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At least 55 records · Page 3

The Use of Positrons to Survey Alteration Layers on Synthetic Nuclear Waste Glasses

In order to safeguard society and the environment, understanding radioactive waste glass alteration mechanisms in interactions with solutions and near-field materials, such as Fe, is essential to nuclear waste repository performance assessments. Alteration products are formed at the surface of glasses after reaction with solution. In this study, glass altered in the presence of Fe0 in aqueous solution formed two alteration layers: one embedded with Fe closer to the surface and one without Fe found deeper in the sample. Both layers were found to be thinner than the alteration layer found in glass altered in aqueous solution only. For the first time, Doppler Broadening Positron Annihilation Spectroscopy (DB-PAS) is used to non-destructively characterize the pore structures of glass altered in the presence of Fe0. Advantages and disadvantages of DB-PAS compared to other techniques used to analyze pore structures for altered glass samples are discussed. Ultimately, DB-PAS has shown to be an excellent choice for pore structure characterization for glasses with multiple alteration layers. Monte Carlo modeling predicted positron trajectories through the layers, and helped explain DB-PAS data, which showed that the deeper alteration layer without Fe had a similar composition and pore structure to layers on glass altered in water only.

Doppler Broadening Positron Annihilation Spectrosc↗

Integrating quantitative defense-in-depth metrics into new reactor designs

Risk-informed, performance-based (RIPB) methods have progressed to the point where high-level guidance can be used to augment traditional, deterministic, nuclear safety design practices in areas important to nuclear reactor safety. This paper describes an approach for augmenting the traditional defense-in-depth (DID) qualitative approach with quantitative risk information from a plant-specific probabilistic risk assessment (PRA) in a way that is structured, can be applied on a consistent basis, and allows for clear acceptance criteria. Adding performance-based targets that should be achieved is expected to result in safer and more economical plant designs. Evaluations of DID can be conducted throughout the design process as well as in support of design certification and operating license applications to identify where defense protections could be enhanced or relaxed. Consistent with the United States Nuclear Regulatory Commission's policy statement encouraging greater use of PRA to improve safety decision making and regulatory efficiency, this scenario-based DID method can be used to evaluate changes and overall plant design as part of the normal design control process. Although the RIPB method presented in this paper was developed for application to advanced passive light water reactor designs, the metrics could be tailored to other reactor designs. This risk-informed approach to DID helps to ensure that public and worker risk insights are integrated into the design process holistically.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Post-irradiation examination to assess performance and safety of nuclear fuel

This work presents some results from testing campaigns performed at JRC-ITU on irradiated fuels and analogues aimed at characterizing fuel alterations during and after irradiation. The characterization of local structural and property changes is the first step towards the description of the overall behaviour of the fuel, including safety- and performance-relevant properties. High burnup light water reactor (LWR) UO{sub 2} fuel (= 60 GWd/tHM) was used for morphology and mechanical property studies. Radial profiles of porosity obtained from scanning electron microscopy image analysis were compared with corresponding sub-surface data obtained using acoustic microscopy. An increase of porosity was observed at the rim of the pellet in correspondence with the high burnup structure (HBS), and also at intermediate radius locations in correspondence with the occurrence of the so-called dark zone. This zone is characterized by several features similar to the HBS: in addition to increased local porosity, grain subdivision features were observed. The examination of grain free surface morphology along the pellet radius revealed the onset of surface alteration which resulted in almost complete loss of the original grain shape in conjunction with the formation of the dark zone. Additionally, possible ageing effects due to accumulation of microstructural decay damage during storage were investigated and compared to the results obtained under accelerated ageing conditions using alpha-doped analogues. Similar hardening trends were observed by comparing the hardness evolution as a function of accumulated damaged in unirradiated analogues and spent fuel. No significant hardness increase was observed on the same high burnup/high dose spent fuel after >10 years of additional storage in hot cell, confirming that hardening saturates at a damage level near 0.1 dpa. These experimental campaigns contribute establishing a basis of data for further analysis, in combination with suitable modelling tools. The final goal is to achieve the full scientific understanding of mechanisms and processes affecting fuel properties and behaviour, as a necessary step to establish the basis for developing advanced fuel systems with optimized performance and safety. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Light Water Reactor Sustainability Program Interrogation of Alkali-Silica Reaction Degraded Concrete Samples using Acoustic and Thermal Techniques to Support Development of a Structural Health Monitoring Framework

