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At least 55 records · Page 3

Flame propagation and extinction in particle clouds

Two phase flame propagation and extinction theory required to support the corresponding experiments planned for the space shuttle is being developed. Also being planned are specialized collaborative, experimental and theoretical NASA UCSD studies needed to support the ongoing definition of needed experimental hardware, experimental procedures, data acquisition philosophy, and other ground based support activities required to assure the success of space shuttle based experiments concerned with combustion of clouds of particulates at reduced gravitational conditions. The further development of relations delineating premixed particle cloud and premixed gaseous systems as well as burner stabilized and freely propagating flame systems is considered.

Berlad, A. L.↗

Particle cloud combustion in reduced gravity

The prinicipal objectives of this microgravity experiment program are to obtain flame propagation rate and flame extinction limit data for several important premixed, quiescent particle cloud combustion systems under near zero-gravity conditions. The data resulting from these experiments are needed for utilization with currently available and tractable flame propagation and extinction theory. These data are also expected to provide standards for the evaluation of fire hazards in particle suspensions in both Earth-based and space-based applications. Both terrestrial and space-based fire safety criteria require the identification of the critical concentrations of particulate fuels and inerts at the flame extinction conditions.

Berlad, A. L.↗

The phase function of Venus cloud particles from Mariner 10 data

Mariner 10 images of Venus taken at several phase angles were photometrically reduced. The analysis shows that the phase function of the cloud particles is not isotropic, as had been deduced earlier from the brightness distribution on spacecraft images taken at a single phase angle, but has a broad minimum near 60 deg and is forward-scattering. The scattering properties are in quantitative agreement with previous deductions from earth-based polarization measurements by Hansen and his associates.

Hapke, B.↗

Homogenous Surface Nucleation of Solid Polar Stratospheric Cloud Particles

A general surface nucleation rate theory is presented for the homogeneous freezing of crystalline germs on the surfaces of aqueous particles. While nucleation rates in a standard classical homogeneous freezing rate theory scale with volume, the rates in a surface-based theory scale with surface area. The theory is used to convert volume-based information on laboratory freezing rates (in units of cu cm, seconds) of nitric acid trihydrate (NAT) and nitric acid dihydrate (NAD) aerosols into surface-based values (in units of sq cm, seconds). We show that a surface-based model is capable of reproducing measured nucleation rates of NAT and NAD aerosols from concentrated aqueous HNO3 solutions in the temperature range of 165 to 205 K. Laboratory measured nucleation rates are used to derive free energies for NAT and NAD germ formation in the stratosphere. NAD germ free energies range from about 23 to 26 kcal mole, allowing for fast and efficient homogeneous NAD particle production in the stratosphere. However, NAT germ formation energies are large (greater than 26 kcal mole) enough to prevent efficient NAT particle production in the stratosphere. We show that the atmospheric NAD particle production rates based on the surface rate theory are roughly 2 orders of magnitude larger than those obtained from a standard volume-based rate theory. Atmospheric volume and surface production of NAD particles will nearly cease in the stratosphere when denitrification in the air exceeds 40 and 78%, respectively. We show that a surface-based (volume-based) homogeneous freezing rate theory gives particle production rates, which are (not) consistent with both laboratory and atmospheric data on the nucleation of solid polar stratospheric cloud particles.

Tabazadeh, A.↗

The structure of particle cloud premixed flames

The aim of this study is to provide a numerical and asymptotic description of the structure of planar laminar flames, propagating in a medium containing a uniform cloud of fuel-particles premixed with air. Attention is restricted here to systems where the fuel-particles first vaporize to form a known gaseous fuel, which is then oxidized in the gas-phase. This program is supported for the period September 14, 1991 to September 13, 1992. Some results of the study is shown in Ref. 1. The work summarized in Ref. 1 was initiated prior to September 14, 1991 and was completed on February 1992. Research performed in addition to that described in Ref. 1 in collaboration with Professor A. Linan, is summarized here.

