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Evaluating the Impact of Agricultural Soil NOx Emissions on Air Quality Using Advanced Satellite, Ground-based, and Model Data

Soil moisture can also influence the concentration of atmospheric trace gases by moderating the emission of nitrogen oxides (NOx = NO + NO2) from agricultural fields. Human activities can play an important role in controlling the available soil moisture depending on irrigation demand and agricultural management. To further complicate matters, nitrogen fertilizer use has also been found to be a significant source of NOx emissions in agricultural areas. In fact, some of the highest emissions have been reported from fertilized soils in high-temperature agricultural regions, such as the Imperial Valley of California. Since NO2 is an important precursor to ozone formation in the troposphere, which is a leading cause of premature death in humans, it is critical to understand how natural and anthropogenic factors contribute to NOx emissions in these areas. O3 pollution is also a growing threat to global food security due to its detrimental impacts on crop production. This work uses a suite of satellite, ground-based, and model data to investigate how agricultural soil NOx emissions from natural (rainfall) and anthropogenic factors (irrigation, nitrogen fertilizer) govern air quality over California. We evaluate the capabilities of using SMAP retrievals and SMAP Land Information System (LIS) output for monitoring irrigation activities over the major agricultural areas of California by conducting intensive analyses of soil moisture and precipitation data. High-resolution trace gas observations from the new generation TROPOspheric Monitoring Instrument (TROPOMI) sensor are used to characterize and monitor the variability of trace gases and air quality conditions associated with soil NOx emissions. We also synthesize satellite, ground-based, and agriculture data to estimate the separate contributions from rainfall, irrigation, and nitrogen fertilizer practices on soil NOx emissions and associated air quality conditions. Finally, unprecedented hourly trace gas retrievals from the NASA Tropospheric Emissions: Monitoring of Pollution (TEMPO) geostationary satellite sensor are used to monitor the diurnal evolution of NO2 and O3 concentrations from soil NOx emissions.

Aaron R Naeger↗

NASA NTRS1999

Investigation of NOx Removal from Small Engine Exhaust

Contribution of emissions from small engines to the air pollution is significant. Due to differences in operating conditions and economics, the pollution control systems designed for automobiles will be neither suitable nor economically feasible for use on small engines. The objective of this project was to find a catalyst for the removal of NOx from the exhaust of small engines which use a rich air to fuel ratio. The desired catalyst should be inexpensive so that the cost of the pollution control unit will be only a small fraction of the total equipment cost. The high cost of noble metals makes them too expensive for use as NOx catalyst for small engines. Catalytic reduction of Nitrogen Oxide (NO) can also be accomplished by base-metal oxide catalysts. The main disadvantage of base-metal catalysts is their deactivation by poisons and high temperatures. Requirements for the length of the life of the small engine exhaust catalysts are much less than those for automobile exhaust catalysts. Since there is no oxygen in the exhaust gases, reduction selectivity is not a problem. Also, the reducing exhaust gases might help prevent the harmful interactions of the catalyst with the support. For these reasons only the supported metal oxide catalysts were investigated in this project.

Akyurtlu, Ates↗

NASA NTRS2013

Control of Emissions

Methods and apparatus utilizing chlorine dioxide and hydrogen peroxide are useful to reduce NOx emissions, as well as SOx and mercury (or other heavy metal) emissions, from combustion flue gas streams.

Parrish, Clyde F.↗

NASA NTRS2004

Innovative Technology Reduces Power Plant Emissions-Commercialization Success

Overview of emission control system development: (1) Development of new oxidizer scrubber system to eliminate NOx waste and produce fertilizer (2) Technology licensed and a 1 to 3 MWatt-scale prototype installed on power plant (3) Development of method to oxidize NO to NO2 (4) Experience gained from licensing NASA technology.

Parrish, Clyde↗

NASA NTRS2013

Control of Emissions

Methods and apparatus utilizing chlorine dioxide and hydrogen peroxide are useful to reduce emissions of NOx, SOx, and heavy metals, e.g., mercury, emissions from combustion flue gas streams.