Assessment and management of aging concrete structures in nuclear power plants require a more systematic approach than simple reliance on existing code margins of safety. Health monitoring of concrete structures is performed to understand the current condition of a structure based on heterogeneous measurements and then produce high-confidence actionable information regarding structural integrity. This information can then be used to support operational and maintenance decisions. The proposed diagnosis and prognosis framework consists of four elements: health monitoring, data analytics, uncertainty quantification, and prognosis. The objectives of this ongoing research project focuses on health monitoring and data analytics of concrete slab cast, which is cured using four pockets of reactive aggregates: pure silica, wells, placitas, and spratt. A controlled concrete slab with four aggregates is cast at Vanderbilt University in representative conditions to accelerate degradation due to alkali-silica reaction (ASR). Four nondestructive evaluation (NDE) techniques (thermography, mechanical deformation measurements, nonlinear impact resonance-acoustic spectroscopy, and vibro-acoustic modulation) are used to examine the degraded concrete slab. Heterogeneous data from these techniques are analyzed for assessing ASRrelated degradation in concrete samples. In addition, this report discusses thermography assessment of three cement bricks cured under different conditions to accelerate ASR-related degradation. The application of the digital image correlation technique to study ASR-related degradation on a large concrete sample at the University of Tennessee Knoxville is discussed and initial observations are presented in this report. The results from the data analysis of the NDE techniques on concrete slab cured at Vanderbilt University are discussed in detail in this report. The major outcome of the analysis suggests that the nonlinear impact resonance acoustic spectroscopy is able to detect potential degradation in a concrete slab but is unable to locate or isolate the degradation. Alternatively, the vibro-acoustic technique is able to detect degradation and locate the damage in the concrete slab cast. The outcomes supports development of a structural health monitoring framework.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Activities in Support of Continuing the Service of Nuclear Power Plant Safety-Related Concrete Structures

Nuclear power plant (NPP) concrete structures are described. In-service inspection and testing requirements in the U.S. are summarized. The license renewal process in the U.S. is outlined and its current status provided. Operating experience related to performance of the concrete structures is presented. Basic components of a program to manage aging of the concrete structures are identified and described: (1) Degradation mechanisms, damage models, and material performance; (2) Assessment and remediation: i.e., component selection, in- service inspection, non-destructive examinations, and remedial actions; and (3) Estimation of performance at present or some future point in time: i.e., application of structural reliability theory to the design and optimization of in-service inspection/maintenance strategies, and determination of the effects of degradation on plant risk. Finally, areas are noted where additional research would be of benefit to aging management of nuclear power plant concrete structures.

codes and standards↗

Laser-based characterization of nuclear fuel plates

Ensuring the integrity of fuel-clad and clad-clad bonding in nuclear fuels is important for safe reactor operation and assessment of fuel performance, yet the measurement of bond strengths in actual fuels has proved challenging. The laser shockwave technique (LST) originally developed to characterize structural adhesion in composites is being employed to characterize interface strength in a new type of plate fuel being developed at Idaho National Laboratory (INL). LST is a non-contact method that uses lasers for the generation and detection of large-amplitude acoustic waves and is well suited for application to both fresh and irradiated nuclear-fuel plates. This paper will report on initial characterization results obtained from fresh fuel plates manufactured by different processes, including hot isostatic pressing, friction stir welding, and hot rolling.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Laser-Based Characterization of Nuclear Fuel Plates