Seshadri, K.↗

Chlorine chemistry on polar stratospheric cloud particles in the Arctic winter

Simultaneous in situ measurements of hydrochloric acid (HCl) and chlorine monoxide (ClO) in the Arctic winter vortex showed large HCl losses of up to 1 ppbv, which were correlated with high ClO levels of up to 1.4 ppbv. Air parcel trajectory analysis identified that this conversion of inorganic chlorine occurred at air temperatures of less than 196 -/+ 4 kelvin. High ClO was always accompanied by loss of HCl mixing ratios equal to 1/2(ClO+ 2Cl2O2). These data indicate that the heterogeneous reaction HCl + ClONO2 - Cl2 + HNO3 on particles of polar stratospheric clouds establishes the chlorine partitioning, which, contrary to earlier notions, begins with an excess of ClONO2, not HCl.

Webster, C. R.↗

A Laboratory Study on the Phase Transition for Polar Stratospheric Cloud Particles

The nucleation and growth of different phases of simulated polar stratospheric cloud (PSC) particles were investigated in the laboratory. Solutions and mixtures of solutions at concentrations 1 to 5 m (molality) of ammonium sulfate, ammonium bisulfate, sodium chloride, sulfuric acid, and nitric acid were supercooled to prescribed temperatures below their equilibrium melting point. These solutions were contained in small diameter glass tubing of volumes ranging from 2.6 to 0.04 ml. Samples were nucleated by insertion of an ice crystal, or in some cases by a liquid nitrogen cooled wire. Crystallization velocities were determined by timing the crystal growth front passages along the glass tubing. Solution mixtures containing aircraft exhaust (soot) were also examined. Crystallization rates increased as deltaT2, where deltaT is the supercooling for weak solutions (2 m or less). The higher concentrated solutions (greater than 3 m) showed rates significantly less than deltaT2. This reduced rate suggested an onset of a glass phase. Results were applied to the nucleation of highly concentrated solutions at various stages of polar stratospheric cloud development within the polar stratosphere.

Teets, Edward H., Jr.↗

The ozone hole - The role of polar stratospheric cloud particles

The role of polar stratospheric clouds in the formation of the Antarctic ozone hole is considered. Several researchers have suggested that the decrease in ozone over Antarctica is related to the polar stratospheric clouds (PSCs) which had been observed in the antarctic winter stratosphere. Some of the pertinent characteristics of polar stratospheric clouds are discussed, and it is shown how these clouds may participate in the ozone destruction process. The satellite data for PSCs is analyzed, and statistical information regarding the number and maximum extinctions of these clouds is presented. Evidence that the polar stratospheric clouds are composed of frozen nitric acid is considered. It is suggested that the evaporation of the clouds, in late August and September, will release HOCl and HNO3 to the environment. This could be followed by the photodissociation of HOCl to OH and Cl, which would very effectively destroy ozone. However, the ozone destruction mechanism could be halted when enough of the evaporated nitric acid is photolized.

Hamill, Patrick↗

Can Semi-Volatile Organic Aerosols Lead to Fewer Cloud Particles?

The impact of condensing organic aerosols on activated cloud number concentration is examined in a new aerosol microphysics box model, MATRIX-VBS. The model includes the volatility-basis set (VBS) framework coupled with the aerosol microphysical scheme MATRIX (Multiconfiguration Aerosol TRacker of mIXing state) that resolves aerosol mass and number concentrations and aerosol mixing state. By including the condensation of organic aerosols, the new model produces less activated particles compared to the original model, which treats organic aerosols as non-volatile. Parameters such as aerosol chemical composition, mass and number concentrations, and particle sizes which affect activated cloud number concentration are thoroughly tested via a suite of Monte-Carlo simulations. Results show that by considering semi-volatile organics in MATRIX-VBS, there is lower activated particle number concentration, except in cases with low cloud updrafts, in clean environment at above freezing temperatures, and in polluted environments at high temperature (310K) and extremely low humidity conditions.

Gao, Chloe Y.↗

Balloon-borne measurements of aerosol, condensation nuclei, and cloud particles in the stratosphere at McMurdo Station, Antarctica, during the spring of 1987

Measurements of the vertical profile of particles with condensation nuclei counters and eight channel aerosol detectors at McMurdo Station, Antarctica, in 1987 verified observations made in 1986 concerning the absence of upwelling in the polar vortex and the presence of a condensation nuclei layer in conjunction with the ozone hole region. New observations of a bimodal aerosol size distribution, consisting of a large-particle mode mixed in with the small-particle sulfate mode, at temperatures below -79 C are consistent with the presence of nitric acid-water particles at low concentrations. Higher concentrations of large particles were observed in association with nacreous clouds. An unusual particle layer which contained enhanced concentrations of both the small-particle (sulfate) mode and the large-particle (nitric acid) mode was detected at temperatures below -85 C, suggesting simultaneous nucleation and growth phenomena. The vortex condensation nuclei layer was observed to form at the same time as the ozone hole, indicating that formation of the layer is triggered by photochemical processes and may be important in controlling ozone depletion above 22 km.

