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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Computational Fluid Dynamics Modeling of Low Temperature Ignition Processes From a Nanosecond Pulsed Discharge at Quiescent Conditions

Recent interest in nonequilibrium plasma discharges as sources of ignition for the automotive industry has not yet been accompanied by the availability of dedicated models to perform this task in computational fluid dynamics (CFD) engine simulations. The need for a low-temperature plasma (LTP) ignition model has motivated much work in simulating these discharges from first principles. Most ignition models assume that an equilibrium plasma comprises the bulk of discharge kernels. LTP discharges, however, exhibit highly nonequilibrium behavior. In this work, a method to determine a consistent initialization of LTP discharge kernels for use in engine CFD codes like CONVERGE is proposed. The method utilizes first principles discharge simulations. Such an LTP kernel is introduced in a flammable mixture of air and fuel, and the subsequent plasma expansion and ignition simulation is carried out using a reacting flow solver with detailed chemistry. Finally, the proposed numerical approach is shown to produce results that agree with experimental observations regarding the ignitability of methane-air and ethylene-air mixtures by LTP discharges.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS1991

Cold plasma processing of local planetary ores for oxygen and metallurgically important metals

The utilization of a cold or nonequilibrium plasma in chlorination processing is discussed. Titanium dioxide (TiO2) was successfully chlorinated at temperatures between 700 and 900 C without the aid of carbon. In addition to these initial experiments, a technique was developed for determining the temperature of a specimen in a plasma. Development of that technique has required evaluating the emissivity of TiO2, ZrO2, and FeOTiO2 and analyzing the specimen temperature in a plasma as a function of both power absorbed by the plasma and the pressure of the plasma. The mass spectrometer was also calibrated with TiCl4 and CCl4 vapor.

Lynch, D. C.↗
NASA NTRS2005

Probing the Reverse Shock in an Oxygen-Rich Supernovae Remnant

The purpose of this investigation is to examine the O VI emission from the X-ray bright ring of the supernova remnant 1 E0102.2-729 in the small Magellanic cloud. Three pointings were positioned tangent to the ring, north (N), northeast (NE), and southeast (SE), to examine a range of X-ray emitting regions overlapping a range of optical [O III] nebulosity and to examine the velocity structure. One background pointing was also obtained, but it was contaminated by a star. The background levels in the pointings on the remnant were low enough that the background pointing was not required for the remaining analysis. The SE pointing was reobserved in August, 2004, in order to bring the total exposure up to the originally requested 15 ks. The archive notified us of the data's availability in mid September. Significant broad O VI 1032 and O VI 1038 emission was found, brightest in the NE and SE pointings. In the NE and SE pointings, the FWHM of the broad O VI component is approx.800-1000 km/s, while in the N pointing, the line is approx.1500 km/s wide. The O VI is redshifted in the N (approx.380 km/s) and NE (approx.60 km/s) but is blueshifted in the SE (approx. -160 km/s). These FUSE O VI velocity dispersions can be compared to the X-ray gas velocities inferred from Doppler distortions in the Chandra X-ray data as reported by Flanagan et al. 2004 (ApJ 605, 230). The bulk velocities in the X-ray bright ring of order +/- 1000 km/s, comparable to the velocity dispersion seen in the FUSE data. However, the X-ray data indicates a redshift of approx.1000 km/s in the SE, while the FUSE data show a blueshift of approx.160 km/s, underscoring the complex velocity structure in this remnant. The O VI fluxes estimated from the fits to the FUSE data were combined with X-ray (XMM- Newton) O VI1 and O VIII fluxes and compared with predictions from a plasma nonequilibrium ionization model in a "line-based" analysis. We found that the plasma departs significantly from collisional ionization equilibrium, particularly in the SE, and that the plasma excitation conditions vary among the pointings: the O plasma sees different conditions than the Ne and Mg plasmas.

Gaetz, Terrance↗
NASA NTRS1999

Shock Wave Dynamics in Weakly Ionized Plasmas

An investigation of the dynamics of shock waves in weakly ionized argon plasmas has been performed using a pressure ruptured shock tube. The velocity of the shock is observed to increase when the shock traverses the plasma. The observed increases cannot be accounted for by thermal effects alone. Possible mechanisms that could explain the anomalous behavior include a vibrational/translational relaxation in the nonequilibrium plasma, electron diffusion across the shock front resulting from high electron mobility, and the propagation of ion-acoustic waves generated at the shock front. Using a turbulence model based on reduced kinetic theory, analysis of the observed results suggest a role for turbulence in anomalous shock dynamics in weakly ionized media and plasma-induced hypersonic drag reduction.