Ensuring the integrity of fuel-clad and clad-clad bonding in nuclear fuels is important for safe reactor operation and assessment of fuel performance, yet the measurement of bond strengths in actual fuels has proved challenging. The laser shockwave technique (LST) originally developed to characterize structural adhesion in composites is being employed to characterize interface strength in a new type of plate fuel being developed at Idaho National Laboratory (INL). LST is a non-contact method that uses lasers for the generation and detection of large-amplitude acoustic waves and is well suited for application to both fresh and irradiated nuclear-fuel plates. This paper will report on initial characterization results obtained from fresh fuel plates manufactured by different processes, including hot isostatic pressing, friction stir welding, and hot rolling.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Multi-Modal Characterization of Interfacial Corrosion of Ni-based Alloys in Chloride-based Molten Salts

The United States Department of Energy (DOE) is committed to the advancement of nuclear reactor technology through initiatives such as the Advanced Reactor Development Program (ARDP), to diversify the United States energy portfolio towards more sustainable energy options. The ARDP includes demonstration by industry partners of molten salt fast reactors (MSRs). Construction of molten salt reactor technology requires qualified nuclear structural materials. Unfortunately, there are no current materials that meet current qualification requirements dictated by the Nuclear Regulatory Commission for construction of MSRs. Adapting current structural material qualifications requires expansion of our current knowledgebase on corrosion performance. In this investigation, we assess microstructural changes in a Ni-based superalloy after exposure to a chloride-containing salt system through a correlated multi-modal approach combining several advanced characterization techniques. Namely we will highlight the impact of grain boundary phenomena at the onset of corrosion attack, including the role of intergranular crack propagation and development of internal corrosion products. The findings from this investigation will further expand our assessment of the corrosion performance of structural materials being investigated for construction of MSR components.

36 - MATERIALS SCIENCE↗

Sorption (K d ) Measurements in Support of Dose Assessments for Zion Nuclear Station Decommissioning

The Zion Nuclear Power Station is being decommissioned. ZionSolutions proposes to leave much of the below grade structures in place and to fill them with “clean” concrete demolition debris from the above grade parts of the facility. This study, commissioned by ZionSolutions and conducted by the Brookhaven National Laboratory (BNL) was performed to provide site-specific data for performance assessment calculations to support the request to terminate the NRC license and allow unrestricted use of the facility. Specifically, this study measured the distribution coefficient for five radionuclides of concern using site-specific soils and groundwater. The distributions coefficient is a measure of the amount of the radionuclide that will remain sorbed to the soil or concrete that is present relative to the amount that will remain in solution. A high distribution coefficient indicates most of the radionuclide will remain on the solid material and will not be available for transport by the groundwater. The radionuclides of concern are Fe-55, Co-60, Ni-63, Sr-90, and Cs-137. Tests were performed following ASTM C1733-10, Standard Test Methods for Distribution Coefficients of Inorganic Species by the Batch Method. Sr-85 was used in the testing as an analogue for Sr-90 because it behaves similarly with respect to sorption and has a gamma emission that is easier to detect than the beta emission from Sr-90. Site-specific soils included disturbed sand (sand removed during construction and used as backfill), native sand, silt/clay and silt. In addition, concrete cores from the Unit-1 Containment Building and the Crib House were broken into particles less than 2 mm in size and tested to obtain distribution coefficients for the five nuclides.

54 ENVIRONMENTAL SCIENCES↗

Approach to proliferation risk assessment based on multiple objective analysis framework

The approach to the assessment of proliferation risk using the methods of multi-criteria decision making and multi-objective optimization is presented. The approach allows the taking into account of the specifics features of the national nuclear infrastructure, and possible proliferation strategies (motivations, intentions, and capabilities). 3 examples of applying the approach are shown. First, the approach has been used to evaluate the attractiveness of HEU (high enriched uranium)production scenarios at a clandestine enrichment facility using centrifuge enrichment technology. Secondly, the approach has been applied to assess the attractiveness of scenarios for undeclared production of plutonium or HEU by theft of materials circulating in nuclear fuel cycle facilities and thermal reactors. Thirdly, the approach has been used to perform a comparative analysis of the structures of developing nuclear power systems based on different types of nuclear fuel cycles, the analysis being based on indicators of proliferation risk.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Documentation, assessment, and improvements of fission gas modeling capabilities in BISON