Hofmann, D. J.↗

Rain, Snow, Hurricanes, and Blizzards: Remote Sensing of Cloud Particles

Hurricanes, blizzards and other weather events are important to understand not only for disaster preparation, but also to track the global energy balance and to improve weather and climate forecasts. For several decades, passive radiometers and active radars on aircraft and satellites have been employed to remotely sense rain rates and the properties of liquid particles. In the past few years the relationships between frozen particles and millimeter-wave observations have become understood well enough to estimate the properties of ice in clouds. This colloquium will start with a broad background of the use of remote sensing of precipitation and then focus on recent research in the estimation of frozen cloud properties, both for ice that will eventually melt into rain and for solid precipitation falling in northern climates. The electromagnetic absorption and scattering properties of liquid rain and frozen particles will be explained. Retrieved cloud particle contents and size distributions for Hurricane Erin (2001 ) and the March 5-6, 2001 New England regional blizzard will be discussed. Future directions and challenges of this work will also be presented.

Gail Skofronick-Jackson↗

Classification of Cloud Particle Imagery from Aircraft Platforms Using Convolutional Neural Networks

Abstract A vast amount of ice crystal imagery exists from a variety of field campaign initiatives that can be utilized for cloud microphysical research. Here, nine convolutional neural networks are used to classify particles into nine regimes on over 10 million images from the Cloud Particle Imager probe, including liquid and frozen states and particles with evidence of riming. A transfer learning approach proves that the Visual Geometry Group (VGG-16) network best classifies imagery with respect to multiple performance metrics. Classification accuracies on a validation dataset reach 97% and surpass traditional automated classification. Furthermore, after initial model training and preprocessing, 10 000 images can be classified in approximately 35 s using 20 central processing unit cores and two graphics processing units, which reaches real-time classification capabilities. Statistical analysis of the classified images indicates that a large portion (57%) of the dataset is unusable, meaning the images are too blurry or represent indistinguishable small fragments. In addition, 19% of the dataset is classified as liquid drops. After removal of fragments, blurry images, and cloud drops, 38% of the remaining ice particles are largely intersecting the image border (≥10% cutoff) and therefore are considered unusable because of the inability to properly classify and dimensionalize. After this filtering, an unprecedented database of 1 560 364 images across all campaigns is available for parameter extraction and bulk statistics on specific particle types in a wide variety of storm systems, which can act to improve the current state of microphysical parameterizations.

54 ENVIRONMENTAL SCIENCES↗

Correlations among the Optical Properties of Cirrus-Cloud Particles: Microphysical Interpretation

Cirrus measurements obtained with a ground-based polarization Raman lidar at 67.9 deg N in January 1997 reveal a strong positive correlation between the particle optical properties, specifically depolarization ratio delta(sub par) and extinction- to-backscatter (lidar) ratio S, for delta(sub par) less than approximately 40%, and an anti-correlation for delta(sub par) greater than approximately 40%. Over the length of the measurements the particle properties vary systematically. Initially, delta (sub par) approximately equals 60% and S approximately equals 10sr are observed. Then, with decreasing delta(sub par), S first increases to approximately 27sr (delta(sub par) approximately equals 40%) before decreasing to values around 10sr again (delta(sub par) approximately equals 20%). The analysis of lidar humidity and radiosonde temperature data shows that the measured optical properties stem from scattering by dry solid ice particles, while scattering by supercooled droplets, or by wetted or subliming ice particles can be excluded. For the microphysical interpretation of the lidar measurements, ray-tracing computations of particle scattering properties have been used. The comparison with the theoretical data suggests that the observed cirrus data can be interpreted in terms of size, shape, and, under the assumption that the lidar measurements of consecutive cloud segments can be mapped on the temporal development of a single cloud parcel moving along its trajectory, growth of the cirrus particles: Near the cloud top in the early stage of cirrus development, light scattering by nearly isometric particles that have the optical characteristics of hexagonal columns (short, column-like particles) is dominant. Over time the ice particles grow, and as the cloud base height extends to lower altitudes characterized by warmer temperatures they become morphologically diverse. For large S and depolarization values of approximately 40%, the scattering contributions of column- and plate-like particles are roughly the same. In the lower ranges of the cirrus clouds, light scattering is predominantly by plate-like ice particles. This interpretation assumes random orientation of the cirrus particles. Simulations with a simple model suggest, however, that the positive correlation between S and delta(sub par) which is observed for depolarization ratios less than 40% mainly at low cloud altitudes, can be alternatively explained by horizontal alignment of a fraction of the cirrus particle population.

