Search NASA⌕ Search

SEARCH · Search NASA

Results for “O VII”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Suzaku Reveals He-burning Products in the X-ray Emitting Planetary Nebula BD +30deg 3639

BD +30deg 3639, the brightest planetary nebula at X-ray energies, was observed with Suzaku, an X-ray observatory launched on 2005 July 10. Using the X-ray Imaging Spectrometer, the K-lines from C VI, O VII, and O VIII were resolved for the first time, and C/O, N/O, and Ne/O abundance ratios determined. The C/O abundance ratio exceeds the solar value by nearly two orders of magnitude, and that of Ne/O by at least a factor of 5. These results indicate that the X-rays are emitted mainly by helium shell-burning products.

Murashima, M.↗
NASA NTRS2006

"Suzaku Highlight Results on Supernova Remnants"

Highlights of the early Suzaku (formerly Astro-E2) observations of supernova remnants are presented. Suzaku offers unique capabilities for the study of supernova remnants. The unprecedented combination of imaging and spectral resolution below 1 keV in the X-ray Imaging Spectrometer (XIS) makes possible mapping of C, N and O abundances in Galactic remnants of all ages. The first detection of carbon lines in the Cygnus Loop and mapping of the O VII to O VIII ratio in SN 1006 demonstrate this capability. The XIS sensitivity to soft, low surface brightness emission is exemplified by spectroscopy in the 0.3-1.0 keV band of the North Polar Spur and other Galactic ISM structures. Such observations make possible inferences about plasma conditions and abundances. The sensitivity above 6 keV via a combination of the XIS (below 10 keV) and the Hard X-ray Detector (above 10 keV) allows broad band (2-40 keV) spectroscopy and mapping of extended remnants with hard emission components. These components are generally associated with sites of particle acceleration, and measuring their spectral shape potentially provides information about the TeV electron population and its acceleration and energy loss mechanisms. Examples of such remnants observed by Suzaku are the non-thermal emission dominated remnants RX J1713.7-3946 and RX J0852.0-4622, for which flux beyond 30 keV has been detected. The status of the mission and prospects for future groundbreaking observations of supernova remnants will be discussed.

Petre, Robert↗
NASA NTRS2008

SWCX Emission from the Helium Focusing Cone - Preliminary Results

Preliminary results from an XMM-Newton campaign to study solar wind charge exchange (SWCX) emission from the heliospheric focusing cone of interstellar helium are presented. The detections of enhanced O VII and O VIII emission from the cone are at the 2(sigma) and 4(sigma) levels. The solar wind charge exchange (SWCX) emission in the heliosphere not associated with distinct objects (e.g., comets and planets including exospheric material in and near Earth s magnetosheath) is proportional to the flux of the solar wind and the space density of neutral material. The neutral material originates in the interstellar medium (ISM) and passes through the solar system due to the relative motion of the Sun and the ISM. The flow of the neutral material through the solar system is strongly perturbed by the Sun both by gravity and by radiation pressure. Because of the relative radiative scattering cross sections and the effect of solar gravitation the density of interstellar hydrogen near the Sun is reduced while interstellar helium is gravitationally focused. This creates a helium focusing cone downstream of the Sun [e.g., 1, and references therein].

Snowden, S. L.↗
NASA NTRS2010

Chandra High Resolution Spectroscopy of the Circumnuclear Matter in the Broad Line Radio Galaxy, 3C 445

We present evidence for X-ray line emitting and absorbing gas in the nucleus of the Broad-Line Radio Galaxy (BLRG), 3C445. A 200 ks Chandra LETG observation of 3C 445 reveals the presence of several highly ionized emission lines in the soft X-ray spectrum, primarily from the He and H-like ions of O, Ne, Mg and Si. Radiative recombination emission is detected from O VII and O VIII, indicating that the emitting gas is photoionized. The He-like emission appears to be resolved into forbidden and intercombination line components, which implies a high density of greater than 10(sup 10) cm(sup -3), while the lines are velocity broadened with a mean width of 2600 km s(sup -1). The density and widths of the ionized lines indicate an origin of the gas on sub-parsec scales in the Broad Line Region (BLR). The X-ray continuum of 3C 445 is heavily obscured by a photoionized absorber of column density N(sub H) = 2 x 10(sup 23) cm(sup -2) and ionization parameter log xi = 1.4 erg cm s(sup -1). However the view of the X-ray line emission is unobscured, which requires the absorber to be located at radii well within any parsec scale molecular torus. Instead we suggest that the X-ray absorber in 3C 445 may be associated with an outflowing, but clumpy accretion disk wind, with an observed outflow velocity of approximately 10000 km s(sup -1).