Fission gas behavior critically affects nuclear fuel performance, influencing thermal conductivity, microstructure, swelling, and fuel-cladding interactions. The Simple Integrated Fission Gas Release and Swelling (Sifgrs) model, implemented within the BISON fuel performance code, provides advanced capabilities for modeling these phenomena. This manuscript reviews and assesses Sifgrs’ modular structure and submodels describing intragranular, intergranular, and release mechanisms. The modular implementation enables rapid improvements as our understanding advances and new fuel forms emerge. After an overview of capabilities, we present a comprehensive validation suite, comparing predictions to experimental data from tests under normal and transient conditions, including reproduction of the Vitanza curve. Results demonstrate Sifgrs’ accuracy, robustness, and applicability. Current limitations and ongoing efforts are discussed, including mechanistic, multiscale modeling, uncertainty quantification, and validation within the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program, supporting the safe and efficient use of nuclear fuels.

BISON↗

Resolution of Qualification Issues for Existing Structural Materials

This report gives a detailed assessment of several key technical issues that needs resolution for the existing structural materials with emphasis on application in liquid metal reactors (LMRs), in particular, sodium cooled fast reactors. The work is a combined effort between Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL) with ANL as the technical lead, as part of Advanced Structural Materials Program for the Advanced Fuel Cycle Initiative (AFCI) Reactor Campaign. The report is the second deliverable in FY09 (M2505050201) under the work package “Advanced Materials Code Qualification”. The overall objective of the Advanced Materials Code Qualification project is to evaluate the key technical requirements for the qualification of currently available and future advanced materials for application in sodium reactor systems and the resolution of issues that the U.S. Nuclear Regulatory Commission (NRC) has raised in the past on structural materials in support of the design and licensing of the LMR. Advanced materials are a critical element in the development of sodium reactor technologies. Enhanced materials performance not only improves safety margins and provides design flexibility, but also is essential for the economics of future advanced sodium reactors. Qualification and licensing of advanced materials are prominent needs for developing and implementing advanced sodium reactor technologies. However, the development of sufficient database and qualification of these materials for application in LMRs require considerable amount of time and resources. In the meantime, the currently available materials will be used in the early development of fast reactors. Nuclear structural component designs in the U.S. comply with the ASME Boiler and Pressure Vessel Code Section III (Rules for Construction of Nuclear Facility Components) and the NRC grants licensing. As the LMR will operate at higher temperatures than the current light water reactors (LWRs), the design of elevated-temperature components must comply with ASME Section III Subsection NH (Class 1 Components in Elevated Temperature Service). Assessment of materials performance issues and high temperature design methodology issues pertinent to the LMR were presented in an earlier report (Natesan et al. 2008). In a subsequent report (Majumdar et al. 2009), we addressed the needs in high temperature methodologies for design of various high temperature components in sodium cooled fast reactor. The present report addresses several key technical issues for the currently available structural materials such as Type 304 and 316 austenitic stainless steels and ferritic steels such as 2.25Cr-1Mo and modified 9Cr-1Mo. The 60-year design life for the LMR presents a significant challenge to the development of database, extrapolation/prediction of long-term performance, and high temperature structural design methodology. The current Subsection NH is applicable to the design life only up to 34 years. No experimental data contain test durations of 525,000 hours, and it is impractical to conduct such long-term tests in any types of testing. So far the longest creep tests for Grade 91 and Grade 92 steels have run up to 100,000 hours. It has been noted that there is a large drop in creep rupture strength in long-term tests for these high-Cr creep-resistant steels, which may result in overestimation of the long-term creep strength and allowable stress. The report addresses in detail the need for a mechanistic understanding of the structural materials, from the standpoint of the effects of thermal aging, creep deformation, creep fracture, fatigue and creep-fatigue, creep-fatigue predictive models, fatigue and creep crack growth, and fracture toughness. Based on an in-depth assessment of the available data and mechanistic understanding, key technical issues are identified and discussed for each of the property areas. Furthermore, we have proposed viable approaches to resolve the issues and prioritized our recommendations.