Johnson, Joseph A., III↗
NASA NTRS1995

First spectral observations of the diffuse background with the Extreme Ultraviolet Explorer

We present the first results from the analysis of the spectroscopic observations of diffuse extreme ultraviolet (EUV) emission taken with the Extreme Ultraviolet Explorer (EUVE) spectrometers in the wavelength range 160-740 A. Although not designed or optimized for diffuse observation, the EUVE spectrometers are the most sensitive diffuse EUV spectrometer in orbit. The spectral resolution for diffuse emission of the medium and long-wavelength spectrometers are 17 and 34 A FWHM, respectively. During the period from 1992 July 25 to 1992 August 19, the spectrometers surveyed a 2 x 20 deg field scanned from (l, b) = (24 deg, -28 deg) to (44 deg, -74 deg) with a total effective exposure time of 575,232 s. The only emission lines detected were those of He I and He II (584, 537, 304 A) with intensities consistent with local geocoronal and/or interplanetary scattering of solar radiation (584 A = 1.30 rayleighs; 537 A = 0.040 R; and 304 A = 0.029 R). Models of the soft X-ray background, which results from a 10(exp 6) K plasma (Local Bubble) surrounding the neutral gas near the Sun (Local Cloud), predict that most of the flux from the hot plasma appears as emission lines in the EUV. We have compared these spectral predictions with our observations to place limits on the emission measure versus temperature of the proposed hot plasma. Using the same plasma model, we derived emissions measures for our data and the C and B soft X-ray bands of the Wisconsin rocket survey. We find that our limits for the plasma emission measure are a factor of 5-10 below the C- and B-band emission measures over the temperature range from 10(exp 5.7) to 10(exp 6.4) K. We explore possible scenarios that could reconcile our results with the X-ray surveys and conclude that depletion or a nonequilibrium plasma state rather than absorption are the more likely explanations of the discrepancy. We also show that our spectrum is inconsistent with the spectrum from the approximately 10(exp 5) K gas at the conductive interface between the hot Local Bubble and the cooler Local Cloud given by Slavin (1989). In addition, we place new limits on the helium ionization parameter in the Sun's vicinity caused by the 10(exp 6) K plasma in the Local Bubble.

Jelinksy, P.↗
DOE OSTI2024

Nonequilibrium Phenomena in Plasmas in Contact with Liquids

Plasma-liquid interaction is a low-temperature plasma science frontier involving fundamental issues in plasma-materials interaction, multiphase kinetics, and collective effects. Plasmas in contact with liquids present two distinctive types of nonequilibrium: kinetic - across the interface - involving complex physical and chemical kinetics; and dissipative - along the interface - comprising superficial transport that is often conducive to instabilities and the formation of dissipative structures such as spot patterns. The project investigated dissipative and kinetic nonequilibrium phenomena concurrently in plasmas in contact with liquid water electrodes. The project’s objective was to determine the properties of dissipative (macroscopic) and kinetic (microscopic) nonequilibrium phenomena, and the interrelation between them, in low-temperature atmospheric-pressure plasmas in contact with liquid electrodes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Toward sustainable production of N-containing products via nonthermal plasma-enhanced conversion of natural gas resources

Nonthermal plasmas can directly activate and cleave the strong chemical bonds in molecular nitrogen and methane to facilitate the transformation of these inherently stable molecules through the application of electrical energy. Here, we report a low temperature, atmospheric pressure, nonthermal plasma for the “one-pot” synthesis of olefins, alkynes, higher molecular weight hydrocarbons, ammonia, and nitrogen-containing liquids from a representative shale gas feed enriched with nitrogen. Furthermore, we reproducibly observe a wide range of valuable and synthetically challenging gas-phase and liquid-phase products containing C-N, C-C, and N-H bonding by controlling the N 2 concentration in the inlet feed stream. In nitrogen-lean regimes, hydrocarbon products dominate (e.g., ethylene, acetylene, etc.), while nitrogen-rich regimes promote incorporation of nitrogen into the products, leading to the formation of ammonia and liquid products containing a variety of functionalities (e.g., nitriles, amines, heterocycles). High resolution electrospray ionization mass spectrometry was used to measure molecular weights and identify the chemical formulas of the liquid products. Van Krevelen diagrams were created and showed many products with compositions around H/C = 2 and N/C = 0.5, indicating the potential importance of intermediate species with these ratios for liquid formation (e.g., CH 3 CN + H).