Reeves, J. N.↗
NASA NTRS1987

Dynamic evolution of the source volumes of gradual and impulsive solar flare emissions

This study compares flare source volumes inferred from impulsive hard X-rays and microwaves with those derived from density sensitive soft X-ray line ratios in the O VII spectrum. The data for this study were obtained with the SMM Hard X-Ray Burst Spectrometer, Earth-based radio observatories, and the SOLEX-B spectrometer on the P78-1 satellite. Data were available for the flares of 1980 April 8, 1980 May 9, and 1981 February 26. The hard X-ray/microwave source volume is determined under the assumption that the same electron temperature or power law index characterizes both the source of hard X-rays and the source of microwaves. The O VII line ratios yield the density and volume of the 2 X 10 to the 6th K plasma. For all three flares, the O VII source volume is found to be smallest at the beginning of the flare, near the time when the impulsive hard X-ray/microwave volume reaches its first maximum. At this time, the O VII volume is three to four orders of magnitude smaller than that inferred from the hard X-ray/microwave analysis. Subsequently, the O VII source volume increases by one or two orders of magnitude then remains almost constant until the end of the flare when it apparently increases again.

Bruner, M. E.↗
NASA NTRS1988

Dynamic evolution of the source volumes of gradual and impulsive solar flare emissions

This study compares flare source volumes inferred from impulsive hard X-rays and microwaves with those derived from density sensitive soft X-ray line ratios in the O VII spectrum. The data for this study were obtained with the SMM Hard X-ray Burst Spectrometer, Earth-based radio observatories, and the SOLEX-B spectrometer on the P78-1 satellite. Data were available for the flares of 1980 April 8, 1980 May 9, and 1981 February 26. The hard X-ray/microwave source volume is determined under the assumption that the same electron temperature or power law index characterizes both the source of hard X-rays and the source of microwaves. The O VII line ratios yield the density and volume of the 2 x 10 to the 6th K plasma. For all three flares, the O VII source volume is found to be smallest at the beginning of the flare, near the time when the impulsive hard X-ray/microwave volume reaches its first maximum. At this time, the O VII volume is three to four orders of magnitude smaller than that inferred from the hard X-ray/microwave analysis. Subsequently, the O VII source volume increases by one or two orders of magnitude then remains almost constant until the end of the flare when it apparently increases again.

Bruner, M. E.↗
NASA NTRS1984

Search for plasma shifts of C VI, N VII, and O VIII resonance lines

The resonance lines of the hydrogenlike ions C VI, N VII, and O VIII were observed in laser-produced plasmas with electron densities in the range 10 to the 21st - 10 to the 22nd per cu cm and electron temperatures between about 70 and 100 eV. The lines of the hydrogenlike ions were recorded photographically with a 3-m grazing-incidence spectrograph. No significant plasma line shift was observed.

Goldsmith, S.↗
NASA NTRS2004

RGS Spectroscopy of the Cygnus Loop XA Knot

The observations were performed at the end of April 2002, and the data were received in July 2002. Unfortunately, the observations were badly compromised by high levels of background radiation; one of the three observations was lost entirely. Two replacement observations were scheduled for November 2002, and were only made available in January of 2003. A preliminary analysis of the RGS data has been performed. Analysis of these data is complicated by the extended nature of the source, and the limited statistics. Nevertheless, examination of the 'm lambda' vs. 'xdsp-corr' data shows that the bright knot is visible in C VI Ly-alpha and Ly-beta, the O VII triplet and He-beta, and O VIII Ly-alpha. The dispersed C VI Ly-alpha image is the first image of the remnant at that energy. The F, I, R components of the O VII triplet can be seen, and the 0 VII He-beta is distinct from the O VIII Ly-alpha (although the dispersed diffuse emission provides a pseudo-continuum). Trial-and-error adjustment of the rgsproc parameters allowed the extraction of a narrow (approx. 1 arcmin wide) region centered on the knot; corresponding background spectra were extracted from the sky background data sets. The xspec rgsxsrc model was used to convolve the response with a Chandra spatial image. Because the spatial distribution of the emission is energy-dependent, the use of a single convolution kernel is only approximate.