Natesan, K.↗

Enhancement of Structural Health Monitoring Framework by Optimizing Vibro-Acoustic Modulation Technique to Localize Alkali-Silica Reaction Degradation in Medium-Sized Concrete Samples

Assessment and management of aging concrete structures in nuclear power plants require a more systematic approach than simple reliance on existing code margins of safety. Health monitoring of concrete structures is performed to understand the current condition of a structure based on heterogeneous measurements and then produce high confidence actionable information regarding structural integrity. This information can then be used to support operational and maintenance decisions. The objectives of this ongoing research project focus on health monitoring and data analytics of concrete slabs containing reactive aggregates and thus subjected to degradation due to alkali-silica reaction (ASR). A controlled concrete slab with four pockets of reactive aggregates (pure silica, wells, placitas, and spratt) was cast at Vanderbilt University and cured in representative conditions to accelerate degradation due to ASR. A set of four concrete samples were also cast and cured at the University of Alabama for ASR testing. Of these four samples, two slabs contained reactive aggregates while the other two had the non-reactive aggregate counterparts mixed throughout the samples. Vibro-acoustic methods were used on these slabs to locate large pockets of ASR within the reactive samples and determine the effects of rebar using the non-reactive slabs. Vibro-acoustic modulation (VAM) is a vibration-based NDE method that utilizes signatures of nonlinear dynamic interactions on contact surfaces of crack or delamination damage to detect and localize the damage. VAM analysis was conducted on both Vanderbilt and Alabama’s samples using multiple variables for damage detection and localization. The results from the data analysis of the NDE vibro-acoustic techniques on concrete slabs cured at Vanderbilt University and the University of Alabama are discussed in detail in this report. The major outcome of the analysis suggests that the VAM method can be used to detect damage within the concrete samples by comparing the results found in different sections of the samples. Results for damage localization are dependent on multiple variables used in the vibro-acoustic modulation experiments. Digital image correlation (DIC) is a three-dimensional, full-field, optical NDE technique to measure contour, deformation, vibration, and strain. The application of the digital image correlation technique to study ASR-related degradation on a large concrete sample at the University of Tennessee Knoxville is discussed and observations are presented in this report.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Concrete Structural Health Monitoring in Nuclear Power Plants

Assessment and management of aging concrete structures in nuclear power plants require a more systematic approach than simple reliance on existing code margins of safety. Health monitoring of concrete structures is performed in order to understand the current condition of a structure based on heterogeneous measurements and then produce high confidence actionable information regarding structural integrity; this information can then be used to support operational and maintenance decisions. The paper describes a framework of research activities for the health monitoring of nuclear power plant concrete structures. The proposed framework consists of four elements: health monitoring, data analytics, uncertainty quantification, and prognosis. The goal of this framework is to enable plant operators to make risk-informed decisions on structural integrity, remaining useful life, and performance of concrete structures across the nuclear fleet. Among several concrete degradations, the research focuses on the degradation caused by the Alkali-Silica Reaction (ASR). ASR is a chemical reaction that in presence of sufficient moisture forms a gel that increases in volume and exerts an expansive pressure inside the material causing micro- to macro-cracks. The paper also presents development of controlled concrete samples with reactive aggregates to cause ASR degradation and application of different non-destructive evaluation techniques to detect the damage caused by ASR. Initial results are presented in the paper along with potential path forward.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Concrete structural health monitoring in nuclear power plants - 212