Parrish, Clyde F.↗

NASA NTRS1999

Investigation of NO(x) Removal from Small Engine Exhaust

Contribution of emissions from small engines to the air pollution is significant. Due to differences in operating conditions and economics, the pollution control systems designed for automobiles will be neither suitable nor economically feasible for use on small engines. The objective of this project was to find a catalyst for the removal of NOx from the exhaust of small engines which use a rich air to fuel ratio. The desired catalyst should be inexpensive so that the cost of the pollution control unit will be only a small fraction of the total equipment cost. The high cost of noble metals makes them too expensive for use as NOx catalyst for small engines. Catalytic reduction of NO can also be accomplished by base-metal oxide catalysts. The main disadvantage of base-metal catalysts is their deactivation by poisons and high temperatures. Requirements for the length of the life of the small engine exhaust catalysts are much less than those for automobile exhaust catalysts. Since there is no oxygen in the exhaust gases, reduction selectivity is not a problem. Also, the reducing exhaust gases might help prevent the harmful interactions of the catalyst with the support. For these reasons only the supported metal oxide catalysts were investigated in this project.

Akyurtlu, Ates↗

NASA NTRS2004

Innovative Technology Reduces Power Plant Emissions - Commercialization Success

Emission control system development includes: (1) Development of new oxidizer scrubber system to eliminate NOx waste and produce fertilizer (2) Technology licensed and a 1 to 3 MWatt-scale prototype installed on. power plant (3) Development of method to oxidize NO. to N02 (4) Experience gained from licensing NASA technology

Parrish, Clyde↗

NASA NTRS2013

Low Temperature Catalyst for NH3 Removal

Air revitalization technologies maintain a safe atmosphere inside spacecraft by the removal of C02, ammonia (NH3), and trace contaminants. NH3 onboard the International Space Station (ISS) is produced by crew metabolism, payloads, or during an accidental release of thermal control refrigerant. Currently, the ISS relies on removing NH3 via humidity condensate and the crew wears hooded respirators during emergencies. A different approach to cabin NH3 removal is to use selective catalytic oxidation (SCO), which builds on thermal catalytic oxidation concepts that could be incorporated into the existing TCCS process equipment architecture on ISS. A low temperature platinum-based catalyst (LTP-Catalyst) developed at KSC was used for converting NH3 to H20 and N2 gas by SCO. The challenge of implementing SCO is to reduce formation of undesirable byproducts like NOx (N20 and NO). Gas mixture analysis was conducted using FTIR spectrometry in the Regenerable VOC Control System (RVCS) Testbed. The RVCS was modified by adding a 66 L semi-sealed chamber, and a custom NH3 generator. The effect of temperature on NH3 removal using the LTP-Catalyst was examined. A suitable temperature was found where NH3 removal did not produce toxic NO, (NO, N02) and N20 formation was reduced.

Monje, Oscar↗

NASA NTRS2001

Experimental Assessment of the Emissions Control Potential of a Rich/Quench/Lean Combustor for High Speed Civil Transport Aircraft Engines

