Nitrogen

Rotational temperatures have been measured in rarefied, nonequilibrium, heated freejet expansions of nitrogen using the electron beam fluorescence technique at the University of California at Berkeley Low Density Wind Tunnel facility. Spectroscopic measurements of the (0,0) band of the first negative system of nitrogen reveal the nonequilibrium behavior in the flowfield upstream of, and through the Mach disk, which forms as the freejet expands into a region of finite back pressure. Results compare well with previous freejet expansion data and computations regarding location of the Mach disk and terminal rotational temperature in the expansion. Measurements are also presented for shock thickness based on the rotational temperature changes in the flow. Thickening shock layers, departures of rotational temperature from equilibrium in the expansion region, and downstream rotational temperature recovery much below that of an isentropic normal shock provide indications of the rarefied, nonequilibrium flow behavior. The data are analyzed to infer constant values of the rotational-relaxation collision number from 2.2 to 6.5 for the various flow conditions. Collision numbers are also calculated in a consistent manner for data from other investigations for which is seen a qualitative increase with increasing temperature. Rotational-relaxation collision numbers are seen as not fully descriptive of the rarefied freejet flows. This may be due to the high degree of nonequilibrium in the flowfields, and/or to the use of a temperature-insensitive rotational-relaxation collision number model in the data analyses.

Gochberg, Lawrence A.↗
NASA NTRS2019

Multiple Boundary Layer Instability Modes with Nonequilibrium and Wall Temperature Effects Using LASTRAC

Prediction and control of boundary layer transition from laminar to turbulent is important to many flow regimes and vehicle designs, including vehicles operating at hypersonic conditions where nonequilibrium effects may be encountered. Wall cooling is known to affect the instability characteristics of the boundary layer and subsequently the transition location. Design considerations, including material failure and fuel chemistry, require the use of actively cooled walls in hypersonic vehicles, further motivating the study of wall temperature effects on top of the considerations of reducing heat flux, drag, and uncertainty. In this work, we analyze the stability of a boundary layer with chemical and thermal nonequilibrium on a Mach 20, 6 wedge. We investigate the effects of wall temperature on multiple unstable modes individually and on the integrated growth of disturbances along the surface. We use the LAngley Stability and TRansition Analysis Code (LASTRAC) to evaluate boundary layer stability, using capabilities implemented by the authors. Included are results that address chemical nonequilibrium with both thermal equilibrium and nonequilibrium.

Kline, H. L.↗
DOE OSTI2024

On Gibbs Equilibrium and Hillert Nonequilibrium Thermodynamics

During his time at Royal Institute of Technology (Kungliga Tekniska högskolan) in Sweden, the present author learned nonequilibrium thermodynamics from Mats Hillert. The key concepts are the separation of internal and external variables of a system and the definitions of potentials and molar quantities. In equilibrium thermodynamics derived by Gibbs, the internal variables are not independent and can be fully evaluated from given external variables. While irreversible thermodynamics led by Onsager focuses on internal variables though often mixed with external variables. Hillert integrated them together by first emphasizing their differences and then examining their connections. His philosophy was reflected by the title of his book “Phase Equilibria, Phase Diagrams and Phase Transformations” that puts equilibrium, nonequilibrium, and internal processes on equal footing. Here, in the present paper honoring Hillert, the present author reflects his experiences with Hillert and his work in last 40 years and expresses his gratitude for all the wisdom and support from him in terms of “Hillert nonequilibrium thermodynamics” and discusses some recent topics that the present author has been working on.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Insight into Pyroelectricity and Phase Transitions in Ferroelectrics from Nonequilibrium Approach: The Case of PbTiO 3

Computational methodology is proposed to simulate time dependent temperature variations via thermostat approach. Here, the methodology is applied to study pyroelectricity under nonequilibrium conditions in prototypical ferroelectric PbTiO 3 . It is found that at room temperature the nonequilibrium effects in pyroelectricity begin manifesting above 1.0 THz and originate from the overlap with the intrinsic soft mode frequency. Therefore, the proposed computational methodology can be used to predict equilibrium pyroelectric response by choosing a frequency of temperature variation below the intrinsic polar mode frequencies for the material. Probing the dynamics of ferroelectric phase transition with the proposed methodology revealed that it takes about a nanosecond for the computational supercell to undergo phase transition. It is concluded that computational techniques capable of simulating picoseconds can be used to compute pyroelectric response from nonequilibrium dynamical approach while those that can reach nanoseconds are suitable for simulating phase transitions in ferroelectrics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Nonequilibrium dynamics of spontaneous symmetry breaking into a hidden state of charge-density wave