Assessment and management of aging concrete structures in nuclear power plants require a more systematic approach than simple reliance on existing code margins of safety. Health monitoring of concrete structures is performed in order to understand the current condition of a structure based on heterogeneous measurements and produce high-confidence actionable information regarding structural integrity. This information can be used to support operational and maintenance decisions. This paper describes a framework of research activities for health monitoring of nuclear power plant concrete structures. The proposed framework consists of four elements: (1) health monitoring, (2) data analytics, (3) uncertainty quantification, and (4) prognosis. The goal of this framework is to enable plant operators to make risk-informed decisions about structural integrity, remaining useful life, and performance of concrete structures across the nuclear fleet. Among several concrete degradations, research focuses on degradation caused by the alkali-silica reaction (ASR). ASR is a chemical reaction that, in the presence of sufficient moisture, forms a gel that increases in volume and exerts an expansive pressure inside the material, thus causing micro to macro-cracks. This paper also presents development of controlled concrete samples with reactive aggregates to cause ASR degradation and application of different non-destructive evaluation techniques to detect the damage caused by ASR. Initial results are presented in the paper along with a potential path forward. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Applying QMU to Nuclear Weapon Stewardship

Quantification of Margins and Uncertainty (QMU) is a principle means and metric by which nuclear weapons performance is measured. At Lawrence Livermore National Laboratory (LLNL), Nuclear weapon QMU is predominately a Physics assessment of the performance margin and associated uncertainties of not achieving the designed nuclear performance. To more completely apply QMU to Nuclear Weapon Stewardship, a Systems Engineering or systematic approach is being employed to identify and define requirements, allowing assessment of performance with QMU. This paper describes the basics of QMU and how it is applied below the highest level nuclear performance function down and throughout the nuclear weapon design architecture. The intended audience for this paper is a novice QMU practitioner at LLNL. The application of QMU to the entire set of nuclear weapon functions demands a broad engagement of Science and Engineering disciplines. Using a hierarchical flow-down requirements structure, performance functions and failure modes are identified for all levels of system requirements. There can be multiple failure modes per functional requirement. For each function there is a spectrum of possible outputs that can vary from outright failure to excellent performance. The possible consequences and impacts on the next higher level functions will also vary. Since performance variations exist in a weapon functional hierarchy, the assessment process needs and benefits from a system perspective. Incorporating QMU into assessments using a Systems Engineering approach to stockpile management provides a means to quantify weapon performance risks against a multitude of possible failure modes and from the highest level functions down to the lowest level component functionality. Performance risk management is a core practice of nuclear weapon management. Assessing the likelihood and consequences of the many possible failure modes is done yearly as part of Annual Assessment Reviews (AAR). When annual surveillance discovers an anomaly defect as part of weapon surveillance, investigations are launched and QMU is a key tool for quantifying performance impacts. QMU assessments are separated into two pieces, failure mode assessments and QMU analysis.

42 ENGINEERING↗

The RISMC Approach to Perform Advanced PRA Analyses

The existing fleet of nuclear power plants is in the process of extending its lifetime and increasing the power generated from these plants via power uprates. In order to evaluate the impact of these two factors on the safety of the plant, the RISMC Pathway aims to develop simulation-based tools and methods to assess risks for existing nuclear power plants in order to optimize safety. This pathway, by developing new methods, is extending the state-of-the-practice methods that have been traditionally based on logic structures such as Event-Trees and Fault-Trees. These static types of models mimic system response in an inductive and deductive way respectively, yet are restrictive in the ways they can represent spatial and temporal constructs. RISMC analyses are performed by using a combination of thermal-hydraulic codes and a stochastic analysis tool currently under development at the Idaho National Laboratory, i.e. RAVEN. This paper presents a case study in order to show the capabilities of the RISMC methodology to assess impact of power uprate of a boiling water reactor system during a station blackout accident scenario. We employ the system simulator code, RELAP5-3D, coupled with RAVEN which perform the stochastic analysis. Our analysis is in fact performed by: 1) sampling values of a set of parameters from the uncertainty space of interest, 2) simulating the system behavior for that specific set of parameter values and 3) analyzing the set of simulation runs. Results obtained give a detailed investigation of the issues associated with a plant power uprate including the effects of station blackout accident scenarios. We are able to quantify how the timing of specific events was impacted by a higher nominal reactor core power. Such safety insights can provide useful information to the decision makers to perform risk informed margins management.

97 MATHEMATICS AND COMPUTING↗