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DOE OSTI2024

Evaluation of Surface Crack Formation in Photovoltaic Backsheets Using Fragmentation and Finite Element Simulations

Backsheet cracking is among the most commonly observed degradation modes of photovoltaic modules in the field. Cracks can reduce the ability of backsheets to fulfill their functions, such as protection of the modules from the environment or electrical insulation. Here, this work presents an evaluation of the degradation and cracking propensity of two backsheets during accelerated IEC TS 62788-7-2 (International Electrotechnical Commission) aging under the A3 condition with a fragmentation test using a coextruded polyamide backsheet (AAA), and a laminated multilayer backsheet with a polyethylene terephthalate core and outer layer and ethylene vinyl acetate inner layer (PPE). Results show the surface embrittlement of the AAA outer layer during exposure. A longer time of exposure causes cracks to form at lower strains during stretching and creates deeper cracks. Accordingly, Young's modulus of the outer layer increases, as measured by cross-sectional nanoindentation. PPE exhibits cracking after exposure as well. While no similar increase of modulus or crack depth can be observed, the outer layer of PPE exhibits more obvious signs of erosion during exposure, including progressive morphological changes and thickness losses. A finite element model is developed to simulate surface crack formation, based on initially zero-thickness decohesion elements. Decohesion criteria define a critical stress, at which these elements grow, and cracks can begin to form. These criteria are obtained via parameter optimization by comparison between simulation and experiment. The model is used to interpret crack formation in both backsheets.

14 SOLAR ENERGY↗

DOE OSTI2025

Aircraft in-situ measurements from SOCRATES constrain the anthropogenic perturbations of cloud droplet number

Aerosol-cloud interactions (ACI) in warm clouds alter reflected shortwave radiation by influencing cloud microphysical and macrophysical properties. The variable of state controlling ACI is the cloud droplet number concentration (N d ). Here, we examine the perturbations in N d due to anthropogenic aerosols (ΔN d, PD-PI ) using a perturbed parameter ensemble (PPE) hosted in the sixth Community Atmosphere Model (CAM6). Surrogate models are created for the CAM6 PPE outputs and are used to generate 1 million model variants of CAM6 by sampling 45 sources of parameter uncertainty. The range of uncertain physical parameters related to ACI are constrained with observations of aerosol and cloud properties from SOCRATES. The likely range of uncertain parameters and the associated range of ΔN d, PD-PI are more strongly constrained with observations of N d relative to observations of cloud condensation nuclei. We conduct sensitivity tests of how constraints on ΔN d, PD-PI are affected by systematic uncertainties in observations and our limitations in our surrogate models created for CAM6 PPE outputs. Based on this, we provide guidance on the impact of reducing systematic uncertainty in airborne microphysical observations and in surrogate models.

Song, Ci [Univ. of Wyoming, Laramie, WY (United St↗

DOE OSTI2026

E3SMv3 ‘Nephele’ Perturbed Parameter Ensemble Value-Added Product for ENA, SGP, NSA, and Global Means

Processed output from the E3SMv3 Nephele perturbed parameter ensemble (PPE). This product contains global means of present-day (using 2010 aerosol forcings) and preindustrial (using 1850 aerosol forcings) monthly and daily global-mean quantities, as well as hourly mean quantities at the E3SMv3 model grid cell closest to the ENA, SGP, and NSA ARM sites. In this PPE, the E3SMv3 model was run for 27 months in an atmosphere-only configuration with free tropospheric winds nudged to reanalysis. Each ensemble member represents a unique combination of 25 model parameter values (in the microphysics, convective microphysics, and aerosol schemes) that were perturbed randomly and simultaneously. The E3SMv3 default configuration is included as member 0. See https://doi.org/10.22541/essoar.174907165.57104591/v1 (in review) for more information on the Nephele PPE and the perturbed parameters.

Model atmospheric temperature↗

NASA NTRS2009

Functionalizing CNTs for Making Epoxy/CNT Composites

Functionalization of carbon nanotubes (CNTs) with linear molecular side chains of polyphenylene ether (PPE) has been shown to be effective in solubilizing the CNTs in the solvent components of solutions that are cast to make epoxy/CNT composite films. (In the absence of solubilization, the CNTs tend to clump together instead of becoming dispersed in solution as needed to impart, to the films, the desired CNT properties of electrical conductivity and mechanical strength.) Because the PPE functionalizes the CNTs in a noncovalent manner, the functionalization does not damage the CNTs. The functionalization can also be exploited to improve the interactions between CNTs and epoxy matrices to enhance the properties of the resulting composite films. In addition to the CNTs, solvent, epoxy resin, epoxy hardener, and PPE, a properly formulated solution also includes a small amount of polycarbonate, which serves to fill voids that, if allowed to remain, would degrade the performance of the film. To form the film, the solution is drop-cast or spin-cast, then the solvent is allowed to evaporate.