Abstract Nonequilibrium phase transitions play a pivotal role in broad physical contexts, from condensed matter to cosmology. Tracking the formation of nonequilibrium phases in condensed matter requires a resolution of the long-range cooperativity on ultra-short timescales. Here, we study the spontaneous transformation of a charge-density wave in CeTe 3 from a stripe order into a bi-directional state inaccessible thermodynamically but is induced by intense laser pulses. With ≈100 fs resolution coherent electron diffraction, we capture the entire course of this transformation and show self-organization that defines a nonthermal critical point, unveiling the nonequilibrium energy landscape. We discuss the generation of instabilities by a swift interaction quench that changes the system symmetry preference, and the phase ordering dynamics orchestrated over a nonadiabatic timescale to allow new order parameter fluctuations to gain long-range correlations. Remarkably, the subsequent thermalization locks the remnants of the transient order into longer-lived topological defects for more than 2 ns.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Dynamic pair-breaking current, critical superfluid velocity, and nonlinear electromagnetic response of nonequilibrium superconductors

Here, we report numerical calculations of a dynamic pair-breaking current density $J_d$ and a critical superfluid velocity $v_d$ in a nonequilibrium superconductor carrying a uniform, large-amplitude AC current density $J(t) = J_a$sinΩ$\textit{t}$ with Ω well below the gap frequency Ω $\ll Δ_0/ℏ$. The dependencies $J_d$(Ω, $\textit{T}$) and $v_d$(Ω, $\textit{T}$) near the critical temperature $T_c$ were calculated from either the full time-dependent nonequilibrium equations for a dirty $\textit{s}$-wave superconductor or the time-dependent Ginzburg-Landau (TDGL) equations for a gapped superconductor, taking into account the GL relaxation time of the order parameter $τ_{\text{GL}}$ and the inelastic electron-phonon relaxation time of quasiparticles $τ_E$. We show that both approaches give similar frequency dependencies of $J_d$(Ω) and $v_d$(Ω) which gradually increase from their static pair-breaking GL values $J_c$ and $v_c$ at Ω$τ_E \ll$1 to $\sqrt{2}J_c$ and $\sqrt{2}v_c$ at Ω$τ_E \gg$ 1. Here $J_d, v_d$ and a dynamic superheating field at which the Meissner state becomes unstable were calculated in two different regimes of a fixed AC current and a fixed AC superfluid velocity induced by the applied AC magnetic field $H = H_a$ sinΩ$\textit{t}$ in a thin superconducting filament or a type-II superconductor with a large GL parameter. We also calculated a nonlinear electromagnetic response of a nonequilibrium superconducting state, particularly a dynamic kinetic inductance and a dissipative quasiparticle conductivity, taking into account the oscillatory dynamics of superconducting condensate and the kinetics of quasiparticles driven by a strong AC current. It is shown that an AC current density produces multiple harmonics of the electric field, the amplitudes of the higher-order harmonics diminishing as $τ_E$ increases.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Conductance of a dissipative quantum dot: Nonequilibrium crossover near a non-Fermi-liquid quantum critical point

In this work, we find the nonlinear conductance of a dissipative resonant level in the nonequilibrium steady state near its quantum critical point. The system consists of a spin-polarized quantum dot connected to two resistive leads that provide ohmic dissipation. We focus on the crossover from the strong-coupling, non-Fermi-liquid regime to the weak-coupling, Fermi-liquid ground state, a crossover driven by the instability of the quantum critical point to hybridization asymmetry or detuning of the level in the dot. We show that the crossover properties are given by tunneling through an effective single barrier described by the boundary sine-Gordon model. The nonlinear conductance is then obtained from thermodynamic Bethe ansatz results in the literature, which were developed to treat tunneling in a Luttinger liquid. The current-voltage characteristics are thus found for any value of the resistance of the leads. For the special case of lead resistance equal to the quantum resistance, we find mappings onto, first, the two-channel Kondo model and, second, an effectively noninteracting model from which the nonlinear conductance is found analytically. A key feature of the general crossover function is that the nonequilibrium crossover driven by applied bias is different from the crossover driven by temperature---we find that the nonequilibrium crossover is substantially sharper. Finally, we compare to experimental results for both the bias and temperature crossovers: the agreement is excellent.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Nonequilibrium spintronic transport through Kondo impurities

In this work we analyze the nonequilibrium transport through a quantum impurity (quantum dot or molecule) attached to ferromagnetic leads by using a hybrid numerical renormalization group–time-dependent density matrix renormalization group thermofield quench approach. For this, we study the bias dependence of the differential conductance through the system, which shows a finite zero-bias peak, characteristic of the Kondo resonance and reminiscent of the equilibrium local density of states. In the nonequilibrium settings, the resonance in the differential conductance is also found to decrease with increasing the lead spin polarization. The latter induces an effective exchange field that lifts the spin degeneracy of the dot level. Therefore, as we demonstrate, the Kondo resonance can be restored by counteracting the exchange field with a finite external magnetic field applied to the system. Lastly, we investigate the influence of temperature on the nonequilibrium conductance, focusing on the split Kondo resonance. Our work thus provides an accurate quantitative description of the spin-resolved transport properties relevant for quantum dots and molecules embedded in magnetic tunnel junctions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