In support of Pratt & Whitney efforts to define the Rich burn/Quick mix/Lean burn (RQL) combustor for the High Speed Civil Transport (HSCT) aircraft engine, UTRC conducted a flametube-scale study of the RQL concept. Extensive combustor testing was performed at the Supersonic Cruise (SSC) condition of a HSCT engine cycle, Data obtained from probe traverses near the exit of the mixing section confirmed that the mixing section was the critical component in controlling combustor emissions. Circular-hole configurations, which produced rapidly-, highly-penetrating jets, were most effective in limiting NOx. The spatial profiles of NOx and CO at the mixer exit were not directly interpretable using a simple flow model based on jet penetration, and a greater understanding of the flow and chemical processes in this section are required to optimize it. Neither the rich-combustor equivalence ratio nor its residence time was a direct contributor to the exit NOx. Based on this study, it was also concluded that (1) While NOx formation in both the mixing section and the lean combustor contribute to the overall emission, the NOx formation in the mixing section dominates. The gas composition exiting the rich combustor can be reasonably represented by the equilibrium composition corresponding to the rich combustor operating condition. Negligible NOx exits the rich combustor. (2) At the SSC condition, the oxidation processes occurring in the mixing section consume 99 percent of the CO exiting the rich combustor. Soot formed in the rich combustor is also highly oxidized, with combustor exit SAE Smoke Number <3. (3) Mixing section configurations which demonstrated enhanced emissions control at SSC also performed better at part-power conditions. Data from mixer exit traverses reflected the expected mixing behavior for off-design jet to crossflow momentum-flux ratios. (4) Low power operating conditions require that the RQL combustor operate as a lean-lean combustor to achieve low CO and high efficiency. (5) A RQL combustor can achieve the emissions goal of EINOX = 5 at the Supersonic Cruise operating condition for a HSCT engine.

Rosfjord, T. J.↗

NASA NTRS2012

The Kinematic and Microphysical Control of Storm Integrated Lightning Flash Extent

The objective of this preliminary study is to investigate the kinematic and microphysical control of lightning properties, particularly those that may govern the production of nitrogen oxides (NOx) in thunderstorms, such as flash rate, type and extent. The mixed-phase region is where the noninductive charging (NIC) process is thought to generate most storm electrification during rebounding collisions between ice particles in the presence of supercooled water. As a result, prior radar-based studies have demonstrated that lightning flash rate is well correlated to kinematic and microphysical properties in the mixed-phase region of thunderstorms such as updraft volume, graupel mass, or ice mass flux. There is also some evidence that lightning type is associated with the convective state. Intracloud (IC) lightning tends to dominate during the updraft accumulation of precipitation ice mass while cloud-to-ground (CG) lightning is more numerous during the downdraft-driven descent of radar echo associated with graupel and hail. More study is required to generalize these relationships, especially regarding lightning type, in a wide variety of storm modes and meteorological conditions. Less is known about the co-evolving relationship between storm kinematics, microphysics, morphology and three-dimensional flash extent, despite its importance for lightning NOx production. To address this conceptual gap, the NASA MSFC Lightning Nitrogen Oxides Model (LNOM) is applied to North Alabama Lightning Mapping Array (NALMA) and Vaisala National Lightning Detection NetworkTM (NLDN) observations following ordinary convective cells through their lifecycle. LNOM provides estimates of flash type, channel length distributions, lightning segment altitude distributions (SADs) and lightning NOx production profiles. For this study, LNOM is applied in a Lagrangian sense to well isolated convective cells on 3 April 2007 (single cell and multi-cell hailstorm, non-severe multicell) and 6 July 2007 (non-severe multi-cell) over Northern Alabama. The LNOM lightning characteristics are compared to the evolution of updraft and precipitation properties inferred from dual-Doppler and polarimetric radar analyses applied to observations from a nearby Doppler radar network, including the UA Huntsville Advanced Radar for Meteorological and Operational Research (ARMOR, C-band, polarimetric). The LNOM estimated SAD and lightning NOx production profiles are placed in the context of radar derived profiles of vertical motion, precipitation types and amounts. Finally, these analyses are used to determine if storm integrated flash channel extent is as well correlated to volumetric updraft and precipitation ice characteristics in the mixed phase region as flash rate for these individual convective cells.