Reichardt, J.↗

Influence of Convection and Aerosol Pollution on Ice Cloud Particle Effective Radius

Satellite observations show that ice cloud effective radius (r(sub e)) increases with ice water content (IWC) but decreases with aerosol optical thickness (AOT). Using least-squares fitting to the observed data, we obtain an analytical formula to describe the variations of r(sub e) with IWC and AOT for several regions with distinct characteristics of r(sub e) -IWC-AOT relationships. As IWC directly relates to convective strength and AOT represents aerosol loading, our empirical formula provides a means to quantify the relative roles of dynamics and aerosols in controlling r(sub e) in different geographical regions, and to establish a framework for parameterization of aerosol effects on r(sub e) in climate models.

Jiang, J. H.↗

Cloud particle effects on laminar flow and instrumentation for their measurement aboard a NASA LFC aircraft

Fuel costs account now for approximately 60 percent of the direct operating costs of airlines and future commercial transport will utilize advanced technologies for saving fuel on the basis of drag reduction. Laminar flow control (LFC) represents such an advanced technology. A new laminar flow wing on a reconfigured WB-66 aircraft was tested in the X-21 flight program. The tests confirmed that extensive laminar flow could be achieved at subsonic transport cruise conditions. Factors affecting adversely the maintenance of laminar flow were found to be related to ice particles encountered during the penetration of cirrus clouds or haze. The present investigation is concerned with the effect of ice particles on LFC, taking into account the results obtained in the Leading Edge Flight Test (LEFT) being conducted by NASA. Attention is given to ice particle measurements in the LEFT program.

Davis, R. E.↗

Comparison of Ice Cloud Particle Sizes Retrieved From Satellite Data Derived From In Situ Measurements

Cloud microphysical parameterizations have attracted a great deal of attention in recent years due to their effect on cloud radiative properties and cloud-related hydrological processes in large-scale models. The parameterization of cirrus particle size has been demonstrated as an indispensable component in the climate feedback analysis. Therefore, global-scale, long-term observations of cirrus particle sizes are required both as a basis of and as a validation of parameterizations for climate models. While there is a global scale, long-term survey of water cloud droplet sizes (Han et al. 1994), there is no comparable study for cirrus ice crystals. In this paper a near-global survey of cirrus ice crystal sizes is conducted using ISCCP satellite data analysis. The retrieval scheme uses phase functions based upon hexagonal crystals calculated by a ray tracing technique. The results show that global mean values of D(e) are about 60 micro-m. This study also investigates the possible reasons for the significant difference between satellite retrieved effective radii (approx. 60 micro-m) and aircraft measured particle sizes (approx. 200 micro-m) during the FIRE I IFO experiment. They are (1) vertical inhomogeneity of cirrus particle sizes; (2) lower limit of the instrument used in aircraft measurements; (3) different definitions of effective particle sizes; and (4) possible inappropriate phase functions used in satellite retrieval.

Han, Qingyuan↗

Comparison of Ice Cloud Particle Sizes Retrieved from Satellite Data Derived from In Situ Measurements

Cloud microphysical parameterizations have attracted a great deal of attention in recent years due to their effect on cloud radiative properties and cloud-related hydrological processes in large-scale models. The parameterization of cirrus particle size has been demonstrated as an indispensable component in the climate feedback analysis. Therefore, global-scale, long-term observations of cirrus particle sizes are required both as a basis of and as a validation of parameterizations for climate models. While there is a global scale, long-term survey of water cloud droplet sizes (Han et al.), there is no comparable study for cirrus ice crystals. This study is an effort to supply such a data set.

Han, Qingyuan↗