03 NATURAL GAS↗
DOE OSTI2022

Ambient-temperature liquid jet targets for high-repetition-rate HED discovery science

High-power lasers can generate energetic particle beams and astrophysically relevant pressure and temperature states in the high-energy-density (HED) regime. Recently-commissioned high-repetition-rate (HRR) laser drivers are capable of producing these conditions at rates exceeding 1 Hz. However, experimental output from these systems is often limited by the difficulty of designing targets that match these repetition rates. To overcome this challenge, we have developed tungsten microfluidic nozzles, which produce a continuously replenishing jet that operates at flow speeds of approximately 10 m/s and can sustain shot frequencies up to 1 kHz. The ambient-temperature planar liquid jets produced by these nozzles can have thicknesses ranging from hundreds of nanometers to tens of micrometers. In this work, we illustrate the operational principle of the microfluidic nozzle and describe its implementation in a vacuum environment. Further, we provide evidence of successful laser-driven ion acceleration using this target and discuss the prospect of optimizing the ion acceleration performance through an in situ jet thickness scan. Future applications for the jet throughout HED science include shock compression and studies of strongly heated nonequilibrium plasmas. When fielded in concert with HRR-compatible laser, diagnostic, and active feedback technology, this target will facilitate advanced automated studies in HRR HED science, including machine learning-based optimization and high-dimensional statistical analysis.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1990

Preliminary plume characteristics of an arcjet thruster

An experimental program initiated to characterize the near field of an arcjet plume is described. The complete emission spectrum from 3200 to 7200 A at the nozzle exit plane detected the electronically excited species N2, N2(+), NH, and H, indicating excitation, dissociation, ionization, and recombination in the nozzle. Axial intensity profiles indicated an exponential decay in excited state population for H(alpha), H(beta), and NH. The rate of axial decay indicated lower velocities for NH than H in the plume and population of the third excited energy state of hydrogen from the decay of higher energy levels. Rotational temperatures ranged from 750 K for N2 to 2500 K for NH. Based on these results, the arcjet plume is found to be a highly nonequilibrium plasma. Anode electrical configuration is found to have a large effect on the spectral intensities measured in the plume.

Manzella, David H.↗
NASA NTRS1994

GRO: Black hole models for gamma-ray bursts

The possibility of creating gamma ray bursts (GRB's) from accretion flows on to black holes is investigated. The mechanism of initial energy release in the form of a burst is not understood yet. The typical time scales involved in this energy release and the initial distribution of photons as a function of energy are studied. As a first step the problem is formulated in the Minkowski spacetime for a homogeneous and isotropic burst. For an arbitrary initial distribution of photons, the equations of relativistic kinetic theory are formulated for nonequilibrium plasmas which can take into account various particle creation and annihilation processes and various scattering processes.

Shaham, Jacob↗
NASA NTRS1994

CCD soft X-ray observations of the Puppis a supernova remnant

We present the first images and spectra of an astronomical object, other than the Sun, acquired with a charge coupled device (CCD) imaging X-ray spectrometer. During a 230 s sounding rocket observation, we have acquired moderate-resolution spectra and moderate-resolution images of a portion of the Pup A supernova remnant (SNR). Based on these data, we conclude that the X-ray spectrum of Pup A is inconsistent with any single-temperature equilibrium or nonequilibrium plasma model. We find evidence for variations in the emitting plasma on scales as small as 5.0 min and as large as 30.0 min. The spatial structure of the spectral variations in the remnant is found to be inconsistent with the standard Sedov model for the evolution of a SRN into a homogeneous interstellar medium (ISM). We suggest that the remnant is expanding into a region of the ISM having a density of approximately 1 cm(exp -3) with inhomogeneities on the order of 50%. We have found evidence for the presence of a knot of plasma enriched in neon, but require more data to be conclusive.

Berthiaume, G. D.↗