Chen, Jian↗

NASA NTRS2019

Thermal Design Challenges for In-Flight Exposure to an Electric Propulsion Plasma Plume Environment

The use of electric propulsion to carry out NASA in-space propulsion demands has been increasing. A big part of fulfilling this demand is the Power and Propulsion Element (PPE) for NASA's Lunar Gateway. When built, the PPE will have the largest electric propulsion system to ever fly on a spacecraft, which brings new and difficult challenges. The environment created by the electric propulsion system during on-orbit operation of the thrusters has been shown to be different than those measured during operation in terrestrial vacuum facilities. Understanding the on-orbit environment created by the thrusters and its impacts on the spacecraft is the goal of the Plasma Diagnostic Package (PDP). The PDP is a sensor package, which is being developed by NASA GRC (Glenn Research Center), to fly on the PPE. The PDP will measure different aspects of the thruster plume in order to develop higher fidelity modeling of EP (Electric Power) systems. In order to capture quality measurements of the plume the PDP will need to install sensors in close proximity of it. This poses several unique thermal design challenges. Some of these challenges include: the long duration exposure to plume induced heating, the effects of plume induced erosion and sputter deposition on thermal control surfaces, and the extreme environments of a cis-lunar orbit. This paper looks to define the thermal challenges, explain modeling techniques, and offer design solutions for unique challenges of the PDP mission.

Thermal↗

NASA NTRSDate not supplied

Extended Performance Characterization of the 12.5-kW Advanced Electric Propulsion System Engineering Test Unit Hall Thruster

This work presents a summary of the first detailed performance assessment of the Advanced Electric Propulsion System (AEPS) Engineering Test Unit 2 (ETU-2) thruster produced by Aerojet Rocketdyne at the throttle conditions most relevant for AEPS application on the Gateway Power and Propulsion Element (PPE). First, an assessment was performed of ETU-2 performance and backpressure sensitivity at the previously-tested throttle points of 300 V/6.25 kW, 400 V/8.33 kW, 500 V/10.42 kW, and 600 V/12.5 kW that confirmed ETU-2 and the test facility were both operating nominally and consistent with historical baselines. ETU-2 performance and stability were then assessed throughout the PPE throttle range of 2.6-12 kW and shown to be in-family with predictions based on the scaling of previous results. Taken together, these results will help inform application of AEPS on PPE as the AEPS design progresses towards its Critical Design Review.

Jason D Frieman↗

NASA NTRSDate not supplied

Extended Performance Characterization of the 12.5-kW Advanced Electric Propulsion System Engineering Test Unit Hall Thruster

HERMeS↗

NASA NTRSDate not supplied

NASA Lunar Exploration – Gateway’s Power and Propulsion Element Communications Links

As a key part of NASA’s Artemis program to return to the moon, the Lunar Gateway will provide a platform for staging lunar missions, for gaining experience in operations beyond earth orbit, and for creating sustainable infrastructure. Of specific interest, the Lunar Gateway will provide communications support to landers, orbiters, and surface systems, including in the South Polar Region where direct line of sight (LOS) to Earth is limited or non-existent. A foundational segment of the Gateway is the Power and Propulsion Element (PPE), which will carry: solar arrays to provide power to the Gateway; electric propulsion to maintain the Gateway in its operational orbit; and communication links between the Earth and Gateway, the Moon and Gateway, and relays from the Moon to the Earth. PPE Communication Links include an X-band link to Earth for Command, Ranging, and Telemetry (CR&T), which also carries low to medium rate data; a Ka-band Direct to Earth(DTE) link for high rate data transmissions; and a Ka-band Lunar link for high data rate connections to lunar systems. This paper describes the PPE communication links from a technical perspective. Other Gateway links supported by other modules are outside the scope of this paper.