Mushotzky, Richard F.↗
NASA NTRS2000

The XMM-Newton View of Stellar Coronae: High-Resolution X-Ray Spectroscopy of Capella

We present the high-resolution RGS spectrum of the bright stellar binary Capella observed by the XMM-Newton satellite. A multi-thermal approach has been applied to fit the data and derive elemental abundances. The differential emission measure distribution is reconstructed using a Chebychev polynomial fit. The DEM shape is found to display a sharp peak around 7 MK, consistent with previous EUVE and ASCA results. A small but significant amount of emission measure is required around 1.8 MK in order to explain the O VII He-like triplet and the C VI Ly(alpha) line. Using the sensitivity to temperature of dielectronic recombination lines from O VI around 22 A, we confirm that the cool plasma temperature needs to be higher than 1.2 MK. In the approximation of a cool plasma described by one temperature, we used line ratios from the forbidden, intercombination, and resonance lines of the O VII triplet and derived an average density for the cool coronal plasma at the low density limit. A tentative study of line ratios from the M XI triplet gives an average temperature close to the sharp peak in emission measure and an average density of the order of 10(exp 12)cu cm, three orders of magnitude higher than for O VII. Implications for the coronal physics of Capella are discussed. We complement this paper with a discussion of the importance of the atomic code uncertainties on the spectral fitting procedure.

Audard, M.↗
NASA NTRS1988

Recombination line intensities for hydrogenic ions. II - Case B calculations for C VI, N VII and O VIII

The intensities of recombination lines formed in extended, optically thim, photoionized plasmas such as those found in PN, H II regions, and winds of certain hot stars are an important source of information on chemical abundances and can sometimes provide estimates of electron temperature. In this paper, the intensities of the recombination lines of C VI, N VII, and O VIII are calculated, accounting for both electron and heavy particle collisions and assuming case B of Baker and Menzel. The computational procedure is explained. The intensities of lines formed by transitions n(u) - n(l) are tabulated for n(u) of 50 or less, n(l) of 29 or less, at log N(e) = 4(1)13 and 10 values of electron temperature in the interval 10,000 K to 500,000 K.

Storey, P. J.↗
NASA NTRS2009

SWCX Emission from the Helium Focusing Cone - Model to Data Comparison

A model for heliospheric solar wind charge exchange (SWCX) X-ray emission is applied to a series of XMM-Newton observations of the interplanetary focusing cone of interstellar helium. The X-ray data are from three coupled observations of the South Ecliptic Pole (SEP, to observe the cone) and the Hubble Deep Field-North (HDFN. to monitor global variations of the SWCX emission due to variations in the solar wind) from the period 24 November to 15 December 2003. There is good qualitative agreement between the model predictions and thc data with the maximum SWCX flux observed at an ecliptic longitude of approx. 72deg, consistent with the central longitude of the He cone. We observe a total excess of 2.1 +/- 1.3 LU in the O VII line and 2.0 +/- 0.9 LU in the 0 VIII line. However. the SWCX emission model, which was adjusted for solar wind conditions appropriate for late 2003, predicts an excess from the He cone of only 0.5 LU and 0.2 LU, respectively, in the O VII and O VIII lines. We discuss thc model to data comparison and provide possible explanations for the discrepancies. We also qualitatively reexamine our SWCX n~ocicl predictions in the 1/4 keV band with data from the ROSAT All-Sky Survey towards the North and South Ecliptic Poles, when the He cone was probably first detected in soft X-rays.

Koutroumpa, D.↗
NASA NTRS1972

Experimental study of spectral and spatial distribution of solar X-rays

The study of the physical conditions within the solar corona and the development of instrumentation and technical expertise necessary for advanced studies of solar X-ray emission are reported. Details are given on the Aerobee-borne-X-ray spectrometer/monochromator and also on the observing program. Preliminary discussions of some results are presented and include studies of helium-like line emission, mapping O(VII) and Ne(IX) lines, survey of O(VII) and Ne(IX) lines, study of plage regions and small flares, and analysis of line emission from individual active regions. It is concluded that the use of large-area collimated Bragg spectrometers to scan narrow wavelength intervals and the capability of the SPARCS pointing control to execute a complex observing program are established.