Carey, Lawrence↗

NASA NTRS2012

The Kinematic and Microphysical Control of Storm Integrated Lightning Flash Extent

Objective: To investigate the kinematic and microphysical control of lightning properties, particularly those that may govern the production of nitrogen oxides (NOx) in thunderstorms, such as flash rate, type (intracloud [IC] vs. cloud-to-ground [CG] ) and extent. Data and Methodology: a) NASA MSFC Lightning Nitrogen Oxides Model (LNOM) is applied to North Alabama Lightning Mapping Array (NALMA) and Vaisala National Lightning Detection Network(TradeMark) (NLDN) observations following ordinary convective cells through their lifecycle. b) LNOM provides estimates of flash type, channel length distributions, lightning segment altitude distributions (SADs) and lightning NOx production profiles (Koshak et al. 2012). c) LNOM lightning characteristics are compared to the evolution of updraft and precipitation properties inferred from dual-Doppler (DD) and polarimetric radar analyses of UAHuntsville Advanced Radar for Meteorological and Operational Research (ARMOR, Cband, polarimetric) and KHTX (S-band, Doppler).

Carey, Lawrence D.↗

NASA NTRS2014

Variation of a Lightning NOx Indicator for National Climate Assessment

Lightning nitrogen oxides (LNOx) indirectly influences our climate since these molecules are important in controlling the concentration of ozone (O3) and hydroxyl radicals (OH) in the atmosphere [Huntrieser et al., 1998]. In support of the National Climate Assessment (NCA) program, satellite Lightning Imaging Sensor (LIS; Christian et al. [1999]; Cecil et al. [2014]) data is used to estimate LNOx production over the southern portion of the conterminous US for the 16 year period 1998-2013.

Koshak, William↗

NASA NTRS1978

Automotive fuel economy and emissions program

Experimental data were generated to support an assessment of the relationship between automobile fuel economy and emissions control systems. Tests were made at both the engine and vehicle levels. Detailed investigations were made on cold-start emissions devices, exhaust gas recirculation systems, and air injection reactor systems. Based on the results of engine tests, an alternative emission control system and modified control strategy were implemented and tested in the vehicle. With the same fuel economy and NOx emissions as the stock vehicle, the modified vehicle reduced HC and CO emissions by about 20 percent. By removing the NOx emissions constraint, the modified vehicle demonstrated about 12 percent better fuel economy than the stock vehicle.

Dowdy, M. W.↗

NASA NTRS1986

Combustion characteristics in the transition region of liquid fuel sprays

A number of important effects have been observed in the droplet size transition region in spray combustion systems. In this region, where the mechanism of flame propagation is transformed from diffusive to premixed dominated combustion, the following effects have been observed: (1) maxima in burning velocity; (2) extension of flammability limits; (3) minima in ignition energy; and (4) minima in NOx formation. A monodisperse aerosol generator has been used to form and deliver a well controlled liquid fuel spray to the combustion test section where measurements of ignition energy have been made. The ignition studies were performed on monodisperse n-heptane sprays at atmospheric pressure over a range of equivalence ratios and droplet diameters. A capacitive discharge spark ignition system was used as the ignition source, providing independent control of spark energy and duration. Preliminary measurements were made to optimize spark duration and spark gap, optimum conditions being those at which the maximum frequency or probability of ignition was observed. Using the optimum electrode spacing and spark duration, the frequency of ignition was determined as a function of spark energy for three overall equivalence ratios (0.6, 0.8, and 1.0) and for initial droplet diameters of 25, 40, 50, 60, and 70 micro m.

Cernansky, N. P.↗

NASA NTRS2005

Water Injected Turbomachinery

From antiquity, water has been a source of cooling, lubrication, and power for energy transfer devices. More recent applications in gas turbines demonstrate an added facet, emissions control. Fogging gas turbine inlets or direct injection of water into gas turbine combustors, decreases NOx and increases power. Herein we demonstrate that injection of water into the air upstream of the combustor reduces NOx by factors up to three in a natural gas fueled Trapped Vortex Combustor (TVC) and up to two in a liquid JP-8 fueled (TVC) for a range in water/fuel and fuel/air ratios.