ARTEMIS↗

NASA NTRSDate not supplied

Attitude Profile Reference for the Earth Orbit Raising Phase of NASA Gateway’s Co-Manifested Vehicle

As part of NASAs lunar exploration Artemis program, the agency is designing a Gateway to orbit8near the moon and provide long term support of a sustained lunar presence at the moon’s south pole.9The first element launched for the Gateway is the Co-Manifested Vehicle (CMV), comprised of the10Power and Propulsion Element (PPE) and Habitation and Lunar Outpost (HALO). The PPE Mission11Design team of McGuire & et. al (2021) has developed a Design Reference Mission (DRM) trajectory12for CMV’s Earth Orbit Raising (EOR) mission phase, which provides the vehicle’s 3 degrees of freedom13(DoF) trajectory information during the approximately yearlong spiral out from low Earth orbit and14into the lunar near-rectilinear halo orbit (NRHO). In tandem, the PPE GN&C team is developing a15high-fidelity and fine temporal resolution 6DoF model of the CMV spacecrafts GN&C performance16for delivery to the Gateway team; this work acts to bridge the gap between Mission Designs 3DoF17reference and detailed GN&Cs attitude simulation.

Guidance Navigation and Control↗

NASA NTRSDate not supplied

Development Of 12 Kw Hall Thrusters for Nasa Lunar Gateway Power And Propulsion Element

NASA is embarking on a new and exciting era of human exploration to the Moon and its vicinity. As part of the Artemis program, NASA is developing the lunar Gateway, an orbiting platform in Near Rectilinear Halo Orbit (NRHO) about the Moon. The first two elements of the Gateway will be launched in 2024 and will be transferred from a high Earth orbit to the NRHO via the use of Solar Electric Propulsion (SEP). The SEP system is located on the Power and Propulsion Element (PPE) which will provide up to 60 kW of power. Aerojet Rocketdyne is developing the 12 kW flight Hall thrusters to be used for transferring the PPE and the Habitat and Logistics Outpost (HALO) module to NRHO. Work is continuing on the development testing, and these results will be described in the paper. The project has also recently completed its critical design review and is transitioning to the fabrication of the three flight thrusters. The 12 kW Hall thrusters are being developed under the NASA Advanced Electric Propulsion System (AEPS) program. As part of the AEPS program, AR built two Engineering Test Unit (ETU) Hall thrusters based on the NASA HERMeS engine and conducted a series of tests to validate the design. One series of tests focused on environments and functional testing, while the other series was mainly focused on long duration test blocks. Results from these tests were used to compare with NASA data from the HERMeS thruster. The comparison of the test results showed no change to the critical performance and lifetime parameters, which enabled the next phase of the program to proceed. Currently testing is continuing on the Engineering Development Units (EDU) as part of the flight qualification activities. The successful completion of the CDR serves as the starting point for the flight thruster fabrication, which is now underway to support the launch of the Gateway modules in 2024. The development and qualification of the AEPS 12 kW Hall thrusters is proceeding well. As the program completes CDR and transitions into flight builds of the three 12 kW Hall thrusters that will be used to transfer the combined PPE and HALO stack to the NRHO, the results of the development testing are reviewed in this presentation, and a status of the program and future plans is provided. The launch of the two Gateway modules and the transfer of this large payload to cislunar orbit will mark a significant milestone in electric propulsion, as it will demonstrate the ability of SEP to transfer very large payloads over great distances. This establishes the precedent that could lead to cargo transfers from the Earth to the Moon or even to Mars using SEP.

Hall thrusters↗

NASA NTRSDate not supplied

Solar Array System Combined Environmental Effects Tests: Gateway Power and Propulsion Element

The NASA Lunar Orbital Platform-Gateway (LOP-G), a vital component of NASA’s Artemis program, will serve as a multi-purpose outpost orbiting the Moon. A foundational component of LOP-G is the Power and Propulsion Element (PPE). The PPE is a high-power, +60-kilowatt solar electric propulsion spacecraft that will provide power, high-rate communications, attitude control, and orbital transfer capabilities for the Gateway. The solar array system will utilize 4-junction photovoltaic cell technology on a flexible substrate (roll-out solar array or ROSA) in combination with multiple diode assemblies to combine the power of the solar array strings. NASA’s Marshall Space Flight Center, together with the PPE developer, Maxar, are in the midst of completing a rigorous combined environments test campaign of 3 solar array coupons and 1 array blocking diode board coupon. The campaign includes Ultra-Violet Radiation, Charged Particle Radiation, Ion Erosion, Thermal Cycles, and Electrostatic Discharge tests. The environments are applied in 3 separate incremental stages reflecting the various mission phases: 460 days of Earth-to-Lunar Transit, with much of that time through the Van Allen Belts, 5-years in Lunar Near-Rectilinear Halo Orbit (NRHO) at the Moon, and finally 15-years in Lunar NRHO, which represents the end of the design life. This paper will report on the state of the testing for each coupon, and brief look at the array performance, including some unexpected sensitivities of array blocking diodes.