Acton, L. W.↗
NASA NTRS2012

Observed Limits on Charge Exchange Contributions to the Diffuse X-Ray Background

We present a high-resolution spectrum of the diffuse X-ray background from 0.1 to 1 keV for an approximately 1 sr region of the sky centered at l = 90 degrees b = +60 degrees using a 36 pixel array of microcalorimeters flown on a sounding rocket. With an energy resolution of 11 eV FWHM below 1 keV, the spectrum s observed line ratios help separate charge exchange contributions originating within the heliosphere from thermal emission of hot gas in the interstellar medium. The X-ray sensitivity below 1 keV was reduced by about a factor of four from contamination that occurred early in the flight, limiting the significance of the results. The observed centroid of helium-like O VII is 568 (sup +2 (sub -3) eV at 90% confidence. Since the centroid expected for thermal emission is 568.4 eV and for charge exchange is 564.2 eV, thermal emission appears to dominate for this line complex. The dominance of thermal emission is consistent with much of the high-latitude O VII emission originating in 2-3 x 10(exp 6) K gas in the Galactic halo. On the other hand, the observed ratio of C VI Lygamma to Lyalpha is 0.3 plus or minus 0.2. The expected ratios are 0.04 for thermal emission and 0.24 for charge exchange, indicating that charge exchange must contribute strongly to this line and therefore potentially to the rest of the ROSAT R12 band usually associated with 10(sup 6) K emission from the Local Hot Bubble. The limited statistics of this experiment and systematic uncertainties due to the contamination require only greater than 32% thermal emission for O VII and greater than 20% from charge exchange for C VI at the 90% confidence level. An experimental gold coating on the silicon substrate of the array greatly reduced extraneous signals induced on nearby pixels from cosmic rays passing through the substrate, reducing the triggered event rate by a factor of 15 from a previous flight of the instrument.

Crowder, S. G.↗
NASA NTRS2012

Observed Limits on Charge Exchange Contributions to the Diffuse X-Ray Background

We present a high-resolution spectrum of the diffuse X-ray background from 0.1 to 1 keV for an approximately 1 sr region of the sky centered at l = 90 degrees b = +60 degrees using a 36 pixel array of microcalorimeters flown on a sounding rocket. With an energy resolution of 11 eV FWHM below 1 keV, the spectrum s observed line ratios help separate charge exchange contributions originating within the heliosphere from thermal emission of hot gas in the interstellar medium. The X-ray sensitivity below 1 keV was reduced by about a factor of four from contamination that occurred early in the flight, limiting the significance of the results. The observed centroid of helium-like O VII is 568 (sup +2 (sub -3) eV at 90% confidence. Since the centroid expected for thermal emission is 568.4 eV and for charge exchange is 564.2 eV, thermal emission appears to dominate for this line complex. The dominance of thermal emission is consistent with much of the high-latitude O VII emission originating in 2-3 x 10(exp 6) K gas in the Galactic halo. On the other hand, the observed ratio of C VI Lygamma to Lyalpha is 0.3 plus or minus 0.2. The expected ratios are 0.04 for thermal emission and 0.24 for charge exchange, indicating that charge exchange must contribute strongly to this line and therefore potentially to the rest of the ROSAT R12 band usually associated with 10(sup 6) K emission from the Local Hot Bubble. The limited statistics of this experiment and systematic uncertainties due to the contamination require only greater than 32% thermal emission for O VII and greater than 20% from charge exchange for C VI at the 90% confidence level. An experimental gold coating on the silicon substrate of the array greatly reduced extraneous signals induced on nearby pixels from cosmic rays passing through the substrate, reducing the triggered event rate by a factor of 15 from a previous flight of the instrument.