Hendricks, R. C.↗

NASA NTRS2005

Water Injection Feasibility for Boeing 747 Aircraft

Can water injection be offered at a reasonable cost to large airplane operators to reduce takeoff NO( sub x) emissions? This study suggests it may be possible. This report is a contract deliverable to NASA Glenn Research Center from the prime contractor, The Boeing Commercial Airplane Company of Seattle, WA. This study was supported by a separate contract to the Pratt & Whitney Engine Company of Hartford, CT (contract number NNC04QB58P). Aviation continues to grow and with it, environmental pressures are increasing for airports that service commercial airplanes. The feasibility and performance of an emissions-reducing technology, water injection, was studied for a large commercial airplane (e.g., Boeing 747 with PW4062 engine). The primary use of the water-injection system would be to lower NOx emissions while an important secondary benefit might be to improve engine turbine life. A tradeoff exists between engine fuel efficiency and NOx emissions. As engines improve fuel efficiency, by increasing the overall pressure ratio of the engine s compressor, the resulting increased gas temperature usually results in higher NOx emissions. Low-NO(sub x) combustors have been developed for new airplanes to control the increases in NO(sub x) emissions associated with higher efficiency, higher pressure ratio engines. However, achieving a significant reduction of NO(sub x) emissions at airports has been challenging. Using water injection during takeoff has the potential to cut engine NO(sub x) emissions some 80 percent. This may eliminate operating limitations for airplanes flying into airports with emission constraints. This study suggests an important finding of being able to offer large commercial airplane owners an emission-reduction technology that may also save on operating costs.

Daggett, David L.↗

NASA NTRS2017

Lightning NOx Estimates from Space-Based Lightning Imagers

The intense heating of air by a lightning channel, and subsequent rapid cooling, leads to the production of lightning nitrogen oxides (NOx = NO + NO2) as discussed in Chameides [1979]. In turn, the lightning nitrogen oxides (or "LNOx" for brevity) indirectly influences the Earth's climate because the LNOx molecules are important in controlling the concentration of ozone (O3) and hydroxyl radicals (OH) in the atmosphere. Climate is most sensitive to O3 in the upper troposphere, and LNOx is the most important source of NOx in the upper troposphere at tropical and subtropical latitudes; hence, lightning is a useful parameter to monitor for climate assessments. The National Climate Assessment (NCA) program was created in response to the Congressionally-mandated Global Change Research Act (GCRA) of 1990. Thirteen US government organizations participate in the NCA program which examines the effects of global change on the natural environment, human health and welfare, energy production and use, land and water resources, human social systems, transportation, agriculture, and biological diversity. The NCA focuses on natural and human-induced trends in global change, and projects major trends 25 to 100 years out. In support of the NCA, the NASA Marshall Space Flight Center (MSFC) continues to assess lightning-climate inter-relationships. This activity applies a variety of NASA assets to monitor in detail the changes in both the characteristics of ground- and space- based lightning observations as they pertain to changes in climate. In particular, changes in lightning characteristics over the conterminous US (CONUS) continue to be examined by this author using data from the Tropical Rainfall Measuring Mission Lightning Imaging Sensor. In this study, preliminary estimates of LNOx trends derived from TRMM/LIS lightning optical energy observations in the 17 yr period 1998-2014 are provided. This represents an important first step in testing the ability to make remote retrievals of LNOx from a satellite-based lightning sensor. As is shown, the methodology can also be directly applied to more recently launched lightning mappers, such as the Geostationary Lightning Mapper, and the International Space Station LIS.

Koshak, William J.↗

NASA NTRS1976

Technology for controlling emissions of oxides of nitrogen from supersonic cruise aircraft

Various experiments are sponsored and conducted by NASA to explore the potential of advanced combustion techniques for controlling aircraft engine emissions into the upper atmosphere. Of particular concern are the oxide of nitrogen (NOx) emissions into the stratosphere. The experiments utilize a wide variety of approaches varying from advanced combustor concepts to fundamental flame tube experiments. Results are presented which indicate that substantial reductions in cruise NOx emissions should be achievable in future aircraft engines. A major NASA program is described which focuses the many fundamental experiments into a planned evolution and demonstration of the prevaporized-premixed combustion technique in a full-scale engine.

Reck, G. M.↗