Gateway↗

NASA NTRSDate not supplied

Application of Solar Electric Propulsion to the Low Thrust Lunar Transit of the Gateway Power and Propulsion Element

NASA has committed to returning to the moon, landing the first woman and the next man on its surface. To support a sustained lunar presence, NASA is designing an orbital platform to be assembled in a semi-stable orbit near the moon called the Near Rectilinear Halo Orbit (NRHO). This platform is known as the Gateway and its purpose it to support missions primarily to the lunar south pole. As NASA continues to study ways to reduce the cost of lunar exploration, a simplification implemented in 2020 was combining the first two elements of the Gateway together onto a single commercial launch vehicle (CLV). When launched together, the Power and Propulsion Element (PPE) and NASA’s Habitation and Logistics Outpost (HALO) make up the Co-Manifested Vehicle (CMV). The PPE, a high-power Solar Electric Propulsion (SEP) Stage, will propel the combined stack from a low elliptical orbit to a semi stable orbit near the moon known as a Near Rectilinear Halo Orbit (NRHO). A transit of such a large mass, delivered to the moon from a single launch vehicle is only made possible by the use of the highly efficient SEP low thrust propulsion system. Delivering the same mass via more traditional chemical propulsion systems would require multiple launches and significantly more propellant. This paper captures an overview of the PPE’s SEP system, the lunar transit it will perform to deliver these first two elements of NASA’s Gateway to the NRHO with a comparison of a chemical system performing the same lunar transit to illustrate how SEP enables NASA’s Gateway.

electric propulsion↗

NASA NTRS2024

Buffering of Aerosol-Cloud Adjustments by Coupling Between Radiative Susceptibility and Precipitation Efficiency

Aerosol-cloud interactions (ACI) in warm clouds are the primary source of uncertainty in effective radiative forcing (ERF) during the historical period and, by extension, inferred climate sensitivity. The ERF due to ACI (ERFaci) is composed of the radiative forcing due to changes in cloud microphysics and cloud adjustments to microphysics. Here, we examine the processes that drive ERFaci using a perturbed parameter ensemble (PPE) hosted in CAM6. Observational constraints on the PPE result in substantial constraints in the response of cloud microphysics and macrophysics to anthropogenic aerosol, but only minimal constraint on ERFaci. Examination of cloud and radiation processes in the PPE reveal buffering of ERFaci by the interaction of precipitation efficiency and radiative susceptibility.

perturbed parameter ensemble↗

DOE OSTI2023

Evaluation of Surface Crack Formation in Photovoltaic Backsheets Using Fragmentation and Finite Element Simulations: Preprint

Backsheet cracking is among the most commonly observed degradation modes of photovoltaic (PV) modules in the field. Cracks can reduce the ability of backsheets to fulfil their functions, for example, protection of the modules from the environment or electrical insulation. This work presents an evaluation of the degradation and cracking propensity of two backsheets during accelerated IEC TS 62788-7-2 A3 (International Electrotechnical Commission) aging with the fragmentation test: a co-extruded polyamide backsheet (AAA), and a laminated multilayer backsheet with a polyethylene terephthalate core and outer layer and ethylene vinyl acetate inner layer (PPE). Results show the surface embrittlement of the AAA outer layer during exposure. A longer time of exposure causes cracks to form at lower strains during stretching and creates deeper cracks. Accordingly, Young's modulus of the outer layer increases, as measured by cross-sectional nanoindentation. PPE exhibits cracking after exposure as well. While no similar increase of modulus or crack depth can be observed, the outer layer of PPE exhibits more obvious signs of erosion during exposure, including progressive morphological changes and thickness losses. A finite element model to simulate surface crack formation is devised, based on initially zero-thickness decohesion elements. Decohesion criteria define a critical stress, at which these elements grow, and cracks can begin to form. These criteria are obtained via parameter optimization by comparison between simulation and experiment. The model is used to interpret crack formation in both backsheets.

backsheet↗

DOE OSTI2022

Inactivation of multiple human pathogens by Fathhome's dry sanitizer device: Rapid and eco-friendly ozone-based disinfection

SARS-CoV-2 spread rapidly, causing millions of deaths across the globe. As a result, demand for medical supplies and personal protective equipment (PPE) surged and supplies dwindled. Separate entirely, hospital-acquired infections have become commonplace and challenging to treat. To explore the potential of novel sterilization techniques, this study evaluated the disinfection efficacy of Fathhome's ozone-based, dry-sanitizing device by dose and time response. Inactivation of human pathogens was tested on non-porous (plastic) surfaces. 95.42-100% inactivation was observed across all types of vegetative microorganisms and 27.36% inactivation of bacterial endospores tested, with no residual ozone detectable after completion. These results strongly support the hypothesis that Fathhome's commercial implementation of gas-based disinfection is suitable for rapid decontamination of a wide variety of pathogens on PPE and other industrially relevant materials.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRSDate not supplied