Crowder, S. G.↗
DOE OSTI2024

Insights into the Mechanism of Neptunium Oxidation to the Heptavalent State

Abstract Neptunium can exist in multiple oxidation states, including the rare and poorly understood heptavalent form. In this work, we monitored the formation of heptavalent neptunium [Np(VII)O 4 (OH) 2 ] 3− during ozonolysis of aqueous M OH ( M =Li, Na, K) solutions using a combined experimental and theoretical approach. All experimental reactions were closely monitored via absorption and vibrational spectroscopy to follow both the oxidation state and the speciation of neptunium guided by the calculated vibrational frequencies for various neptunium species. The mechanism of the reaction partly involves oxidative dissolution of transient Np(VI) oxide/hydroxide solid phases, the identity of which are dependent on the co‐precipitating counter‐cation Li + /Na + /K + . Additional calculations suggest that the most favorable energetic pathway occurs through the reaction of a [Np(V)O 2 (OH) 4 ] 3− with the hydroxide radical to form [Np(VI)O 2 (OH) 4 ] 2− , followed by an additional oxidation with HO⋅ to create [Np(VII)O 4 (OH) 2 ] 3− .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2000

An Extended Multi-Zone Model for the MCG-6-30-15 Warm Absorber

The variable warm absorber seen with ASCA in the X-ray spectrum of MCG 6-30-15 shows complex time behaviour in which the optical depth of O VIII anticorrelates with the flux whereas that of O VII is unchanging. The explanation in terms of a two zone absorber has since been challenged by BeppoSAX observations. These present a more complicated behaviour for the O VII edge. The explanation we offer for both ASCA and BeppoSAX observations requires a very simple photoionization model together with the presence of a third, intermediate, zone and a period of very low luminosity. In practice warm absorbers are likely to be extended, multi-zone regions of which only part causes directly observable absorption edges at any given time depending on the value of the luminosity.

Morales, R.↗
NASA NTRS1976

Spectroscopic studies of the solar corona at X-ray wavelengths

The spatial distribution of emission in several X-ray lines is discussed with emphasis on temperature dependence and association with active regions. Results are presented for the trio of helium-like O VII lines which demonstrate (1) a spatial variation in the density-dependent forbidden-to-intersystem line ratio, and (2) a strong spatial variation in the intensity of the O VII resonance line relative to the optically forbidden transitions. The second effect appears to be caused by resonance scattering by material in the line of sight.

Acton, L. W.↗
DOE OSTI2025

Oxidation and recharge of reactive structural Fe( II ) in titanomagnetite (Fe 3− x Ti x O 4 ) nanoparticles

Mixed-valent iron oxide minerals, such as magnetite (Fe(II)(Fe(III)) 2 O 4 ), are an important source of solid-state ferrous iron (Fe(II)) that can impact the speciation and transport of electron accepting contaminants in the Earth’s subsurface, such as radioactive pertechnetate ( 99 Tc(VII)O 4 − ). However, when oxidizing conditions are encountered, structural Fe(II) at the mineral surface is consumed yielding a maghemite (γ-Fe(III) 2 O 3 )-like layer that limits further electron transfer. This oxidized surface layer can be recharged back to the original Fe(II)/(III) ratio by re-exposure to reducing conditions, i.e., aqueous solutions containing Fe 2+ . However, for substituted magnetite (Fe 3−x M x O 4 , M = transition metal cation), the extent of this redox recyclability is unclear. Here, we examine oxidation and recharge for titanomagnetite (Fe 3−x Ti x O 4 ) nanoparticles, where the Fe(II)/Fe(III) ratio varies by the amount of Fe(II) required to charge balance the titanium (Ti(IV)) substituted into the structure. The nanoparticles were synthesized by aqueous precipitation from a solution containing ferrous, ferric and titanium chloride at room temperature. Transmission electron microscopy combined with electron energy loss spectroscopy revealed that rapid precipitation formed core–shell-like nanoparticles consisting of a hyperstoichiometric magnetite core, with Ti(IV) and charge balancing Fe(II) enriched at the surface. This surface enrichment made Fe(II) more available for electron transfer reactions with redox active solution species. Examination of oxidation by H 2 O 2 followed by recharge with aqueous Fe 2+ indicates recyclability of reducing equivalents in the nanoparticles, yielding a core recrystallized to stoichiometric magnetite and a shell bearing excess Fe(II) to charge balance the substituted Ti(IV). The recharged particles are shown to have restored redox reactivity with 99 Tc(VII)O 4 − resulting in reduction to 99 Tc(IV)O 2 and oxidation of the structural Fe(II) to Fe(III).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