Planning for Validation of Optical Property Degradation Predictions Using On-Orbit Telemetry

NASA’s Gateway Power and Propulsion Element (PPE) will employ high power Xenon Hall thrusters to transit from Earth orbit to a lunar near-rectilinear halo orbit (NRHO). Due to the extended duration of this transit phase and a high thruster duty cycle, there is expected to be significant material erosion caused by the ion plume and subsequent redeposition onto the main spacecraft radiators. While plume modeling and tests of redeposition have attempted to quantify the resulting impact to radiator optical properties, significant uncertainties remain. The flight of PPE presents an opportunity to validate some of the assumptions in this analytical chain, but there will be no specialized hardware that can directly characterize the property changes. However, the planned mission includes periods with significant solar flux to the radiators both early and late in the transit inducing differential heat loads on the vehicle. This presentation will explore options for analyzing possible impacts of various levels of redeposition and whether the severity can be accurately characterized via existing planned telemetry during a nominal mission.

PPE↗

DOE OSTI2023

Region and cloud regime dependence of parametric sensitivity in E3SM atmosphere model

Abstract The Department of Energy (DOE)’s Energy Exascale Earth System Model (E3SM), including its atmosphere model (EAM), has many relatively new features. In a previous study we conducted a systematic parametric sensitivity analysis for EAM based on short, perturbed parameter ensemble (PPE) simulations, mainly focusing on global mean climate features and metrics. While parameter values in global climate models are generally invariant in space and time, model response to parameters perturbation may vary by regions and climate regimes, which motivates the need to better understand the EAM model behaviors and physics at regional scale and process level. In this study, using the same set of PPE simulations and a similar sensitivity analysis framework, we identify parameters that cause largest sensitivities over different regions and compare model responses in fast atmospheric processes to the parameters across different cloud regimes for several important cloud-related fidelity metrics. We find that cloud forcing has opposite response to some parameters over mid-latitude vs. tropical land. We also analyze how the parametric sensitivity varies as stratocumulus transitions to shallow convection and to deep convection over ocean. Low cloud forcing and shortwave cloud forcing in the subtropical eastern Pacific are most sensitive to the parameters controlling the width of the probability density function (PDF) of the subgrid vertical velocity ( w’ ) ( gamma ) and the damping of the w’ skewness ( c8 ) near the coast but become more sensitive to the parameter affecting the damping of the w’ variance ( c1 ) further offshore. Detailed interpretation of the spatial dependence of parametric sensitivity is provided. We also investigate how the parametric sensitivity evolves with prediction duration. This study improves our process-level understanding of cloud physics and parameterization and provides insights for developing more advanced regime-aware parameterization schemes in global climate model.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Investigating the linkage between simulated precipitation climatology and ENSO-related precipitation anomaly based on multi-model and perturbed parameter ensembles

It remains a challenge for climate models to correctly capture the relationship between precipitation and ENSO. This studyexamines the linkage between the simulated precipitation climatology and ENSO-related precipitation anomaly during borealwinter based on the multi-model ensemble from the Atmospheric Model Intercomparison Project Phase 5 (AMIP5) and perturbedparameter ensemble (PPE) with the Beijing Climate Center (BCC) atmospheric model. The AMIP5 models have large biases insimulating the tropical precipitation anomaly during El Niño, such as the shifts of the Inter-Tropical Convergence Zone (ITCZ)and South Pacific Convergence Zone (SPCZ). The inter-model differences show that the precipitation change in response to seasurface temperature (SST) change increases with enhanced precipitation climatology. The ENSO-related precipitation anomalycan also be related to the spatial distribution of the mean-state precipitation. The simulated ITCZ/SPCZ displacements aresignificantly correlated with the spatial precipitation-SST relationship in the mean state. Models with stronger mean-stateprecipitation-SST relationship also produce stronger SPCZ/ITCZ displacements. The mean-state tropical precipitation also hasstrong impacts on the ENSO-related precipitation anomalies over East Asia. In the BCC PPE, the connection between the mean-state precipitation and ENSO-related precipitation anomaly is overall consistent with that in AMIP5. Parameters associated withthe low-cloud and deep convection processes are the most influential ones for the precipitation simulations in BCC. Comparedwith the version in AMIP5, the new BCC model can better simulate the precipitation climatology and the relationship betweenENSO and precipitation over southern China. These results have important implications for model development and model-basedclimate predictions.

Yang, Ben↗